CN105742689B - 包含离子传导陶瓷作为电解质的全固态金属-金属蓄电池 - Google Patents
包含离子传导陶瓷作为电解质的全固态金属-金属蓄电池 Download PDFInfo
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- CN105742689B CN105742689B CN201510982742.3A CN201510982742A CN105742689B CN 105742689 B CN105742689 B CN 105742689B CN 201510982742 A CN201510982742 A CN 201510982742A CN 105742689 B CN105742689 B CN 105742689B
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- Prior art keywords
- metal
- cathode
- solid
- anode
- accumulator
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- Expired - Fee Related
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- 239000002184 metal Substances 0.000 title claims abstract description 112
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 111
- 239000007787 solid Substances 0.000 title claims abstract description 63
- 239000000919 ceramic Substances 0.000 title abstract description 39
- 239000003792 electrolyte Substances 0.000 title abstract description 15
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 25
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 12
- 150000001342 alkaline earth metals Chemical class 0.000 claims abstract description 7
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 6
- 150000003624 transition metals Chemical class 0.000 claims abstract description 6
- 239000003513 alkali Substances 0.000 claims abstract description 5
- 239000007784 solid electrolyte Substances 0.000 claims description 13
- 239000010949 copper Substances 0.000 claims description 12
- 239000002131 composite material Substances 0.000 claims description 11
- 229910052744 lithium Inorganic materials 0.000 claims description 9
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 239000011777 magnesium Substances 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 6
- 239000004332 silver Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims 2
- 230000001070 adhesive effect Effects 0.000 claims 2
- CYQAYERJWZKYML-UHFFFAOYSA-N phosphorus pentasulfide Chemical compound S1P(S2)(=S)SP3(=S)SP1(=S)SP2(=S)S3 CYQAYERJWZKYML-UHFFFAOYSA-N 0.000 claims 2
- 238000003860 storage Methods 0.000 abstract description 5
- 239000011521 glass Substances 0.000 description 46
- 229910001416 lithium ion Inorganic materials 0.000 description 29
- 239000013078 crystal Substances 0.000 description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 13
- 229910052799 carbon Inorganic materials 0.000 description 12
- 239000000463 material Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000011888 foil Substances 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 6
- 238000004090 dissolution Methods 0.000 description 6
- 239000010416 ion conductor Substances 0.000 description 6
- 239000000969 carrier Substances 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 239000002227 LISICON Substances 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 238000002484 cyclic voltammetry Methods 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 238000009830 intercalation Methods 0.000 description 4
- 230000002687 intercalation Effects 0.000 description 4
- 239000005300 metallic glass Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000004807 desolvation Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 150000004767 nitrides Chemical class 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000010970 precious metal Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- 239000002228 NASICON Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000002800 charge carrier Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000001465 metallisation Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000005518 polymer electrolyte Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 150000003346 selenoethers Chemical class 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 229910020717 Li0.33La0.56TiO3 Inorganic materials 0.000 description 1
- 229910009178 Li1.3Al0.3Ti1.7(PO4)3 Inorganic materials 0.000 description 1
- 229910007539 Li1.6Al0.6Ge1.4(PO4)3 Inorganic materials 0.000 description 1
- 229910009290 Li2S-GeS2-P2S5 Inorganic materials 0.000 description 1
- 229910009110 Li2S—GeS2—P2S5 Inorganic materials 0.000 description 1
- 229910013043 Li3PO4-Li2S-SiS2 Inorganic materials 0.000 description 1
- 229910013035 Li3PO4-Li2S—SiS2 Inorganic materials 0.000 description 1
- 229910012810 Li3PO4—Li2S-SiS2 Inorganic materials 0.000 description 1
- 229910012797 Li3PO4—Li2S—SiS2 Inorganic materials 0.000 description 1
- 229910032387 LiCoO2 Inorganic materials 0.000 description 1
- 229910003327 LiNbO3 Inorganic materials 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 229910017958 MgNH Inorganic materials 0.000 description 1
- 229910003249 Na3Zr2Si2PO12 Inorganic materials 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000002051 biphasic effect Effects 0.000 description 1
- 238000010349 cathodic reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910000921 lithium phosphorous sulfides (LPS) Inorganic materials 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- -1 perovskite Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/381—Alkaline or alkaline earth metals elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/381—Alkaline or alkaline earth metals elements
- H01M4/382—Lithium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/582,699 US9722279B2 (en) | 2014-12-24 | 2014-12-24 | All-solid-state metal-metal battery comprising ion conducting ceramic as electrolyte |
| US14/582,699 | 2014-12-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105742689A CN105742689A (zh) | 2016-07-06 |
| CN105742689B true CN105742689B (zh) | 2018-07-17 |
Family
ID=56165340
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510982742.3A Expired - Fee Related CN105742689B (zh) | 2014-12-24 | 2015-12-24 | 包含离子传导陶瓷作为电解质的全固态金属-金属蓄电池 |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US9722279B2 (https=) |
| JP (1) | JP6570995B2 (https=) |
| CN (1) | CN105742689B (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11289700B2 (en) | 2016-06-28 | 2022-03-29 | The Research Foundation For The State University Of New York | KVOPO4 cathode for sodium ion batteries |
| CN106450512A (zh) * | 2016-09-29 | 2017-02-22 | 清华大学 | 一种具有分子筛固体电解质层的金属电池 |
| US11108080B2 (en) | 2017-06-01 | 2021-08-31 | Samsung Electronics Co., Ltd | Lithium and sodium solid-state electrolyte materials |
| US10629970B2 (en) | 2017-06-12 | 2020-04-21 | Panasonic Intellectual Property Management Co., Ltd. | Lithium air battery including negative electrode, positive electrode, nonaqueous lithium ion conductor, and copper ion |
| JP2020530188A (ja) * | 2017-08-07 | 2020-10-15 | ザ リージェンツ オブ ザ ユニバーシティ オブ ミシガン | 固体状電池用イオン電子混合伝導体 |
| WO2019195605A1 (en) * | 2018-04-04 | 2019-10-10 | Ab Systems, Inc. (Us) | Glass fiber composite separator |
| JP7172433B2 (ja) * | 2018-10-19 | 2022-11-16 | 三菱瓦斯化学株式会社 | 固体電解質材料およびその成形体 |
| CN110061285A (zh) * | 2019-04-24 | 2019-07-26 | 上海理工大学 | 一种全固态锂电池及其制备方法 |
| US11349150B2 (en) * | 2019-08-01 | 2022-05-31 | Toyota Motor Engineering & Manufacturing North America, Inc. | Ceramic soft composites for solid-state batteries |
| JP7314866B2 (ja) * | 2020-06-18 | 2023-07-26 | トヨタ自動車株式会社 | ナトリウムイオン二次電池 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1826860A1 (en) * | 2006-02-24 | 2007-08-29 | Ngk Insulators, Ltd. | All-solid-state battery |
| CN101341614A (zh) * | 2005-04-21 | 2009-01-07 | 波塔宁协会有限公司 | 二级固态电源 |
| WO2011020073A1 (en) * | 2009-08-14 | 2011-02-17 | Seeo, Inc | High energy polymer battery |
| CN103081215A (zh) * | 2010-09-16 | 2013-05-01 | 丰田自动车株式会社 | 固体电池及其再生方法 |
| WO2014138110A1 (en) * | 2013-03-04 | 2014-09-12 | Ceramatec, Inc. | Alkali metal intercalation material as an electrode in an electrolytic cell |
| CN104205467A (zh) * | 2012-03-22 | 2014-12-10 | 住友电气工业株式会社 | 全固态锂二次电池 |
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| BE782293A (fr) * | 1971-04-30 | 1972-10-19 | Comp Generale Electricite | Generateur electrochimique a couches minces |
| US3736186A (en) | 1971-06-16 | 1973-05-29 | Mallory & Co Inc P R | Separator and electrolyte material for solid electrolyte battery systems |
| US4390446A (en) | 1981-05-13 | 1983-06-28 | Duracell Inc. | Solid state cell with anolyte |
| JPH06275312A (ja) * | 1993-03-22 | 1994-09-30 | Matsushita Electric Ind Co Ltd | 全固体リチウム電池 |
| JPH06275322A (ja) * | 1993-03-22 | 1994-09-30 | Matsushita Electric Ind Co Ltd | リチウム電池 |
| DE69710787T2 (de) | 1996-05-22 | 2002-11-21 | Moltech Corp., Tucson | Komposit-kathoden, elektrochemische zellen mit komposit-kathoden und verfahren zur herstellung |
| JP4030443B2 (ja) | 2003-02-27 | 2008-01-09 | 三洋電機株式会社 | 非水電解質二次電池 |
| US8182943B2 (en) | 2005-12-19 | 2012-05-22 | Polyplus Battery Company | Composite solid electrolyte for protection of active metal anodes |
| JP4612664B2 (ja) * | 2007-09-25 | 2011-01-12 | セイコーエプソン株式会社 | 全固体二次電池、全固体二次電池の製造方法 |
| JP5414075B2 (ja) * | 2008-12-26 | 2014-02-12 | 独立行政法人産業技術総合研究所 | リチウム二次電池 |
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| US9692039B2 (en) * | 2012-07-24 | 2017-06-27 | Quantumscape Corporation | Nanostructured materials for electrochemical conversion reactions |
-
2014
- 2014-12-24 US US14/582,699 patent/US9722279B2/en not_active Expired - Fee Related
-
2015
- 2015-12-22 JP JP2015249560A patent/JP6570995B2/ja not_active Expired - Fee Related
- 2015-12-24 CN CN201510982742.3A patent/CN105742689B/zh not_active Expired - Fee Related
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| CN101341614A (zh) * | 2005-04-21 | 2009-01-07 | 波塔宁协会有限公司 | 二级固态电源 |
| EP1826860A1 (en) * | 2006-02-24 | 2007-08-29 | Ngk Insulators, Ltd. | All-solid-state battery |
| WO2011020073A1 (en) * | 2009-08-14 | 2011-02-17 | Seeo, Inc | High energy polymer battery |
| CN103081215A (zh) * | 2010-09-16 | 2013-05-01 | 丰田自动车株式会社 | 固体电池及其再生方法 |
| CN104205467A (zh) * | 2012-03-22 | 2014-12-10 | 住友电气工业株式会社 | 全固态锂二次电池 |
| WO2014138110A1 (en) * | 2013-03-04 | 2014-09-12 | Ceramatec, Inc. | Alkali metal intercalation material as an electrode in an electrolytic cell |
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| Dong Zhng，et al..A High Power Density Dual-electrolyte Lithium-Silver Battery with Celgard® 2325 Separator.《Electrochimica Acta》.2013,第116卷第429-433页. * |
Also Published As
| Publication number | Publication date |
|---|---|
| US9722279B2 (en) | 2017-08-01 |
| CN105742689A (zh) | 2016-07-06 |
| JP6570995B2 (ja) | 2019-09-04 |
| US20160190636A1 (en) | 2016-06-30 |
| JP2016122650A (ja) | 2016-07-07 |
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