CN106011960B - 一种汽车中控的电镀工艺 - Google Patents
一种汽车中控的电镀工艺 Download PDFInfo
- Publication number
- CN106011960B CN106011960B CN201610332563.XA CN201610332563A CN106011960B CN 106011960 B CN106011960 B CN 106011960B CN 201610332563 A CN201610332563 A CN 201610332563A CN 106011960 B CN106011960 B CN 106011960B
- Authority
- CN
- China
- Prior art keywords
- nickel
- plating
- copper
- middle control
- automobile middle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 238000009713 electroplating Methods 0.000 title claims abstract description 84
- 238000005516 engineering process Methods 0.000 title claims abstract description 33
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 332
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 166
- 238000007747 plating Methods 0.000 claims abstract description 122
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 72
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 54
- 229910052802 copper Inorganic materials 0.000 claims abstract description 54
- 239000010949 copper Substances 0.000 claims abstract description 54
- 239000002253 acid Substances 0.000 claims abstract description 37
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 35
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 35
- 239000011651 chromium Substances 0.000 claims abstract description 35
- 238000000034 method Methods 0.000 claims abstract description 32
- 230000008569 process Effects 0.000 claims abstract description 27
- 230000004913 activation Effects 0.000 claims abstract description 25
- 238000012545 processing Methods 0.000 claims abstract description 22
- 238000006073 displacement reaction Methods 0.000 claims abstract description 18
- 238000002203 pretreatment Methods 0.000 claims abstract description 15
- 238000005554 pickling Methods 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 59
- 239000000243 solution Substances 0.000 claims description 51
- 239000007788 liquid Substances 0.000 claims description 34
- 239000000654 additive Substances 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 238000001035 drying Methods 0.000 claims description 27
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 22
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims description 22
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 21
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 21
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 18
- 239000004327 boric acid Substances 0.000 claims description 18
- 238000001978 electrochemical passivation Methods 0.000 claims description 15
- 150000003839 salts Chemical class 0.000 claims description 12
- 238000007789 sealing Methods 0.000 claims description 12
- 230000000996 additive effect Effects 0.000 claims description 11
- 239000000080 wetting agent Substances 0.000 claims description 11
- 238000010790 dilution Methods 0.000 claims description 9
- 239000012895 dilution Substances 0.000 claims description 9
- 230000009467 reduction Effects 0.000 claims description 8
- 238000007788 roughening Methods 0.000 claims description 8
- 239000004902 Softening Agent Substances 0.000 claims description 6
- 239000000969 carrier Substances 0.000 claims description 6
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 6
- 238000001746 injection moulding Methods 0.000 claims description 6
- 238000002161 passivation Methods 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- HIRWGWMTAVZIPF-UHFFFAOYSA-N nickel;sulfuric acid Chemical compound [Ni].OS(O)(=O)=O HIRWGWMTAVZIPF-UHFFFAOYSA-N 0.000 claims 1
- 239000011248 coating agent Substances 0.000 abstract description 16
- 238000000576 coating method Methods 0.000 abstract description 16
- 230000003749 cleanliness Effects 0.000 abstract description 3
- 238000000926 separation method Methods 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 238000005406 washing Methods 0.000 description 10
- 239000004033 plastic Substances 0.000 description 8
- 229920003023 plastic Polymers 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- 238000007792 addition Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 230000005611 electricity Effects 0.000 description 5
- 238000005868 electrolysis reaction Methods 0.000 description 5
- 238000012797 qualification Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 241000370738 Chlorion Species 0.000 description 3
- 238000005660 chlorination reaction Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- -1 300g/L Chemical compound 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
- C25D5/12—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
- C25D5/14—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium two or more layers being of nickel or chromium, e.g. duplex or triplex layers
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/38—Electroplating: Baths therefor from solutions of copper
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/54—Electroplating of non-metallic surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Electroplating Methods And Accessories (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
Description
实施例1 | 实施例2 | 实施例3 | 对比例 | |
结合力 | 镀层不易分离 | 镀层不易分离 | 镀层不易分离 | 镀层易分离 |
外观 | 洁净,平整 | 洁净,平整 | 洁净,平整 | 凹凸不平 |
产品色泽 | 均匀 | 均匀 | 均匀 | 分布不均 |
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610332563.XA CN106011960B (zh) | 2016-05-19 | 2016-05-19 | 一种汽车中控的电镀工艺 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610332563.XA CN106011960B (zh) | 2016-05-19 | 2016-05-19 | 一种汽车中控的电镀工艺 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106011960A CN106011960A (zh) | 2016-10-12 |
CN106011960B true CN106011960B (zh) | 2018-02-16 |
Family
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Family Applications (1)
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CN201610332563.XA Active CN106011960B (zh) | 2016-05-19 | 2016-05-19 | 一种汽车中控的电镀工艺 |
Country Status (1)
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CN (1) | CN106011960B (zh) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106884160A (zh) * | 2017-02-20 | 2017-06-23 | 宣城托新精密科技有限公司 | 汽车内饰件表面处理工艺 |
CN106835220B (zh) * | 2017-02-20 | 2018-11-27 | 宣城托新精密科技有限公司 | 汽车内饰件表面电镀处理工艺 |
CN107190287B (zh) * | 2017-05-31 | 2019-01-29 | 佛山科学技术学院 | 一种在不锈钢上电镀珍珠镍的镀液及其电镀方法 |
CN107313101B (zh) * | 2017-06-08 | 2019-06-18 | 华南理工大学 | 一种环境友好型镍封-无铬钝化层的制备方法 |
CN107475714B (zh) * | 2017-09-11 | 2019-05-07 | 江阴市羽项汽车饰件有限公司 | 一种三价白铬珍珠镍电镀工艺 |
CN107557829A (zh) * | 2017-09-11 | 2018-01-09 | 江阴市羽项汽车饰件有限公司 | 一种三价黑铬珍珠镍电镀工艺 |
CN107794552A (zh) * | 2017-09-13 | 2018-03-13 | 杭州莱源环保科技有限公司 | 一种保证电镀珍珠镍产品颜色一致的方法 |
CN108070884A (zh) * | 2017-12-18 | 2018-05-25 | 常德力元新材料有限责任公司 | 一种电磁屏蔽材料的预镀液 |
CN108611667B (zh) * | 2018-07-13 | 2021-01-15 | 九牧厨卫股份有限公司 | 一种铜合金基材上环保复合镀层及其制备方法 |
CN109675777B (zh) * | 2019-01-03 | 2022-04-15 | 精英塑胶(珠海)有限公司 | 一种玫瑰金色的电镀喷涂工艺 |
CN109594111A (zh) * | 2019-01-18 | 2019-04-09 | 重庆敏驰塑胶有限公司 | 一种汽车部件石墨烯电镀方法 |
CN109898073A (zh) * | 2019-04-10 | 2019-06-18 | 珠海市永刚塑料制品有限公司 | 一种汽车饰件产品加工用的塑胶电镀工艺 |
CN116024623A (zh) * | 2022-12-27 | 2023-04-28 | 南通申海工业科技有限公司 | 尾管雾镀黑铬工艺 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102181861B (zh) * | 2011-03-31 | 2012-10-10 | 厦门建霖工业有限公司 | 一种金属合金的表面处理方法 |
CN104178794A (zh) * | 2014-07-09 | 2014-12-03 | 南通帝诚华信实业有限公司 | 珍珠镍车把手表面处理工艺 |
CN105177655A (zh) * | 2015-08-20 | 2015-12-23 | 深圳市港鸿信电子有限公司 | 一种透明abs水电镀生产工艺方法 |
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2016
- 2016-05-19 CN CN201610332563.XA patent/CN106011960B/zh active Active
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Publication number | Publication date |
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CN106011960A (zh) | 2016-10-12 |
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CP03 | Change of name, title or address |
Address after: Room 1508, No. 118, Longxing Road, Haining Economic Development Zone, Haining City, Jiaxing City, Zhejiang Province Patentee after: Zhejiang Fanyuan Technology Co.,Ltd. Address before: Hangzhou City, Zhejiang Province, Binjiang District Puyan Street 310000 Dongxin Road No. 270 Building 2 unit 2 days Yi square room 1305 Patentee before: HANGZHOU LEVIN ENVIRONMENTAL TECHNOLOGY Co.,Ltd. |
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TR01 | Transfer of patent right |
Effective date of registration: 20241015 Address after: 226500 No. 18-20, Huimin West Road, Chengbei street, Rugao City, Nantong City, Jiangsu Province Patentee after: Nantong Fanyuan Zhihui Technology Co.,Ltd. Country or region after: China Address before: Room 1508, No. 118, Longxing Road, Haining Economic Development Zone, Haining City, Jiaxing City, Zhejiang Province Patentee before: Zhejiang Fanyuan Technology Co.,Ltd. Country or region before: China |