CN105860220A - 一种高强度抗老化渔网 - Google Patents

一种高强度抗老化渔网 Download PDF

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CN105860220A
CN105860220A CN201610328164.6A CN201610328164A CN105860220A CN 105860220 A CN105860220 A CN 105860220A CN 201610328164 A CN201610328164 A CN 201610328164A CN 105860220 A CN105860220 A CN 105860220A
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fishing net
strength
parts
minutes
ageing resistance
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胡文龙
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CHAOHU XIANGYU FISHING GEAR Co Ltd
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Abstract

发明公开了一种高强度抗老化渔网，由以下成分制成：聚苯乙烯、2‑甲基咪唑、聚乙烯纤维、玻璃纤维、环氧树脂胶膜、纳米陶土、尼龙纤维、二甲基丙烯酸乙二醇酯、碳酸钙粉末、凹凸棒石粉末、邻苯二甲酸二丁酯、硬脂酸钙。本发明制作的渔网加工工艺简单，通过采用对聚乙烯纤维进行预先改性处理，极大的提高了制作出的渔网的性能，由于尼龙纤维缺点为耐旋光性差，在室外长时间受日照时，则易生黄，强度下降，本发明通过采用己二胺和马来酸酐混合物对尼龙纤维进行处理，解决了这些问题，并且还极大的提高了制作的渔网的抗老化能力；通过采用经过处理后的玻璃纤维，配合改性纳米陶土，极大的增强渔网的强度和韧性，提高了渔网的耐水性。

Description

一种高强度抗老化渔网
技术领域
本发明涉及渔具领域，特别是涉及一种高强度抗老化渔网。
背景技术
现代渔网主要采用聚乙烯，尼龙等原料进行加工，有较长的使用周期，和更高的捕捞效率，但是聚乙烯本身的力学性能一般，拉伸强度较低，抗蠕变性不好，就导致传统渔网的强度、耐磨性能、韧性不适宜于复杂海底和大风大浪环境捕捞作业，降低了渔具的使用寿命，不仅浪费资源，还直接影响渔获量；并且现有的许多渔网，强度低，寿命短。
发明内容
本发明的目的是提供一种高强度抗老化渔网，通过以下技术方案实现：
一种高强度抗老化渔网，按重量份计由以下成分制成：聚苯乙烯15份、2-甲基咪唑2份、聚乙烯纤维50份、玻璃纤维10份、环氧树脂胶膜10份、纳米陶土0.5份、尼龙纤维30份、二甲基丙烯酸乙二醇酯3份、碳酸钙粉末0.5份、凹凸棒石粉末0.5份、邻苯二甲酸二丁酯5份、硬脂酸钙1份。
进一步地，所述聚乙烯纤维经过预先改性处理：将1%浓度的苯甲酸与10%浓度的盐酸混合，再将聚乙烯纤维放入到上述混合溶液中，加热至65-70℃，持续15分钟后，过滤，干燥。
进一步地，所述增塑剂为甘油和木糖醇复合增塑剂，其中甘油与木糖醇的复合比例为4:1，复合温度在65-80℃之间。
进一步地，所述凹凸棒石经过预处理：先制备水性聚氨酯乳液，再将制备好的水性聚氨酯乳液与凹凸棒石粉末按质量比为5：1混合,加热至55-60℃，持续40分钟后，过滤；处理过的凹凸棒石粉末外表包覆层厚度约为12nm。
进一步地，所述玻璃纤维先浸泡在1.5%浓度的氢氧化钠溶液中加热至70-80℃，1-1.5小时后，添加重量份为0.1份的羧甲基纤维素钠，加热至85-90℃，持续40分钟后，过滤，干燥。
进一步地，所述尼龙纤维与混合重量份为1份的己二胺和马来酸酐混合物在反应釜中进行混合处理，反应温度为110-115℃，压力为4.5MPa，反应时间为30分钟；所述己二胺和马来酸酐混合物为己二胺和马来酸酐按1:1比例混合。
进一步地，所述环氧树脂胶膜经过预处理：将环氧树脂胶膜与重量份为0.1份的十二烷基三甲氧基硅烷在碱性环境下均匀混合，加热至260℃，持续15分钟后，开始缓慢冷却，当冷却至155℃时，保温15分钟，继续冷却至128℃，保温30分钟，最后冷却到室温为止。
进一步地，所述碳酸钙粉末先采用1.5%浓度羧酸洗涤外表面，再进行干燥即可。
进一步地，所述纳米陶土经过改性处理：将纳米陶土在160℃下与重量份为0.5份的二月桂酸二丁基锡混合处理15分钟；所述纳米陶土粒度为15-20nm。
本发明的有益效果是：本发明制作的渔网加工工艺简单，通过采用对聚乙烯纤维进行预先改性处理，极大的提高了制作出的渔网的性能，由于尼龙纤维缺点为耐旋光性差﹐在室外长时间受日照时﹐则易生黄﹐强度下降，本发明通过采用己二胺和马来酸酐混合物对尼龙纤维进行处理，解决了这些问题，并且还极大的提高了制作的渔网的抗老化能力；通过采用经过处理后的玻璃纤维，配合改性纳米陶土，极大的增强渔网的强度和韧性，提高了渔网的耐水性；通过添加经过处理的环氧树脂胶膜，进一步能够提高各成分之间的相容性，增加渔网的综合性能；通过添加处理过的凹凸棒石粉末，能够提高渔网的力学性能，增强韧性。
具体实施方式
一种高强度抗老化渔网，按重量份计由以下成分制成：聚苯乙烯15份、2-甲基咪唑2份、聚乙烯纤维50份、玻璃纤维10份、环氧树脂胶膜10份、纳米陶土0.5份、尼龙纤维30份、二甲基丙烯酸乙二醇酯3份、碳酸钙粉末0.5份、凹凸棒石粉末0.5份、邻苯二甲酸二丁酯5份、硬脂酸钙1份。
进一步地，所述聚乙烯纤维经过预先改性处理：将1%浓度的苯甲酸与10%浓度的盐酸混合，再将聚乙烯纤维放入到上述混合溶液中，加热至65-70℃，持续15分钟后，过滤，干燥。
进一步地，所述增塑剂为甘油和木糖醇复合增塑剂，其中甘油与木糖醇的复合比例为4:1，复合温度在65-80℃之间。
进一步地，所述凹凸棒石经过预处理：先制备水性聚氨酯乳液，再将制备好的水性聚氨酯乳液与凹凸棒石粉末按质量比为5：1混合,加热至55-60℃，持续40分钟后，过滤；处理过的凹凸棒石粉末外表包覆层厚度约为12nm。
进一步地，所述玻璃纤维先浸泡在1.5%浓度的氢氧化钠溶液中加热至70-80℃，1-1.5小时后，添加重量份为0.1份的羧甲基纤维素钠，加热至85-90℃，持续40分钟后，过滤，干燥。
进一步地，所述尼龙纤维与混合重量份为1份的己二胺和马来酸酐混合物在反应釜中进行混合处理，反应温度为110-115℃，压力为4.5MPa，反应时间为30分钟；所述己二胺和马来酸酐混合物为己二胺和马来酸酐按1:1比例混合。
进一步地，所述环氧树脂胶膜经过预处理：将环氧树脂胶膜与重量份为0.1份的十二烷基三甲氧基硅烷在碱性环境下均匀混合，加热至260℃，持续15分钟后，开始缓慢冷却，当冷却至155℃时，保温15分钟，继续冷却至128℃，保温30分钟，最后冷却到室温为止。
进一步地，所述碳酸钙粉末先采用1.5%浓度羧酸洗涤外表面，再进行干燥即可。
进一步地，所述纳米陶土经过改性处理：将纳米陶土在160℃下与重量份为0.5份的二月桂酸二丁基锡混合处理15分钟；所述纳米陶土粒度为15-20nm。
一种高强度抗老化渔网的制作方法为：
1）按重量份称取以下成分：聚苯乙烯15份、2-甲基咪唑2份、聚乙烯纤维50份、玻璃纤维10份、环氧树脂胶膜10份、纳米陶土0.5份、尼龙纤维30份、二甲基丙烯酸乙二醇酯3份、碳酸钙粉末0.5份、凹凸棒石粉末0.5份、邻苯二甲酸二丁酯5份、硬脂酸钙1份；
2）将上述原料经过相关处理后混合添加到挤出机中，挤出机一段温度为 200℃，二段温度为 220℃，三段温度为225℃，末段温度为230℃；
3）将2）中原料添加到喷丝箱中，使用喷丝装置进行拉丝，然后进行牵伸，然后在 85-90℃下进行烘干，然后使用卷绕辊进行卷绕收集。

Claims (9)

1.一种高强度抗老化渔网，其特征在于，按重量份计由以下成分制成：聚苯乙烯15份、2-甲基咪唑2份、聚乙烯纤维50份、玻璃纤维10份、环氧树脂胶膜10份、纳米陶土0.5份、尼龙纤维30份、二甲基丙烯酸乙二醇酯3份、碳酸钙粉末0.5份、凹凸棒石粉末0.5份、邻苯二甲酸二丁酯5份、硬脂酸钙1份。
2.根据权利要求1所述的一种高强度抗老化渔网，其特征在于，所述聚乙烯纤维经过预先改性处理：将1%浓度的苯甲酸与10%浓度的盐酸混合，再将聚乙烯纤维放入到上述混合溶液中，加热至65-70℃，持续15分钟后，过滤，干燥。
3.根据权利要求1所述的一种高强度抗老化渔网，其特征在于，所述增塑剂为甘油和木糖醇复合增塑剂，其中甘油与木糖醇的复合比例为4:1，复合温度在65-80℃之间。
4.根据权利要求1所述的一种高强度抗老化渔网，其特征在于，所述凹凸棒石经过预处理：先制备水性聚氨酯乳液，再将制备好的水性聚氨酯乳液与凹凸棒石粉末按质量比为5：1混合,加热至55-60℃，持续40分钟后，过滤；处理过的凹凸棒石粉末外表包覆层厚度约为12nm。
5.根据权利要求1所述的一种高强度抗老化渔网，其特征在于，所述玻璃纤维先浸泡在1.5%浓度的氢氧化钠溶液中加热至70-80℃，1-1.5小时后，添加重量份为0.1份的羧甲基纤维素钠，加热至85-90℃，持续40分钟后，过滤，干燥。
6.根据权利要求1所述的一种高强度抗老化渔网，其特征在于，所述尼龙纤维与混合重量份为1份的己二胺和马来酸酐混合物在反应釜中进行混合处理，反应温度为110-115℃，压力为4.5MPa，反应时间为30分钟；所述己二胺和马来酸酐混合物为己二胺和马来酸酐按1:1比例混合。
7.根据权利要求1所述的一种高强度抗老化渔网，其特征在于，所述环氧树脂胶膜经过预处理：将环氧树脂胶膜与重量份为0.1份的十二烷基三甲氧基硅烷在碱性环境下均匀混合，加热至260℃，持续15分钟后，开始缓慢冷却，当冷却至155℃时，保温15分钟，继续冷却至128℃，保温30分钟，最后冷却到室温为止。
8.根据权利要求1所述的一种高强度抗老化渔网，其特征在于，所述碳酸钙粉末先采用1.5%浓度羧酸洗涤外表面，再进行干燥即可。
9.根据权利要求1所述的一种高强度抗老化渔网，其特征在于，所述纳米陶土经过改性处理：将纳米陶土在160℃下与重量份为0.5份的二月桂酸二丁基锡混合处理15分钟；所述纳米陶土粒度为15-20nm。
CN201610328164.6A 2016-05-18 2016-05-18 一种高强度抗老化渔网 Pending CN105860220A (zh)

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