JP2016122650A - 全固体金属−金属電池 - Google Patents
全固体金属−金属電池 Download PDFInfo
- Publication number
- JP2016122650A JP2016122650A JP2015249560A JP2015249560A JP2016122650A JP 2016122650 A JP2016122650 A JP 2016122650A JP 2015249560 A JP2015249560 A JP 2015249560A JP 2015249560 A JP2015249560 A JP 2015249560A JP 2016122650 A JP2016122650 A JP 2016122650A
- Authority
- JP
- Japan
- Prior art keywords
- metal
- cathode
- anode
- solid
- active
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002184 metal Substances 0.000 title claims abstract description 106
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 105
- 239000007787 solid Substances 0.000 title claims abstract description 74
- 239000003792 electrolyte Substances 0.000 claims abstract description 70
- 239000000919 ceramic Substances 0.000 claims abstract description 44
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 40
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 7
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 7
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 7
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 6
- 150000003624 transition metals Chemical class 0.000 claims abstract description 6
- 239000010949 copper Substances 0.000 claims description 13
- 239000007784 solid electrolyte Substances 0.000 claims description 13
- 239000002131 composite material Substances 0.000 claims description 11
- 229910052744 lithium Inorganic materials 0.000 claims description 9
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 7
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
- 241000047703 Nonion Species 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 229910052709 silver Inorganic materials 0.000 claims description 5
- 239000004332 silver Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- -1 silver phosphosulfide Chemical group 0.000 claims description 2
- 229910000921 lithium phosphorous sulfides (LPS) Inorganic materials 0.000 claims 1
- 229910001416 lithium ion Inorganic materials 0.000 abstract description 30
- 239000011521 glass Substances 0.000 description 40
- 239000013078 crystal Substances 0.000 description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 13
- 150000002500 ions Chemical class 0.000 description 13
- 229910052799 carbon Inorganic materials 0.000 description 12
- 239000000463 material Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000011888 foil Substances 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 238000004090 dissolution Methods 0.000 description 6
- 239000002227 LISICON Substances 0.000 description 5
- 239000000969 carrier Substances 0.000 description 5
- 238000004807 desolvation Methods 0.000 description 5
- 150000001768 cations Chemical class 0.000 description 4
- 238000002484 cyclic voltammetry Methods 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 238000009830 intercalation Methods 0.000 description 4
- 230000002687 intercalation Effects 0.000 description 4
- 239000010416 ion conductor Substances 0.000 description 4
- 239000005300 metallic glass Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 150000004767 nitrides Chemical class 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229910010835 LiI-Li2S-P2S5 Inorganic materials 0.000 description 2
- 229910010840 LiI—Li2S—P2S5 Inorganic materials 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- 239000002228 NASICON Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 238000001465 metallisation Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000075 oxide glass Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000005518 polymer electrolyte Substances 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 150000003346 selenoethers Chemical class 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- 238000007614 solvation Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000002203 sulfidic glass Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 description 1
- 229910005839 GeS 2 Inorganic materials 0.000 description 1
- 229910018130 Li 2 S-P 2 S 5 Inorganic materials 0.000 description 1
- 229910018119 Li 3 PO 4 Inorganic materials 0.000 description 1
- 229910020717 Li0.33La0.56TiO3 Inorganic materials 0.000 description 1
- 229910009178 Li1.3Al0.3Ti1.7(PO4)3 Inorganic materials 0.000 description 1
- 229910007539 Li1.6Al0.6Ge1.4(PO4)3 Inorganic materials 0.000 description 1
- 229910013043 Li3PO4-Li2S-SiS2 Inorganic materials 0.000 description 1
- 229910013035 Li3PO4-Li2S—SiS2 Inorganic materials 0.000 description 1
- 229910012810 Li3PO4—Li2S-SiS2 Inorganic materials 0.000 description 1
- 229910012797 Li3PO4—Li2S—SiS2 Inorganic materials 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 229910013641 LiNbO 3 Inorganic materials 0.000 description 1
- 229910017958 MgNH Inorganic materials 0.000 description 1
- 229910003249 Na3Zr2Si2PO12 Inorganic materials 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000002051 biphasic effect Effects 0.000 description 1
- 238000010349 cathodic reaction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- HZZOEADXZLYIHG-UHFFFAOYSA-N magnesiomagnesium Chemical compound [Mg][Mg] HZZOEADXZLYIHG-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000003701 mechanical milling Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000002226 superionic conductor Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/381—Alkaline or alkaline earth metals elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/381—Alkaline or alkaline earth metals elements
- H01M4/382—Lithium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
背景
本出願は、全固体電池に関する。特に、本出願は、電解質としてイオン伝導性セラミック固体を含む全固体金属−金属電池に関する。
本発明の一実施形態においては、全固体金属−金属電池は、活性陽極金属としてアルカリ金属またはアルカリ土類金属を含む陽極と、活性陽極金属イオン伝導性セラミック固体を含む陽極電解質と、活性陰極金属イオン伝導性セラミック固体を含む陰極電解質と、活性陰極金属として遷移金属を含む陰極とを、この順に含む。
この説明全体を通して、「電気化学セル」および「電池」という用語は、説明の文脈において電気化学セルと電池とを明らかに区別しない限り同義に使用され得る。
Liイオン伝導性セラミック陽極電解質の材料として、Li3PS4(LPS)ガラスを選択した。Agイオン伝導性セラミック陰極電解質の材料として、Ag7P3S11(APS)ガラスを選択した。LPSガラスおよびAPSガラスはいずれも、ZrO2ポットおよびボールを用いて、まず、370rpm下で20時間出発材料をメカニカルミリングすることによって調製した。その後、陽極電解質および陰極電解質をプレスして、二相ペレットを作製した。
Liイオン伝導性セラミック陽極電解質の材料として、Li7P3S11(LPS2)ガラスを選択し、Agイオン伝導性セラミック陰極電解質の材料として、APSガラスを選択した。LPS2ガラスおよびAPSガラスの両方を調製し、その後、陽極電解質および陰極電解質をプレスして、実施例1に記載したのと同一の方法で二相ペレットを作製した。
陽極反応:xLi → xLi+ + xe−
陽極電解質反応:Li7P3S11 + xLi+ → Li7P3S11 + xLi+
陰極電解質反応:Ag7P3S11 + xLi+ → Ag7−xLixP3S11 + xAg+
陰極反応:xAg+ + xe− → xAg。
固体電解質として、Li3PS4(LPS)ガラスを選択した。LPSガラスは、ZrO2ポットおよびボールを用いて、まず、370rpm下で20時間出発材料をメカニカルミリングすることによって調製し、その後プレスして、ペレットを作製した。その後、陰極用Ag粉末をLPSガラスの一方側にプレスして、Li箔陽極をLPSガラスの他方側に取付けて、「Li/LPS/Ag」セルを得た。
固体電解質として、Ag7P3S11(APS)ガラスを選択した。APSガラスは、ZrO2ポットおよびボールを用いて、まず、370rpm下で20時間出発材料をメカニカルミリングすることによって調製し、その後プレスして、ペレットを作製した。その後、陰極用Ag粉末をAPSガラスの一方側にプレスし、Li箔陽極をAPSガラスの他方側に取付けて、「Li/APS/Ag」セルを得た。
Claims (15)
- 活性陽極金属としてアルカリ金属またはアルカリ土類金属を含む陽極と、
活性陽極金属イオン伝導性セラミック固体を含む陽極電解質と、
活性陰極金属イオン伝導性セラミック固体を含む陰極電解質と、
活性陰極金属として遷移金属を含む陰極とを、この順に含む、全固体金属−金属電池。 - 前記活性陽極金属は、リチウム、ナトリウム、またはマグネシウムである、請求項1に記載の全固体金属−金属電池。
- 前記活性陽極金属は、リチウムである、請求項2に記載の全固体金属−金属電池。
- 前記陽極電解質は、リチウムリン硫化物である、請求項3に記載の全固体金属−金属電池。
- 前記活性陰極金属は、銀または銅である、請求項1に記載の全固体金属−金属電池。
- 前記活性陰極金属は、銀である、請求項5に記載の全固体金属−金属電池。
- 前記陰極電解質は、銀リン硫化物である、請求項6に記載の全固体金属−金属電池。
- 前記陽極は、活性陽極金属イオン伝導性セラミック固体電解質をさらに含む、複合金属電極である、請求項1に記載の全固体金属−金属電池。
- 前記陰極は、活性陰極金属イオン伝導性セラミック固体電解質をさらに含む、複合金属電極である、請求項1に記載の全固体金属−金属電池。
- 前記陽極電解質は、アモルファスである、請求項1に記載の全固体金属−金属電池。
- 前記陽極電解質は、非イオン伝導性結着剤をさらに含む、複合体である、請求項1に記載の全固体金属−金属電池。
- 前記陰極電解質は、アモルファスである、請求項1に記載の全固体金属−金属電池。
- 前記陰極電解質は、非イオン伝導性結着剤をさらに含む、複合体である、請求項1に記載の全固体金属−金属電池。
- 初めの充電前に活性陽極金属を含まない陽極集電体と、
活性陽極金属イオン伝導性セラミック固体を含む陽極電解質と、
活性陰極金属イオン伝導性セラミック固体を含む陰極電解質と、
活性陰極金属として遷移金属を含む陰極とを、この順に含む、全固体金属−金属電池。 - 活性陽極金属としてアルカリ金属またはアルカリ土類金属を含む陽極と、
活性陽極金属イオン伝導性セラミック固体を含む陽極電解質と、
活性陰極金属イオン伝導性セラミック固体を含む陰極電解質と、
初めの充電前に活性陰極金属を含まない陰極集電体とを、この順に含む、全固体金属−金属電池。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/582,699 | 2014-12-24 | ||
US14/582,699 US9722279B2 (en) | 2014-12-24 | 2014-12-24 | All-solid-state metal-metal battery comprising ion conducting ceramic as electrolyte |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2016122650A true JP2016122650A (ja) | 2016-07-07 |
JP2016122650A5 JP2016122650A5 (ja) | 2019-04-25 |
JP6570995B2 JP6570995B2 (ja) | 2019-09-04 |
Family
ID=56165340
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015249560A Expired - Fee Related JP6570995B2 (ja) | 2014-12-24 | 2015-12-22 | 全固体金属−金属電池 |
Country Status (3)
Country | Link |
---|---|
US (1) | US9722279B2 (ja) |
JP (1) | JP6570995B2 (ja) |
CN (1) | CN105742689B (ja) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10629970B2 (en) | 2017-06-12 | 2020-04-21 | Panasonic Intellectual Property Management Co., Ltd. | Lithium air battery including negative electrode, positive electrode, nonaqueous lithium ion conductor, and copper ion |
JP2020064832A (ja) * | 2018-10-19 | 2020-04-23 | 三菱瓦斯化学株式会社 | 固体電解質材料およびその成形体 |
JP2021515353A (ja) * | 2019-04-24 | 2021-06-17 | 上海理工大学University Of Shanghai For Science And Technology | 全固体リチウム電池及びその製造方法 |
KR20210156737A (ko) * | 2020-06-18 | 2021-12-27 | 도요타 지도샤(주) | 나트륨 이온 이차 전지 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11289700B2 (en) | 2016-06-28 | 2022-03-29 | The Research Foundation For The State University Of New York | KVOPO4 cathode for sodium ion batteries |
CN106450512A (zh) * | 2016-09-29 | 2017-02-22 | 清华大学 | 一种具有分子筛固体电解质层的金属电池 |
US11108080B2 (en) | 2017-06-01 | 2021-08-31 | Samsung Electronics Co., Ltd | Lithium and sodium solid-state electrolyte materials |
KR20200039713A (ko) | 2017-08-07 | 2020-04-16 | 더 리젠츠 오브 더 유니버시티 오브 미시건 | 고체 상태 배터리용 혼합 이온 및 전자 도체 |
WO2019195605A1 (en) * | 2018-04-04 | 2019-10-10 | Ab Systems, Inc. (Us) | Glass fiber composite separator |
US11349150B2 (en) * | 2019-08-01 | 2022-05-31 | Toyota Motor Engineering & Manufacturing North America, Inc. | Ceramic soft composites for solid-state batteries |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06275322A (ja) * | 1993-03-22 | 1994-09-30 | Matsushita Electric Ind Co Ltd | リチウム電池 |
JPH06275312A (ja) * | 1993-03-22 | 1994-09-30 | Matsushita Electric Ind Co Ltd | 全固体リチウム電池 |
JP2009080999A (ja) * | 2007-09-25 | 2009-04-16 | Seiko Epson Corp | 電気化学素子 |
WO2010073978A1 (ja) * | 2008-12-26 | 2010-07-01 | 独立行政法人産業技術総合研究所 | リチウム二次電池 |
JP2010225356A (ja) * | 2009-03-23 | 2010-10-07 | Sumitomo Electric Ind Ltd | 非水電解質電池及びその使用方法 |
US20120141881A1 (en) * | 2009-08-14 | 2012-06-07 | Seeo, Inc | High energy polymer battery |
US20140234715A1 (en) * | 2012-07-24 | 2014-08-21 | Quantumscape Corporation | Protective coatings for conversion material cathodes |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE782293A (fr) | 1971-04-30 | 1972-10-19 | Comp Generale Electricite | Generateur electrochimique a couches minces |
US3736186A (en) | 1971-06-16 | 1973-05-29 | Mallory & Co Inc P R | Separator and electrolyte material for solid electrolyte battery systems |
US4390446A (en) | 1981-05-13 | 1983-06-28 | Duracell Inc. | Solid state cell with anolyte |
WO1997044840A1 (en) | 1996-05-22 | 1997-11-27 | Moltech Corporation | Composite cathodes, electrochemical cells comprising novel composite cathodes, and processes for fabricating same |
JP4030443B2 (ja) | 2003-02-27 | 2008-01-09 | 三洋電機株式会社 | 非水電解質二次電池 |
RU2295178C2 (ru) * | 2005-04-21 | 2007-03-10 | Общество с ограниченной ответственностью "Высокоэнергетические батарейные системы" (ООО "ВЭБС") | Твердотельный вторичный источник тока |
US8182943B2 (en) | 2005-12-19 | 2012-05-22 | Polyplus Battery Company | Composite solid electrolyte for protection of active metal anodes |
US7914932B2 (en) * | 2006-02-24 | 2011-03-29 | Ngk Insulators, Ltd. | All-solid-state battery |
JP5500260B2 (ja) * | 2010-09-16 | 2014-05-21 | トヨタ自動車株式会社 | 固体電池及びその再生方法 |
US8911895B2 (en) | 2011-04-21 | 2014-12-16 | Siemens Aktiengesellschaft | All solid state rechargeable oxide-ion battery (ROB) system |
CN103165900B (zh) | 2011-12-08 | 2016-03-30 | 通用电气公司 | 一种碱金属-金属卤化物电池 |
CN104205467A (zh) * | 2012-03-22 | 2014-12-10 | 住友电气工业株式会社 | 全固态锂二次电池 |
JP2014010043A (ja) * | 2012-06-29 | 2014-01-20 | Brother Ind Ltd | 検査システム、検査対象受体および検査方法 |
KR102202085B1 (ko) * | 2013-03-04 | 2021-01-13 | 필드 업그레이딩 리미티드 | 전해 전지에서의 전극으로서의 알칼리 금속 층간삽입 물질 |
-
2014
- 2014-12-24 US US14/582,699 patent/US9722279B2/en active Active
-
2015
- 2015-12-22 JP JP2015249560A patent/JP6570995B2/ja not_active Expired - Fee Related
- 2015-12-24 CN CN201510982742.3A patent/CN105742689B/zh not_active Expired - Fee Related
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06275322A (ja) * | 1993-03-22 | 1994-09-30 | Matsushita Electric Ind Co Ltd | リチウム電池 |
JPH06275312A (ja) * | 1993-03-22 | 1994-09-30 | Matsushita Electric Ind Co Ltd | 全固体リチウム電池 |
JP2009080999A (ja) * | 2007-09-25 | 2009-04-16 | Seiko Epson Corp | 電気化学素子 |
WO2010073978A1 (ja) * | 2008-12-26 | 2010-07-01 | 独立行政法人産業技術総合研究所 | リチウム二次電池 |
JP2010225356A (ja) * | 2009-03-23 | 2010-10-07 | Sumitomo Electric Ind Ltd | 非水電解質電池及びその使用方法 |
US20120141881A1 (en) * | 2009-08-14 | 2012-06-07 | Seeo, Inc | High energy polymer battery |
US20140234715A1 (en) * | 2012-07-24 | 2014-08-21 | Quantumscape Corporation | Protective coatings for conversion material cathodes |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10629970B2 (en) | 2017-06-12 | 2020-04-21 | Panasonic Intellectual Property Management Co., Ltd. | Lithium air battery including negative electrode, positive electrode, nonaqueous lithium ion conductor, and copper ion |
JP2020064832A (ja) * | 2018-10-19 | 2020-04-23 | 三菱瓦斯化学株式会社 | 固体電解質材料およびその成形体 |
JP7172433B2 (ja) | 2018-10-19 | 2022-11-16 | 三菱瓦斯化学株式会社 | 固体電解質材料およびその成形体 |
JP2021515353A (ja) * | 2019-04-24 | 2021-06-17 | 上海理工大学University Of Shanghai For Science And Technology | 全固体リチウム電池及びその製造方法 |
KR20210156737A (ko) * | 2020-06-18 | 2021-12-27 | 도요타 지도샤(주) | 나트륨 이온 이차 전지 |
KR102601672B1 (ko) | 2020-06-18 | 2023-11-13 | 도요타 지도샤(주) | 나트륨 이온 이차 전지 |
Also Published As
Publication number | Publication date |
---|---|
CN105742689A (zh) | 2016-07-06 |
CN105742689B (zh) | 2018-07-17 |
US20160190636A1 (en) | 2016-06-30 |
JP6570995B2 (ja) | 2019-09-04 |
US9722279B2 (en) | 2017-08-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6570995B2 (ja) | 全固体金属−金属電池 | |
JP2016122650A5 (ja) | ||
Zhao et al. | High-performance rechargeable lithium-iodine batteries using triiodide/iodide redox couples in an aqueous cathode | |
Nazar et al. | Lithium-sulfur batteries | |
US8980485B2 (en) | Rechargeable, thin-film, all solid-state metal-air battery | |
US9293796B2 (en) | Metal-air battery with dual electrode anode | |
US8481195B1 (en) | Lithium battery structures | |
US20140287302A1 (en) | Anode active material for sodium battery, anode, and sodium battery | |
JPH10302794A (ja) | リチウム二次電池 | |
WO2011038233A1 (en) | High-performance rechargeable batteries with fast solid-state ion conductors | |
US20130244085A1 (en) | Battery with non-porous alkali metal ion conductive honeycomb structure separator | |
JP5151329B2 (ja) | 正極体およびそれを用いたリチウム二次電池 | |
JP2015515723A (ja) | 非極性アルカリ金属イオン伝導ハニカム構造セパレーターを有する電池 | |
CN113594468B (zh) | 一种集流体及其制备方法和应用 | |
JP2009193803A (ja) | 全固体リチウム二次電池 | |
US9742027B2 (en) | Anode for sodium-ion and potassium-ion batteries | |
US10483586B2 (en) | All-solid-state battery using sodium ion intercalation cathode with Li/Na exchanging layer | |
JP2020514948A (ja) | 全固体リチウムイオン蓄電池およびその製造方法 | |
US20180312986A1 (en) | Ion-Selective Composite Materials and Method of Preparation | |
JP2018520487A (ja) | 金属触媒が部分導入された副反応防止膜を有するリチウム−空気電池の正極、これを含むリチウム−空気電池及びこの製造方法 | |
CN112054159A (zh) | 一种一体化全固态锂离子电池的制备方法 | |
He et al. | Synthesis and interface modification of oxide solid-state electrolyte-based all-solid-state lithium-ion batteries: Advances and perspectives | |
KR20210037849A (ko) | 리튬 이차전지용 양극, 이의 제조방법 및 상기 양극을 포함하는 리튬 이차전지 | |
CN107528043A (zh) | 电池 | |
CN109119635B (zh) | 电池 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20171011 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20180926 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20181016 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20190115 |
|
A524 | Written submission of copy of amendment under article 19 pct |
Free format text: JAPANESE INTERMEDIATE CODE: A524 Effective date: 20190313 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20190709 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20190807 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6570995 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
LAPS | Cancellation because of no payment of annual fees |