GB1003327A - Improvements in or relating to unsaturated polyester resin compositions - Google Patents
Improvements in or relating to unsaturated polyester resin compositionsInfo
- Publication number
- GB1003327A GB1003327A GB33329/62A GB3332962A GB1003327A GB 1003327 A GB1003327 A GB 1003327A GB 33329/62 A GB33329/62 A GB 33329/62A GB 3332962 A GB3332962 A GB 3332962A GB 1003327 A GB1003327 A GB 1003327A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carbon atoms
- organic
- alcohols
- salts
- phosphoric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0038—Use of organic additives containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
- C08K5/03—Halogenated hydrocarbons aromatic, e.g. C6H5-CH2-Cl
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/06—Unsaturated polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
A foamable unsaturated polyester resin composition is prepared by adding to a non-water containing polymerizable mixture of an unsaturated polyester resin and a cross-linking agent a salt of either an organic half ester of sulphuric acid or of an acid organic ester of phosphoric acid or of an organic sulphonic acid in amount 0.1 to 50 wt. per cent of the polymerizable mixture. The salts of organic half esters of sulphuric acid may contain inorganic cations, e.g. Na, K, Ca, Al, NH4 or Mg or organic cations, e.g. mono-, di- and tri-ethanolamines of sulphuric esters of (1) monohydric aliphatic alcohols containing from 1 to 30 carbon atoms or (2) monohydric aralkyl alcohols containing from 7-40 carbon atoms or (3) alcohols consisting of adducts of alkylene oxides with phenols. Salts of organic esters of phosphoric acid may contain inorganic cations, e.g. K, Na, Ca or organic cations, e.g. triethanolamine and are produced by reaction of phosphoric acid with alcohols, e.g. (1) aliphatic monohydric alcohols containing from 1-30 carbon atoms, (2) dihydric alcohols containing 2-30 carbon atoms, and (3) aralkyl alcohols containing 7-40 carbon atoms. Specified: triethanolamine - 2 - ethylhexyl phosphoric acid monoester. Salts of organic sulphonic acids may be inorganic, e.g. Na, K, Ca, Mg, Al, or organic basic salts, e.g. triethanolamine salts of (1) aliphatic sulphonic acids containing from 1-30 carbon atoms, (2) aryl alkyl sulphonic acids containing 7-40 carbon atoms, (3) aliphatic sulphonic acids substituted by aryl alkyl groups containing 7-40 carbon atoms, e.g. sodium lauryl benzene sulphonate or sodium lauryl sulphonate. The unsaturated polyester resin may be obtained by esterification of a -b unsaturated dibasic acids and/or saturated dibasic acids and/or saturated and/or unsaturated monobasic acids with alcohols. Many suitable acids and alcohols are listed. Cross-linking agents may be: vinyl, allyl, acrylic and vinylidene compounds, many are specified. Polymerization inhibitors may be present, e.g. polyhydric phenols, quinones, aromatic nitro compound, aromatic amines and quaternary ammonium salts. Modifying agents may be: paraffin, Japan wax and fillers, e.g. CaCO3, Ca3(PO4)2, CaSO4, BaSO4, SiO2, silica gel, Sb2O3, glass powders, mica, clay, iron and aluminium, iron sand, wood flour, starch and cellulose derivatives, polyvinyl compounds, polyethylene. The above inorganic fillers may be incorporated in amount 0.1 to 20% and may be of particle size, less than 1 micron. Reinforcing agents, e.g. asbestos, glass fibre, regenerated fibres may be added. Catalysts, accelerators and foaming agents may be added and include azides, carbonates, nitroso compounds, peroxides, amines, alkanolamines, naphthenates, mercaptans, many such compounds are listed. In Example (1) maleic anhydride was reacted with propylene glycol and diethylene glycol. Styrene, hydroquinone and paraffin were added followed by the triethanolamine salt of 2-ethylhexyl phosphoric acid monoester and the mixture foamed by agitation at room temperature. In Example (8) an alkyd was prepared from HET acid, maleic anhydride and propylene glycol. A mixture of styrene, tertiary butyl catechol and copper naphthenate was added followed by the triethanolamine salt of 2-ethylhexyl phosphoric acid diester and the mixture foamed by adding NH4HCO3 and ditertbutyl peroxide and heating.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1962T0026213 DE1242867C2 (en) | 1962-09-01 | 1962-09-01 | FOAM STABILIZERS IN POLYESTER MOLDING COMPOUNDS |
DET22682A DE1239095B (en) | 1962-09-01 | 1962-09-01 | Foam stabilizers in polyester molding compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1003327A true GB1003327A (en) | 1965-09-02 |
Family
ID=25999647
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB33329/62A Expired GB1003327A (en) | 1962-09-01 | 1962-08-30 | Improvements in or relating to unsaturated polyester resin compositions |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1239095B (en) |
GB (1) | GB1003327A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4013815A (en) | 1973-07-30 | 1977-03-22 | Hooker Chemicals & Plastics Corporation | Fire retardant unsaturated polyesters |
US4152368A (en) | 1974-07-22 | 1979-05-01 | Hooker Chemicals & Plastics Corp. | Unsaturated polyester resins having improved fire retardance |
US10395633B2 (en) * | 2013-05-09 | 2019-08-27 | Acoustic Space Pty Ltd | Sound insulating sheet material with a cellular structure including gelatine and/or a process for producing the same |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4322502A (en) * | 1980-09-11 | 1982-03-30 | Uniroyal, Inc. | Simultaneous expansion and cure of polyester resin composition |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1046874B (en) * | 1953-11-12 | 1958-12-18 | Huels Chemische Werke Ag | Process for increasing the shelf life of peroxide-catalyzed unsaturated polyester resin compositions |
DE1045649B (en) * | 1957-03-28 | 1958-12-04 | Hoechst Ag | Process for the production of hardened phosphorus-containing synthetic resins |
-
1962
- 1962-08-30 GB GB33329/62A patent/GB1003327A/en not_active Expired
- 1962-09-01 DE DET22682A patent/DE1239095B/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4013815A (en) | 1973-07-30 | 1977-03-22 | Hooker Chemicals & Plastics Corporation | Fire retardant unsaturated polyesters |
US4152368A (en) | 1974-07-22 | 1979-05-01 | Hooker Chemicals & Plastics Corp. | Unsaturated polyester resins having improved fire retardance |
US10395633B2 (en) * | 2013-05-09 | 2019-08-27 | Acoustic Space Pty Ltd | Sound insulating sheet material with a cellular structure including gelatine and/or a process for producing the same |
Also Published As
Publication number | Publication date |
---|---|
DE1239095B (en) | 1967-04-20 |
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