CN105503113A - Energy-saving environment-friendly water-permeable autoclaved brick and preparation method thereof - Google Patents

Energy-saving environment-friendly water-permeable autoclaved brick and preparation method thereof Download PDF

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Publication number
CN105503113A
CN105503113A CN201510952036.4A CN201510952036A CN105503113A CN 105503113 A CN105503113 A CN 105503113A CN 201510952036 A CN201510952036 A CN 201510952036A CN 105503113 A CN105503113 A CN 105503113A
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parts
permeable
water
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energy
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CN105503113B (en
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乔生艮
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Xuzhou chuangjie new building materials Co.,Ltd.
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乔生艮
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/142Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
    • C04B28/144Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being a flue gas desulfurization product
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction

Abstract

An energy-saving environment-friendly water-permeable autoclaved brick is prepared from, by weight, 38-44 parts of fly ash, 12-16 parts of desulfurization gypsum, 12-16 parts of oil shale waste residues, 8-11 parts of electrolytic manganese residues, 7-9 parts of ordinary Portland cement, 3-4 parts of flint clay, 3-4 parts of titanium nitride, 4-5 parts of medical stone, 1-1.5 parts of chopped carbon fiber, 3-3.5 parts of basalt fiber, 0.5-0.8 part of glycol distearate, 0.7-0.8 part of Dioctyl sodium sulfosuccinate, 3-4 parts of dextrin, 1.5-2 parts of lithium chromate, 0.3-0.4 part of cocamidopropyl betaine and 8-10 parts of water. The energy-saving environment-friendly water-permeable autoclaved brick is prepared by utilizing various types of industrial waste residues and through a special formula and a special process, has an excellent permeation coefficient and an excellent water-retaining property, and has quite outstanding compressive strength.

Description

Permeable autoclaved brick of a kind of energy-conserving and environment-protective and preparation method thereof
Technical field
The invention belongs to building material technical field, be specially permeable autoclaved brick of a kind of energy-conserving and environment-protective and preparation method thereof.
Background technology
Water-permeable brick has good water permeate, water-retentivity and higher physical strength, and product is layed in the ground of the public place such as square, road, can reduce city water resource and run off, regulates urban climate, beautifying urban environment, reduction city noise.Because water-permeable brick had both had good water-permeable, having again ornamental, can also prevent erosion, protection of the environment, therefore be widely used at present in urban road, is also the popular industry of a lot of investor's investment at present.
Concrete permeable brick: material is river sand, cement, water, then the concrete product adding a certain proportion of impregnating agent and make.This product is compared with resin water-permeable brick, ceramic water-permeable brick, gap water-permeable brick, and production cost is low, and Making programme is simple, easy to operate.Be widely used in expressway, airport runways, driveway, the scopes such as walkway, square and garden architecture.
Colored stone epoxy entire body water-permeable brick: material aggregate is that natural color stone and import modified epoxy glue together, shape through special process, this product can be prefabricated, all right in-situ casting, and various artistic character/image and color lines can be risked, to a kind of pleasing impression of people.Be mainly used in garden landscape engineering and Deluxe villa community.
Colored stone composite concrete permeable brick: material surface layer is that natural colorful grouan, marble and modified epoxy glue together, again with the repressed combined shaping of underlying polymer fiber multihole concrete, this product surface layer is magnificent, natural colour, have the texture general with stone material, after concrete compound, intensity higher than stone material and cost a little more than concrete permeable brick, and price is 1/2 of stone material floor tile, be a kind of economy, high-grade flooring products.Be mainly used in the places such as luxurious commercial zone, large-scale square, parking lot, hotel and Deluxe villa community.
Polymer fiber concrete permeable brick: material is granite aggregate, high-strength cement and cement polymer toughener, and fusion polypropylene fibre, feeding proportioning are tight, through press forming after stirring, be mainly used in the mating formation of the place such as pavement, square, parking lot of municipal administration, important engineering and residential quarters.
Summary of the invention
The object of the invention is to overcome deficiency of the prior art, provides permeable autoclaved brick of a kind of energy-conserving and environment-protective and preparation method thereof.
The permeable autoclaved brick of energy-conserving and environment-protective of the present invention, be made up of the component of following parts by weight: 38 ~ 44 parts, flyash, desulfurated plaster 12 ~ 16 parts, oil shale residues 12 ~ 16 parts, electrolytic manganese residues 8 ~ 11 parts, ordinary Portland cement 7 ~ 9 parts, flint clay 3 ~ 4 parts, titanium nitride 3 ~ 4 parts, medical stone 4 ~ 5 parts, chopped carbon fiber 1 ~ 1.5 part, basalt fibre 3 ~ 3.5 parts, Unister E 275 0.5 ~ 0.8 part, two fourth sodium dioctyl sulfo 0.7 ~ 0.8 part, 3 ~ 4 parts, dextrin, lithium chromate 1.5 ~ 2 parts, cocamidopropyl betaine 0.3 ~ 0.4 part, 8 ~ 10 parts, water.
As optimization, the permeable autoclaved brick of these energy-conserving and environment-protective, is made up of the raw material of following parts by weight: 41 parts, flyash, desulfurated plaster 13 parts, oil shale residues 13 parts, electrolytic manganese residues 10 parts, ordinary Portland cement 8 parts, flint clay 3.5 parts, titanium nitride 3.5 parts, medical stone 4.5 parts, chopped carbon fiber 1.2 parts, basalt fibre 3.3 parts, Unister E 275 0.6 part, two fourth sodium dioctyl sulfo 0.7 part, 3.5 parts, dextrin, lithium chromate 1.6 parts, cocamidopropyl betaine 0.35 part, 9 parts, water.
As optimization, the permeable autoclaved brick of energy-conserving and environment-protective, flyash powder fineness is 325 orders, desulfurated plaster powder fineness is 250 orders, oil shale residues powder fineness is 250 orders, electrolytic manganese residues powder fineness is 250 orders, flint clay powder fineness is 200 orders, nitride powder fineness is 400 orders, medical stone powder fineness is 200 orders.Can be ground by Shanghai Jia Pu auspicious company limited HGM100 tri-ring middling speed ultra-fine micropowder.
Prepare the method for the permeable autoclaved brick of these energy-conserving and environment-protective, comprise the following steps:
A, by the flyash of described parts by weight, desulfurated plaster, oil shale residues, electrolytic manganese residues, ordinary Portland cement, flint clay, titanium nitride, medical stone; Join stirrer to stir;
B, by the chopped carbon fiber of described parts by weight, basalt fibre, Unister E 275, two fourth sodium dioctyl sulfo, dextrin, lithium chromate, join successively in the mixture in step a, stir;
C, by the cocamidopropyl betaine of described parts by weight, water, after mixing, join in the mixture in step b, stir;
D, by the mixture of step c under the pressure of 20MPa, compacting 5 ~ 10s, static press-forming; Then be transported in autoclave, steam pressure temperature 180 DEG C, pressure 0.8 ~ 1.2MPa, steam pressure 8 ~ 12h, goes out still.
The permeable autoclaved brick of energy-conserving and environment-protective of the present invention, reasonable employment various industrial waste residues, is prepared from by special composition and engineering, has excellent coefficient of permeability and water-retentivity, has very outstanding ultimate compression strength simultaneously.The ultimate compression strength that water-permeable brick is good, water-permeable and water-retentivity, product is layed in the ground of the public place such as square, road, can reduce city water resource and run off, regulates urban climate, beautifying urban environment, reduction city noise.
Performance measurement: compressive strength determination: adopt HD-504A-2 type compressive strength instrument to measure intensity.Accurately measure water-permeable brick length data and input computer.With 2 × 10 2n/s uniform load, reads the force value F (kN) during the disposable destruction of sample, calculates resistance to compression degree R (MPa).In R=P/A formula: A is carrying area, cm 2.
Water permeability measures: water permeable device is made up of dropping bottle, dropper, water receiving bottle, iron stand.Sample is fixed on iron stand, and dropper drips to specimen surface and namely starts timing, and when namely the infiltration of sample lower surface stops timing, the time difference is △ t (s), calculates coefficient of permeability K (cm/s); K=H/ △ t, in formula: H is specimen height, cm.
Water retention property measures: by sample in 110 ± 5 DEG C of dryings, every 2h sampling and measuring quality, until the difference <0.1% of twice continuously measured, weigh dry sample mass m1 (g).Sample is vertically put into tank, injects 20 ± l0 DEG C of distilled water, make the water surface exceed sample 20mm, 12h samples, and gently wipes surface water, weigh immediately with wet cloth, is the quality m2 (g) of sample water suction 12h, calculates water retention coefficient.B=(m2-m1)/V; In formula: B is water retention coefficient, g/cm3; V is the volume of sample, cm3.Different group test result is in table 1.
Embodiment
The invention will be further described for embodiment plan given below; but can not be interpreted as it is limiting the scope of the invention; those skilled in the art to nonessential improvement and adjustment more of the present invention, still belong to protection scope of the present invention according to content of the present invention.
Embodiment 1:a, by 41 kilograms, 325 order flyash, 250 order desulfurated plaster 13 kilograms, 250 order oil shale residues 13 kilograms, 250 order electrolytic manganese residues 10 kilograms, ordinary Portland cement 8 kilograms, 200 order flint clay 3.5 kilograms, 400 order titanium nitride 3.5 kilograms, 200 order medical stone 4.5 kilograms; Join stirrer to stir;
B, by length 5mm chopped carbon fiber 1.2 kilograms, length 6mm basalt fibre 3.3 kilograms, Unister E 275 0.6 kilogram, two fourth sodium dioctyl sulfo 0.7 kilogram, 3.5 kilograms, dextrin, lithium chromate 1.6 kilograms, join successively in the mixture in step a, stir;
C, by cocamidopropyl betaine 0.35 kilogram, 9 kilograms, water, after mixing, join in the mixture in step b, stir;
D, by the mixture of step c under the pressure of 20MPa, compacting 5 ~ 10s, static press-forming; Then be transported in autoclave, steam pressure temperature 180 DEG C, pressure 0.8 ~ 1.2MPa, steam pressure 8 ~ 12h, goes out still.
Embodiment 2:a, by 38 kilograms, 325 order flyash, 250 order desulfurated plaster 12 kilograms, 250 order oil shale residues 12 kilograms, 250 order electrolytic manganese residues 8 kilograms, ordinary Portland cement 7 kilograms, 200 order flint clay 3 kilograms, 400 order titanium nitride 3 kilograms, 200 order medical stone 4 kilograms; Join stirrer to stir;
B, by 5mm chopped carbon fiber 1 kilogram, 6mm basalt fibre 3 kilograms, Unister E 275 0.5 kilogram, two fourth sodium dioctyl sulfo 0.7 kilogram, 3 kilograms, dextrin, lithium chromate 1.5 kilograms, join successively in the mixture in step a, stir;
C, by cocamidopropyl betaine 0.3 kilogram, 8 kilograms, water, after mixing, join in the mixture in step b, stir;
D, by the mixture of step c under the pressure of 20MPa, compacting 5 ~ 10s, static press-forming; Then be transported in autoclave, steam pressure temperature 180 DEG C, pressure 0.8 ~ 1.2MPa, steam pressure 8 ~ 12h, goes out still.
Embodiment 3:a, by 44 kilograms, 325 order flyash, 250 order desulfurated plaster 16 kilograms, 250 order oil shale residues 16 kilograms, 250 order electrolytic manganese residues 11 kilograms, ordinary Portland cement 9 kilograms, 200 order flint clay 4 kilograms, 400 order titanium nitride 4 kilograms, 200 order medical stone 5 kilograms; Join stirrer to stir;
B, by 5mm chopped carbon fiber 1.5 kilograms, 6mm basalt fibre 3.5 kilograms, Unister E 275 0.8 kilogram, two fourth sodium dioctyl sulfo 0.8 kilogram, 4 kilograms, dextrin, lithium chromate 2 kilograms, join successively in the mixture in step a, stir;
C, by cocamidopropyl betaine 0.4 kilogram, 10 kilograms, water, after mixing, join in the mixture in step b, stir;
D, by the mixture of step c under the pressure of 20MPa, compacting 5 ~ 10s, static press-forming; Then be transported in autoclave, steam pressure temperature 180 DEG C, pressure 0.8 ~ 1.2MPa, steam pressure 8 ~ 12h, goes out still.

Claims (4)

1. the permeable autoclaved brick of energy-conserving and environment-protective, it is characterized in that being made up of the component of following parts by weight: 38 ~ 44 parts, flyash, desulfurated plaster 12 ~ 16 parts, oil shale residues 12 ~ 16 parts, electrolytic manganese residues 8 ~ 11 parts, ordinary Portland cement 7 ~ 9 parts, flint clay 3 ~ 4 parts, titanium nitride 3 ~ 4 parts, medical stone 4 ~ 5 parts, chopped carbon fiber 1 ~ 1.5 part, basalt fibre 3 ~ 3.5 parts, Unister E 275 0.5 ~ 0.8 part, two fourth sodium dioctyl sulfo 0.7 ~ 0.8 part, 3 ~ 4 parts, dextrin, lithium chromate 1.5 ~ 2 parts, cocamidopropyl betaine 0.3 ~ 0.4 part, 8 ~ 10 parts, water.
2. the permeable autoclaved brick of energy-conserving and environment-protective according to claim 1, is characterized in that being made up of the raw material of following parts by weight: 41 parts, flyash, desulfurated plaster 13 parts, oil shale residues 13 parts, electrolytic manganese residues 10 parts, ordinary Portland cement 8 parts, flint clay 3.5 parts, titanium nitride 3.5 parts, medical stone 4.5 parts, chopped carbon fiber 1.2 parts, basalt fibre 3.3 parts, Unister E 275 0.6 part, two fourth sodium dioctyl sulfo 0.7 part, 3.5 parts, dextrin, lithium chromate 1.6 parts, cocamidopropyl betaine 0.35 part, 9 parts, water.
3. the permeable autoclaved brick of energy-conserving and environment-protective according to claim 1, is characterized in that described flyash powder fineness is 325 orders, desulfurated plaster powder fineness is 250 orders, oil shale residues powder fineness is 250 orders, electrolytic manganese residues powder fineness is 250 orders, flint clay powder fineness is 200 orders, nitride powder fineness is 400 orders, medical stone powder fineness is 200 orders.
4. prepare a method for the permeable autoclaved brick of energy-conserving and environment-protective described in above claim, it is characterized in that comprising the following steps:
A, by the flyash of described parts by weight, desulfurated plaster, oil shale residues, electrolytic manganese residues, ordinary Portland cement, flint clay, titanium nitride, medical stone, join stirrer and stir;
B, by the chopped carbon fiber of described parts by weight, basalt fibre, Unister E 275, two fourth sodium dioctyl sulfo, dextrin, lithium chromate, join successively in the mixture in step a, stir;
C, by the cocamidopropyl betaine of described parts by weight, water, after mixing, join in the mixture in step b, stir;
D, by the mixture of step c under the pressure of 20MPa, compacting 5 ~ 10s, static press-forming; Then be transported in autoclave, steam pressure temperature 180 DEG C, pressure 0.8 ~ 1.2MPa, steam pressure 8 ~ 12h, goes out still.
CN201510952036.4A 2015-12-17 2015-12-17 A kind of permeable steam-pressing brisk of energy conservation and environmental protection and preparation method thereof Active CN105503113B (en)

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CN109781316A (en) * 2019-03-05 2019-05-21 齐鲁工业大学 A kind of preparation method of cellulose base pliable pressure sensory device

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