CN106103806B - 处理含锂材料的方法 - Google Patents

处理含锂材料的方法 Download PDF

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Publication number
CN106103806B
CN106103806B CN201580015620.5A CN201580015620A CN106103806B CN 106103806 B CN106103806 B CN 106103806B CN 201580015620 A CN201580015620 A CN 201580015620A CN 106103806 B CN106103806 B CN 106103806B
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lithium
sulfate
composition
aquo
electrolytic process
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CN106103806A (zh
Inventor
让·弗朗索瓦·马尼昂
盖伊·布拉沙
尼古拉斯·拉罗什
盖瑞·皮尔斯
史蒂芬·查尔斯·麦基
麦考拉斯·格莱德考瓦斯
皮特·西蒙斯
J·大卫·詹德斯
吉纳维芙·克雷顿
皮埃尔·布沙尔
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Nemaska Lithium Inc
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Nemaska Lithium Inc
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/14—Alkali metal compounds
    • C25B1/16—Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/025—Reverse osmosis; Hyperfiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/422—Electrodialysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44—Ion-selective electrodialysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/58—Multistep processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D1/00—Oxides or hydroxides of sodium, potassium or alkali metals in general
    • C01D1/04—Hydroxides
    • C01D1/20—Preparation by reacting oxides or hydroxides with alkali metal salts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/02—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/06—Sulfates; Sulfites
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00—Preliminary treatment of ores or scrap
    • C22B1/02—Roasting processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00—Preliminary treatment of ores or scrap
    • C22B1/02—Roasting processes
    • C22B1/06—Sulfating roasting
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • C22B26/12—Obtaining lithium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/26—Further operations combined with membrane separation processes
    • B01D2311/2684—Electrochemical processes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Water Supply & Treatment (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Urology & Nephrology (AREA)
  • Electrochemistry (AREA)
  • Nanotechnology (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Processing Of Solid Wastes (AREA)
  • Treatment Of Sludge (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Electrolytic Production Of Metals (AREA)
CN201580015620.5A 2014-02-24 2015-02-24 处理含锂材料的方法 Active CN106103806B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910480277.1A CN110331417A (zh) 2014-02-24 2015-02-24 处理含锂材料的方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201461943700P 2014-02-24 2014-02-24
US61/943,700 2014-02-24
PCT/CA2015/000115 WO2015123762A1 (en) 2014-02-24 2015-02-24 Methods for treating lithium-containing materials

Related Child Applications (1)

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CN106103806A CN106103806A (zh) 2016-11-09
CN106103806B true CN106103806B (zh) 2019-07-12

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US (5) US10544512B2 (https=)
EP (3) EP3492632B1 (https=)
JP (3) JP6449317B2 (https=)
KR (3) KR102153976B1 (https=)
CN (2) CN106103806B (https=)
AU (4) AU2015221373C1 (https=)
CA (8) CA3047774C (https=)
CL (2) CL2016002121A1 (https=)
DK (2) DK3492632T3 (https=)
ES (2) ES2863453T3 (https=)
HR (2) HRP20191302T1 (https=)
PL (2) PL3110988T3 (https=)
PT (2) PT3492632T (https=)
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WO (1) WO2015123762A1 (https=)

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2841623B1 (en) 2012-04-23 2020-10-28 Nemaska Lithium Inc. Processes for preparing lithium hydroxide
US9382126B2 (en) 2012-05-30 2016-07-05 Nemaska Lithium Inc. Processes for preparing lithium carbonate
EP4424408A3 (en) 2013-03-15 2025-04-09 Nemaska Lithium Inc. Processes for preparing lithium hydroxide
JP6335316B2 (ja) 2013-10-23 2018-05-30 ネマスカ リチウム インコーポレイテッド 炭酸リチウムの調製のためのプロセス
AU2014339706B2 (en) 2013-10-23 2017-05-18 Nemaska Lithium Inc. Processes and systems for preparing lithium hydroxide
CA3047774C (en) * 2014-02-24 2020-08-18 Nemaska Lithium Inc. Methods for treating lithium-containing materials
CA2996651C (en) 2015-08-27 2021-06-01 Nemaska Lithium Inc. Method for preparing lithium hydroxide and lithium sulfate monohydrate using hydrogen depolarized anode
CN106906359B (zh) 2015-12-22 2018-12-11 理查德.亨威克 从硅酸盐矿物收取锂
GB201602259D0 (en) * 2016-02-08 2016-03-23 Bateman Advanced Technologies Ltd Integrated Lithium production process
PT109396A (pt) 2016-05-18 2017-11-20 Inst Superior Tecnico Processo de extração de lítio de minérios e concentrados por ativação mecânica e reação com ácido sulfúrico
CA2940509A1 (en) * 2016-08-26 2018-02-26 Nemaska Lithium Inc. Processes for treating aqueous compositions comprising lithium sulfate and sulfuric acid
KR20190072667A (ko) 2016-11-14 2019-06-25 리락 솔루션즈, 인크. 코팅된 이온 교환 입자를 이용한 리튬 추출
CN107034355B (zh) * 2017-05-05 2018-03-27 江西南氏锂电新材料有限公司 一种从锂云母矿中提取铷和铯的方法
RU2663021C1 (ru) * 2017-07-17 2018-08-01 Акционерное общество "Ведущий научно-исследовательский институт химической технологии" Способ извлечения лития из сподумена
US10450633B2 (en) * 2017-07-21 2019-10-22 Larry Lien Recovery of lithium from an acid solution
EP3661620A4 (en) 2017-08-02 2021-05-12 Lilac Solutions, Inc. Ion exchange system for lithium extraction
US11253848B2 (en) 2017-08-02 2022-02-22 Lilac Solutions, Inc. Lithium extraction with porous ion exchange beads
WO2019094674A1 (en) * 2017-11-09 2019-05-16 U.S. Borax, Inc. Mineral recovery process
CN113772750B (zh) 2017-11-22 2024-05-10 内玛斯卡锂业有限公司 制备各种金属的氢氧化物和氧化物以及其衍生物的方法
CN112352059A (zh) * 2018-02-17 2021-02-09 锂莱克解决方案公司 用于锂提取和转化的集成系统
US10648090B2 (en) 2018-02-17 2020-05-12 Lilac Solutions, Inc. Integrated system for lithium extraction and conversion
AR114412A1 (es) 2018-02-28 2020-09-02 Lilac Solutions Inc Reactor de intercambio iónico con trampas de partículas para la extracción de litio
CN110451534A (zh) * 2018-08-06 2019-11-15 南方科技大学 一种锂盐的提纯装置、提纯系统和提纯方法
KR102177039B1 (ko) * 2018-09-11 2020-11-10 주식회사 포스코 리튬 화합물 제조방법
CA3201685C (en) 2018-11-29 2025-12-02 ICSIP Pty Ltd PRODUCTION OF LITHIUM CHEMICALS AND LITHIUM METALLIC
KR102164661B1 (ko) * 2018-12-06 2020-10-12 주식회사 에코프로이노베이션 리튬 정광으로부터 황산나트튬 혼합 배소에 의한 수산화리튬 제조방법
CN113316664B (zh) 2018-12-18 2023-12-08 浦项股份有限公司 合金涂覆钢板及其制造方法
CN109371227A (zh) * 2018-12-19 2019-02-22 王永成 锂辉石磁性物的硫酸法提锂工艺
CN109680295B (zh) * 2019-02-22 2019-11-22 北京廷润膜技术开发股份有限公司 一种工业级碳酸锂固体制备氢氧化锂的方法
KR102278372B1 (ko) * 2019-04-29 2021-07-19 고등기술연구원연구조합 리튬 함유 물질로부터 리튬 회수방법
WO2020232556A1 (en) 2019-05-22 2020-11-26 Nemaska Lithium Inc. Processes for preparing hydroxides and oxides of various metals and derivatives thereof
CN110643831B (zh) * 2019-09-29 2021-09-17 天津科技大学 一种无隔膜电化学提锂系统及其提锂方法
EP4087825A4 (en) 2020-01-09 2024-01-24 Lilac Solutions, Inc. Process for separating undesirable metals
JP2023529444A (ja) 2020-06-09 2023-07-10 ライラック ソリューションズ，インク． スケール物質存在下におけるリチウム抽出
WO2022109009A1 (en) * 2020-11-20 2022-05-27 Applied Materials, Inc. Cleaning materials and processes for lithium processing equipment
WO2022109156A1 (en) * 2020-11-20 2022-05-27 Lilac Solutions, Inc. Lithium production with volatile acid
EP4247759A1 (en) 2020-11-20 2023-09-27 Lilac Solutions, Inc. Lithium production with volatile acid
CN112645361A (zh) * 2020-12-23 2021-04-13 广西天源新能源材料有限公司 一种用锂辉石和锂聚合物生产单水氢氧化锂的工艺
WO2022226219A1 (en) 2021-04-23 2022-10-27 Lilac Solutions, Inc. Ion exchange devices for lithium extraction
CN117616159A (zh) * 2021-07-09 2024-02-27 巴斯夫欧洲公司 在低pH范围内Li2SO4的电解
EP4384644A4 (en) * 2021-08-11 2026-03-11 Tenova Advanced Tech Ltd PROCESS FOR THE PRODUCTION OF LITHIUM SALTS
CN119528181A (zh) 2022-01-17 2025-02-28 Icsip私人有限公司 用于锂生产的方法和系统
WO2023192192A1 (en) 2022-03-28 2023-10-05 Lilac Solutions, Inc. Lithium extraction enhanced by an alternate phase
WO2023192623A2 (en) 2022-04-01 2023-10-05 Lilac Solutions, Inc. Extraction of lithium with chemical additives
CA3249725A1 (en) * 2022-05-02 2025-02-03 Sociedad Quimica Y Minera De Chile S.A. GENERAL PROCESS FOR OBTAINING A LITHIUM SULFATE MONOHYDRATE ORE WITH LOW CONTENTS OF IMPURITIES ASSOCIATED WITH CHLORINE AND MAGNESIUM
CA3249741A1 (en) * 2022-05-02 2025-06-17 Sociedad Quimica Y Minera De Chile S.A. GLOBAL PROCESS FOR OBTAINING LITHIUM SULFATE MONOHYDRATE ORE WITH LOW CONTENTS OF IMPURITIES ASSOCIATED WITH CHLORINE AND MAGNESIUM
KR102641852B1 (ko) * 2023-01-30 2024-02-27 주식회사 영풍 폐리튬전지로부터 리튬을 회수하는 방법
WO2024259211A2 (en) * 2023-06-16 2024-12-19 Energy Exploration Technologies, Inc. Compositions, systems and methods for recovering a metal from an aqueous solution
KR102780890B1 (ko) * 2023-08-23 2025-03-14 한국지질자원연구원 리튬 함유 광물로부터 리튬을 추출하는 방법 및 이에 의해 추출된 리튬 화합물
KR20250094469A (ko) * 2023-12-18 2025-06-25 포스코홀딩스 주식회사 리튬을 함유한 원료에서 수산화리튬을 제조하는 방법

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103097587A (zh) * 2010-06-30 2013-05-08 史蒂文·C·阿门多拉 锂金属的电解产物
WO2013159194A1 (en) * 2012-04-23 2013-10-31 Nemaska Lithium Inc. Processes for preparing lithium hydroxide

Family Cites Families (125)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA659894A (en) 1963-03-19 N. Glew David Aqueous solution treatment
CA504477A (en) 1954-07-20 B. Ellestad Reuben Method of extracting lithium values from spodumene ores
GB530028A (en) 1938-06-22 1940-12-03 Bolidens Gruv Ab Method of recovering lithium from minerals
US2331838A (en) 1938-06-22 1943-10-12 Bolidens Gruv Ab Method of recovering lithium from minerals
US2516109A (en) * 1948-09-16 1950-07-25 Metalloy Corp Method of extracting lithium values from spodumene ores
US2793941A (en) * 1949-03-21 1957-05-28 Nelson N Estes Apparatus for growing crystals
US2882243A (en) 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US2872393A (en) 1954-12-03 1959-02-03 Olin Mathieson Production of lithium hydroxide
GB841989A (en) 1955-06-03 1960-07-20 Ronald Herbert Henry Morley Improvements in and relating to methods of extracting lithium from petalite, products of those methods and applications of those products
GB845511A (en) 1956-01-03 1960-08-24 Permutit Co Ltd Improvements relating to the production of metal hydroxides
US3007771A (en) 1956-11-30 1961-11-07 American Potash & Chem Corp Manufacture of lithium carbonate
US3214362A (en) 1961-01-09 1965-10-26 Ionics Electrolysis of aqueous electrolyte solutions and apparatus therefor
US3597340A (en) 1968-11-05 1971-08-03 Lithium Corp Recovery of lithium as lioh.h20 from aqueous chloride brines containing lithium chloride and sodium chloride
SU310538A1 (https=) 1969-08-04 1974-08-05 Институт неорганической химии , электрохимии Грузинской ССР
US3857920A (en) 1971-07-29 1974-12-31 Department Of Health Education Recovery of lithium carbonate
US3899403A (en) 1973-11-01 1975-08-12 Hooker Chemicals Plastics Corp Electrolytic method of making concentrated hydroxide solutions by sequential use of 3-compartment and 2-compartment electrolytic cells having separating compartment walls of particular cation-active permselective membranes
US3959095A (en) 1975-01-31 1976-05-25 Hooker Chemicals & Plastics Corporation Method of operating a three compartment electrolytic cell for the production of alkali metal hydroxides
JPS51113108A (en) 1975-03-28 1976-10-06 Sawafuji Electric Co Ltd Automatic voltage control system in brushless generator
US4036713A (en) 1976-03-04 1977-07-19 Foote Mineral Company Process for the production of high purity lithium hydroxide
JPS5948870B2 (ja) * 1977-09-13 1984-11-29 旭硝子株式会社 水酸化リチウムの製造方法
US4207297A (en) 1978-03-27 1980-06-10 Foote Mineral Company Process for producing high purity lithium carbonate
US4287163A (en) 1979-05-29 1981-09-01 Saline Processors, Inc. Process for recovering lithium from brine by salting out lithium sulfate monohydrate
US4273628A (en) 1979-05-29 1981-06-16 Diamond Shamrock Corp. Production of chromic acid using two-compartment and three-compartment cells
JPS5795826A (en) * 1980-12-04 1982-06-14 Rasa Kogyo Kk Manufacture of high purity lithium salt of mineral acid
US4391680A (en) 1981-12-03 1983-07-05 Allied Corporation Preparing alkali metal hydroxide by water splitting and hydrolysis
US4561945A (en) 1984-07-30 1985-12-31 United Technologies Corporation Electrolysis of alkali metal salts with hydrogen depolarized anodes
US4723962A (en) * 1985-02-04 1988-02-09 Lithium Corporation Of America Process for recovering lithium from salt brines
US4999095A (en) 1985-05-03 1991-03-12 Allied-Signal Inc. Recovery of mixed acids from mixed salts
US4707234A (en) 1985-10-25 1987-11-17 Toyo Soda Manufacturing Co., Ltd. Method for separating an acid and an alkali from an aqueous solution of a salt
CA1272982A (en) 1985-11-14 1990-08-21 Donald Lorne Ball Method for the recovery of lithium from solutions by electrodialysis
US4806215A (en) 1988-07-27 1989-02-21 Tenneco Canada Inc. Combined process for production of chlorine dioxide and sodium hydroxide
US4961909A (en) 1989-11-09 1990-10-09 Comino Ltd. Process for the manufacture of copper arsenate
DE4009410A1 (de) 1990-03-23 1991-09-26 Basf Ag Verfahren zur elektrochemischen spaltung von alkali sulfaten
US5198080A (en) 1990-06-08 1993-03-30 Tenneco Canada Inc. Electrochemical processing of aqueous solutions
US5129936A (en) 1990-07-30 1992-07-14 Wilson Harold W Processes for the preparation of acid fortified paramagnetic iron sulfate salt compounds for use in the treatment of agricultural soils
JP2535748B2 (ja) 1991-03-04 1996-09-18 工業技術院長 リチウム回収方法
US5098532A (en) 1991-05-24 1992-03-24 Ormiston Mining And Smelting Co. Ltd. Process for producing sodium hydroxide and ammonium sulfate from sodium sulfate
SE500107C2 (sv) 1991-06-26 1994-04-18 Eka Nobel Ab Förfarande för framställning av klordioxid
IT1248564B (it) 1991-06-27 1995-01-19 Permelec Spa Nora Processo di decomposizione elettrochimica di sali neutri senza co-produzione di alogeni o di acido e cella di elettrolisi adatta per la sua realizzazione.
GB9119613D0 (en) * 1991-09-13 1991-10-23 Ici Plc Electrochemical process
US5246551A (en) 1992-02-11 1993-09-21 Chemetics International Company Ltd. Electrochemical methods for production of alkali metal hydroxides without the co-production of chlorine
SE511003C2 (sv) 1992-03-16 1999-07-19 Eka Chemicals Ab Förfarande och apparat för framställning av svavelsyra och alkalimetallhydroxid
FI94063C (fi) 1993-08-17 1995-07-10 Kemira Oy Menetelmä alkalimetalli- tai ammoniumperoksodisulfaattisuolojen ja alkalimetallihydroksidin samanaikaiseksi valmistamiseksi
US5830422A (en) 1995-06-23 1998-11-03 Ormiston Mining And Smelting Co. Ltd. Method for production of sodium bicarbonate, sodium carbonate and ammonium sulfate from sodium sulfate
US6514640B1 (en) 1996-04-23 2003-02-04 Board Of Regents, The University Of Texas System Cathode materials for secondary (rechargeable) lithium batteries
US5788943A (en) 1996-09-05 1998-08-04 The Hall Chemical Company Battery-grade nickel hydroxide and method for its preparation
JP2001508925A (ja) 1997-06-23 2001-07-03 パシフィック・リシアム・リミテッド リチウムの回収および精製
CA2293601A1 (en) 1997-06-30 1999-01-07 The Electrosynthesis Company, Inc. Electrochemical methods for recovery of ascorbic acid
US6120576A (en) 1997-09-11 2000-09-19 Mitsui Mining And Smelting Co., Ltd. Method for preparing nickel fine powder
US6048507A (en) * 1997-12-09 2000-04-11 Limtech Process for the purification of lithium carbonate
DE19809420A1 (de) 1998-03-05 1999-09-09 Basf Ag Verfahren zur Herstellung von hochreinen Lithiumsalzen
US6306787B1 (en) 1998-06-10 2001-10-23 Sakai Chemical Industry Co., Ltd. Nickel hydroxide particles and production and use thereof
US6331236B1 (en) 1998-07-21 2001-12-18 Archer Daniels Midland Company Electrodialysis of salts for producing acids and bases
US6547836B1 (en) * 1998-11-10 2003-04-15 Sqm Salar S.A. Process for obtaining monohydrated lithium sulfate from natural brines
US6627061B2 (en) 1999-05-05 2003-09-30 Archer-Daniels-Midland Company Apparatus and process for electrodialysis of salts
US7390466B2 (en) 1999-07-14 2008-06-24 Chemetall Foote Corporation Production of lithium compounds directly from lithium containing brines
DE19940069A1 (de) 1999-08-24 2001-03-08 Basf Ag Verfahren zur elektrochemischen Herstellung eines Alkalimetalls aus wäßriger Lösung
US6747065B1 (en) 2000-09-01 2004-06-08 Chemical Products Corporation System and method for producing high purity colloidal silica and potassium hydroxide
CA2319285A1 (en) * 2000-09-13 2002-03-13 Hydro-Quebec A method for neutralizing and recycling spent lithium metal polymer rechargeable batteries
US6375824B1 (en) 2001-01-16 2002-04-23 Airborne Industrial Minerals Inc. Process for producing potassium hydroxide and potassium sulfate from sodium sulfate
RU2196735C1 (ru) 2001-07-20 2003-01-20 Закрытое акционерное общество "Экостар-Наутех" Способ получения моногидрата гидроксида лития высокой степени чистоты из материалов, содержащих карбонат лития
TW511306B (en) 2001-08-20 2002-11-21 Ind Tech Res Inst Clean process of recovering metals from waste lithium ion batteries
NZ520452A (en) 2002-10-31 2005-03-24 Lg Chemical Ltd Anion containing mixed hydroxide and lithium transition metal oxide with gradient of metal composition
CA2533628C (en) 2003-07-24 2013-12-10 Otv Sa System and method for treatment of acidic wastewater
EA013353B1 (ru) 2005-10-03 2010-04-30 Ототек Оюй Способ переработки никельсодержащего сырьевого материала в выщелачивающем растворе на основе хлорида
JP4211865B2 (ja) 2006-12-06 2009-01-21 戸田工業株式会社 非水電解質二次電池用Ｌｉ−Ｎｉ複合酸化物粒子粉末及びその製造方法、並びに非水電解質二次電池
CN102016123A (zh) * 2008-04-22 2011-04-13 凯米涛弗特公司 制备高纯度氢氧化锂和盐酸的方法
JP2009270189A (ja) * 2008-05-07 2009-11-19 Kee:Kk 高純度水酸化リチウムの製法
JP5087790B2 (ja) 2008-06-17 2012-12-05 住友金属鉱山株式会社 アルミニウム含有水酸化ニッケル粒子の製造方法
JP5251401B2 (ja) 2008-09-29 2013-07-31 住友金属鉱山株式会社 非水系電解質二次電池用正極活物質及びその製造方法、並びに非水系電解質二次電池
CA2731677C (en) * 2008-11-17 2014-01-21 Chemetall Foote Corporation Recovery of lithium from aqueous solutions
AU2012261548B2 (en) 2008-11-17 2013-02-21 Rockwood Lithium Inc. Recovery of lithium from aqueous solutions
DE102009010264B4 (de) 2009-02-24 2015-04-23 Süd-Chemie Ip Gmbh & Co. Kg Verfahren zur Aufreinigung lithiumhaltiger Abwässer bei der kontinuierlichen Herstellung von Lithiumübergangsmetallphosphaten
FI121785B (fi) 2009-03-11 2011-04-15 Outotec Oyj Menetelmä litiumbikarbonaatin puhdistamiseksi
JP2011031232A (ja) * 2009-08-04 2011-02-17 Kee:Kk 水酸化リチウムの製造方法
AU2010341402B2 (en) 2010-01-07 2014-01-30 Tianqi Lithium Corporation Process for the production of lithium carbonate
US8936770B2 (en) 2010-01-22 2015-01-20 Molycorp Minerals, Llc Hydrometallurgical process and method for recovering metals
RS59835B1 (sr) 2010-02-17 2020-02-28 All American Lithium LLC Postupak za dobijanje veoma čistog litijum karbonata i drugih jedinjenja koja sadrže veoma čist litijum
FI122188B (fi) 2010-03-18 2011-09-30 Outotec Oyj Hydrometallurginen menetelmä metallisen nikkelin valmistamiseksi
WO2011133165A1 (en) 2010-04-23 2011-10-27 Simbol Mining Corp. A process for making lithium carbonate from lithium chloride
FI122831B (fi) 2010-05-25 2012-07-31 Outotec Oyj Menetelmä spodumeenin käsittelemiseksi
WO2011156861A1 (en) 2010-06-15 2011-12-22 The University Of Queensland Method of recovering a metal
US8431005B1 (en) * 2010-06-24 2013-04-30 Western Lithium Corporation Production of lithium and potassium compounds
EP2603620A4 (en) 2010-08-12 2016-10-12 Res Inst Ind Science & Tech PROCESS FOR EXTRACTION OF LITHIUM OF HIGH PURITY FROM A LITHIUM-BASED SOLUTION BY ELECTROLYSIS
CN102020295B (zh) 2010-12-22 2012-07-25 四川天齐锂业股份有限公司 高纯碳酸锂的制备方法
WO2012100293A1 (en) 2011-01-25 2012-08-02 The University Of Queensland Improved method of ore processing
US9493881B2 (en) 2011-03-24 2016-11-15 New Sky Energy, Inc. Sulfate-based electrolysis processing with flexible feed control, and use to capture carbon dioxide
WO2012145797A1 (en) * 2011-04-29 2012-11-01 Commonwealth Scientific And Industrial Research Organisation Recovery of soda from bauxite residue
US10128501B2 (en) 2011-06-07 2018-11-13 Sumitomo Metal Mining Co., Ltd. Nickel composite hydroxide and manufacturing method thereof, cathode active material for nonaqueous-electrolyte secondary battery and manufacturing method thereof, and nonaqueous-electrolyte secondary battery
JP6007601B2 (ja) 2011-06-23 2016-10-12 東ソー株式会社 マンガン酸化物の製造方法
CN102408411B (zh) 2011-09-19 2014-10-22 北京康辰药业股份有限公司 一种含喹啉基的羟肟酸类化合物及其制备方法、以及含有该化合物的药物组合物及其应用
JP5138822B1 (ja) 2012-02-23 2013-02-06 株式会社アストム 高純度水酸化リチウムの製造方法
AU2013237292B2 (en) 2012-03-19 2015-09-10 Metso Finland Oy Method for recovering lithium carbonate
JP5406955B2 (ja) 2012-03-22 2014-02-05 日鉄鉱業株式会社 炭酸リチウムを製造する方法
JPWO2013153692A1 (ja) * 2012-04-13 2015-12-17 旭化成株式会社 リチウム回収方法
JP5770675B2 (ja) * 2012-04-26 2015-08-26 古河機械金属株式会社 硫化リチウムの製造方法
US9382126B2 (en) 2012-05-30 2016-07-05 Nemaska Lithium Inc. Processes for preparing lithium carbonate
FI124088B (fi) 2012-06-05 2014-03-14 Outotec Oyj Menetelmä ja laitteisto puhtaan litiumpitoisen liuoksen valmistamiseksi
WO2014040138A1 (en) 2012-09-14 2014-03-20 The University Of Queensland Resin scavenging of nickel and cobalt
RU2648807C2 (ru) 2012-10-10 2018-03-28 Роквуд Литиум Гмбх Способ гидрометаллургического извлечения лития, никеля, кобальта из фракции отработанных гальванических элементов, содержащей оксид лития и переходного металла
CN103086405B (zh) 2013-01-05 2013-12-25 阿坝中晟锂业有限公司 一种电池级碳酸锂的清洁化生产方法
EP4424408A3 (en) 2013-03-15 2025-04-09 Nemaska Lithium Inc. Processes for preparing lithium hydroxide
JP6335316B2 (ja) 2013-10-23 2018-05-30 ネマスカ リチウム インコーポレイテッド 炭酸リチウムの調製のためのプロセス
AU2014339706B2 (en) 2013-10-23 2017-05-18 Nemaska Lithium Inc. Processes and systems for preparing lithium hydroxide
PE20160918A1 (es) 2013-12-03 2016-09-14 Univ Queensland Metodo de procesamiento de cobre
CA3047774C (en) 2014-02-24 2020-08-18 Nemaska Lithium Inc. Methods for treating lithium-containing materials
AU2015330958B2 (en) 2014-10-10 2019-11-28 Cornish Lithium plc Recovery process
JP2016162601A (ja) 2015-03-02 2016-09-05 Ｊｘ金属株式会社 リチウムイオン電池用正極活物質の製造方法、リチウムイオン電池用正極活物質、リチウムイオン電池用正極及びリチウムイオン電池
KR101711854B1 (ko) 2015-05-13 2017-03-03 재단법인 포항산업과학연구원 수산화리튬 및 탄산리튬의 제조 방법
CA2996651C (en) 2015-08-27 2021-06-01 Nemaska Lithium Inc. Method for preparing lithium hydroxide and lithium sulfate monohydrate using hydrogen depolarized anode
GB201602259D0 (en) 2016-02-08 2016-03-23 Bateman Advanced Technologies Ltd Integrated Lithium production process
DE102016103100A1 (de) 2016-02-23 2017-08-24 Outotec (Finland) Oy Verfahren und Vorrichtung zur thermischen Behandlung von körnigen Feststoffen
DE102016104738A1 (de) 2016-03-15 2017-09-21 Outotec (Finland) Oy Verfahren und Vorrichtung zur thermischen Behandlung von körnigen Feststoffen
CN106365181B (zh) 2016-08-26 2018-03-09 成都开飞高能化学工业有限公司 一种利用含较高杂质富锂溶液制备电池级碳酸锂的方法
CA2940509A1 (en) 2016-08-26 2018-02-26 Nemaska Lithium Inc. Processes for treating aqueous compositions comprising lithium sulfate and sulfuric acid
CN106315625B (zh) 2016-08-26 2018-07-10 成都开飞高能化学工业有限公司 复合生产高纯单水氢氧化锂、高纯碳酸锂和电池级碳酸锂的方法
WO2018087697A1 (en) 2016-11-09 2018-05-17 Avalon Advanced Materials Inc. Methods and systems for preparing lithium hydroxide
US10508049B2 (en) 2017-05-11 2019-12-17 Tesla, Inc. System for regenerating sodium hydroxide and sulfuric acid from waste water stream containing sodium and sulfate ions
US20210079495A1 (en) 2017-06-08 2021-03-18 Urban Mining Pty Ltd Process for the recovery of cobalt, lithium, and other metals from spent lithium-based batteries and other feeds
JP2020522621A (ja) 2017-06-08 2020-07-30 アーバン マイニング プロプライエタリー リミテッド リチウムを回収する方法
JP2020523482A (ja) 2017-06-14 2020-08-06 アーバン マイニング プロプライエタリー リミテッド さまざまな原料からコバルト及び関連酸化物を製造する方法
DK3642374T3 (da) 2017-06-22 2023-02-20 Metso Outotec Finland Oy Fremgangsmåde til ekstraktion af lithiumforbindelse(r)
WO2019059654A1 (ko) 2017-09-19 2019-03-28 주식회사 엘지화학 이차전지용 양극 활물질 전구체, 양극 활물질 및 이를 포함하는 리튬 이차전지
CN113772750B (zh) 2017-11-22 2024-05-10 内玛斯卡锂业有限公司 制备各种金属的氢氧化物和氧化物以及其衍生物的方法
CN109694957B (zh) 2019-02-26 2020-12-18 中国科学院城市环境研究所 一种利用离子液体萃取锂离子电池浸出液金属离子的方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103097587A (zh) * 2010-06-30 2013-05-08 史蒂文·C·阿门多拉 锂金属的电解产物
WO2013159194A1 (en) * 2012-04-23 2013-10-31 Nemaska Lithium Inc. Processes for preparing lithium hydroxide

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