CN106116660A - Heat-conducting type zeolite hafnium carbide ceramic fine bead is prepared porous and is catchmented the method for sponge brick - Google Patents

Heat-conducting type zeolite hafnium carbide ceramic fine bead is prepared porous and is catchmented the method for sponge brick Download PDF

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Publication number
CN106116660A
CN106116660A CN201610518590.6A CN201610518590A CN106116660A CN 106116660 A CN106116660 A CN 106116660A CN 201610518590 A CN201610518590 A CN 201610518590A CN 106116660 A CN106116660 A CN 106116660A
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porous
sponge brick
hafnium carbide
zeolite
catchmented
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CN201610518590.6A
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CN106116660B (en
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孙航
郭志东
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Shandong University of Technology
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Shandong University of Technology
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • C04B18/023Fired or melted materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C11/00Details of pavings
    • E01C11/22Gutters; Kerbs ; Surface drainage of streets, roads or like traffic areas
    • E01C11/224Surface drainage of streets
    • E01C11/225Paving specially adapted for through-the-surfacing drainage, e.g. perforated, porous; Preformed paving elements comprising, or adapted to form, passageways for carrying off drainage
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C5/00Pavings made of prefabricated single units
    • E01C5/04Pavings made of prefabricated single units made of bricks
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Architecture (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Road Paving Structures (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

nullThe present invention provides heat-conducting type zeolite hafnium carbide ceramic fine bead to prepare porous to catchment the method for sponge brick,Comprise the following steps: porous is catchmented the dispensing of sponge brick: cement 15~20wt%、Particle diameter is 100~250 m zeolite hafnium carbide perforate hollow ceramic microspheres 60~75wt%、The sodium silicate 5~15wt% of modulus 3.2~3.5、The flyash 3~10wt% of loss on ignition 1.1% and polyvinyl alcohol High hydrophilous resin fiber 0.5~5.0wt% proportion sample mix homogeneously,Compound is sized mixing with the ratio of mud of 0.5~0.7,Add the aluminium powder cream that compound gross weight is 0.2~1.0%,Aluminium powder cream hydration reaction generates bubble,Form porous and expand the serosity of water suction,The water suction serosity that expands of preparation is stirred in the die trial pouring sponge brick press into,Through striking off、Compacting、The demoulding、Dry,Make porous to catchment sponge brick.

Description

Heat-conducting type zeolite hafnium carbide ceramic fine bead is prepared porous and is catchmented the method for sponge brick
Technical field
The present invention relates to heat-conducting type zeolite hafnium carbide ceramic fine bead prepare porous and catchment the method for sponge brick, belong to material skill Art is led.
Background technology
Due to EI Nino and La Nina Phenomenon, there is extreme change in the weather of China, and rainfall distributed pole is uneven, south North drought and waterlogging are uneven, and in same area, in 1 year, rainfall is the most unequal, and hydropenia has restricted expanding economy and the people Life, the existing precipitation of Appropriate application, road surface, community, road, the effective precipitation in public leisure square are rationally collected, store, Utilize, alleviate the use water in drought and water shortage season, significant.
Summary of the invention
Zeolite hafnium carbide cenosphere is as base material, and hafnium carbide high rigidity, high-melting-point, intensity toughness big, anti-is strong, antioxygen Changing, sized zeolite particles more small specific surface is long-pending the biggest, and absorbability is the strongest, and zeolite can adsorb the ammoniacal nitrogen in water, Organic substance and weight Metal ion, also has ion exchange and the performance of acidproof heat-proof, the pH value of regulation water, it is possible to by the heat biography on sponge brick surface Leading in soil, using sodium silicate as binding agent, cement is that the porous sponge brick that catchments increases mechanical strength and cementation, fine coal The resin fibre of ash and the water suction of polyvinyl alcohol height is strong water absorbent, uses dilatant slurry, reduces the density of serosity, the porous made A catchment face of sponge brick is dovetail channel-shaped, and the porous moisture that sponge brick absorbs that catchments enters dovetail groove, is acted on by gravity Flowing into collector pipe again, the collector pipe sponge brick that porous catchmented links together, in rainwater catchment to collecting-tank.
Its technical scheme is: heat-conducting type zeolite hafnium carbide ceramic fine bead is prepared porous and catchmented the method for sponge brick, the first step, Porous is catchmented the dispensing of sponge brick: cement 15~20wt%, particle diameter are 100~250 m zeolite hafnium carbide perforate hollow ceramic microspheres 60~75wt%, the sodium silicate 5~15wt% of modulus 3.2~3.5, the flyash 3~10wt% of loss on ignition 1.1% and polyvinyl alcohol High hydrophilous resin fiber 0.5~5.0wt%, the percentage by weight sum of above each component is 100%;
Second step, porous catchment sponge brick expand water suction serosity preparation: by the first step percentage by weight sample, first by particle diameter Being that 100~250 m zeolite hafnium carbide perforate hollow ceramic microspheres are put in feed bin, elevator send into distributing device, distributing device will Zeolite hafnium carbide perforate hollow ceramic microspheres is evenly distributed on governing belt balance, and spray thrower is by the sodium silicate of modulus 3.2~3.5 Uniformly being sprayed at the outer surface of zeolite hafnium carbide perforate hollow ceramic microspheres, zeolite hafnium carbide perforate hollow ceramic microspheres is with speed governing Belt conveyer scale enters in internal coiling drum agitation device, and the outer surface making each zeolite hafnium carbide perforate hollow ceramic microspheres is the most attached Sodium silicate, sodium silicate is inorganic bond, is hydrophilic, and cohesive force is strong, intensity is higher, acid resistance, heat-resist, hydrophilic Performance does not affect caking property, compound be cement 15~20wt%, particle diameter be 100~250 m zeolite hafnium carbide perforate hollow ceramics Microballon 60~75wt%, the sodium silicate 5~15wt% of modulus 3.2~3.5, the flyash 3~10wt% of loss on ignition 1.1% and poly-second Enol High hydrophilous resin fiber 0.5~5.0wt%, then compound is sized mixing with the ratio of mud of 0.5~0.7, ash is compound, Rear addition compound gross weight is the aluminium powder cream of 0.2~1.0%, and hydration reaction generates bubble, forms porous and expands the slurry of water suction Liquid, reduces the weight of sponge brick, and polyvinyl alcohol High hydrophilous resin fiber has extremely strong water absorption, the sponge brick resistance to compression after water suction Intensity is constant;
3rd step, heat-conducting type porous are catchmented the preparation of sponge brick: the expansion water suction serosity prepared by second step stirs and pours into In the die trial of sponge brick press, by 1.2~2.0:1 volume ratio compactings, ratio 1.2~2.0 is the volume before compacting, ratio 1 For the volume after compacting, through striking off, suppressing, the demoulding, drying, the porous made is catchmented sponge brick, and porous is catchmented the one of sponge brick Individual face is dovetail channel-shaped, and the porous moisture that sponge brick absorbs that catchments enters in dovetail groove, and collector pipe embeds in dovetail groove, collector pipe The a part of arc surface embedded in dovetail groove is opening shape, and another part arc surface is closed, and rainwater catchments sea through porous Collecting of continuous brick, entering in dovetail groove, flowed into collector pipe again by the effect of gravity, single porous is catchmented sponge brick even by collector pipe Being connected together, the rainwater that collector pipe collects enters in collecting-tank.
The preparation of zeolite hafnium carbide perforate hollow ceramic microspheres: by particle diameter 80~200 m zeolite, 200~400 m hafnium carbides Powder stirs by weight 70~85:15~30 compounds, and the percentage by weight sum of two kinds of components is 100%, compound Sizing mixing by the ratio of mud of 0.5~0.7, ash becomes, for zeolite, the compound being grouped into hafnium carbide two kinds, through centrifugal rotation at a high speed Injection forms microballon, then through 800~950 DEG C of expansion, 1000~1500 DEG C fire, quickly cool down, formation wall thickness 50~100 m, The zeolite hafnium carbide perforate hollow ceramic microspheres of particle diameter 100~250 m, through high-temperature firing, defines the zeolite carbonization of modification Hafnium composite ceramics resistance to compression microballon, the component of material is different, and the chemical property of modified material is the most different, hafnium carbide high rigidity, height Fusing point, intensity toughness big, anti-is strong, antioxidation, and Heat stability is good, the coefficient of expansion are little, and sized zeolite particles more small specific surface is long-pending the biggest, inhales Attached ability is the strongest, and zeolite can adsorb the ammoniacal nitrogen in water, Organic substance and heavy metal ion, also has ion exchange with acidproof resistance to The performance of heat, the pH value of regulation water, it is possible to by being thermally conducted in soil of sponge brick surface.
The modulus of sodium silicate is most important, and when modulus is more than 3.5, along with the increase of modulus, sodium silicate is hardening to become fragile, viscous Knot property is deteriorated, and when modulus is less than 3.2, caking property declines.
Flyash is strong water absorbent, through high temperature sintering, has higher activity.
A rainwater part for accumulation is pooled in collecting-tank by the porous sponge brick that catchments by collector pipe, and another part penetrates into In soil, increasing soil water content, in summer high-temperature season, the heat on surface can also be transmitted to by the porous sponge brick that catchments In soil, reducing the temperature on sponge tile floor surface, the thermal capacity of water is big, and can absorb heat also can heat release.
The present invention has the following advantages.
1, preparation Materials Inorganic environment-friendly materials used by sponge brick, do not result in harm, the recyclable energy of sponge brick to environment It is used for multiple times.
2, the resin fibre of preparation sponge brick flyash and the water suction of polyvinyl alcohol height is strong water absorbent, can absorb sponge brick table The moisture in face enters internal, when reaching some, is fallen to entering in collector pipe by the effect of gravity.
3, in compound, add aluminium powder cream, form the serosity that porous expands, reduce the density of serosity.
4, zeolite can adsorb the ammoniacal nitrogen in water, Organic substance and heavy metal ion, also has ion exchange with acidproof resistance to The performance of heat, the pH value of regulation water, it is possible to by being thermally conducted in soil of sponge brick surface.
5, hafnium carbide high rigidity, high-melting-point, intensity toughness big, anti-is strong, antioxidation.
Accompanying drawing explanation
Fig. 1 is the axle geodesic structure schematic diagram of the sea brick of the embodiment of the present invention.
Fig. 2 is the end TV structure schematic diagram of the sea brick of the embodiment of the present invention.
Fig. 3 is the structural representation that the monolithic sponge brick of the embodiment of the present invention is linked together by collector pipe.
Wherein in figure 1, sponge brick 2, dovetail groove 3, collector pipe.
Detailed description of the invention
Embodiment.
In embodiment as shown in Figures 1 to 3, heat-conducting type zeolite hafnium carbide ceramic fine bead is prepared porous and is catchmented sponge brick Method, the first step, the preparation of zeolite hafnium carbide perforate hollow ceramic microspheres: first particle diameter 100 m zeolite, 250 m hafnium carbides are pressed Weight ratio 85:15 compound stirs, and compound is sized mixing by the ratio of mud of 0.6, is formed micro-through centrifugal rotation high velocity jet Pearl, then through 800 DEG C of expansions, 1200 DEG C fire, quickly cool down, form wall thickness 80 m, particle diameter is the zeolite hafnium carbide perforate of 200 m Hollow ceramic microspheres.
Second step, porous are catchmented the dispensing of sponge brick: take cement 18wt%, particle diameter is that 200 m zeolite hafnium carbide perforates are empty Heart ceramic fine bead 62wt%, the sodium silicate 10wt% of modulus 3.5, the flyash 7wt% of loss on ignition 1.1%, polyvinyl alcohol super absorbent resin Fat fiber 3wt%.
3rd step, porous catchment sponge brick expand water suction serosity preparation: by the first step percentage by weight sample, first will Particle diameter is that 200 m zeolite hafnium carbide perforate hollow ceramic microspheres are put in feed bin, elevator send into distributing device, and distributing device will boiling Stone hafnium carbide perforate hollow ceramic microspheres is evenly distributed on governing belt balance, and the sodium silicate of modulus 3.5 is uniformly sprayed by spray thrower It is sprinkled upon the outer surface of zeolite hafnium carbide perforate hollow ceramic microspheres, enters internal coiling drum agitation device with governing belt balance, will be mixed Closing material to size mixing with the ratio of mud of 0.55, add the aluminium powder cream that compound gross weight is 0.5%, hydration reaction generates bubble, is formed Porous expands the serosity of water suction, reduces the weight of sponge brick, and polyvinyl alcohol High hydrophilous resin fiber has extremely strong water absorption, inhales Sponge brick comprcssive strength after water is constant, and zeolite has adsorptivity, it is possible to absorption water in ammoniacal nitrogen, Organic substance and heavy metal from Son, also has ion exchange and the performance of acidproof heat-proof, the pH value of regulation water, it is possible to sponge brick surface is thermally conducted to soil In earth.
4th step, absorbent-type porous are catchmented the preparation of sponge brick: the expansion water suction serosity prepared by second step stirs Pour in the die trial of sponge brick press, suppress by the volume ratio of 1.5:1, through striking off, suppressing, the demoulding, dry, make porous Catchment sponge brick 1, and a catchment face of sponge brick 1 of porous is dovetail groove 2 shape, and the porous moisture that sponge brick 1 absorbs that catchments enters In dovetail groove 2, being installed with collector pipe 3 in dovetail groove 2, rainwater catchments the collecting of sponge brick 1 through porous, enters dovetail groove 2 In, being flowed into collector pipe 3 again by the effect of gravity, the collector pipe 3 sponge brick 1 that single porous catchmented links together, and collector pipe 3 converges The rainwater of collection enters in collecting-tank, through precipitation, filters, reuses.
The above, be only presently preferred embodiments of the present invention, is not the restriction that the present invention makees other form, appoints What those skilled in the art changed possibly also with the technology contents of the disclosure above or be modified as equivalent variations etc. Effect embodiment, every without departing from technical solution of the present invention content, according to the technical spirit of type of the present invention, above example is made Any simple modification, equivalent variations and remodeling, still fall within the protection domain of type technical scheme of the present invention.

Claims (1)

1. heat-conducting type zeolite hafnium carbide ceramic fine bead is prepared porous and is catchmented the method for sponge brick, comprises the following steps:
The first step, porous are catchmented the dispensing of sponge brick: cement 15~20wt%, particle diameter are 100~250 m zeolite hafnium carbide perforates Hollow ceramic microspheres 60~75wt%, the sodium silicate 5~15wt% of modulus 3.2~3.5, the flyash 3 of loss on ignition 1.1%~ 10wt% and polyvinyl alcohol High hydrophilous resin fiber 0.5~5.0wt%, the percentage by weight sum of above each component is 100%;
Second step, porous catchment sponge brick expand water suction serosity preparation: by the first step percentage by weight sample, first by particle diameter Being that 100~250 m zeolite hafnium carbide perforate hollow ceramic microspheres are put in feed bin, elevator send into distributing device, distributing device will Zeolite hafnium carbide perforate hollow ceramic microspheres is evenly distributed on governing belt balance, and spray thrower is by the sodium silicate of modulus 3.2~3.5 Uniformly being sprayed at the outer surface of zeolite hafnium carbide perforate hollow ceramic microspheres, zeolite hafnium carbide perforate hollow ceramic microspheres is with speed governing Belt conveyer scale stirs in entering internal coiling drum agitation device, then is sized mixing with the ratio of mud of 0.5~0.7 by compound, finally adds Enter compound gross weight be 0.2~1.0% aluminium powder cream stir, aluminium powder cream hydration reaction generate bubble, formed porous expand The serosity of water suction;
3rd step, heat-conducting type porous are catchmented the preparation of sponge brick: the expansion water suction serosity prepared by second step stirs and pours into In the die trial of sponge brick press, through striking off, suppressing, the demoulding, drying, make porous and catchment sponge brick (1), porous is catchmented sponge One face of brick (1) is dovetail groove (2) shape, and collector pipe (3) embeds in dovetail groove (2), and collector pipe (3) embeds in dovetail groove (2) A part of arc surface be opening shape, another part arc surface is closed, and rainwater catchments through porous the remittance of sponge brick (1) Collection, enters in dovetail groove (2), is entered collector pipe (3) by the effect of gravity, and single porous is catchmented sponge brick (1) by collector pipe (3) Linking together, the rainwater that collector pipe (3) collects enters in collecting-tank.
CN201610518590.6A 2016-07-05 2016-07-05 The method that heat-conducting type zeolite hafnium carbide ceramic fine bead prepares the porous sponge brick that catchments Expired - Fee Related CN106116660B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100133166A1 (en) * 2006-09-30 2010-06-03 Beijing Rechsand Science & Technology Group Co., L Composite water permeable brick and composition for producing the same
CN103553448A (en) * 2013-09-27 2014-02-05 北京仁创科技集团有限公司 Ceramsite water permeable brick and preparation method thereof
CN104452525A (en) * 2014-11-18 2015-03-25 浙江大学宁波理工学院 Water permeable brick and preparation method thereof
CN105016765A (en) * 2015-07-27 2015-11-04 江苏溧阳建设集团有限公司 Corrosion resistant water permeable brick
CN105503113A (en) * 2015-12-17 2016-04-20 乔生艮 Energy-saving environment-friendly water-permeable autoclaved brick and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100133166A1 (en) * 2006-09-30 2010-06-03 Beijing Rechsand Science & Technology Group Co., L Composite water permeable brick and composition for producing the same
CN103553448A (en) * 2013-09-27 2014-02-05 北京仁创科技集团有限公司 Ceramsite water permeable brick and preparation method thereof
CN104452525A (en) * 2014-11-18 2015-03-25 浙江大学宁波理工学院 Water permeable brick and preparation method thereof
CN105016765A (en) * 2015-07-27 2015-11-04 江苏溧阳建设集团有限公司 Corrosion resistant water permeable brick
CN105503113A (en) * 2015-12-17 2016-04-20 乔生艮 Energy-saving environment-friendly water-permeable autoclaved brick and preparation method thereof

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