ES346795A1 - Thermosetting Ethylenically Unsaturated Ester Resin Compositions - Google Patents

Thermosetting Ethylenically Unsaturated Ester Resin Compositions

Info

Publication number
ES346795A1
ES346795A1 ES346795A ES346795A ES346795A1 ES 346795 A1 ES346795 A1 ES 346795A1 ES 346795 A ES346795 A ES 346795A ES 346795 A ES346795 A ES 346795A ES 346795 A1 ES346795 A1 ES 346795A1
Authority
ES
Spain
Prior art keywords
acid
ethylenically unsaturated
water
equivalent
acrylic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES346795A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of ES346795A1 publication Critical patent/ES346795A1/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/026Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from the reaction products of polyepoxides and unsaturated monocarboxylic acids, their anhydrides, halogenides or esters with low molecular weight
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • C09J163/10Epoxy resins modified by unsaturated compounds

Abstract

A thermosetting resin composition comprises a blend of: (A) at least 30% by wt. of an ethylenically unsaturated resin prepared by first reacting an ethylenically unsaturated monocarboxylic acid, e.g. (meth)acrylic acid or cinnamic acid, with a polyepoxide, e.g. a diglycidyl ether of bisphenol A or an epoxy novolac resin. A dicarboxylic acid anhydride is then reacted with the secondary hydroxyl groups to provide pendant half-ester groups from 0À8 to 1À2 equivalents of epoxide are used per equivalent of monocarboxylic acid and from 0À1 to 1À2 moles of dicarboxylic acid anhydride, e.g. of maleic or phthalic acid per equivalent epoxide. (B) Up to 70% by weight of a polymerizable monomer containing a >C = CH 2 group, e.g. a vinyl aromatic monomer such as styrene, a hydroxyalkyl ester of (meth)acrylic acid or of crotonic acid, alkyl esters of these acids or acrylic or methacrylic acid. Rapidly thickening compositions may be obtained by mixing: (A) a thermosetting composition as set out above (B) an oxide or hydroxide of a metal of Group II of the Periodic Table, e.g. MgO, in an amount sufficient to provide at least 0À75 equivalents per -COOH equivalent and (C) a catalytic amount of water, i.e. at least 0À25 equivalents per -COOH equivalent. Water may be provided as water of adsorption by adding clay or other inert fillers. Reinforcing fillers, e.g. glass fibres, may also be present. The composition may contain a catalyst for free radical polymerization, e.g. an organic peroxide.
ES346795A 1966-11-07 1967-11-04 Thermosetting Ethylenically Unsaturated Ester Resin Compositions Expired ES346795A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US59227066A 1966-11-07 1966-11-07
US59225566A 1966-11-07 1966-11-07
US60560366A 1966-12-29 1966-12-29

Publications (1)

Publication Number Publication Date
ES346795A1 true ES346795A1 (en) 1969-03-16

Family

ID=27416633

Family Applications (1)

Application Number Title Priority Date Filing Date
ES346795A Expired ES346795A1 (en) 1966-11-07 1967-11-04 Thermosetting Ethylenically Unsaturated Ester Resin Compositions

Country Status (13)

Country Link
AT (1) AT288031B (en)
BE (1) BE706100A (en)
CH (1) CH496042A (en)
DE (1) DE1720515C3 (en)
DK (1) DK126384B (en)
ES (1) ES346795A1 (en)
FR (1) FR1552979A (en)
GB (1) GB1197810A (en)
IL (1) IL28844A (en)
LU (1) LU54798A1 (en)
NL (1) NL152885B (en)
NO (1) NO128405B (en)
SE (1) SE338159B (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2101018B1 (en) * 1970-08-07 1973-12-21 Dow Chemical Co
JPS5080382A (en) * 1973-11-20 1975-06-30
JPS5232989A (en) * 1975-09-09 1977-03-12 Nippon Shokubai Kagaku Kogyo Co Ltd Thermosetting resin composition
FR2407899A1 (en) * 1977-11-03 1979-06-01 Jacques Guerrini PROCESS FOR THE MANUFACTURE OF LAMINATED GLASS AND PRODUCT OBTAINED ACCORDING TO THIS PROCEDURE
EP0009055B1 (en) * 1978-09-22 1982-05-05 The Dow Chemical Company Compositions containing (a) a resin with vinyl groups and (b) a monomer mixture comprising (1) dicyclopentadiene alkenoate and (2) a vinyl aromatic monomer or dialhylphtalate
US4197390A (en) * 1979-02-22 1980-04-08 Shell Oil Company Thickenable thermosetting vinyl ester resins
NL8701618A (en) * 1987-07-09 1989-02-01
GB2235925B (en) * 1989-09-12 1992-09-30 Sericol Group Ltd Photocurable compositions
JP3190251B2 (en) * 1995-06-06 2001-07-23 太陽インキ製造株式会社 Photocurable and thermosetting resin composition for alkali-developed flexible printed wiring boards
EP1340775A1 (en) * 2002-02-28 2003-09-03 Resolution Research Nederland B.V. High functionality vinyl ester resins compatible with vinyl esters of alpha, alpha branched alkane carboxilic acids

Also Published As

Publication number Publication date
DK126384B (en) 1973-07-09
DE1720515C3 (en) 1981-02-12
DE1720515B2 (en) 1980-05-22
AT288031B (en) 1971-02-25
LU54798A1 (en) 1968-01-31
NL152885B (en) 1977-04-15
CH496042A (en) 1970-09-15
NO128405B (en) 1973-11-12
FR1552979A (en) 1969-01-10
DE1720515A1 (en) 1971-07-01
IL28844A (en) 1971-02-25
GB1197810A (en) 1970-07-08
BE706100A (en) 1968-05-06
NL6715079A (en) 1968-05-08
SE338159B (en) 1971-08-30

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