CN105683456B - 具有包括明胶的微孔结构的隔音板材和/或制备方法 - Google Patents

具有包括明胶的微孔结构的隔音板材和/或制备方法 Download PDF

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Publication number
CN105683456B
CN105683456B CN201480026367.9A CN201480026367A CN105683456B CN 105683456 B CN105683456 B CN 105683456B CN 201480026367 A CN201480026367 A CN 201480026367A CN 105683456 B CN105683456 B CN 105683456B
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China
Prior art keywords
composition
plank
microcellular structure
accelerating agent
filler
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Expired - Fee Related
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CN201480026367.9A
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CN105683456A (zh
Inventor
B·塔卡科斯
P·P·M·J·多诺克斯
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Acoustic Space Pty Ltd
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Acoustic Space Pty Ltd
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Priority claimed from AU2013901646A external-priority patent/AU2013901646A0/en
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Abstract

用于制造具有微孔结构的板材的组合物,所述组合物包括如下的组分:(a)约5wt%至约25wt%的明胶,(b)约25wt%至约60wt%的填料,(c)约15wt%至约40wt%的水,和(d)微孔结构促进剂。

Description

具有包括明胶的微孔结构的隔音板材和/或制备方法
本发明涉及具有微孔结构的并且具有隔音特性的板材,并且本发明特别是涉及用于制造所述板材的并且是环境友好的组合物。本发明还涉及用于制备所述板材的方法。
背景技术
具有高传声损失的材料具有隔音特性。材料的传声损失由多个不同的物理因素来确定,例如质量和刚性。每单位面积材料的质量是控制声音经过材料传输的最为重要的因素。所谓的质量定律在本文中是值得重复的,因为其对于绝大多数材料是最为常见的:
TL=20log10(msf)-48。
其中:TL=传声损失(dB)
ms=每单位面积质量(kg/m2)
f=声音频率(Hz)
材料的刚性是影响TL的另一个因素。更硬的材料表现出“一致倾斜”,其无法由如上的质量定律来解释。一致性或临界频率表示如下:
fc=A/t
其中:A为材料常数
t为材料厚度(mm)
通常用于制备具有隔音特性的板材的组合物的一个例子为所谓的加载乙烯树脂。在这样的组合物中,具有高密度的材料在配制阶段与乙烯树脂结合。所获得的产物具有高密度,同时仍保持高弹性,并由此提供隔音特性。
然而,乙烯树脂为衍生自油气源的产物,所以其成本和生产是与油价直接相关的,并由油源来决定。此外,乙烯树脂并不是容易生物降解的,并且在燃烧时还会产生有毒烟尘。当加载乙烯树脂在建筑领域中使用的时候,这会产生特别的问题。
据此,需要可用于制造具有隔音特性的板材并克服加载乙烯树脂缺点的替代材料。
提供这样的材料的一种尝试描述于WO 2006/053393中,其描述了用于制备板材的组合物,由水、明胶、甘油和填料构成。然而,发现由这样的组合物制备的板材在高于25℃的温度下是不稳定的,特别是在制备之后立即包装并随后暴露至阳光下的时候。发现所述材料会熔融并变形,当在建筑领域中使用这种材料时会提供所不期望的特性。
本发明试图提供用于制备具有隔音特性的板材的组合物,其旨在解决如上所述的问题。本发明还试图提供用于制备这样的板材的方法。
发明概述
根据本发明的一个方面,提供了用于制备具有微孔结构的板材的组合物,所述组合物包括如下组分:
(a)约5wt%至约25wt%的明胶,
(b)约25wt%至约60wt%的填料,
(c)约15wt%至约40wt%的水,和
(d)微孔结构促进剂。
在一种实施方式中,微孔结构促进剂与组分(a)、(b)和/或(c)中的一种或多种反应以提供板材的微孔结构。在一种实施方式中,微孔结构促进剂与组分(a)、(b)和/或(c)中的一种或多种反应以产生在组合物内形成微孔结构的气体,在固化时提供板材的微孔结构。
根据本发明的另一个方面,提供了用于制备具有微孔结构的板材,所述组合物基本上由如下组分构成:
(a)约5wt%至约25wt%的明胶,
(b)约25wt%至约60wt%的填料,
(c)约15wt%至约40wt%的水,
(d)约0.5wt%至约2wt%的微孔结构促进剂,和
(e)约10wt%至约30wt%的润滑化合物。
在一种实施方式中,除了组分(a)至(e),所述组合物的余量由选自如下的一种或多种的组分组成:谷蛋白、淀粉、一种或多种碱土金属、颜料、杀菌剂、香料和除臭剂。
在一种实施方式中,微孔结构促进剂为包括过氧基团的组分。在一种实施方式中,微孔结构促进剂为过碳酸钠。在一种实施方式中,微孔结构促进剂与组合物中的水反应以产生在组合物中提供微孔结构的氧气。在一种实施方式中,所述组合物包括约0.2wt%至约5wt%,并且优选0.5wt%至约2wt%的微孔结构促进剂。在另一种实施方式中,所述组合物包括约1wt%至约2wt%的微孔结构化试剂。
在一种实施方式中,所述组合物包括约20wt%至约30wt%的水。
在一种实施方式中,所述组合物进一步包括润滑化合物,例如乙二醇和丙二醇,丙三醇(甘油)。在一种实施方式中,所述组合物包括约10wt%至约30wt%的润滑化合物。在另一种实施方式中,所述组合物包括约10wt%至约15wt%的润滑化合物。在一种实施方式中,所述润滑化合物方甘油。
在一种实施方式中,所述组合物进一步包括碱土金属氯化物。在一种实施方式中,所述组合物包括约1wt%至约5wt%的碱土金属氯化物。在另一种实施方式中,所述组合物包括约1wt%至约2wt%的碱土金属氯化物。在一种实施方式中,碱土金属氯化物为氯化镁。
在一种实施方式中,所述组合物进一步包括谷蛋白。在一种实施方式中,所述组合物包括约1wt%至约5wt%的谷蛋白。在另一种实施方式中,所述组合物包括约2wt%至约4wt%的谷蛋白。
在一种实施方式中,所述组合物包括淀粉。在一种实施方式中,所述淀粉为木薯淀粉的形式。在一种实施方式中,所述组合物包括约1wt%至约5wt%的淀粉。在另一种实施方式中,所述组合物包括约2wt%至约4wt%的淀粉。
在一种实施方式中,明胶具有约220至约260的勃鲁(bloom)。在一种实施方式中,所述明胶具有约250的勃鲁。在一种实施方式中,所述明胶为B型明胶。在一种实施方式中,所述组合物包括约5wt%至约15wt%的明胶。在另一种实施方式中,所述组合物包括约10wt%至15wt%的明胶。
在一种实施方式中,填料的密度大于1g/cm3。在一种实施方式中,填料的密度为约2.0至约5.0g/cm3。在一种实施方式中,填料选自碳酸钙和/或硫酸钡。在一种实施方式中,所述组合物包括约30wt%至约50wt%的填料。在另一种实施方式中,所述组合物包括约35wt%至约45wt%的填料。在一种实施方式中,所述填料选自碳酸钙和硫酸钡的组合。在一种实施方式中,所述填料为碳酸钙。
在一种实施方式中,所述组合物进一步包括杀菌剂。
在一种实施方式中,所述组合物进一步包括除臭剂。
在一种实施方式中,所述组合物进一步包括香料化合物。
在一种实施方式中,所述组合物进一步包括颜料。在另一种实施方式中,所述颜料为水基的。
根据本发明的另一个方面,提供了用于制备具有微孔结构的板材的方法,所述方法包括步骤:
a.制备组合物,包括步骤:
i.提供15wt%至约40wt%的水;
ii.将约5wt%至约25wt%的明胶溶解于水中,以提供第一混合物;
iii.将约20wt%至约60wt%的填料混合于第一混合物中,从而形成第二混合物;
iv.将微孔结构促进剂引入至第二混合物以形成所述组合物,上述的wt%均基于全部组合物的总重量计,
b.使所述组合物成型为板材;和
c.使所述板材固化。
在一种实施方式中,微孔结构促进剂选自包括过氧基团的组分。在一种实施方式中,微孔结构促进剂为过碳酸钠。在一种实施方式中,微孔结构促进剂与组合物中的水反应以产生在组合物中提供微孔结构的氧气,所述氧气在固化时提供板材内的微孔结构。
在一种实施方式中,制备所述组合物的步骤a.在约75℃至约95℃的温度下实施。在一种实施方式中,步骤a.在约80℃的温度下实施。
在一种实施方式中,步骤iii.的填料为碳酸钙。
在一种实施方式中,在步骤a.iii.之前,将约10wt%至约30wt%的甘油添加至填料。在替换实施方式中,在步骤a.i.之后将约5wt%至约15wt%的甘油添加至水,并在步骤a.ii.之后和步骤a.iii.之前添加剩余的约5wt%至约15wt%的甘油。
在一种实施方式中,在步骤a.i.之后并在步骤a.ii.之前,将约1wt%至5wt%的氯化镁添加至水。
在一种实施方式中,在步骤b.之前的约1分钟至约15分钟,将微孔结构促进剂引入至第二混合物。在一种实施方式中,在步骤b.之前的约2分钟,将微孔结构促进剂引入至第二混合物。
在一种实施方式中,步骤b.包括将组合物倾注至基本上水平的表面上以形成板材。
根据本发明的另一个方面,提供了由如在本文描述的组合物制备的或者由如在本文描述的方法制备的板材。
在一种实施方式中,可将另一个平坦的板材结合至板材的一个或两个平面上以提供层状板材。在一种实施方式中,平坦的板材由热结合的聚酯薄片或针刺的聚酯薄片组成。在一种实施方式中,平坦的板材为热结合的聚酯薄片,并且所述热结合的聚酯薄片结合至铝箔形式的其它板材。
在一种实施方式中,使用粘合剂以层压制品形式将铝箔结合至所述热结合的聚酯薄片。
实施方式的详细说明
上文的描述仅为本发明的某些实施方式,并且改进和/或变形可以在不背离本发明范围和精神的情况下做出,所述实施方式仅为说明性的,而非限制性的。
在本说明书的内容中,术语“包含”是指“原则上包括,但并不必须是唯一地”或者“具有”或者“包括”,并非“仅由......构成”。术语“包含(comprising)”的变形,例如“包含(comprise)”和“包含(comprises)”具有相应变化的含义。
在特定实施方式中,如本文的组合物能够产生具有微孔结构的声学板材,其具有显著的隔音特性。板材一旦形成,就会具有约0.2g/cm3的密度(组合物中不包括填料),并且当包括填料时,就会具有约0.8至1.2g/cm3的密度,高至约2.5g/cm3的密度。除了高密度,所述板材还是非常柔软的,并具有高弹性记忆。高密度和弹性的组合为板材提供了极佳的隔音特性。
因为本发明的组合物由非石油基产物组成,所以由所述组合物制备的板材是生物可降解的,并且是非毒性的。此外,板材的成本不依赖于油价和油源。
所述组合物的另一个优点在于所获得的板材是阻燃的,并且当燃烧的时候,与由装载乙烯树脂的替代隔音板材产物相比,不会放出有毒烟雾。这使得由在本文中描述的组合物所制备的板材可被广泛地用于多种不同应用的建筑材料,从而提供比装载乙烯树脂的更加安全和更加环保的替代品。由所述组合物制备的板材还可被用于存在火灾隐患的区域,例如船舶引擎环境和重工业设施。
在制备具有隔音特性的板材的过程中,所述组合物还可以通过使用任何合适的着色技术来着色,从而根据需要制备具有任何颜色的薄片。此外,在固化之前,所述组合物具有极佳的粘合性能,并因此如果希望将所述板材粘合至另一个基底,在成型阶段无需单独的粘合剂。可替换地,一旦固化所述板材,材料就还与绝大多数胶水和粘合剂相容,从而还可以以这种方式来制备复合材料。
所发现的是,所提供的包括微孔结构促进剂以及水、明胶和填料的组合物在成型为薄片或其它结构并固化的时候,所提供的材料在其整个组成内具有微孔结构。
在特定的实施方式中,微孔结构促进剂选自与用于制备板材的组合物的一种或多种其它组分进行反应的化合物,由此在板材的成型阶段产生气体,所述气体在板材成型时提供所获得组合物的微孔结构。
一类优选的微孔结构促进剂选自包括过氧基团的组分,例如如下的化合物:
2Na2CO3·3H2O2
(NH4)2SO4·H2O2
K2CO3·H2O2
Na2HPO4·H2O2
脲·H2O2
在一种替换实施方式中,微孔结构促进剂还可以选自包括过硫酸盐基团的组分,例如过硫酸钠Na2S2O8
在一种优选的实施方式中,微孔结构促进剂选自过碳酸钠。
还令人惊讶地发现,当微孔结构促进剂为包括过氧基团的组分(例如过碳酸钠)形式时,微孔结构促进剂会与组分中的水反应以产生被认为是氧气的气体。一旦包括微孔结构促进剂,就会在组合物内产生氧气,一旦组合物被固化,在整个组合物内形成的气泡就会以微孔结构的形式整体保持。
此外,并且不希望通过理论所限制,还认为通过过氧基团与水的反应,在明胶开始胶化的时候,将氧气提供至组合物内的明胶,在组合物固化时,在明胶分子之间提供更强的交联。更强的交联使得在高湿度、低湿度和温度变化条件下,由所述组合物制备的经固化的板材的“粘弹”性稳定,从而使得板材可以在约负40℃至约180℃的温度(在冷冻条件下测试超过90天)以及在干燥和潮湿条件下实施,而不会损失结构完整性。
这提供了所述板材能够容易地承受高至约90℃的温度,如果将所述板材保留暴露至阳光直射,例如在建筑工地或者当板材位于由塑料等构成的包装内的时候,这种情况就是经常会发生的。还发现的是,材料会保持弹性,并且甚至是在低于0℃的非常冷的温度下也保持相同的粘弹性。
不希望通过理论来限制,认为至少是包括微孔结构促进剂,并且特别是包括过氧基团的微孔结构促进剂,和/或添加选自碳酸钙的填料,会使板材的结构完整性在环境温度提高时而保持。这是与在WO 2006/053393中描述的组合物相反的,当暴露至高于25℃的温度时,其趋于熔融并变为油灰样,并损失其结构完整性。
此外,还发现的是,添加过氧基团形式的微孔结构促进剂所提供的是,所获得的材料对烃、油类和润滑脂以及水的存在具有提高的耐受性。
在特定的实施方式中,提供了用于制备具有微孔结构的板材的组合物,所述组合物由如下组分构成:
(a)约5wt%至约25wt%的明胶,
(b)约25wt%至约60wt%的填料,
(c)约15wt%至约40wt%的水,
(d)约0.5wt%至约2wt%的微孔结构促进剂,和
(e)约10wt%至约30wt%的润滑化合物;
其中,所述组合物的余量由选自一种或多种如下的组分构成:约1wt%至约5wt%的谷蛋白,约1wt%至约5wt%的淀粉,约1wt%至约5wt%的一种或多种碱土金属,和任选痕量的如下的任意一种:颜料、灭菌剂、香料和除臭剂。
在特定实施方式中,包括微孔结构促进剂的组合物可被用于制造不同厚度的微孔结构的板材。发现这些板材具有增强的弹性,低导热性,增强的隔音特性,以及高防火等级。就其本身而言,发现以这种方式制备的板材适用于多种不同的应用,例如管套和地板总成衬底。此外,由于所述组合物的弹性和高放火等级,其可被用作为床垫构造中的组分。据此,包括微孔结构的板材的厚度在用于建筑结构的包括声学薄片的应用、用于地板总成的衬底和管套时可在小于1mm至8mm之间变化,对于床垫结构可高至100mm至250mm。
所述组合物的微孔结构还意外地对于给定的重量将传声损失(STL)提高约3至4dB,其相对于现有技术的例如装载乙烯树脂的产物来说是具有明显优势的并高于其。
所述组合物的微孔结构一旦固化,就还发现会提高板材的弹性。还发现当本发明的板材与结合至其的其它层(例如:针刺聚酯薄片)相组合的时候,就会显著地提高冲击隔音,当板材被用作为提供地板声学/冲击噪音处理的隔音衬底的时候。在测试时,确实发现会提供高至6STAR冲击隔音等级。
再次由于组合物的微孔结构,一旦形成板材,所述板材就会提供耐热性(0.082W/mK)@23℃平均温度,50-70%R.H),和良好的蒸汽渗透阻力8.19×10-15Kg/Pa.m2。
在另一种实施方式中,具有微孔结构的板材可被结合至结构面板,例如石膏板,从而成型复合建筑材料。在另一种实施方式中,具有微孔结构的板材确实会夹在两个例如石膏板的结构面板之间,从而形成复合建筑材料。具有微孔结构的板材可以以一个连续层或者可替换地以不连续的间隔部分位于结构面板之间。
结构面板可以由任何常规的结构面板材料组成,例如石膏板、胶合板和纤维板。
这样的复合建筑材料可被用于多种不同的应用中,其中结构面板可以具有额外的益处,其为结构面板提供与常规结构面板相比增强的隔音特性。
在一种实施方式中,具有微孔结构的板材结合至结构面板的一侧,所获得的复合建筑材料可以通过第一刻痕或切割沿着复合材料包括具有微孔结构的板材的一侧而被切成一定的尺寸。复合建筑材料随后可被拉断或折叠以使结构面板沿着刻痕/切割线断裂,由此提供建筑领域中具有期望尺寸的复合建筑材料。
在特定实施方式中,用于制备根据本发明的板材的方法包括如下步骤:
a.制备组合物,包括步骤:
1.在约80℃的温度下,在约15wt%至约40wt%的水中溶解约1wt%至约5wt%的氯化镁(该步骤耗时约5分钟);
2.将约5wt%至约25wt%的明胶溶解于步骤1.的水和氯化镁中,从而形成混合物(该步骤耗时约45分钟);
3.将例如碳酸钙的填料添加至约一半的10wt%至约30wt%的甘油,从而形成第一甘油混合物,并在约75℃至80℃加热约0.5小时;
4.将约1wt%至约5wt%的谷蛋白分散于另一半的甘油中,从而在约55℃的温度下形成混合物(该步骤耗时约15分钟);
5.将步骤3的混合物添加至步骤4的混合物,从而形成混合物。
6.使步骤2的混合物与步骤5的混合物混合,从而形成混合物(该步骤耗时约15分钟);
7.将约1wt%至约5wt%的木薯淀粉添加至步骤6的混合物,并溶解木薯淀粉以形成混合物(该步骤耗时约15分钟);
8.在步骤b之前的约1分钟至约15分钟,将约0.5wt%至约2wt%的例如过碳酸钠的微孔结构化试剂添加至步骤7的混合物。
b.将组合物挤出至平面上以形成薄片;和
c.使所述薄片固化。
在一种替换实施方式中,用于制备根据本发明板材的方法包括如下步骤:
a.制备组合物,包括步骤:
1.在约15wt%至约40wt%的水中溶解约1wt%至约5wt%的氯化镁,并随后添加约5wt%至约15wt%的润滑化合物,例如甘油,并将所获得的混合物加热至约80℃至约95℃;
2.将约5wt%至约25wt%的明胶溶解于步骤1.的混合物中,从而形成混合物;
3.将约1wt%至约5wt%的谷蛋白溶解于约5wt%至约15wt%的例如甘油的润滑化合物中,从而形成混合物;
4.将步骤2.的混合物添加至步骤3.的混合物,从而形成混合物;
5.将约1wt%至约5wt%的例如木薯形式的淀粉和约25wt%至约60wt%的例如碳酸钙和/或硫酸钡的填料添加至步骤4.的混合物,并搅拌消除结块以形成混合物;
6.在步骤b.之前的约1分钟至约15分钟,将约0.5wt%至约2wt%的例如过碳酸钠的微孔结构化试剂添加至步骤5.的混合物。
b.将组合物挤出至平面上以形成薄片;并使所述薄片固化。
在一种优选的实施方式中,在步骤b之前被添加之前,过碳酸钠之类的微孔结构化试剂与一定量的甘油混合。甘油的添加意味着微孔结构化试剂以悬浮液的形式而添加,使得微孔结构化试剂在步骤b.之前供给至混合物并不会结块或团聚,如果微孔结构化试剂为粉末的形式,有时会发生结块或团聚。
形成具有微孔结构的板材的组合物的另一个优点在于,一旦微孔结构化试剂包括于剩余的组合物,所述组合物就可使用任何适用的方法成型为薄片,例如通过将组合物浇注在水平表面上,挤出组合物或者模制组合物。所述组合物随后在环境温度下固化,无需例如通过加热所述组合物而施加任何其它的能量。所述组合物还可以在高湿度的条件下固化。
在本发明的另一种实施方式中,由所述组合物制备的板材,或者如在本文中描述的方法,被用作为多层板材基础。在这种实施方式中,其它薄片形式的材料会被结合至板材的一个或两个平面以形成多层板材。
在一种实施方式中,已与其它箔层一起层压在一个平坦表面上的热结合的聚酯薄片在制备过程中会被粘合至由在本文中描述的组合物制备的板材的一侧或两侧。不包括其它箔层的热结合的聚酯薄片的平坦表面在组合物固化之前结合以形成板材。一旦板材固化,就会在板材和热结合的聚酯薄片之间形成强力粘合。所获得的多层板材被发现具有所期望的特性,包括:增强的强度和耐撕裂型以及防水性能。
发现在固化之前,热处理的聚酯会牢固地结合至如在本文中描述的组合物,并且无需任何其它的粘合剂或胶水。在热结合的聚酯的箔平面上呈现出的图案或者“凸起”状还帮助分散高频(超过1000Hz),并还提供热反射。多层板材提供了弹性隔音屏障,在其两侧具有箔反射层,这使得其成为防水的/防热的(热传递),并允许产物以多种不同的应用来使用,例如作为“声学衬垫材料”。
本发明将根据下文优选的而非限制性实施方式的示例而更好地理解。
实施例1
根据如下组成的组合物来制备试样:
9wt% 明胶
37wt% 碳酸钙
27wt% 水
2wt% 氯化镁
18wt% 甘油
2wt% 谷蛋白
3wt% 木薯淀粉
1wt% 过碳酸钠
余量的组合物由其他组分构成,例如着色剂。
组合物的制备包括在约80℃的温度下将氯化镁溶解于水中,持续约5分钟,并随后在相同的温度下将明胶溶解于混合物中,同时持续混合45分钟。与此同时,将甘油总量的一半加热至约55℃的温度,添加碳酸钙,随后将甘油和碳酸钙的混合物加热至约75℃至80℃的温度,持续约30分钟。随后在55℃下将谷蛋白分散在整个剩余的一半甘油中,持续15分钟。随后将甘油、碳酸钙混合物和甘油、谷蛋白混合物结合在一起以形成第二混合物。包括水、氯化镁和明胶的原始混合物随后与第二混合物混合15分钟,直至获得均匀的组合物。随后将木薯添加至均匀的组合物并溶解于其中,典型地搅拌约15分钟。随后,恰在以薄片的形式倾注混合物之前,将过碳酸钠添加至组合物。
实施例2
根据如下组成的组合物来制备具有微孔结构的板材试样:
13wt% 明胶
41wt% 碳酸钙
26wt% 水
1wt% 氯化镁
13wt% 甘油
2wt% 谷蛋白
3wt% 木薯淀粉
1wt% 过碳酸钠
余量的组合物由其他痕量组分构成,例如着色剂、除臭剂和灭菌剂。
组合物的制备包括通过将氯化镁溶解于水中并随后添加所需要的一半量的甘油,并随后将所获得的混合物加热至大于95℃的温度来制备第一混合物。随后添加明胶并溶解于第一混合物中。
通过采用剩余的甘油并在其中混合谷蛋白以形成第二混合物来制备第二混合物,随后将所述第二混合物添加至第一混合物以形成相结合的混合物。
随后将木薯淀粉和碳酸钙形式的填料添加至相结合的混合物,并强烈地搅拌以消除结块,随后将所获得的混合物加热至约76至78℃。
微孔结构化试剂随后通过将过碳酸钠研磨成粉末来制备。随后使粉末过碳酸钠与甘油混合形成浆料,从而帮助将过碳酸钠添加至相结合的混合物。
板材的制备随后包括使用螺旋式混合器/进料器使过碳酸钠浆料与相结合的混合物混合以形成未固化的组合物,恰在将未固化的组合物供给至刮涂台上之前,将未固化的组合物形成为具有微孔结构的连续薄片。
随后将连续薄片固化成型为具有微孔结构的板材,其重量为2.5kg/m2
板材的声学特性随后使用标准的“声音强度探测器”根据美国标准和ISO进行测试,测试结果在下文的表和图中示出:
2.5kg/m2
这些结果与重量为4kg/m2的形成如下结果的装载乙烯树脂板材进行比较:
装载乙烯树脂4kg/m2
根据重量为2.5kg/m2的具有微孔结构的板材的结果与重量为4kg/m2的装载乙烯树脂板材的结果的对比,可以看出具有微孔结构的板材对于多种应用都具有显著更好的STL(传声损失)结果,因为与所示的装载乙烯树脂板材相比,声音震动会以更快的速率消散。
多种改进对于本领域技术人员来说,在不背离本发明范围的情况下都将是明显的。

Claims (46)

1.用于制备具有微孔结构的板材的组合物,所述组合物包括如下组分:
(a)5wt%至25wt%的明胶,
(b)25wt%至60wt%的填料,
(c)15wt%至40wt%的水,和
(d)微孔结构促进剂,
其中微孔结构促进剂与组合物中的水反应以形成氧气,所述氧气提供组合物中的微孔结构,且所述的微孔结构促进剂为包括过氧基团或过硫酸盐基团的组分。
2.根据权利要求1的组合物,其中微孔结构促进剂为过碳酸钠。
3.根据权利要求1的组合物,其中所述组合物包括0.5wt%至2wt%的微孔结构促进剂。
4.根据前述权利要求任一项的组合物,其中所述组合物进一步包括润滑化合物。
5.根据权利要求4的组合物,其中所述组合物包括10wt%至30wt%的润滑化合物。
6.根据权利要求5的组合物,其中所述润滑化合物为甘油。
7.根据权利要求1或2的组合物,其中所述组合物进一步包括碱土金属氯化物。
8.根据权利要求7的组合物,其中所述组合物包括1wt%至5wt%的碱土金属氯化物。
9.根据权利要求7的组合物,其中所述碱土金属氯化物为氯化镁。
10.根据权利要求1或2的组合物,其中所述组合物进一步包括谷蛋白。
11.根据权利要求10的组合物,其中所述组合物包括1wt%至5wt%的谷蛋白。
12.根据权利要求1或2的组合物,其中所述组合物包括淀粉。
13.根据权利要求12的组合物,其中所述淀粉以木薯淀粉的形式而包括。
14.根据权利要求12的组合物,其中所述组合物包括1wt%至5wt%的淀粉。
15.根据权利要求1或2的组合物,其中明胶具有220至260的勃鲁。
16.根据权利要求1或2的组合物,其中所述明胶具有250的勃鲁。
17.根据权利要求1或2的组合物,其中所述明胶为B型明胶。
18.根据权利要求1或2的组合物,其中所述组合物包括5wt%至15wt%的明胶。
19.根据权利要求1或2的组合物,其中填料的密度大于1g/cm3
20.根据权利要求1或2的组合物,其中填料的密度为2.0至5.0g/cm3
21.根据权利要求1或2的组合物,其中填料选自碳酸钙和/或硫酸钡。
22.根据权利要求1或2的组合物,其中所述组合物包括30wt%至50wt%的填料。
23.根据权利要求1或2的组合物,其中所述填料选自碳酸钙和硫酸钡的组合。
24.根据权利要求1或2的组合物,其中所述填料为碳酸钙。
25.根据权利要求1或2的组合物,进一步包括灭菌剂。
26.根据权利要求1或2的组合物,进一步包括除臭剂。
27.根据权利要求1或2的组合物,进一步包括香料化合物。
28.根据权利要求1或2的组合物,进一步包括颜料。
29.用于制备具有微孔结构的板材的组合物,所述组合物基本上由如下组分构成:
(f)5wt%至25wt%的明胶,
(g)25wt%至60wt%的填料,
(h)15wt%至40wt%的水,
(i)0.5wt%至2wt%的微孔结构促进剂,和
(j)10wt%至30wt%的润滑化合物;
其中微孔结构促进剂与组合物中的水反应以形成氧气,所述氧气提供组合物中的微孔结构,且所述的微孔结构促进剂为包括过氧基团或过硫酸盐基团的组分。
30.根据权利要求29的组合物,其中除了组分(a)至(e),余量的组合物由选自一种或多种如下的组分构成:谷蛋白、淀粉、一种或多种碱土金属、颜料、灭菌剂、香料和除臭剂。
31.用于制备具有微孔结构的板材的方法,所述方法包括步骤:
a.制备组合物,包括步骤:
i.提供15wt%至40wt%的水;
ii.将5wt%至25wt%的明胶溶解于水中,以提供第一混合物;
iii.将20wt%至60wt%的填料混合于第一混合物中,从而形成第二混合物;
iv.将微孔结构促进剂引入至第二混合物以形成所述组合物,上述的wt%均基于全部组合物的总重量计,
b.使所述组合物成型为板材;和
c.使所述板材固化,
其中微孔结构促进剂与组合物中的水反应以形成氧气,所述氧气提供组合物中的微孔结构,且所述的微孔结构促进剂为包括过氧基团或过硫酸盐基团的组分。
32.根据权利要求31的方法,其中微孔结构促进剂为过碳酸钠。
33.根据权利要求31或32的方法,其中制备组合物的步骤a.在75℃至90℃的温度下实施。
34.根据权利要求33的方法,其中步骤a.在80℃的温度下实施。
35.根据权利要求31至32任一项的方法,其中步骤iii.的填料为碳酸钙。
36.根据权利要求31至32任一项的方法,其中在步骤a.iii.之前,将10wt%至30wt%的甘油添加至填料中。
37.根据权利要求31至32任一项的方法,其中在步骤a.i.之后并在步骤a.ii.之前,将1wt%至5wt%的氯化镁添加至水。
38.根据权利要求31至32任一项的方法,其中在步骤b之前的1分钟至15分钟,将微孔结构促进剂引入至第二混合物。
39.根据权利要求31至32任一项的方法,其中在步骤b之前的2分钟,将微孔结构促进剂引入至第二混合物。
40.根据权利要求31至32任一项的方法,其中步骤b包括将组合物倾注至基本上水平的表面上以形成板材。
41.板材,由根据权利要求1至30任一项的组合物来制备,或者由根据权利要求31至40任一项的方法来制备。
42.根据权利要求41的板材,进一步包括结合至所述板材的一个或两个平面以提供层状板材的平面板材。
43.根据权利要求42的板材,其中平面板材由热结合的聚酯薄片或针刺聚酯薄片组成。
44.根据权利要求43的板材,其中平面板材为热结合的聚酯薄片,并且所述热结合的聚酯薄片被结合至铝箔形式的其它板材。
45.根据权利要求44的板材,以层压制品形式用粘合剂将铝箔结合至热结合的聚酯薄片上。
46.复合建筑材料,包括由根据权利要求1至30任一项的组合物制备的或者由根据权利要求31至40任一项的方法制备的具有微孔结构的板材,具有微孔结构的板材结合至结构面板的一侧,由此形成复合建筑材料。
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