CN105384949B - 一种阴离子乳化剂及其制备方法与应用 - Google Patents
一种阴离子乳化剂及其制备方法与应用 Download PDFInfo
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- CN105384949B CN105384949B CN201510883957.XA CN201510883957A CN105384949B CN 105384949 B CN105384949 B CN 105384949B CN 201510883957 A CN201510883957 A CN 201510883957A CN 105384949 B CN105384949 B CN 105384949B
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- epoxy
- anion emulsifier
- epoxy resin
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- sulfonic acid
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- 150000001450 anions Chemical class 0.000 title claims abstract description 55
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
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- 239000003822 epoxy resin Substances 0.000 claims abstract description 30
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 30
- 239000003085 diluting agent Substances 0.000 claims abstract description 26
- HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229950000244 sulfanilic acid Drugs 0.000 claims abstract description 17
- 239000007787 solid Substances 0.000 claims abstract description 16
- 239000000839 emulsion Substances 0.000 claims abstract description 15
- 239000003054 catalyst Substances 0.000 claims abstract description 13
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 230000001804 emulsifying effect Effects 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 11
- 238000010792 warming Methods 0.000 claims description 9
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 6
- 229960002887 deanol Drugs 0.000 claims description 6
- 239000012972 dimethylethanolamine Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000013557 residual solvent Substances 0.000 claims description 6
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 claims description 5
- QNYBOILAKBSWFG-UHFFFAOYSA-N 2-(phenylmethoxymethyl)oxirane Chemical compound C1OC1COCC1=CC=CC=C1 QNYBOILAKBSWFG-UHFFFAOYSA-N 0.000 claims description 5
- 125000000129 anionic group Chemical group 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 4
- 239000010426 asphalt Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 3
- ZAJAQTYSTDTMCU-UHFFFAOYSA-N 3-aminobenzenesulfonic acid Chemical compound NC1=CC=CC(S(O)(=O)=O)=C1 ZAJAQTYSTDTMCU-UHFFFAOYSA-N 0.000 claims description 2
- 229940106691 bisphenol a Drugs 0.000 claims description 2
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 claims description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 claims 4
- 150000002576 ketones Chemical class 0.000 claims 2
- JCYHHICXJAGYEL-UHFFFAOYSA-N 3-butoxypropane-1,2-diol Chemical compound CCCCOCC(O)CO JCYHHICXJAGYEL-UHFFFAOYSA-N 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 239000003973 paint Substances 0.000 abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 10
- 239000002994 raw material Substances 0.000 abstract description 4
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 abstract description 3
- 229940092714 benzenesulfonic acid Drugs 0.000 abstract description 2
- 230000005012 migration Effects 0.000 abstract description 2
- 238000013508 migration Methods 0.000 abstract description 2
- 230000004044 response Effects 0.000 abstract description 2
- 125000003700 epoxy group Chemical group 0.000 abstract 1
- 239000004848 polyfunctional curative Substances 0.000 abstract 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
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- 239000000126 substance Substances 0.000 description 3
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- 238000002474 experimental method Methods 0.000 description 2
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- 150000003839 salts Chemical class 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
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- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
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- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 206010041954 Starvation Diseases 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
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- -1 alcohol ethers Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
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- 230000008901 benefit Effects 0.000 description 1
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- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
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- 238000004140 cleaning Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
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- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
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- 239000000049 pigment Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Landscapes
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Paints Or Removers (AREA)
Abstract
Description
实验组1 | 实验组2 | 实验组1 | |
乳化能力 | 30 | 15 | 21 |
漆膜耐水性 | 7天 | 90天 | 90天 |
耐盐雾性能 | 48h | 500h | 800h |
Claims (10)
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CN201510883957.XA CN105384949B (zh) | 2015-12-04 | 2015-12-04 | 一种阴离子乳化剂及其制备方法与应用 |
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CN201510883957.XA CN105384949B (zh) | 2015-12-04 | 2015-12-04 | 一种阴离子乳化剂及其制备方法与应用 |
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CN105384949A CN105384949A (zh) | 2016-03-09 |
CN105384949B true CN105384949B (zh) | 2017-12-01 |
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Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105925148A (zh) * | 2016-06-15 | 2016-09-07 | 青岛源之林农业科技开发有限公司 | 一种耐腐蚀取样器及其制备方法 |
CN106010137A (zh) * | 2016-06-15 | 2016-10-12 | 青岛源之林农业科技开发有限公司 | 一种耐腐蚀金属连杆及其制备方法 |
CN106085106A (zh) * | 2016-06-15 | 2016-11-09 | 青岛源之林农业科技开发有限公司 | 一种水性防腐涂料及其制备方法 |
CN106221506B (zh) * | 2016-08-30 | 2017-06-30 | 河北晨阳工贸集团有限公司 | 一种环氧乳液及其制备方法 |
CN111100329B (zh) * | 2018-10-29 | 2021-08-17 | 奕益实业股份有限公司 | 供作为树脂滑剂的化合物、其制备方法及用途与树脂滑剂 |
CN111378095B (zh) * | 2018-12-29 | 2023-05-26 | 万华化学集团股份有限公司 | 乳化剂制备方法及乳化剂、环氧树脂水分散体及配制方法 |
US20220055000A1 (en) | 2018-12-29 | 2022-02-24 | Wanhua Chemical Group Co., Ltd. | Preparation method for emulsifier, emulsifier, aqueous epoxy resin dispersion and formulation method |
CN116284687A (zh) * | 2023-04-10 | 2023-06-23 | 湖南林特科技有限公司 | 一种环氧乳化剂、丙烯酸酯改性环氧树脂乳液及其制备方法 |
Citations (5)
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---|---|---|---|---|
US5189081A (en) * | 1988-07-04 | 1993-02-23 | Somar Corporation | Penetrable, epoxy resin composition comprising glycidyl ether of bisphenol modified with glycol or urethane, and inorganic filler |
CN1891771A (zh) * | 2005-07-05 | 2007-01-10 | 浙江安邦新材料发展有限公司 | 一种用于水性环氧涂料的环氧固化剂乳液及其制备方法 |
CN102942683A (zh) * | 2012-11-29 | 2013-02-27 | 湖南大学 | 一种复合环氧树脂乳化剂及其制备方法 |
CN103497338A (zh) * | 2013-07-29 | 2014-01-08 | 中国石油大学(华东) | 水性环氧涂料中离子型环氧树脂专用乳化剂的制备及应用方法 |
CN104004204A (zh) * | 2014-05-12 | 2014-08-27 | 华南理工大学 | 一种含环氧基团的磺酸盐型双阴离子乳化剂及其制备方法 |
Family Cites Families (1)
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CA2818334A1 (en) * | 2010-11-17 | 2012-05-24 | Dow Global Technologies Llc | Process using bisphenol a aminated and alkoxylated derivative as demulsifier |
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Patent Citations (5)
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US5189081A (en) * | 1988-07-04 | 1993-02-23 | Somar Corporation | Penetrable, epoxy resin composition comprising glycidyl ether of bisphenol modified with glycol or urethane, and inorganic filler |
CN1891771A (zh) * | 2005-07-05 | 2007-01-10 | 浙江安邦新材料发展有限公司 | 一种用于水性环氧涂料的环氧固化剂乳液及其制备方法 |
CN102942683A (zh) * | 2012-11-29 | 2013-02-27 | 湖南大学 | 一种复合环氧树脂乳化剂及其制备方法 |
CN103497338A (zh) * | 2013-07-29 | 2014-01-08 | 中国石油大学(华东) | 水性环氧涂料中离子型环氧树脂专用乳化剂的制备及应用方法 |
CN104004204A (zh) * | 2014-05-12 | 2014-08-27 | 华南理工大学 | 一种含环氧基团的磺酸盐型双阴离子乳化剂及其制备方法 |
Non-Patent Citations (1)
Title |
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复合乳化剂制备水性环氧乳液及涂膜性能研究;黄娟萍 等;《涂料工业》;20130601;第43卷(第6期);38-43 * |
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