CN106187030A - Luminous phosphorous sunflower straw extrusion granule of inhaling is prepared porous and is catchmented sponge brick method - Google Patents

Luminous phosphorous sunflower straw extrusion granule of inhaling is prepared porous and is catchmented sponge brick method Download PDF

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Publication number
CN106187030A
CN106187030A CN201610518571.3A CN201610518571A CN106187030A CN 106187030 A CN106187030 A CN 106187030A CN 201610518571 A CN201610518571 A CN 201610518571A CN 106187030 A CN106187030 A CN 106187030A
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sponge brick
porous
particle diameter
sunflower straw
straw extrusion
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CN106187030B (en
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郭志东
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Shandong University of Technology
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Shandong University of Technology
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • C04B18/027Lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/08Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding porous substances
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C11/00Details of pavings
    • E01C11/22Gutters; Kerbs ; Surface drainage of streets, roads or like traffic areas
    • E01C11/224Surface drainage of streets
    • E01C11/225Paving specially adapted for through-the-surfacing drainage, e.g. perforated, porous; Preformed paving elements comprising, or adapted to form, passageways for carrying off drainage
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C5/00Pavings made of prefabricated single units
    • E01C5/04Pavings made of prefabricated single units made of bricks
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80Optical properties, e.g. transparency or reflexibility
    • C04B2111/807Luminescent or fluorescent materials

Abstract

nullThe present invention provides luminous phosphorous sunflower straw extrusion granule of inhaling to prepare porous and catchment sponge brick method,Comprise the following steps: porous is catchmented the dispensing of sponge brick: by cement 15~20wt%、Particle diameter is 250~450 m sunflower straw extrusion granules 45~65wt%、The sodium silicate 5~15wt% of modulus 3.2~3.5、Particle diameter is 100~200 m calcium oxide 3~5wt%、Glass fibre 5~10wt%、High hydrophilous resin fiber 0.5~5.0wt% and particle diameter 100~200 m Maifanitum 10~30wt% sampling mix homogeneously,Size mixing with the ratio of mud of 0.4~0.7,Add the aluminium powder cream that compound gross weight is 0.2~1.5%,Aluminium powder cream hydration reaction generates bubble,Form porous and expand the serosity of water suction,Serosity stirs in the die trial pouring sponge brick press into,Strike off、Compacting、The demoulding、Dry,Make sponge brick.

Description

Luminous phosphorous sunflower straw extrusion granule of inhaling is prepared porous and is catchmented sponge brick method
Technical field
The present invention relates to luminous phosphorous sunflower straw extrusion granule of inhaling prepare porous and catchment sponge brick method, belong to material Technology is led.
Background technology
Due to EI Nino and La Nina Phenomenon, there is extreme change in the weather of China, and rainfall distributed pole is uneven, south North drought and waterlogging are uneven, and in same area, in 1 year, rainfall is the most unequal, and hydropenia has restricted expanding economy and the people Life, the existing precipitation of Appropriate application, road surface, community, road, the effective precipitation in public leisure square are rationally collected, store, Utilize, alleviate drought and water shortage season with water, the thermal capacity of water is big, can absorb heat also can heat release, improve miniclimate.
Summary of the invention
Sunflower straw be mainly composed of cellulose, hemicellulose, modified sunflower straw can be adsorbed in water Phosphate anion, phosphate anion is the key factor causing water eutrophication, and bentonite is modifying agent and strong adsorbent, to water In heavy metal ion also have adsorption, heavy metal ion adsorbed in water of Maifanitum, the substantially sun in Maifanitum Ion swaps with the heavy metal cation in water, has adsorbed the heavy metal cation in water through ion exchange Maifanitum, The pH value of regulation water, cement is that the porous sponge brick that catchments increases mechanical strength and cementation, the resin of polyvinyl alcohol height water suction Fiber is strong water absorbent, uses dilatant slurry, reduces the density of serosity, and a catchment face of sponge brick of the porous made is dovetail Channel-shaped, porous catchment sponge brick absorb moisture enter dovetail groove, flowed into collector pipe again by the effect of gravity, collector pipe is by porous The sponge brick that catchments links together, in rainwater catchment to collecting-tank.
Its technical scheme is: luminous phosphorous sunflower straw extrusion granule of inhaling is prepared porous and catchmented sponge brick method, first Step, porous are catchmented the dispensing of sponge brick: be sunflower straw extrusion modified for 250~450 m by cement 15~20wt%, particle diameter Granule 45~65wt%, the sodium silicate 5~15wt% of modulus 3.2~3.5, particle diameter are 100~200 m calcium oxide 3~5wt%, glass The Maifanitum 10~30wt% of glass fiber 3~10wt%, High hydrophilous resin fiber 0.5~5.0wt% and particle diameter 100~200 m takes Sample, the percentage by weight sum of above each component is 100%;
Second step, porous catchment sponge brick expand water suction serosity preparation: by the first step percentage by weight sample, first by particle diameter The sunflower straw extrusion granule being modified for 250~450 m is put in feed bin, elevator send into distributing device, and distributing device will change Property sunflower straw extrusion granule be evenly distributed on governing belt balance, spray thrower is by uniform for the sodium silicate of modulus 3.2~3.5 It is sprayed at the outer surface of the sunflower straw extrusion granule of modification, enters internal coiling drum agitation device, silicic acid with governing belt balance Sodium is inorganic bond, is hydrophilic, and cohesive force is strong, intensity is higher, acid resistance, heat-resist, and hydrophilicity does not affect viscous Knot property, compound be cement 15~20wt%, particle diameter be 250~450 m sunflower straw extrusion granule 45~65wt%, moduluses Sodium silicate 5~15wt%, the particle diameter of 3.2~3.5 are 100~200 m calcium oxide 3~5wt%, glass fibre 3~10wt%, high suction Water-resin fiber 0.5~5.0wt% and the Maifanitum 10~30wt% of particle diameter 100~200 m, by compound with 0.4~0.7 water Gray scale is sized mixing, and ash is compound, and adding compound gross weight is 0.2~one in the aluminium powder cream of 1.5% or aluminum sulfate, Hydration reaction generates bubble, forms porous and expands the serosity of water suction, reduces the weight of sponge brick, and polyvinyl alcohol High hydrophilous resin is fine Dimension has extremely strong water absorption, and the sponge brick comprcssive strength after water suction is constant;
3rd step, porous are catchmented the preparation of sponge brick: the expansion water suction serosity prepared by second step stirs and pours sponge brick into In the die trial of press, by 1.2~2.0:1 volume ratio compactings, ratio 1.2~2.0 is the volume before compacting, and ratio 1 is compacting After volume, through striking off, suppressing, the demoulding, dry, porous one face of sponge brick of catchmenting is provided with multiple groove, by solar-electricity Pond plate and LED light emitting diode are placed in groove, and the solar energy of absorption is converted to electrical power storage by solar panel, LED light emitting diode is luminous by the effect contacting of external force, as lighting installation, uses multiple flexible color, in module Can also implant different music, by wireless network regular update, when external force disappears, contact disconnects, and LED light emitting diode puts out Going out, catchment another face of sponge brick of porous is provided with dovetail channel-shaped, and the porous moisture that sponge brick absorbs that catchments enters in dovetail groove, Collector pipe embeds in dovetail groove, and rainwater catchments the collecting of sponge brick through porous, enters in dovetail groove, is flowed by the effect of gravity again Entering collector pipe, the collector pipe sponge brick that single porous catchmented links together, and the rainwater that collector pipe collects enters in collecting-tank.
The preparation of modified sunflower straw extrusion granule: first sunflower straw is pulverized and make particle diameter 200~400 m Grain, then by sunflower straw powder, dimethylformamide, epoxychloropropane and dimethylamine agueous solution by 1~3:12.5~15:8~10: 12~18 sampling mix homogeneously, put into retort, react 3~8 hours at 80~120 DEG C, clean, be dried, form modification Sunflower straw powder, adds particle diameter 100~200 m bentonite, and both by weight percentage 70~85wt%:15~35wt% take Sample mix homogeneously, the percentage by weight sum of two kinds of components is 100%, and compound is pressed the ratio of mud 0.1~0.3 preparation, compound For modified sunflower straw granular powder and bentonite, ash is compound, and compound is put in screw mixer and stirred, then Enter pelletize in extruding granulator, make sunflower straw extrusion spheroidal particle modified for particle diameter 250~450 m after drying, to Day, certain herbaceous plants with big flowers straw was mainly composed of cellulose, hemicellulose, lignin and ash, and content of cellulose is high, and toughness is strong, tension, anti-folding Property strong, modified sunflower straw can adsorb the phosphate anion in water, and phosphate anion is the pass causing water eutrophication The key factor, moreover it is possible to the absorption to the heavy metal ion in radioelement and water, bentonite is modifying agent and strong adsorbent, to water In heavy metal ion also have an adsorption, material component is different, and modified chemical property is the most different.
Heavy metal ion adsorbed in water of Maifanitum, the substantially cation in Maifanitum and the heavy metal sun in water Ion swaps, and has adsorbed the heavy metal cation in water, the pH value of regulation water through ion exchange Maifanitum.
Calcium oxide hydration reaction, produces substantial amounts of heat, and it is as a form of gel for generating calcium hydroxide, with silicon oxide, aluminium oxide life Becoming calcium silicates, calcium oxide is activator, the activity of excited cement.
Glass fibre is hollow type, can increase the mechanical tenacity of sponge brick, moreover it is possible to makes sponge brick be formed and multiple intersects in length and breadth Micropore, micropore has stronger sound absorption function.
A rainwater part for accumulation is pooled in collecting-tank by the porous sponge brick that catchments by collector pipe, and another part penetrates into In soil, increasing soil water content, in summer high-temperature season, the heat on surface can also be transmitted to by the porous sponge brick that catchments In soil, reducing the temperature on sponge tile floor surface, the thermal capacity of water is big, and can absorb heat also can heat release.
The present invention has the following advantages.
1, preparation Materials Inorganic environment-friendly materials used by sponge brick, do not result in harm, the recyclable energy of sponge brick to environment Secondary uses.
2, the resin fibre of the polyvinyl alcohol height water suction of preparation sponge brick is strong water absorbent, can absorb the water on sponge brick surface Divide and enter inside, when reaching some, fallen to entering in collector pipe by the effect of gravity.
3, in compound, add aluminium powder cream, form the serosity that porous expands, reduce the density of serosity.
4, sunflower straw is mainly composed of cellulose, hemicellulose and lignin, and content of cellulose is high, modified to day Certain herbaceous plants with big flowers straw can adsorb the phosphate anion in water, and phosphate anion is the key factor causing water eutrophication.
Accompanying drawing explanation
Fig. 1 is the axle geodesic structure schematic diagram of the sea brick of the embodiment of the present invention.
Fig. 2 is the end TV structure schematic diagram of the sea brick of the embodiment of the present invention.
Fig. 3 is the structural representation that the monolithic sponge brick of the embodiment of the present invention is linked together by collector pipe.
Wherein in figure 1, sponge brick 2, dovetail groove 3, collector pipe 4, LED light emitting diode 5, solar panel.
Detailed description of the invention
Embodiment.
In embodiment as shown in Figures 1 to 3, luminous phosphorous sunflower straw extrusion granule of inhaling is prepared porous and is catchmented sponge Brick method, the first step, the preparation of modified sunflower straw extrusion granule: first sunflower straw is pulverized and make particle diameter 200 m Grain powder, presses 1:12.5:10:15 sampling mixing by sunflower straw powder, dimethylformamide, epoxychloropropane and dimethylamine agueous solution Uniformly, put into retort, react 4 hours at 120 DEG C, clean, be dried, form modified sunflower straw powder, add grain Footpath 100 m bentonite, both 85wt%:15wt% by weight percentage sample mix homogeneously, are joined by the ratio of mud 0.15 by compound System, compound is modified sunflower straw granular powder and bentonite, and compound is put in screw mixer and stirred, then enters Enter pelletize in extruding granulator, make particle diameter 450 m sunflower straw extrusion spheroidal particle after drying.
Second step, porous are catchmented the dispensing of sponge brick: cement 15wt%, particle diameter are sunflower straw extrusion modified for 450 m Granule 50wt%, the sodium silicate 10wt% of modulus 3.4, particle diameter are 150 m calcium oxide 3wt%, glass fibre 7wt%, High hydrophilous resin Fiber 3.0wt% and particle diameter are 100 m Maifanitum 12wt%.
3rd step, porous catchment sponge brick expand water suction serosity preparation: by the first step percentage by weight sample, first will The sunflower straw extrusion granule that particle diameter is modified for 450 m is put in feed bin, elevator send into distributing device, and distributing device is by modification Sunflower straw extrusion granule be evenly distributed on governing belt balance, the sodium silicate of modulus 3.4 is uniformly sprayed at by spray thrower The outer surface of modified sunflower straw extrusion granule, enters internal coiling drum agitation device with governing belt balance, by compound with The ratio of mud of 0.4 is sized mixing, and adds the aluminium powder cream that compound gross weight is 0.8%, and hydration reaction generates bubble, forms porous swollen Swollen serosity, reduces the weight of sponge brick, and polyvinyl alcohol High hydrophilous resin fiber has extremely strong water absorption, the sponge after water suction Brick comprcssive strength is constant, glass fibre increase sponge brick mechanical tenacity, moreover it is possible to make sponge brick formed multiple intersect in length and breadth micro- Hole, micropore has the function of sound-absorbing.
4th step, porous are catchmented the preparation of sponge brick: the expansion water suction serosity prepared by second step stirs and pours sea into In the die trial of continuous brick press, suppress by the volume ratio of 1.5:1, through striking off, suppressing, the demoulding, dry, make porous and catchment sponge Brick 1, porous 1 one faces of sponge brick of catchmenting are provided with groove, solar panel 5 and LED light emitting diode 4 are placed in groove In, the solar energy of absorption is converted to electrical power storage by solar panel 5, and LED light emitting diode 4 is acted on by external force Contact point connects luminescence, as lighting installation, uses multiple flexible color, can also implant different music, pass through in module Wireless network regular update, when external force disappears, contact disconnects, and LED light emitting diode 4 extinguishes, and porous is catchmented another of sponge brick 1 Individual face is provided with dovetail groove 2 shape, and the porous moisture that sponge brick 1 absorbs that catchments enters in dovetail groove 2, is installed with collection in dovetail groove 2 Water pipe 3, rainwater catchments the collecting of sponge brick 1 through porous, enters in dovetail groove 2, is flowed into collector pipe 3 again by the effect of gravity, The collector pipe 3 sponge brick 1 that single porous catchmented links together, and the rainwater that collector pipe 3 collects enters in collecting-tank, Jing Guochen Form sediment, filter, reuse.
The above, be only presently preferred embodiments of the present invention, is not the restriction that the present invention makees other form, appoints What those skilled in the art changed possibly also with the technology contents of the disclosure above or be modified as equivalent variations etc. Effect embodiment, every without departing from technical solution of the present invention content, according to the technical spirit of type of the present invention, above example is made Any simple modification, equivalent variations and remodeling, still fall within the protection domain of type technical scheme of the present invention.

Claims (1)

1. luminous phosphorous sunflower straw extrusion granule of inhaling is prepared porous and is catchmented sponge brick method, comprises the following steps:
The first step, porous are catchmented the dispensing of sponge brick: be Helianthi modified for 250~450 m by cement 15~20wt%, particle diameter Straw extrusion granule 45~65wt%, the sodium silicate 5~15wt% of modulus 3.2~3.5, particle diameter be 100~200 m calcium oxide 3~ 5wt%, glass fibre 3~10wt%, High hydrophilous resin fiber 0.5~5.0wt% and the Maifanitum 10 of particle diameter 100~200 m~ 30wt% samples, and the percentage by weight sum of above each component is 100%;
Second step, porous catchment sponge brick expand water suction serosity preparation: by the first step percentage by weight sample, first by particle diameter The sunflower straw extrusion granule being modified for 250~450 m is put in feed bin, elevator send into distributing device, and distributing device will change Property sunflower straw extrusion granule be evenly distributed on governing belt balance, spray thrower is by uniform for the sodium silicate of modulus 3.2~3.5 Being sprayed at the outer surface of the sunflower straw extrusion granule of modification, modified sunflower straw extrusion granule enters with governing belt balance Enter internal coiling drum agitation device, compound sized mixing with the ratio of mud of 0.4~0.7, add compound gross weight be 0.2~ The aluminium powder cream of 1.5% stirs, and aluminium powder cream hydration reaction generates bubble, forms porous and expands the serosity of water suction;
3rd step, porous are catchmented the preparation of sponge brick: the expansion water suction serosity prepared by second step stirs and pours sponge brick into In the die trial of press, through striking off, suppressing, the demoulding, drying, make porous and catchment sponge brick (1), porous is catchmented sponge brick (1) One face is provided with groove, solar panel (5) and LED light emitting diode (4) is placed in groove, solar panel (5) solar energy of absorption being converted to electrical power storage, LED light emitting diode (4) is connected luminescence by the effect of external force, makees For lighting installation, use multiple flexible color, module can also be implanted different music, by wireless network regular update, when When external force disappears, contact disconnects, and LED light emitting diode (4) extinguishes, and catchment another face of sponge brick (1) of porous is provided with dovetail Groove (2) shape, collector pipe (3) embeds in dovetail groove (2), and rainwater catchments the collecting of sponge brick (1) through porous, enters dovetail groove (2) in, then flowing into collector pipe (3), collector pipe (3) the sponge brick (1) that single porous catchmented links together, and collector pipe (3) converges The rainwater of collection enters in collecting-tank.
CN201610518571.3A 2016-07-05 2016-07-05 It is luminous to inhale the phosphorous sunflower straw extrusion porous sponge brick method of catchmenting of particle preparation Active CN106187030B (en)

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Publication number Priority date Publication date Assignee Title
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CN104452525A (en) * 2014-11-18 2015-03-25 浙江大学宁波理工学院 Water permeable brick and preparation method thereof
CN105016765A (en) * 2015-07-27 2015-11-04 江苏溧阳建设集团有限公司 Corrosion resistant water permeable brick
CN105503113A (en) * 2015-12-17 2016-04-20 乔生艮 Energy-saving environment-friendly water-permeable autoclaved brick and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01161709A (en) * 1987-12-17 1989-06-26 Nec Corp Laminated ceramic component
CN103553448A (en) * 2013-09-27 2014-02-05 北京仁创科技集团有限公司 Ceramsite water permeable brick and preparation method thereof
CN104452525A (en) * 2014-11-18 2015-03-25 浙江大学宁波理工学院 Water permeable brick and preparation method thereof
CN105016765A (en) * 2015-07-27 2015-11-04 江苏溧阳建设集团有限公司 Corrosion resistant water permeable brick
CN105503113A (en) * 2015-12-17 2016-04-20 乔生艮 Energy-saving environment-friendly water-permeable autoclaved brick and preparation method thereof

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* Cited by examiner, † Cited by third party
Title
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