CN105503113B - A kind of permeable steam-pressing brisk of energy conservation and environmental protection and preparation method thereof - Google Patents

A kind of permeable steam-pressing brisk of energy conservation and environmental protection and preparation method thereof Download PDF

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Publication number
CN105503113B
CN105503113B CN201510952036.4A CN201510952036A CN105503113B CN 105503113 B CN105503113 B CN 105503113B CN 201510952036 A CN201510952036 A CN 201510952036A CN 105503113 B CN105503113 B CN 105503113B
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parts
mesh
residues
water
environmental protection
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Expired - Fee Related
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CN201510952036.4A
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Chinese (zh)
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CN105503113A (en
Inventor
乔生艮
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Xuzhou Chuangjie New Building Materials Co ltd
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Huian Osim Industrial Design Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/142Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
    • C04B28/144Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being a flue gas desulfurization product
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The permeable steam-pressing brisk of energy conservation and environmental protection of the present invention, is made of the component of following parts by weight:38~44 parts of flyash, 12~16 parts of desulfurated plaster, 12~16 parts of oil shale residues, 8~11 parts of electrolytic manganese residues, 7~9 parts of Portland cement, 3~4 parts of flint clay, 3~4 parts of titanium nitride, 4~5 parts of medical stone, 1~1.5 part of chopped carbon fiber, 3~3.5 parts of basalt fibre, 0.5~0.8 part of glycol distearate, 0.7~0.8 part of dioctyl sodium sulfosuccinate, 3~4 parts of dextrin, 1.5~2 parts of lithium chromate, 0.3~0.4 part of cocamidopropyl betaine, 8~10 parts of water.The permeable steam-pressing brisk of energy conservation and environmental protection of the present invention, reasonable employment various industrial waste residues are prepared by special formula and technique, have excellent coefficient of permeability and water-retaining property, while have very prominent compression strength.

Description

A kind of permeable steam-pressing brisk of energy conservation and environmental protection and preparation method thereof
Technical field
The invention belongs to building material technical field, specially a kind of permeable steam-pressing brisk of energy conservation and environmental protection and preparation method thereof.
Background technology
Water-permeable brick has good water permeability, water-retaining property and higher mechanical strength, and product is layed in the public affairs such as square, road The ground in place altogether, it is possible to reduce city water resource is lost in, adjusts urban climate, beautifying urban environment, reduces city noise.By Not only there is preferable water penetration, but also with dicoration in water-permeable brick, moreover it is possible to it prevents erosion, environmental protection, thus it is wide at present It is general to be used for the popular industry that in urban road and many investors invest at present.
Concrete permeable brick:Material is river sand, cement, water, then adds a certain proportion of impregnating agent and manufactured concrete Product.For this product compared with resin water-permeable brick, ceramic water-permeable brick, gap water-permeable brick, production cost is low, and production process is simple, easy Operation.It is widely used in expressway, airport runways, driveway, the ranges such as pavement, square and garden architecture.
Colored stone epoxy entire body water-permeable brick:Material aggregate is glued with import modified epoxy for natural color stone, through special work Skill shapes, this product can be prefabricated, can be with in-situ casting, and can risk various artistic character/images and color lines, to people A kind of pleasing impression.It is mainly used for garden landscape engineering and Deluxe villa cell.
Colored stone composite concrete permeable brick:Material face layer is natural colorful granite, marble and modified epoxy glue Close, then with the repressed combined shaping of underlying polymer fiber multihole concrete, layer magnificent, natural colour in this product face have and stone The general texture of material, with concrete it is compound after, intensity is slightly above concrete permeable brick, and price is stone material higher than stone material and cost The 1/2 of floor tile is a kind of economic, high-grade flooring products.Be mainly used for luxurious shopping centre, large-scale square, hotel parking lot and The places such as Deluxe villa cell.
Polymer fiber concrete permeable brick:Material be granite aggregate, high-strength cement and cement polymer reinforcing agent, And blend polypropylene fibre, feeding proportioning tightly, through compression moulding after stirring, it is small to be mainly used for municipal administration, important engineering and house Mat formation in the places such as pavement, square, the parking lot in area.
Invention content
Present invention aims to overcome that deficiency of the prior art, provides a kind of permeable steam-pressing brisk of energy conservation and environmental protection and its preparation Method.
The permeable steam-pressing brisk of energy conservation and environmental protection of the present invention, is made of the component of following parts by weight:38~44 parts of flyash, desulfurization 12~16 parts of gypsum, 12~16 parts of oil shale residues, 8~11 parts of electrolytic manganese residues, 7~9 parts of Portland cement, flint clay 3 ~4 parts, 3~4 parts of titanium nitride, 4~5 parts of medical stone, 1~1.5 part of chopped carbon fiber, 3~3.5 parts of basalt fibre, ethylene glycol 0.5~0.8 part of distearate, 0.7~0.8 part of dioctyl sodium sulfosuccinate, 3~4 parts of dextrin, 1.5~2 parts of lithium chromate, 0.3~0.4 part of cocamidopropyl betaine, 8~10 parts of water.
As an optimization, the permeable steam-pressing brisk of the energy conservation and environmental protection, is prepared from the following raw materials in parts by weight:41 parts of flyash takes off 13 parts of sulphur gypsum, 13 parts of oil shale residues, 10 parts of electrolytic manganese residues, 8 parts of Portland cement, 3.5 parts of flint clay, titanium nitride 3.5 parts, 4.5 parts of medical stone, 1.2 parts of chopped carbon fiber, 3.3 parts of basalt fibre, 0.6 part of glycol distearate, two fourths 0.7 part of sodium dioctyl sulfo, 3.5 parts of dextrin, 1.6 parts of lithium chromate, 0.35 part of cocamidopropyl betaine, 9 parts of water.
As an optimization, the permeable steam-pressing brisk of energy conservation and environmental protection, flyash powder fineness is 325 mesh, desulfurated plaster powder fineness is 250 mesh, oil shale residues powder fineness are 250 mesh, electrolytic manganese residues powder fineness is 250 mesh, flint clay powder fineness is 200 Mesh, nitride powder fineness are 400 mesh, medical stone powder fineness is 200 mesh.The auspicious Co., Ltds of Shanghai Jia Pu can be passed through HGM100 tricyclic middling speed super fines are ground.
The method for preparing the permeable steam-pressing brisk of the energy conservation and environmental protection, includes the following steps:
A, by the flyash of the parts by weight, desulfurated plaster, oil shale residues, electrolytic manganese residues, Portland cement, Flint clay, titanium nitride, medical stone;Blender is added to stir evenly;
B, by the chopped carbon fiber of the parts by weight, basalt fibre, glycol distearate, two butyric acid dioctyl esters Sodium sulfonate, dextrin, lithium chromate are added sequentially in the mixture in step a, stir evenly;
C, it by the cocamidopropyl betaine of the parts by weight, water, after mixing, is added in step b In mixture, stir evenly;
D, by the mixture of step c under the pressure of 20MPa, 5~10s, static press-forming are suppressed;It is then delivered to steaming It presses in kettle, 180 DEG C, 0.8~1.2MPa of pressure, 8~12h of steam pressure of steam pressure temperature goes out kettle.
The permeable steam-pressing brisk of energy conservation and environmental protection of the present invention, reasonable employment various industrial waste residues pass through special formula and technique system It is standby to form, there is excellent coefficient of permeability and water-retaining property, while there is very prominent compression strength.The good resistance to compression of water-permeable brick Intensity, water penetration and water-retaining property, product are layed in the ground of the public places such as square, road, it is possible to reduce city water resource stream It loses, adjusts urban climate, beautifying urban environment, reduces city noise.
Performance measurement:Compressive strength determination:Intensity is measured using HD-504A-2 types compressive strength instrument.It accurately measures permeable Brick length data simultaneously input computer.With 2 × 102N/s uniform loads read pressure value F when sample disposably destroys (kN), resistance to compression degree R (MPa) is calculated.In R=P/A formulas:A is bearing area, cm2
Water permeability measures:Water permeable device is made of dropping bottle, dropper, water receiving bottle, iron stand.Sample is fixed on iron stand On, dropper drips to specimen surface starts timing, and when the sweat of sample following table stops timing, the time difference is △ t (s), is counted Calculate coefficient of permeability K (cm/s);K=H/△ t, in formula:H is specimen height, cm.
Water retention property measures:By sample in 110 ± 5 DEG C of dryings, quality is measured by sampling every 2 h, until continuous twice survey The difference of amount<0.1%, weigh dry sample mass m1 (g).Sample is put into sink vertically, 20 ± l0 DEG C of distilled water is injected, makes water Face is higher by sample 20mm, 12h sampling, and surface water is gently wiped with wet cloth, is weighed immediately, the quality m2 (g) for 12 h that absorb water for sample, meter Calculate water retention coefficient.B= (m2- m1)/ V;In formula:B is water retention coefficient, g/cm3;Volumes of the V for sample, cm3.Different groups Test result is shown in Table 1.
Specific embodiment
The invention will be further described, but is not to be construed as to the scope of the present invention for example given below plan Limitation, those skilled in the art still fall within this according to some the nonessential modifications and adaptations of the content of present invention to the present invention The protection domain of invention.
Embodiment 1:A, by 41 kilograms of 325 mesh flyash, 13 kilograms of 250 mesh desulfurated plaster, 250 mesh oil shale residues 13,000 Gram, 10 kilograms of 250 mesh electrolytic manganese residues, 8 kilograms of Portland cement, 3.5 kilograms of 200 mesh flint clay, 400 mesh titanium nitrides 3.5 Kilogram, 4.5 kilograms of 200 mesh medical stone;Blender is added to stir evenly;
B, by 1.2 kilograms of length 5mm chopped carbon fibers, 3.3 kilograms of length 6mm basalt fibres, ethylene glycol distearyl acid 0.6 kilogram of ester, 0.7 kilogram of dioctyl sodium sulfosuccinate, 3.5 kilograms of dextrin, 1.6 kilograms of lithium chromate, are added sequentially to step a In mixture in, stir evenly;
C, it by 0.35 kilogram of cocamidopropyl betaine, 9 kilograms of water, after mixing, is added to mixed in step b It closes in object, stirs evenly;
D, by the mixture of step c under the pressure of 20MPa, 5~10s, static press-forming are suppressed;It is then delivered to steaming It presses in kettle, 180 DEG C, 0.8~1.2MPa of pressure, 8~12h of steam pressure of steam pressure temperature goes out kettle.
Embodiment 2:A, by 38 kilograms of 325 mesh flyash, 12 kilograms of 250 mesh desulfurated plaster, 250 mesh oil shale residues 12,000 Gram, 8 kilograms of 250 mesh electrolytic manganese residues, 7 kilograms of Portland cement, 3 kilograms of 200 mesh flint clay, 3 kilograms of 400 mesh titanium nitride, 200 4 kilograms of mesh medical stones;Blender is added to stir evenly;
B, by 1 kilogram of 5mm chopped carbon fibers, 3 kilograms of 6mm basalt fibres, 0.5 kilogram of glycol distearate, two 0.7 kilogram of fourth sodium dioctyl sulfo, 3 kilograms of dextrin, 1.5 kilograms of lithium chromate, are added sequentially in the mixture in step a, It stirs evenly;
C, it by 0.3 kilogram of cocamidopropyl betaine, 8 kilograms of water, after mixing, is added to mixed in step b It closes in object, stirs evenly;
D, by the mixture of step c under the pressure of 20MPa, 5~10s, static press-forming are suppressed;It is then delivered to steaming It presses in kettle, 180 DEG C, 0.8~1.2MPa of pressure, 8~12h of steam pressure of steam pressure temperature goes out kettle.
Embodiment 3:A, by 44 kilograms of 325 mesh flyash, 16 kilograms of 250 mesh desulfurated plaster, 250 mesh oil shale residues 16,000 Gram, 11 kilograms of 250 mesh electrolytic manganese residues, 9 kilograms of Portland cement, 4 kilograms of 200 mesh flint clay, 4 kilograms of 400 mesh titanium nitride, 200 5 kilograms of mesh medical stones;Blender is added to stir evenly;
B, by 1.5 kilograms of 5mm chopped carbon fibers, 3.5 kilograms of 6mm basalt fibres, glycol distearate 0.8 thousand Gram, 0.8 kilogram of dioctyl sodium sulfosuccinate, 4 kilograms of dextrin, 2 kilograms of lithium chromate, the mixture being added sequentially in step a In, it stirs evenly;
C, it by 0.4 kilogram of cocamidopropyl betaine, 10 kilograms of water, after mixing, is added to mixed in step b It closes in object, stirs evenly;
D, by the mixture of step c under the pressure of 20MPa, 5~10s, static press-forming are suppressed;It is then delivered to steaming It presses in kettle, 180 DEG C, 0.8~1.2MPa of pressure, 8~12h of steam pressure of steam pressure temperature goes out kettle.

Claims (3)

1. a kind of permeable steam-pressing brisk of energy conservation and environmental protection, it is characterised in that be by the component of following parts by weight:38~44 parts of flyash, 12~16 parts of desulfurated plaster, 12~16 parts of oil shale residues, 8~11 parts of electrolytic manganese residues, 7~9 parts of Portland cement, Jiao Bao 3~4 parts of stone, 3~4 parts of titanium nitride, 4~5 parts of medical stone, 1~1.5 part of chopped carbon fiber, 3~3.5 parts of basalt fibre, second two 0.5~0.8 part of alcohol distearate, 0.7~0.8 part of dioctyl sodium sulfosuccinate, 3~4 parts of dextrin, lithium chromate 1.5~2 Part, 0.3~0.4 part of cocamidopropyl betaine, 8~10 parts of water;
It is made up of following steps:
A, by the flyash of the parts by weight, desulfurated plaster, oil shale residues, electrolytic manganese residues, Portland cement, Jiao Bao Stone, titanium nitride, medical stone are added to blender and stir evenly;
B, by the chopped carbon fiber of the parts by weight, basalt fibre, glycol distearate, two butyric acid dioctyl ester sulfonic acid Sodium, dextrin, lithium chromate are added sequentially in the mixture in step a, stir evenly;
C, by the cocamidopropyl betaine of the parts by weight, water, after mixing, the mixing being added in step b In object, stir evenly;
D, by the mixture of step c under the pressure of 20MPa, 5~10s, static press-forming are suppressed;It is then delivered to still kettle In, 180 DEG C, 0.8~1.2MPa of pressure, 8~12h of steam pressure of steam pressure temperature goes out kettle.
2. the permeable steam-pressing brisk of energy conservation and environmental protection according to claim 1, it is characterised in that by the raw material system of following parts by weight Into:41 parts of flyash, 13 parts of desulfurated plaster, 13 parts of oil shale residues, 10 parts of electrolytic manganese residues, 8 parts of Portland cement, Jiao Bao 3.5 parts of stone, 3.5 parts of titanium nitride, 4.5 parts of medical stone, 1.2 parts of chopped carbon fiber, 3.3 parts of basalt fibre, ethylene glycol distearyl 0.6 part of acid esters, 0.7 part of dioctyl sodium sulfosuccinate, 3.5 parts of dextrin, 1.6 parts of lithium chromate, cocamidopropyl betaine 0.35 part, 9 parts of water.
3. the permeable steam-pressing brisk of energy conservation and environmental protection according to claim 1, it is characterised in that the flyash powder fineness is 325 Mesh, desulfurated plaster powder fineness are 250 mesh, oil shale residues powder fineness is 250 mesh, electrolytic manganese residues powder fineness be 250 mesh, Flint clay powder fineness is 200 mesh, nitride powder fineness is 400 mesh, medical stone powder fineness is 200 mesh.
CN201510952036.4A 2015-12-17 2015-12-17 A kind of permeable steam-pressing brisk of energy conservation and environmental protection and preparation method thereof Expired - Fee Related CN105503113B (en)

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CN106587829A (en) * 2016-12-11 2017-04-26 吴硕 Concrete block and preparation method thereof
CN106587844A (en) * 2016-12-19 2017-04-26 钦州市科学技术开发中心 Permeable steam-pressing brisk and preparation method thereof
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CN108117407A (en) * 2018-01-12 2018-06-05 吉林大学 A kind of technique that light ceramic is prepared as major ingredient using basalt tailing
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