ES346795A1 - Thermosetting Ethylenically Unsaturated Ester Resin Compositions - Google Patents
Thermosetting Ethylenically Unsaturated Ester Resin CompositionsInfo
- Publication number
- ES346795A1 ES346795A1 ES346795A ES346795A ES346795A1 ES 346795 A1 ES346795 A1 ES 346795A1 ES 346795 A ES346795 A ES 346795A ES 346795 A ES346795 A ES 346795A ES 346795 A1 ES346795 A1 ES 346795A1
- Authority
- ES
- Spain
- Prior art keywords
- acid
- ethylenically unsaturated
- water
- equivalent
- acrylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/026—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from the reaction products of polyepoxides and unsaturated monocarboxylic acids, their anhydrides, halogenides or esters with low molecular weight
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
- C09J163/10—Epoxy resins modified by unsaturated compounds
Abstract
A thermosetting resin composition comprises a blend of: (A) at least 30% by wt. of an ethylenically unsaturated resin prepared by first reacting an ethylenically unsaturated monocarboxylic acid, e.g. (meth)acrylic acid or cinnamic acid, with a polyepoxide, e.g. a diglycidyl ether of bisphenol A or an epoxy novolac resin. A dicarboxylic acid anhydride is then reacted with the secondary hydroxyl groups to provide pendant half-ester groups from 0À8 to 1À2 equivalents of epoxide are used per equivalent of monocarboxylic acid and from 0À1 to 1À2 moles of dicarboxylic acid anhydride, e.g. of maleic or phthalic acid per equivalent epoxide. (B) Up to 70% by weight of a polymerizable monomer containing a >C = CH 2 group, e.g. a vinyl aromatic monomer such as styrene, a hydroxyalkyl ester of (meth)acrylic acid or of crotonic acid, alkyl esters of these acids or acrylic or methacrylic acid. Rapidly thickening compositions may be obtained by mixing: (A) a thermosetting composition as set out above (B) an oxide or hydroxide of a metal of Group II of the Periodic Table, e.g. MgO, in an amount sufficient to provide at least 0À75 equivalents per -COOH equivalent and (C) a catalytic amount of water, i.e. at least 0À25 equivalents per -COOH equivalent. Water may be provided as water of adsorption by adding clay or other inert fillers. Reinforcing fillers, e.g. glass fibres, may also be present. The composition may contain a catalyst for free radical polymerization, e.g. an organic peroxide.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US59227066A | 1966-11-07 | 1966-11-07 | |
US59225566A | 1966-11-07 | 1966-11-07 | |
US60560366A | 1966-12-29 | 1966-12-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES346795A1 true ES346795A1 (en) | 1969-03-16 |
Family
ID=27416633
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES346795A Expired ES346795A1 (en) | 1966-11-07 | 1967-11-04 | Thermosetting Ethylenically Unsaturated Ester Resin Compositions |
Country Status (13)
Country | Link |
---|---|
AT (1) | AT288031B (en) |
BE (1) | BE706100A (en) |
CH (1) | CH496042A (en) |
DE (1) | DE1720515C3 (en) |
DK (1) | DK126384B (en) |
ES (1) | ES346795A1 (en) |
FR (1) | FR1552979A (en) |
GB (1) | GB1197810A (en) |
IL (1) | IL28844A (en) |
LU (1) | LU54798A1 (en) |
NL (1) | NL152885B (en) |
NO (1) | NO128405B (en) |
SE (1) | SE338159B (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2101018B1 (en) * | 1970-08-07 | 1973-12-21 | Dow Chemical Co | |
JPS5080382A (en) * | 1973-11-20 | 1975-06-30 | ||
JPS5232989A (en) * | 1975-09-09 | 1977-03-12 | Nippon Shokubai Kagaku Kogyo Co Ltd | Thermosetting resin composition |
FR2407899A1 (en) * | 1977-11-03 | 1979-06-01 | Jacques Guerrini | PROCESS FOR THE MANUFACTURE OF LAMINATED GLASS AND PRODUCT OBTAINED ACCORDING TO THIS PROCEDURE |
EP0009055B1 (en) * | 1978-09-22 | 1982-05-05 | The Dow Chemical Company | Compositions containing (a) a resin with vinyl groups and (b) a monomer mixture comprising (1) dicyclopentadiene alkenoate and (2) a vinyl aromatic monomer or dialhylphtalate |
US4197390A (en) * | 1979-02-22 | 1980-04-08 | Shell Oil Company | Thickenable thermosetting vinyl ester resins |
NL8701618A (en) * | 1987-07-09 | 1989-02-01 | ||
GB2235925B (en) * | 1989-09-12 | 1992-09-30 | Sericol Group Ltd | Photocurable compositions |
JP3190251B2 (en) * | 1995-06-06 | 2001-07-23 | 太陽インキ製造株式会社 | Photocurable and thermosetting resin composition for alkali-developed flexible printed wiring boards |
EP1340775A1 (en) * | 2002-02-28 | 2003-09-03 | Resolution Research Nederland B.V. | High functionality vinyl ester resins compatible with vinyl esters of alpha, alpha branched alkane carboxilic acids |
-
1967
- 1967-10-26 NO NO17029467A patent/NO128405B/no unknown
- 1967-10-30 IL IL2884467A patent/IL28844A/en unknown
- 1967-11-03 DE DE1967D0054511 patent/DE1720515C3/en not_active Expired
- 1967-11-03 CH CH1540167A patent/CH496042A/en not_active IP Right Cessation
- 1967-11-04 ES ES346795A patent/ES346795A1/en not_active Expired
- 1967-11-06 FR FR1552979D patent/FR1552979A/fr not_active Expired
- 1967-11-06 SE SE1515967A patent/SE338159B/xx unknown
- 1967-11-06 LU LU54798D patent/LU54798A1/xx unknown
- 1967-11-06 DK DK551767A patent/DK126384B/en unknown
- 1967-11-06 BE BE706100D patent/BE706100A/xx not_active IP Right Cessation
- 1967-11-07 NL NL6715079A patent/NL152885B/en not_active IP Right Cessation
- 1967-11-07 AT AT1003067A patent/AT288031B/en not_active IP Right Cessation
- 1967-11-07 GB GB5964668A patent/GB1197810A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DK126384B (en) | 1973-07-09 |
DE1720515C3 (en) | 1981-02-12 |
DE1720515B2 (en) | 1980-05-22 |
AT288031B (en) | 1971-02-25 |
LU54798A1 (en) | 1968-01-31 |
NL152885B (en) | 1977-04-15 |
CH496042A (en) | 1970-09-15 |
NO128405B (en) | 1973-11-12 |
FR1552979A (en) | 1969-01-10 |
DE1720515A1 (en) | 1971-07-01 |
IL28844A (en) | 1971-02-25 |
GB1197810A (en) | 1970-07-08 |
BE706100A (en) | 1968-05-06 |
NL6715079A (en) | 1968-05-08 |
SE338159B (en) | 1971-08-30 |
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