CN106062012B - 负载型混合催化剂及使用其制备基于烯烃的聚合物的方法 - Google Patents

负载型混合催化剂及使用其制备基于烯烃的聚合物的方法 Download PDF

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CN106062012B
CN106062012B CN201580001694.3A CN201580001694A CN106062012B CN 106062012 B CN106062012 B CN 106062012B CN 201580001694 A CN201580001694 A CN 201580001694A CN 106062012 B CN106062012 B CN 106062012B
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catalyst
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solution
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CN106062012A (zh
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权宪容
申殷姈
李琪树
洪大植
金世英
李承珉
权眩志
李龙湖
承裕泽
郑东勋
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LG Corp
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LG Chemical Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/07—Heteroatom-substituted Cp, i.e. Cp or analog where at least one of the substituent of the Cp or analog ring is or contains a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/10—Heteroatom-substituted bridge, i.e. Cp or analog where the bridge linking the two Cps or analogs is substituted by at least one group that contains a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
CN201580001694.3A 2014-09-05 2015-09-07 负载型混合催化剂及使用其制备基于烯烃的聚合物的方法 Active CN106062012B (zh)

Applications Claiming Priority (3)

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KR20140119030 2014-09-05
KR10-2014-0119030 2014-09-05
PCT/KR2015/009418 WO2016036221A1 (ko) 2014-09-05 2015-09-07 흔성 담지 촉매 및 이를 이용하는 을레핀계 중합체의 제조방법

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US (1) US9556289B2 (de)
EP (1) EP3031831B1 (de)
JP (1) JP6420911B2 (de)
KR (1) KR101685664B1 (de)
CN (1) CN106062012B (de)
WO (1) WO2016036221A1 (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101792171B1 (ko) 2014-12-08 2017-10-31 주식회사 엘지화학 우수한 용융 강도를 갖는 올레핀계 중합체 및 이를 포함하는 필름
KR101747396B1 (ko) 2014-12-15 2017-06-14 주식회사 엘지화학 가공성이 우수한 올레핀계 중합체
EP3312201B1 (de) 2016-01-27 2019-12-25 LG Chem, Ltd. Geträgerter hybridkatalysator und verfahren zur herstellung eines olefinpolymers damit
KR102002983B1 (ko) 2016-02-24 2019-07-23 주식회사 엘지화학 혼성 담지 메탈로센 촉매 및 이를 이용한 폴리올레핀의 제조 방법
KR102048521B1 (ko) * 2016-10-20 2019-11-25 주식회사 엘지화학 내환경 응력 균열성이 우수한 에틸렌/알파-올레핀 공중합체
KR101958015B1 (ko) 2016-11-08 2019-07-04 주식회사 엘지화학 에틸렌/알파-올레핀 공중합체
CN108884184B (zh) * 2016-12-05 2021-06-15 Lg化学株式会社 混杂负载型催化剂
KR102072697B1 (ko) 2016-12-09 2020-02-03 주식회사 엘지화학 가공성 및 기계적 물성이 우수한 에틸렌/1-헥센 공중합체
KR102140260B1 (ko) 2016-12-22 2020-07-31 주식회사 엘지화학 올레핀 중합체 및 이의 제조 방법
KR102065719B1 (ko) * 2017-01-25 2020-01-13 주식회사 엘지화학 혼성 담지 촉매
JP7223540B2 (ja) * 2017-09-27 2023-02-16 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法
KR102459861B1 (ko) 2017-12-21 2022-10-27 주식회사 엘지화학 가공성이 우수한 에틸렌/1-부텐 공중합체
WO2019125065A1 (ko) * 2017-12-21 2019-06-27 주식회사 엘지화학 가공성이 우수한 에틸렌/1-부텐 공중합체
US11198747B2 (en) 2018-06-04 2021-12-14 Exxonmobil Chemical Patents Inc. Catalyst systems including two hafnocene catalyst compounds
EP3802643A4 (de) * 2018-06-04 2021-11-24 ExxonMobil Chemical Patents Inc. Katalysatorsysteme mit zwei hafnocen-katalysatorverbindungen
KR20200056800A (ko) * 2018-11-15 2020-05-25 롯데케미칼 주식회사 프로필렌 중합용 담지촉매 및 이를 이용하는 폴리프로필렌 수지의 제조방법
US11325995B2 (en) * 2020-02-21 2022-05-10 Chevron Phillips Chemical Company Lp Metallocene catalysts for polyethylene

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10204112A (ja) * 1997-01-17 1998-08-04 Mitsui Chem Inc オレフィン重合用触媒、オレフィン重合体の製造方法およびオレフィン重合体
CN101119799A (zh) * 2005-02-15 2008-02-06 Lg化学株式会社 负载型茂金属催化剂和使用该催化剂制备基于乙烯的共聚物的方法
KR20100028317A (ko) * 2008-09-04 2010-03-12 주식회사 엘지화학 혼성 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한 폴리올레핀의 제조방법
CN102791746A (zh) * 2010-03-08 2012-11-21 Lg化学株式会社 用于制备负载的茂金属催化剂的方法和使用该催化剂制备聚烯烃的方法

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4935474A (en) 1983-06-06 1990-06-19 Exxon Research & Engineering Company Process and catalyst for producing polyethylene having a broad molecular weight distribution
US5914289A (en) 1996-02-19 1999-06-22 Fina Research, S.A. Supported metallocene-alumoxane catalysts for the preparation of polyethylene having a broad monomodal molecular weight distribution
US6329541B1 (en) 1997-01-08 2001-12-11 Phillips Petroleum Company Organo omega-alkenyl cyclopentacarbyl silane-bridged metallocene compounds
US5886202A (en) 1997-01-08 1999-03-23 Jung; Michael Bridged fluorenyl/indenyl metallocenes and the use thereof
US6255426B1 (en) 1997-04-01 2001-07-03 Exxon Chemical Patents, Inc. Easy processing linear low density polyethylene
WO1999005153A1 (de) * 1997-07-28 1999-02-04 Targor Gmbh Verfahren zur herstellung von metallocenen
US6207606B1 (en) 1998-05-15 2001-03-27 Univation Technologies, Llc Mixed catalysts and their use in a polymerization process
US6274684B1 (en) 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US7041617B2 (en) 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
AR034829A1 (es) 2001-07-19 2004-03-17 Univation Tech Llc Sistemas catalizadores de metaloceno mezclados que contienen un incorporador pobre de comonomeros y un buen incorporador de comonomeros
KR20030012308A (ko) 2001-07-31 2003-02-12 주식회사 예스아이비 배팅형 복권 시스템 및 배팅 방법
EP1319665B1 (de) * 2001-12-11 2004-09-22 Crompton GmbH Verfahren zur Hydrierung von ungesättigten Übergangsmetallverbindungen
EP1403288A1 (de) 2002-09-27 2004-03-31 ATOFINA Research Hafnocenverbindungen enthaltendes Dual-site Katalysatorsystem zur Herstellung von bimodalen Polyolefinen
KR20040076965A (ko) 2003-02-27 2004-09-04 호남석유화학 주식회사 올레핀 중합용 담지 다중핵 메탈로센 촉매 및 이의 제조방법
KR100579843B1 (ko) * 2003-04-01 2006-05-12 주식회사 엘지화학 혼성 담지 메탈로센 촉매 및 그의 제조방법과 이를 이용한폴리올레핀의 제조방법
KR100646249B1 (ko) 2004-04-08 2006-11-23 주식회사 엘지화학 혼성 담지 메탈로센 촉매를 이용한 가공성 및 내압 특성이뛰어난 급수관 파이프용 폴리에틸렌 및 그의 제조방법
DE102005052654A1 (de) 2005-11-04 2007-05-16 Ticona Gmbh Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren
JP4940649B2 (ja) * 2005-12-19 2012-05-30 東ソー株式会社 エチレン系重合体製造用触媒およびエチレン系重合体の製造方法
US20100121006A1 (en) * 2007-05-02 2010-05-13 Joon-Hee Cho Polyolefin and preparation method thereof
KR101154507B1 (ko) * 2009-07-31 2012-06-13 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하여 제조된 올레핀계 중합체
US8288487B2 (en) * 2010-07-06 2012-10-16 Chevron Phillips Chemical Company Lp Catalysts for producing broad molecular weight distribution polyolefins in the absence of added hydrogen
KR101492571B1 (ko) 2012-11-26 2015-02-11 주식회사 엘지화학 혼성 담지 메탈로센 촉매와 그 제조방법
KR101637026B1 (ko) * 2013-11-18 2016-07-07 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조방법
KR101658172B1 (ko) 2013-12-02 2016-09-20 주식회사 엘지화학 혼성 담지 메탈로센 촉매 및 이를 이용하는 올레핀계 중합체의 제조방법
KR20150066484A (ko) * 2013-12-06 2015-06-16 주식회사 엘지화학 메탈로센 화합물
KR101747396B1 (ko) * 2014-12-15 2017-06-14 주식회사 엘지화학 가공성이 우수한 올레핀계 중합체

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10204112A (ja) * 1997-01-17 1998-08-04 Mitsui Chem Inc オレフィン重合用触媒、オレフィン重合体の製造方法およびオレフィン重合体
CN101119799A (zh) * 2005-02-15 2008-02-06 Lg化学株式会社 负载型茂金属催化剂和使用该催化剂制备基于乙烯的共聚物的方法
KR20100028317A (ko) * 2008-09-04 2010-03-12 주식회사 엘지화학 혼성 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한 폴리올레핀의 제조방법
CN102791746A (zh) * 2010-03-08 2012-11-21 Lg化学株式会社 用于制备负载的茂金属催化剂的方法和使用该催化剂制备聚烯烃的方法

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EP3031831B1 (de) 2019-06-19
KR20160029718A (ko) 2016-03-15
JP6420911B2 (ja) 2018-11-07
CN106062012A (zh) 2016-10-26
WO2016036221A1 (ko) 2016-03-10
US20160280813A1 (en) 2016-09-29
KR101685664B1 (ko) 2016-12-12
US9556289B2 (en) 2017-01-31
JP2017530247A (ja) 2017-10-12
EP3031831A4 (de) 2017-07-05
EP3031831A1 (de) 2016-06-15

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