CN106187030B - It is luminous to inhale the phosphorous sunflower straw extrusion porous sponge brick method of catchmenting of particle preparation - Google Patents
It is luminous to inhale the phosphorous sunflower straw extrusion porous sponge brick method of catchmenting of particle preparation Download PDFInfo
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- CN106187030B CN106187030B CN201610518571.3A CN201610518571A CN106187030B CN 106187030 B CN106187030 B CN 106187030B CN 201610518571 A CN201610518571 A CN 201610518571A CN 106187030 B CN106187030 B CN 106187030B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
- C04B28/26—Silicates of the alkali metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/02—Agglomerated materials, e.g. artificial aggregates
- C04B18/027—Lightweight materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/02—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/08—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding porous substances
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C11/00—Details of pavings
- E01C11/22—Gutters; Kerbs ; Surface drainage of streets, roads or like traffic areas
- E01C11/224—Surface drainage of streets
- E01C11/225—Paving specially adapted for through-the-surfacing drainage, e.g. perforated, porous; Preformed paving elements comprising, or adapted to form, passageways for carrying off drainage
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C5/00—Pavings made of prefabricated single units
- E01C5/04—Pavings made of prefabricated single units made of bricks
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00284—Materials permeable to liquids
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/40—Porous or lightweight materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/807—Luminescent or fluorescent materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Architecture (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Road Paving Structures (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The present invention provides luminous phosphorous sunflower straw of inhaling and extrudes the porous sponge brick method of catchmenting of particle preparation, comprises the following steps:The dispensing of the porous sponge brick that catchments:By 15~20wt% of cement, particle diameter is that 250~450 μm of sunflower straws extrude 45~65wt% of particle, 5~15wt% of sodium metasilicate of modulus 3.2~3.5, particle diameter is 100~200 μm of 3~5wt% of calcium oxide, 5~10wt% of glass fibre, 0.5~5.0wt% of high hydroscopic resin fiber and 100~200 μm of 10~30wt% of medical stone samplings of particle diameter are well mixed, sized mixing with 0.4~0.7 ratio of mud, add the aluminium powder cream that compound gross weight is 0.2~1.5%, aluminium powder cream hydration reaction generates bubble, form the slurries of porous expansion water suction, slurries, which stir, to be poured into the die trial of sponge brick press, strike off, compacting, the demoulding, dry, sponge brick is made.
Description
Technical field
The present invention relates to the luminous suction phosphorous sunflower straw extrusion porous sponge brick method of catchmenting of particle preparation, belong to material
Technology is led.
Background technology
Due to EI Nino and La Nina Phenomenon, there is extreme change in the weather in China, and rainfall distributed pole is uneven, south
Northern drought and waterlogging are uneven, and rainfall is also extremely unequal in same area, 1 year, and water shortage has restricted expanding economy and the people
Life, rationally using existing precipitation, by cell road surface, road, the effective precipitation in public leisure square rationally collect, store,
Utilize, alleviate drought and water shortage season use water, the thermal capacity of water is big, can absorb heat also can heat release, improve miniclimate.
The content of the invention
The main component of sunflower straw is cellulose, hemicellulose, and modified sunflower straw can be adsorbed in water
Phosphate anion, phosphate anion are the key factors for causing water eutrophication, and bentonite is modifying agent and strong adsorbent, to water
In heavy metal ion also have suction-operated, medical stone is to heavy metal ion adsorbed in water, the sun substantially in medical stone
Ion is swapped with the heavy metal cation in water, and the heavy metal cation in water has been adsorbed by ion exchange medical stone,
The pH value of water is adjusted, cement increases mechanical strength and cementation, the resin of polyvinyl alcohol high water absorption for the porous sponge brick that catchments
Fiber is strong water absorbent, using dilatant slurry, reduces the density of slurries, a face of the manufactured porous sponge brick that catchments is in dovetail
Channel-shaped, the porous moisture for catchmenting the absorption of sponge brick enter dovetail groove, are flowed into collector pipe again by the effect of gravity, collector pipe will be porous
The sponge brick that catchments links together, and rainwater catchment is into collecting-tank.
Its technical scheme is:The luminous suction phosphorous sunflower straw extrusion porous sponge brick method of catchmenting of particle preparation, first
Step, the dispensing of the porous sponge brick that catchments:It is that 250~450 μm of modified sunflower straws are extruded by 15~20wt% of cement, particle diameter
45~65wt% of particle, 5~15wt% of sodium metasilicate of modulus 3.2~3.5, particle diameter are 100~200 μm of 3~5wt% of calcium oxide, glass
10~30wt% of medical stone of 3~10wt% of glass fiber, 0.5~5.0wt% of high hydroscopic resin fiber and 100~200 μm of particle diameter takes
Sample, the percentage by weight sum of above each component is 100%;
The preparation of second step, the porous sponge brick expansion water suction slurries that catchment:Sample by the percentage by weight of the first step, first will
Particle diameter is that 250~450 μm of modified sunflower straws extrusion particles are put into feed bin, and distributing device, distributing device are sent into by elevator
Modified sunflower straw extrusion particle is evenly distributed on governing belt balance, spray thrower is by the sodium metasilicate of modulus 3.2~3.5
The outer surface of modified sunflower straw extrusion particle is uniformly sprayed at, enters inside spin drum agitation device with governing belt balance,
Sodium metasilicate is inorganic bond, is hydrophilic, and cohesive force is strong, intensity is higher, acid resistance, heat-resist, hydrophilicity not shadow
Ring caking property, compound is 15~20wt% of cement, particle diameter be 250~450 μm of sunflower straws extrusion particle, 45~65wt%,
5~15wt% of sodium metasilicate of modulus 3.2~3.5, particle diameter are 100~200 μm of 3~5wt% of calcium oxide, 3~10wt% of glass fibre,
100~200 μm of 0.5~5.0wt% of high hydroscopic resin fiber and particle diameter 10~30wt% of medical stone, by compound with 0.4~0.7
The ratio of mud size mixing, ash is compound, add compound gross weight be 0.2~1.5% aluminium powder cream or aluminum sulfate in one
Kind, hydration reaction generation bubble, the slurries that porous expansion absorbs water are formed, reduce the weight of sponge brick, polyvinyl alcohol super absorbent resin
Fat fiber has extremely strong water imbibition, and the sponge brick compression strength after water suction is constant;
The preparation of 3rd step, the porous sponge brick that catchments:Expansion water suction slurries prepared by second step, which stir, pours into sea
In the die trial of continuous brick press, by 1.2~2.0:1 volume ratio is suppressed, and ratio 1.2~2.0 is the volume before compacting, and ratio 1 is
Volume after compacting, through striking off, suppressing, being stripped, dry, porous one face of sponge brick of catchmenting is provided with multiple grooves, by the sun
Energy cell panel and LED light emitting diodes are placed in groove, and the solar energy of absorption is converted to electrical power storage and risen by solar panel
Come, LED light emitting diodes are lighted by the effect contacting of external force, as lighting installation, using a variety of flexible colors, module
In can also be implanted into different music, regularly updated by wireless network, when external force disappears, contact disconnect, LED light emitting diodes
Extinguish, another face of the porous sponge brick that catchments is provided with dovetail channel-shaped, and the porous moisture for catchmenting the absorption of sponge brick enters dovetail groove
Interior, in collector pipe insertion dovetail groove, rainwater collects by the porous sponge brick that catchments, into dovetail groove, is acted on by gravity
Collector pipe is flowed into again, and collector pipe links together the single porous sponge brick that catchments, and the rainwater that collector pipe collects enters collecting-tank
In.
The preparation of modified sunflower straw extrusion particle:First sunflower straw is crushed particle diameter 200~400 μm is made
Grain, then sunflower straw powder, dimethylformamide, epoxychloropropane and dimethylamine agueous solution are pressed 1~3:12.5~15:8~10:
12~18 samplings are well mixed, are put into retort, are reacted 3~8 hours at 80~120 DEG C, clean, dry, are formed and be modified
Sunflower straw powder, add 100~200 μm of bentonites of particle diameter, both 70~85wt% by weight percentage:15~35wt% takes
Sample is well mixed, and the percentage by weight sum of two kinds of components is 100%, compound is prepared by the ratio of mud 0.1~0.3, compound
For modified sunflower straw granular powder and bentonite, ash is compound, and compound is put into screw mixer and stirred, then
It is granulated into extruding granulator, the modified sunflower straw extrusion spheric granules of 250~450 μm of particle diameter is made after drying, to
Day, certain herbaceous plants with big flowers stalk main component was cellulose, hemicellulose, lignin and ash content, and content of cellulose is high, and toughness is strong, tension, anti-folding
Property is strong, and modified sunflower straw can adsorb the phosphate anion in water, and phosphate anion is the pass for causing water eutrophication
The key factor, moreover it is possible to which the absorption to the heavy metal ion in radioactive element and water, bentonite is modifying agent and strong adsorbent, to water
In heavy metal ion also have a suction-operated, material component is different, and modified chemical property is also different.
Medical stone is to heavy metal ion adsorbed in water, the heavy metal sun in the cation and water substantially in medical stone
Ion is swapped, and the heavy metal cation in water has been adsorbed by ion exchange medical stone, adjusts the pH value of water.
Calcium oxide hydration reaction, substantial amounts of heat is produced, generation calcium hydroxide is in as a form of gel, is given birth to silica, aluminum oxide
Into calcium silicates, calcium oxide is activator, the activity of excited cement.
Glass fibre is hollow type, can increase the mechanical tenacity of sponge brick, moreover it is possible to forms sponge brick and multiple intersects in length and breadth
Micropore, micropore has stronger sound absorption function.
A rainwater part for accumulation is pooled in collecting-tank by the porous sponge brick that catchments by collector pipe, and another part penetrates into
Into soil, increase soil water content, in summer high-temperature season, the heat on surface can also be transmitted to by the porous sponge brick that catchments
In soil, the temperature on sponge tile floor surface is reduced, the thermal capacity of water is big, and can absorb heat also can heat release.
The present invention has advantages below.
1st, the Materials Inorganic environment-friendly materials used in sponge brick are prepared, environment will not be damaged, the recyclable energy of sponge brick
Secondary use.
2nd, the resin fibre for preparing the polyvinyl alcohol high water absorption of sponge brick is strong water absorbent, can absorb the water on sponge brick surface
Divide and enter inside, when reaching certain amount, dropped into the presence of by gravity in collector pipe.
3rd, aluminium powder cream is added in compound, forms the slurries of porous expansion, reduces the density of slurries.
4th, sunflower straw main component is cellulose, hemicellulose and lignin, and content of cellulose is high, modified to day
Certain herbaceous plants with big flowers stalk can adsorb the phosphate anion in water, and phosphate anion is the key factor for causing water eutrophication.
Brief description of the drawings
Fig. 1 is the axle geodesic structure schematic diagram of the sea brick of the embodiment of the present invention.
Fig. 2 is that the bottom of the sea brick of the embodiment of the present invention regards structural representation.
Fig. 3 is the structural representation that the monolithic sponge brick of the embodiment of the present invention is linked together by collector pipe.
Wherein 1 in figure, sponge brick 2, dovetail groove 3, collector pipe 4, LED light emitting diodes 5, solar panel.
Embodiment
Embodiment.
In embodiment as shown in Figures 1 to 3, light and inhale the phosphorous sunflower straw extrusion porous sponge of catchmenting of particle preparation
Brick method, the preparation of the first step, modified sunflower straw extrusion particle:First sunflower straw is crushed particle diameter 200 μm is made
Grain powder, sunflower straw powder, dimethylformamide, epoxychloropropane and dimethylamine agueous solution are pressed 1:12.5:10:15 sampling mixing
Uniformly, it is put into retort, is reacted 4 hours at 120 DEG C, clean, dry, form modified sunflower straw powder, is adding grain
100 μm of footpath bentonite, both 85wt% by weight percentage:15wt% samplings are well mixed, and compound is matched somebody with somebody by the ratio of mud 0.15
System, compound is put into screw mixer and stirred for modified sunflower straw granular powder and bentonite, compound, then enters
Enter in extruding granulator and be granulated, 450 μm of sunflower straw extrusion spheric granules of particle diameter are made after drying.
The dispensing of second step, the porous sponge brick that catchments:Cement 15wt%, particle diameter are 450 μm of modified sunflower straw extrusions
Particle 50wt%, the sodium metasilicate 10wt% of modulus 3.4, particle diameter are 150 μm of calcium oxide 3wt%, glass fibre 7wt%, high hydroscopic resin
Fiber 3.0wt% and particle diameter are 100 μm of medical stone 12wt%.
The preparation of 3rd step, the porous sponge brick expansion water suction slurries that catchment:Sample by the percentage by weight of the first step, first will
Particle diameter is that 450 μm of modified sunflower straws extrusion particles are put into feed bin, is sent into distributing device by elevator, distributing device will be modified
Sunflower straw extrusion particle be evenly distributed on governing belt balance, the sodium metasilicate of modulus 3.4 is uniformly sprayed at by spray thrower
The outer surface of modified sunflower straw extrusion particle, enters inside spin drum agitation device with governing belt balance, by compound with
0.4 ratio of mud is sized mixing, and is added the aluminium powder cream that compound gross weight is 0.8%, hydration reaction generation bubble, is formed porous swollen
Swollen slurries, the weight of sponge brick is reduced, polyvinyl alcohol high hydroscopic resin fiber has extremely strong water imbibition, the sponge after water suction
Brick compression strength is constant, glass fibre increase sponge brick mechanical tenacity, moreover it is possible to make sponge brick formed it is multiple intersect in length and breadth it is micro-
Hole, micropore have the function of sound-absorbing.
The preparation of 4th step, the porous sponge brick that catchments:Expansion water suction slurries prepared by second step, which stir, pours into sea
In the die trial of continuous brick press, by 1.5:1 volume ratio compacting, through striking off, suppressing, being stripped, dries, porous sponge of catchmenting is made
Brick 1, porous 1 one faces of sponge brick of catchmenting are provided with groove, solar panel 5 and LED light emitting diodes 4 are placed in into groove
In, the solar energy of absorption is converted to electrical power storage by solar panel 5, and LED light emitting diodes 4 are acted on by external force
Contact point, which is connected, to light, and as lighting installation, using a variety of flexible colors, can also be implanted into different music in module, pass through
Wireless network regularly updates, and when external force disappears, contact disconnects, and LED light emitting diodes 4 extinguish, porous the another of sponge brick 1 that catchment
Individual face is provided with the shape of dovetail groove 2, and the porous moisture for catchmenting the absorption of sponge brick 1 enters in dovetail groove 2, and collection is installed with dovetail groove 2
Water pipe 3, rainwater collect by the porous sponge brick 1 that catchments, and into dovetail groove 2, collector pipe 3 is flowed into again by the effect of gravity,
Collector pipe 3 links together the single porous sponge brick 1 that catchments, and the rainwater that collector pipe 3 collects enters in collecting-tank, by heavy
Form sediment, filtering, reuse.
The above described is only a preferred embodiment of the present invention, being not the limitation for making other forms to the present invention, appoint
What those skilled in the art changed or be modified as possibly also with the technology contents of the disclosure above equivalent variations etc.
Embodiment is imitated, every without departing from technical solution of the present invention content, the technical spirit according to type of the present invention is made to above example
Any simple modification, equivalent variations and remodeling, still fall within the protection domain of type technical scheme of the present invention.
Claims (1)
1. luminous inhale the phosphorous sunflower straw extrusion porous sponge brick method of catchmenting of particle preparation, comprise the following steps:
The dispensing of the first step, the porous sponge brick that catchments:It is 250~450 μm of modified sunflowers by 15~20wt% of cement, particle diameter
Stalk extrusion particle 45~65wt%, 5~15wt% of sodium metasilicate of modulus 3.2~3.5, particle diameter be 100~200 μm of calcium oxide 3~
5wt%, 3~10wt% of glass fibre, 100~200 μm of 0.5~5.0wt% of high hydroscopic resin fiber and particle diameter medical stone 10~
30wt% is sampled, and the percentage by weight sum of above each component is 100%, and modified sunflower straw extrudes the preparation of particle:First
Sunflower straw is crushed and is made 200~400 μm of particles of particle diameter, then by sunflower straw powder, dimethylformamide, epoxychloropropane
1~3 is pressed with dimethylamine agueous solution:12.5~15:8~10:12~18 samplings are well mixed, are put into retort, 80~120
Reacted 3~8 hours at DEG C, clean, dry, form modified sunflower straw powder, add 100~200 μm of bentonites of particle diameter, two
Person 70~85wt% by weight percentage:15~35wt% samplings are well mixed, and the percentage by weight sum of two kinds of components is 100%,
Compound is prepared by the ratio of mud 0.1~0.3, compound is modified sunflower straw granular powder and bentonite, and ash is mixing
Material, compound is put into screw mixer and stirs, enter back into extruding granulator and be granulated, be made after drying particle diameter 250~
450 μm of modified sunflower straw extrusion spheric granules;
The preparation of second step, the porous sponge brick expansion water suction slurries that catchment:Sampled by the percentage by weight of the first step, first by particle diameter
Particle is extruded for 250~450 μm of modified sunflower straws to be put into feed bin, distributing device is sent into by elevator, distributing device will change
Property sunflower straw extrusion particle be evenly distributed on governing belt balance, spray thrower is uniform by the sodium metasilicate of modulus 3.2~3.5
The outer surface of modified sunflower straw extrusion particle is sprayed at, modified sunflower straw extrusion particle enters with governing belt balance
Enter inside spin drum agitation device, compound sized mixing with 0.4~0.7 ratio of mud, add compound gross weight for 0.2~
1.5% aluminium powder cream stirs, aluminium powder cream hydration reaction generation bubble, forms the slurries of porous expansion water suction;
The preparation of 3rd step, the porous sponge brick that catchments:Expansion water suction slurries prepared by second step, which stir, pours into sponge brick
In the die trial of press, through striking off, suppressing, being stripped, dry, the porous sponge brick that catchments is made(1), the porous sponge brick that catchments(1)
One face is provided with groove, by solar panel(5)With LED light emitting diodes(4)It is placed in groove, solar panel
(5)The solar energy of absorption is converted into electrical power storage, LED light emitting diodes(4)Luminous, work is connected by the effect of external force
For lighting installation, using a variety of flexible colors, different music can also be implanted into module, is regularly updated by wireless network, when
When external force disappears, contact disconnects, LED light emitting diodes(4)Extinguish, the porous sponge brick that catchments(1)Another face be provided with dovetail
Groove(2)Shape, collector pipe(3)Embedded dovetail groove(2)Interior, rainwater passes through the porous sponge brick that catchments(1)Collect, into dovetail groove
(2)It is interior, then flow into collector pipe(3), collector pipe(3)By the single porous sponge brick that catchments(1)Link together, collector pipe(3)Converge
The rainwater of collection enters in collecting-tank.
Priority Applications (1)
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CN201610518571.3A CN106187030B (en) | 2016-07-05 | 2016-07-05 | It is luminous to inhale the phosphorous sunflower straw extrusion porous sponge brick method of catchmenting of particle preparation |
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CN201610518571.3A CN106187030B (en) | 2016-07-05 | 2016-07-05 | It is luminous to inhale the phosphorous sunflower straw extrusion porous sponge brick method of catchmenting of particle preparation |
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CN106187030B true CN106187030B (en) | 2018-03-23 |
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JPH01161709A (en) * | 1987-12-17 | 1989-06-26 | Nec Corp | Laminated ceramic component |
CN103553448B (en) * | 2013-09-27 | 2015-05-20 | 北京仁创科技集团有限公司 | Ceramsite water permeable brick and preparation method thereof |
CN104452525B (en) * | 2014-11-18 | 2016-08-24 | 浙江大学宁波理工学院 | A kind of water-permeable brick and preparation method thereof |
CN105016765B (en) * | 2015-07-27 | 2018-08-21 | 江苏溧阳建设集团有限公司 | A kind of corrosion-resistant water-permeable brick |
CN105503113B (en) * | 2015-12-17 | 2018-06-12 | 惠安傲胜工业设计有限公司 | A kind of permeable steam-pressing brisk of energy conservation and environmental protection and preparation method thereof |
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