GB1197810A - Thermosetting Ethylenically Unsaturated Ester Resin Compositions - Google Patents

Thermosetting Ethylenically Unsaturated Ester Resin Compositions

Info

Publication number
GB1197810A
GB1197810A GB5964668A GB5964668A GB1197810A GB 1197810 A GB1197810 A GB 1197810A GB 5964668 A GB5964668 A GB 5964668A GB 5964668 A GB5964668 A GB 5964668A GB 1197810 A GB1197810 A GB 1197810A
Authority
GB
United Kingdom
Prior art keywords
acid
ethylenically unsaturated
water
equivalent
acrylic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5964668A
Inventor
David Hale Swisher
David Charles Garms
Jack Wilburn Jernigan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of GB1197810A publication Critical patent/GB1197810A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/026—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from the reaction products of polyepoxides and unsaturated monocarboxylic acids, their anhydrides, halogenides or esters with low molecular weight
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • C09J163/10—Epoxy resins modified by unsaturated compounds

Abstract

1,197,810. Modified epoxy resins. DOW CHEMICAL CO. 7 Nov., 1967 [7 Nov., 1966 (2); 29 Dec., 1966], No. 59646/68. Headings C3B and C3P. A thermosetting resin composition comprises a blend of: (A) at least 30% by wt. of an ethylenically unsaturated resin prepared by first reacting an ethylenically unsaturated monocarboxylic acid, e.g. (meth)acrylic acid or cinnamic acid, with a polyepoxide, e.g. a diglycidyl ether of bisphenol A or an epoxy novolac resin. A dicarboxylic acid anhydride is then reacted with the secondary hydroxyl groups to provide pendant half-ester groups; from 0À8 to 1À2 equivalents of epoxide are used per equivalent of monocarboxylic acid and from 0À1 to 1À2 moles of dicarboxylic acid anhydride, e.g. of maleic or phthalic acid per equivalent epoxide. (B) Up to 70% by weight of a polymerizable monomer containing a >C = CH 2 group, e.g. a vinyl aromatic monomer such as styrene, a hydroxyalkyl ester of (meth)acrylic acid or of crotonic acid, alkyl esters of these acids or acrylic or methacrylic acid. Rapidly thickening compositions may be obtained by mixing: (A) a thermosetting composition as set out above; (B) an oxide or hydroxide of a metal of Group II of the Periodic Table, e.g. MgO, in an amount sufficient to provide at least 0À75 equivalents per -COOH equivalent; and (C) a catalytic amount of water, i.e. at least 0À25 equivalents per -COOH equivalent. Water may be provided as water of adsorption by adding clay or other inert fillers. Reinforcing fillers, e.g. glass fibres, may also be present. The composition may contain a catalyst for free radical polymerization, e.g. an organic peroxide.
GB5964668A 1966-11-07 1967-11-07 Thermosetting Ethylenically Unsaturated Ester Resin Compositions Expired GB1197810A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US59227066A 1966-11-07 1966-11-07
US59225566A 1966-11-07 1966-11-07
US60560366A 1966-12-29 1966-12-29

Publications (1)

Publication Number Publication Date
GB1197810A true GB1197810A (en) 1970-07-08

Family

ID=27416633

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5964668A Expired GB1197810A (en) 1966-11-07 1967-11-07 Thermosetting Ethylenically Unsaturated Ester Resin Compositions

Country Status (13)

Country Link
AT (1) AT288031B (en)
BE (1) BE706100A (en)
CH (1) CH496042A (en)
DE (1) DE1720515C3 (en)
DK (1) DK126384B (en)
ES (1) ES346795A1 (en)
FR (1) FR1552979A (en)
GB (1) GB1197810A (en)
IL (1) IL28844A (en)
LU (1) LU54798A1 (en)
NL (1) NL152885B (en)
NO (1) NO128405B (en)
SE (1) SE338159B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0015029A1 (en) * 1979-02-22 1980-09-03 Shell Internationale Researchmaatschappij B.V. Vinyl ester resin composition thickened by a group II metal oxide or hydroxide
EP0299565A2 (en) * 1987-07-09 1989-01-18 Akzo N.V. Optical products made from a thermosetting copolymer having an index of refraction nD20 - 1,52
GB2235925A (en) * 1989-09-12 1991-03-20 Sericol Group Ltd Photocurable compositions suitable for use in solder mask inks
GB2301826A (en) * 1995-06-06 1996-12-18 Taiyo Ink Mfg Co Ltd Photocurable thermoplastic resin composition developable with aqueous alkali

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2101018B1 (en) * 1970-08-07 1973-12-21 Dow Chemical Co
JPS5080382A (en) * 1973-11-20 1975-06-30
JPS5232989A (en) * 1975-09-09 1977-03-12 Nippon Shokubai Kagaku Kogyo Co Ltd Thermosetting resin composition
FR2407899A1 (en) * 1977-11-03 1979-06-01 Jacques Guerrini PROCESS FOR THE MANUFACTURE OF LAMINATED GLASS AND PRODUCT OBTAINED ACCORDING TO THIS PROCEDURE
DE2861785D1 (en) * 1978-09-22 1982-06-24 Dow Chemical Co Compositions containing (a) a resin with vinyl groups and (b) a monomer mixture comprising (1) dicyclopentadiene alkenoate and (2) a vinyl aromatic monomer or dialhylphtalate
EP1340775A1 (en) * 2002-02-28 2003-09-03 Resolution Research Nederland B.V. High functionality vinyl ester resins compatible with vinyl esters of alpha, alpha branched alkane carboxilic acids

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0015029A1 (en) * 1979-02-22 1980-09-03 Shell Internationale Researchmaatschappij B.V. Vinyl ester resin composition thickened by a group II metal oxide or hydroxide
EP0299565A2 (en) * 1987-07-09 1989-01-18 Akzo N.V. Optical products made from a thermosetting copolymer having an index of refraction nD20 - 1,52
EP0299565A3 (en) * 1987-07-09 1989-02-15 Akzo N.V. Optical products made from a thermosetting copolymer having an index of refraction nd20 - 1,52
GB2235925A (en) * 1989-09-12 1991-03-20 Sericol Group Ltd Photocurable compositions suitable for use in solder mask inks
GB2235925B (en) * 1989-09-12 1992-09-30 Sericol Group Ltd Photocurable compositions
GB2301826A (en) * 1995-06-06 1996-12-18 Taiyo Ink Mfg Co Ltd Photocurable thermoplastic resin composition developable with aqueous alkali
GB2301826B (en) * 1995-06-06 1999-07-14 Taiyo Ink Mfg Co Ltd Photocurable, thermosetting resin composition developable with aqueous alkali solution

Also Published As

Publication number Publication date
CH496042A (en) 1970-09-15
DK126384B (en) 1973-07-09
IL28844A (en) 1971-02-25
DE1720515B2 (en) 1980-05-22
NO128405B (en) 1973-11-12
BE706100A (en) 1968-05-06
FR1552979A (en) 1969-01-10
ES346795A1 (en) 1969-03-16
DE1720515C3 (en) 1981-02-12
AT288031B (en) 1971-02-25
NL152885B (en) 1977-04-15
LU54798A1 (en) 1968-01-31
SE338159B (en) 1971-08-30
DE1720515A1 (en) 1971-07-01
NL6715079A (en) 1968-05-08

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years