CN105821506A - 一种防藻渔网线 - Google Patents
一种防藻渔网线 Download PDFInfo
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- CN105821506A CN105821506A CN201610233969.2A CN201610233969A CN105821506A CN 105821506 A CN105821506 A CN 105821506A CN 201610233969 A CN201610233969 A CN 201610233969A CN 105821506 A CN105821506 A CN 105821506A
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 241000195493 Cryptophyta Species 0.000 claims abstract description 21
- 239000003094 microcapsule Substances 0.000 claims abstract description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 18
- 239000011248 coating agent Substances 0.000 claims abstract description 16
- 238000000576 coating method Methods 0.000 claims abstract description 16
- 239000000835 fiber Substances 0.000 claims abstract description 14
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000004698 Polyethylene Substances 0.000 claims abstract description 10
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 claims abstract description 10
- -1 polyethylene Polymers 0.000 claims abstract description 10
- 229920000573 polyethylene Polymers 0.000 claims abstract description 10
- 229920000903 polyhydroxyalkanoate Polymers 0.000 claims abstract description 10
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000005011 phenolic resin Substances 0.000 claims abstract description 9
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 9
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 9
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000049 pigment Substances 0.000 claims description 12
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 8
- 239000003431 cross linking reagent Substances 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 8
- 238000001125 extrusion Methods 0.000 claims description 8
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 8
- 238000004804 winding Methods 0.000 claims description 8
- 239000004925 Acrylic resin Substances 0.000 claims description 4
- 229920000178 Acrylic resin Polymers 0.000 claims description 4
- 102000004190 Enzymes Human genes 0.000 claims description 4
- 108090000790 Enzymes Proteins 0.000 claims description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 238000007796 conventional method Methods 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 238000005538 encapsulation Methods 0.000 claims description 4
- 239000012948 isocyanate Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 238000006396 nitration reaction Methods 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 238000007711 solidification Methods 0.000 claims description 4
- 230000008023 solidification Effects 0.000 claims description 4
- 238000009987 spinning Methods 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- GVCGWXSZNUOTDW-UHFFFAOYSA-N sulfo cyanate Chemical compound OS(=O)(=O)OC#N GVCGWXSZNUOTDW-UHFFFAOYSA-N 0.000 claims description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 4
- 238000005491 wire drawing Methods 0.000 claims description 4
- 239000008096 xylene Substances 0.000 claims description 4
- 150000003738 xylenes Chemical class 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 1
- 239000004677 Nylon Substances 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
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- D01D5/00—Formation of filaments, threads, or the like
- D01D5/12—Stretch-spinning methods
- D01D5/16—Stretch-spinning methods using rollers, or like mechanical devices, e.g. snubbing pins
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- D01F1/00—General methods for the manufacture of artificial filaments or the like
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Abstract
本发明公开了一种防藻渔网线,由聚乙烯纤维、轻质碳酸钙、酚醛树脂、二氧化硅、氧化钛、松香、聚羟基脂肪酸酯、防藻微胶囊、有机涂料制成。本发明原料中加入了聚乙烯纤维、聚羟基脂肪酸酯、防藻微胶囊、有机涂料,使得在保证渔网的耐酸碱性之外,还具有长效防藻的作用。
Description
技术领域
本发明涉及一种渔网线,具体为一种防藻渔网线。
背景技术
渔网线是指编制网片和缝扎网渔具的直径小于4毫米的线,是制作渔网的主要材料。现在的渔网线主要是用尼龙原料制备,但是尼龙加工工艺复杂,对温度、湿度要求苛刻,成品率低,而且尼龙成本较高,吸水率也较高,造成渔网易腐蚀,而且在长时间的使用中,容易受到海水中藻的感染,从而影响了捕鱼效率,并且会降低渔网的使用寿命,增加了渔民的投资成本。
发明内容
为解决以上问题,本发明旨在提供一种能够长效防藻的渔网线,由以下技术方案实现:
一种防藻渔网线,其特征在于由以下原料制成:聚乙烯纤维175-185、轻质碳酸钙7-10、酚醛树脂4-6、二氧化硅6-8、氧化钛2-3、松香5-7、聚羟基脂肪酸酯7-12、防藻微胶囊3-7、有机涂料5-8。
作为优选,所述的有机涂料由以下重量份的原料制成:有机硅树脂45-55、硅油8-20、钛白粉2-4、硅酸铝纤维2-5、硅烷类偶联剂3-6、交联剂1-2、溶剂6-10、功能荧光颜料3-5。
作为优选,所述的交联剂为2,6-甲苯二异氰酸酯。
作为优选,所述的溶剂为混合二甲苯。
作为优选,所述的功能荧光颜料为市售水乳型红、绿、黄色颜料。
作为优选,所述的防藻微胶囊由以下重量份的原料制成:硫氰酸亚铜10,氧化锰3-5,丙烯酸树脂20-25,纯丙乳液10-15,钛白粉4-5,滑石粉3-5;将以上原料混合后经过包囊、酶固化制作成粒径为50-60um的防藻微胶囊。
作为优选,一种防藻渔网线由以下步骤制成:
(1)将聚乙烯纤维、轻质碳酸钙、酚醛树脂混合后置于60-70℃下混合均匀,然后加入二氧化硅、氧化钛、松香、聚羟基脂肪酸酯、防藻微胶囊,于80-90℃下搅拌均匀,然后将混合物放入挤出机挤出,挤出机一段温度为150-160℃,二段温度为155-170℃,三段温度为158-174℃,末段温度为162-175℃。
(2)挤出后加入喷丝箱,然后使用喷丝装置进行拉丝,然后进行牵伸,第一牵伸辊压力为0.85-0.90bar、第二牵伸辊压力为3.05-3.12bar,然后在85-92℃下进行烘干,然后使用卷绕辊进行卷绕,第一卷绕辊转速为3000m/min,第二卷绕辊转速为3200m/min,第三卷绕辊转速为3700m/min,进行进一步牵伸,然后进行卷绕得到线材。
(3)将有机涂料用常规方法涂布于线材上即可。
有益效果:为了达到良好的防藻效果,本发明添加了防藻微胶囊与有机涂料,有机涂料具有一定的防藻作用;防藻微胶囊可缓慢释放防藻物质,具有长效的防藻作用,与其他同类产品相比防藻能力提高了2-3倍。同时,由于防藻微胶囊粒径很小(50-60um),在实际生产中对渔网线的线材质量几乎没有影响。
具体实施方式
实施例1:
一种防藻渔网线,由以下原料制成:聚乙烯纤维178、轻质碳酸钙8.5、酚醛树脂5.2、二氧化硅6.8、氧化钛2.3、松香5.7、聚羟基脂肪酸酯8.2、防藻微胶囊5、有机涂料6。
作为优选,所述的有机涂料由以下重量份的原料制成:有机硅树脂52、硅油15、钛白粉3、硅酸铝纤维4、硅烷类偶联剂4.2、交联剂1.2、溶剂8.5、功能荧光颜料4.5。
作为优选,所述的交联剂为2,6-甲苯二异氰酸酯。
作为优选,所述的溶剂为混合二甲苯。
作为优选,所述的功能荧光颜料为市售水乳型红、绿、黄色颜料。
作为优选,所述的防藻微胶囊由以下重量份的原料制成:硫氰酸亚铜8,氧化锰4,丙烯酸树脂25,纯丙乳液13,钛白粉4.4,滑石粉3.8;将以上原料混合后经过包囊、酶固化制作成防藻微胶囊。
作为优选,一种防藻渔网线由以下步骤制成:
(1)将聚乙烯纤维、轻质碳酸钙、酚醛树脂混合后置于66℃下混合均匀,然后加入二氧化硅、氧化钛、松香、聚羟基脂肪酸酯、防藻微胶囊,于86℃下搅拌均匀,然后将混合物放入挤出机挤出,挤出机一段温度为155℃,二段温度为165℃,三段温度为166℃,末段温度为171℃。
(2)挤出后加入喷丝箱,然后使用喷丝装置进行拉丝,然后进行牵伸,第一牵伸辊压力为0.86bar、第二牵伸辊压力为3.07bar,然后在90℃下进行烘干,然后使用卷绕辊进行卷绕,第一卷绕辊转速为3000m/min,第二卷绕辊转速为3200m/min,第三卷绕辊转速为3700m/min,进行进一步牵伸,然后进行卷绕得到线材。
(3)将有机涂料用常规方法涂布于线材上即可。
实施例2:
一种防藻渔网线,由以下原料制成:聚乙烯纤维185、轻质碳酸钙8、酚醛树脂5.5、二氧化硅6.5、氧化钛2.7、松香5.2、聚羟基脂肪酸酯8.5、防藻微胶囊4.8、有机涂料5.6。
作为优选,所述的有机涂料由以下重量份的原料制成:有机硅树脂54、硅油12、钛白粉3.4、硅酸铝纤维4.2、硅烷类偶联剂4.5、交联剂1、溶剂8.1、功能荧光颜料4.8。
作为优选,所述的交联剂为2,6-甲苯二异氰酸酯。
作为优选,所述的溶剂为混合二甲苯。
作为优选,所述的功能荧光颜料为市售水乳型红、绿、黄色颜料。
作为优选,所述的防藻微胶囊由以下重量份的原料制成:硫氰酸亚铜8.5,氧化锰4.6,丙烯酸树脂22,纯丙乳液12,钛白粉4.5,滑石粉3.9;将以上原料混合后经过包囊、酶固化制作成防藻微胶囊。
作为优选,一种防藻渔网线由以下步骤制成:
(1)将聚乙烯纤维、轻质碳酸钙、酚醛树脂混合后置于66℃下混合均匀,然后加入二氧化硅、氧化钛、松香、聚羟基脂肪酸酯、防藻微胶囊,于86℃下搅拌均匀,然后将混合物放入挤出机挤出,挤出机一段温度为155℃,二段温度为159℃,三段温度为162℃,末段温度为169℃。
(2)挤出后加入喷丝箱,然后使用喷丝装置进行拉丝,然后进行牵伸,第一牵伸辊压力为0.89bar、第二牵伸辊压力为3.08bar,然后在89℃下进行烘干,然后使用卷绕辊进行卷绕,第一卷绕辊转速为3000m/min,第二卷绕辊转速为3200m/min,第三卷绕辊转速为3700m/min,进行进一步牵伸,然后进行卷绕得到线材。
(3)将有机涂料用常规方法涂布于线材上即可。
实施例3:
将实施例1、2与市售防藻渔网线编成渔网后,放于同一海域30天、60天后取出,对比其防藻效果,结果如下表:
由以上数据对比可知本发明的防藻效果好,防藻时效长。
Claims (7)
1.一种防藻渔网线,其特征在于由以下原料制成:聚乙烯纤维175-185、轻质碳酸钙7-10、酚醛树脂4-6、二氧化硅6-8、氧化钛2-3、松香5-7、聚羟基脂肪酸酯7-12、防藻微胶囊4-7、有机涂料5-8。
2.如权利要求1所述的一种防藻渔网线,其特征在于所述的有机涂料由以下重量份的原料制成:有机硅树脂175-185、硅油8-20、钛白粉2-4、硅酸铝纤维2-5、硅烷类偶联剂3-6、交联剂1-2、溶剂6-10、功能荧光颜料3-5。
3.根据权利要求1所述的一种防藻渔网线,其特征在于:所述的交联剂为2,6-甲苯二异氰酸酯。
4.根据权利要求1所述的一种防藻渔网线,其特征在于:所述的溶剂为混合二甲苯。
5.根据权利要求1所述的一种防藻渔网线,其特征在于:所述的功能荧光颜料为市售水乳型红、绿、黄色颜料。
6.根据权利要求1所述的一种防藻渔网线,其特征在于:所述的防藻微胶囊由以下重量份的原料制成:硫氰酸亚铜10,氧化锰3-5,丙烯酸树脂20-25,纯丙乳液10-15,钛白粉4-5,滑石粉3-5;将以上原料混合后经过包囊、酶固化制作成防藻微胶囊。
7.一种防藻渔网线,其特征在于由以下步骤制成:
(1)将聚乙烯纤维、轻质碳酸钙、酚醛树脂混合后置于60-70℃下混合均匀,然后加入二氧化硅、氧化钛、松香、聚羟基脂肪酸酯、防藻微胶囊,于80-90℃下搅拌均匀,然后将混合物放入挤出机挤出,挤出机一段温度为150-160℃,二段温度为155-170℃,三段温度为158-174℃,末段温度为162-175℃。
(2)挤出后加入喷丝箱,然后使用喷丝装置进行拉丝,然后进行牵伸,第一牵伸辊压力为0.85-0.90bar、第二牵伸辊压力为3.05-3.12bar,然后在85-92℃下进行烘干,然后使用卷绕辊进行卷绕,第一卷绕辊转速为3000m/min,第二卷绕辊转速为3200m/min,第三卷绕辊转速为3700m/min,进行进一步牵伸,然后进行卷绕得到线材。
(3)将有机涂料用常规方法涂布于线材上即可。
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