CN105442086A - 一种防藻抗老化渔网 - Google Patents
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Abstract
发明公开了一种防藻抗老化渔网，由以下成分制成：聚苯乙烯、聚乙烯纤维、尼龙纤维、MBS树脂、环氧树脂胶膜、二甲基丙烯酸乙二醇酯、碳酸钙粉末、凹凸棒石粉末、邻苯二甲酸二丁酯、硬脂酸钙。本发明制作的渔网加工工艺简单，通过在对聚乙烯纤维处理的过程中，进行紫外线间断辐照处理，能够使得制作的渔网具有极强的防止海藻附着的性能，由于尼龙纤维缺点为耐旋光性差﹐在室外长时间受日照时﹐则易生黄﹐强度下降，本发明通过采用己二胺和马来酸酐混合物对尼龙纤维进行处理，解决了这些问题，并且还极大的提高了制作的渔网的抗老化能力；通过添加处理过的凹凸棒石粉末，能够提高渔网的力学性能，增强韧性。
Description
技术领域
本发明涉及渔具领域，特别是涉及一种防藻抗老化渔网。
背景技术
现代渔网主要采用聚乙烯，尼龙等原料进行加工，有较长的使用周期，和更高的捕捞效率，但是聚乙烯本身的力学性能一般，拉伸强度较低，抗蠕变性不好，就导致传统渔网的强度、耐磨性能、韧性不适宜于复杂海底和大风大浪环境捕捞作业，降低了渔具的使用寿命，不仅浪费资源，还直接影响渔获量；并且现有的渔网中，在长时间的使用中，容易受到海水中藻的感染，从而影响了了捕鱼效率，并且渔网受到感染，降低了渔网的使用寿命，增加了渔民的投资成本。
发明内容
本发明的目的是提供一种防藻抗老化渔网，通过以下技术方案实现：
一种防藻抗老化渔网，按重量份计由以下成分制成：聚苯乙烯10份、聚乙烯纤维50份、尼龙纤维30份、MBS树脂10份、环氧树脂胶膜10份、二甲基丙烯酸乙二醇酯3份、碳酸钙粉末0.5份、凹凸棒石粉末0.5份、邻苯二甲酸二丁酯5份、硬脂酸钙1份。
进一步地，所述聚乙烯纤维经过预先改性处理：将1%浓度的苯甲酸与10%浓度的盐酸混合，再将聚乙烯纤维放入到上述混合溶液中，加热至65-70℃，同时采用紫外线进行间断性辐照处理，持续40分钟后，过滤，干燥；所述紫外线辐照间断间隔为5分钟。
进一步地，所述增塑剂为甘油和木糖醇复合增塑剂，其中甘油与木糖醇的复合比例为4:1，复合温度在65-80℃之间。
进一步地，所述凹凸棒石经过预处理：先制备水性聚氨酯乳液，再将制备好的水性聚氨酯乳液与凹凸棒石粉末按质量比为5：1混合,加热至55-60℃，持续40分钟后，过滤；处理过的凹凸棒石粉末外表包覆层厚度约为12nm。
进一步地，所述MBS树脂与二羟基丙烷经过共混处理：将MBS树脂与二羟基丙烷共混加热，先持续加热至120℃，再缓慢冷却至室温，静置1-2小时。
进一步地，所述尼龙纤维与混合重量份为1份的己二胺和马来酸酐混合物在反应釜中进行混合处理，反应温度为110-115℃，压力为4.5MPa，反应时间为30分钟，所述己二胺和马来酸酐混合物为己二胺和马来酸酐按1:1比例混合。
进一步地，所述环氧树脂胶膜经过预处理：将环氧树脂胶膜与重量份为0.1份的十二烷基三甲氧基硅烷在碱性环境下均匀混合，加热至260℃，持续15分钟后，开始缓慢冷却，当冷却至155℃时，保温15分钟，继续冷却至128℃，保温30分钟，最后冷却到室温为止。
进一步地，所述碳酸钙粉末先采用1.5%浓度羧酸洗涤外表面，再进行干燥即可。
本发明的有益效果是：本发明制作的渔网加工工艺简单，通过在对聚乙烯纤维处理的过程中，进行紫外线间断辐照处理，能够使得制作的渔网具有极强的防止海藻附着的性能；通过采用MBS树脂与二羟基丙烷的共混处理，能够增强渔网的韧性，提高了渔网的承载能力；通过添加经过处理的环氧树脂胶膜，能够提高各成分之间的相容性，增加渔网的综合性能；本发明渔网具有优异的拉伸强度和耐磨性，由于尼龙纤维缺点为耐旋光性差﹐在室外长时间受日照时﹐则易生黄﹐强度下降，本发明通过采用己二胺和马来酸酐混合物对尼龙纤维进行处理，解决了这些问题，并且还极大的提高了制作的渔网的抗老化能力；通过添加处理过的凹凸棒石粉末，能够提高渔网的力学性能，增强韧性。
具体实施方式
一种防藻抗老化渔网，按重量份计由以下成分制成：聚苯乙烯10份、聚乙烯纤维50份、尼龙纤维30份、MBS树脂10份、环氧树脂胶膜10份、二甲基丙烯酸乙二醇酯3份、碳酸钙粉末0.5份、凹凸棒石粉末0.5份、邻苯二甲酸二丁酯5份、硬脂酸钙1份。
进一步地，所述聚乙烯纤维经过预先改性处理：将1%浓度的苯甲酸与10%浓度的盐酸混合，再将聚乙烯纤维放入到上述混合溶液中，加热至65-70℃，同时采用紫外线进行间断性辐照处理，持续40分钟后，过滤，干燥；所述紫外线辐照间断间隔为5分钟。
进一步地，所述增塑剂为甘油和木糖醇复合增塑剂，其中甘油与木糖醇的复合比例为4:1，复合温度在65-80℃之间。
进一步地，所述凹凸棒石经过预处理：先制备水性聚氨酯乳液，再将制备好的水性聚氨酯乳液与凹凸棒石粉末按质量比为5：1混合,加热至55-60℃，持续40分钟后，过滤；处理过的凹凸棒石粉末外表包覆层厚度约为12nm。
进一步地，所述MBS树脂与二羟基丙烷经过共混处理：将MBS树脂与二羟基丙烷共混加热，先持续加热至120℃，再缓慢冷却至室温，静置1-2小时。
进一步地，所述尼龙纤维与混合重量份为1份的己二胺和马来酸酐混合物在反应釜中进行混合处理，反应温度为110-115℃，压力为4.5MPa，反应时间为30分钟，所述己二胺和马来酸酐混合物为己二胺和马来酸酐按1:1比例混合。
进一步地，所述环氧树脂胶膜经过预处理：将环氧树脂胶膜与重量份为0.1份的十二烷基三甲氧基硅烷在碱性环境下均匀混合，加热至260℃，持续15分钟后，开始缓慢冷却，当冷却至155℃时，保温15分钟，继续冷却至128℃，保温30分钟，最后冷却到室温为止。
进一步地，所述碳酸钙粉末先采用1.5%浓度羧酸洗涤外表面，再进行干燥即可。
一种防藻抗老化渔网的制作方法为：
1）按重量份称取以下成分：聚苯乙烯10份、聚乙烯纤维50份、尼龙纤维30份、MBS树脂10份、环氧树脂胶膜10份、二甲基丙烯酸乙二醇酯3份、碳酸钙粉末0.5份、凹凸棒石粉末0.5份、邻苯二甲酸二丁酯5份、硬脂酸钙1份；
2）将上述原料经过相关处理后混合添加到挤出机中，挤出机一段温度为200℃，二段温度为220℃，三段温度为225℃，末段温度为230℃；
3）将2）中原料添加到喷丝箱中，使用喷丝装置进行拉丝，然后进行牵伸，然后在85-90℃下进行烘干，然后使用卷绕辊进行卷绕收集。
Claims (8)
1.一种防藻抗老化渔网，其特征在于，按重量份计由以下成分制成：聚苯乙烯10份、聚乙烯纤维50份、尼龙纤维30份、MBS树脂10份、环氧树脂胶膜10份、二甲基丙烯酸乙二醇酯3份、碳酸钙粉末0.5份、凹凸棒石粉末0.5份、邻苯二甲酸二丁酯5份、硬脂酸钙1份。
2.根据权利要求1所述的一种防藻抗老化渔网，其特征在于，所述聚乙烯纤维经过预先改性处理：将1%浓度的苯甲酸与10%浓度的盐酸混合，再将聚乙烯纤维放入到上述混合溶液中，加热至65-70℃，同时采用紫外线进行间断性辐照处理，持续40分钟后，过滤，干燥；所述紫外线辐照间断间隔为5分钟。
3.根据权利要求1所述的一种防藻抗老化渔网，其特征在于，所述增塑剂为甘油和木糖醇复合增塑剂，其中甘油与木糖醇的复合比例为4:1，复合温度在65-80℃之间。
4.根据权利要求1所述的一种防藻抗老化渔网，其特征在于，所述凹凸棒石经过预处理：先制备水性聚氨酯乳液，再将制备好的水性聚氨酯乳液与凹凸棒石粉末按质量比为5：1混合,加热至55-60℃，持续40分钟后，过滤；处理过的凹凸棒石粉末外表包覆层厚度约为12nm。
5.根据权利要求1所述的一种防藻抗老化渔网，其特征在于，所述MBS树脂与二羟基丙烷经过共混处理：将MBS树脂与二羟基丙烷共混加热，先持续加热至120℃，再缓慢冷却至室温，静置1-2小时。
6.根据权利要求1所述的一种防藻抗老化渔网，其特征在于，所述尼龙纤维与混合重量份为1份的己二胺和马来酸酐混合物在反应釜中进行混合处理，反应温度为110-115℃，压力为4.5MPa，反应时间为30分钟，所述己二胺和马来酸酐混合物为己二胺和马来酸酐按1:1比例混合。
7.根据权利要求1所述的一种防藻抗老化渔网，其特征在于，所述环氧树脂胶膜经过预处理：将环氧树脂胶膜与重量份为0.1份的十二烷基三甲氧基硅烷在碱性环境下均匀混合，加热至260℃，持续15分钟后，开始缓慢冷却，当冷却至155℃时，保温15分钟，继续冷却至128℃，保温30分钟，最后冷却到室温为止。
8.根据权利要求1所述的一种防藻抗老化渔网，其特征在于，所述碳酸钙粉末先采用1.5%浓度羧酸洗涤外表面，再进行干燥即可。
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