CN104923270B - 基于viiib族金属和包含氧化铝、二氧化硅、尖晶石和磷的氧化物载体的费托催化剂 - Google Patents
基于viiib族金属和包含氧化铝、二氧化硅、尖晶石和磷的氧化物载体的费托催化剂 Download PDFInfo
- Publication number
- CN104923270B CN104923270B CN201510124262.3A CN201510124262A CN104923270B CN 104923270 B CN104923270 B CN 104923270B CN 201510124262 A CN201510124262 A CN 201510124262A CN 104923270 B CN104923270 B CN 104923270B
- Authority
- CN
- China
- Prior art keywords
- catalyst
- weight
- silica
- cobalt
- carrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 185
- 239000003054 catalyst Substances 0.000 title claims abstract description 161
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title claims abstract description 148
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 92
- 229910052698 phosphorus Inorganic materials 0.000 title claims abstract description 91
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 79
- 239000011574 phosphorus Substances 0.000 title claims abstract description 79
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 65
- 239000002184 metal Substances 0.000 title claims abstract description 65
- 239000010941 cobalt Substances 0.000 claims abstract description 107
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 107
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 106
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 73
- 238000000034 method Methods 0.000 claims abstract description 56
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 33
- 230000008569 process Effects 0.000 claims abstract description 33
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 32
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052742 iron Inorganic materials 0.000 claims abstract description 12
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 11
- 238000001354 calcination Methods 0.000 claims description 35
- 238000001035 drying Methods 0.000 claims description 35
- 230000015572 biosynthetic process Effects 0.000 claims description 32
- 239000011148 porous material Substances 0.000 claims description 29
- 239000011777 magnesium Substances 0.000 claims description 25
- 238000003786 synthesis reaction Methods 0.000 claims description 22
- 239000011575 calcium Substances 0.000 claims description 21
- 239000011734 sodium Substances 0.000 claims description 20
- 239000010949 copper Substances 0.000 claims description 19
- 239000011135 tin Substances 0.000 claims description 19
- 239000002019 doping agent Substances 0.000 claims description 18
- 239000011572 manganese Substances 0.000 claims description 18
- 229910052749 magnesium Inorganic materials 0.000 claims description 15
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 14
- 150000002430 hydrocarbons Chemical class 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 12
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 11
- 229910052791 calcium Inorganic materials 0.000 claims description 11
- 239000007789 gas Substances 0.000 claims description 11
- 229930195733 hydrocarbon Natural products 0.000 claims description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 229910052700 potassium Inorganic materials 0.000 claims description 10
- 239000011591 potassium Substances 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 229910052718 tin Inorganic materials 0.000 claims description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 9
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 9
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 9
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 9
- 229910052792 caesium Inorganic materials 0.000 claims description 9
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 9
- 229910052744 lithium Inorganic materials 0.000 claims description 9
- 229910052748 manganese Inorganic materials 0.000 claims description 9
- 239000012688 phosphorus precursor Substances 0.000 claims description 9
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 claims description 8
- 230000000694 effects Effects 0.000 claims description 6
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 6
- 239000011701 zinc Chemical group 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 5
- 229910052753 mercury Inorganic materials 0.000 claims description 5
- 229910000510 noble metal Inorganic materials 0.000 claims description 5
- 238000002459 porosimetry Methods 0.000 claims description 5
- 229910052725 zinc Chemical group 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 238000007598 dipping method Methods 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 2
- 230000002194 synthesizing effect Effects 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims 2
- 230000007717 exclusion Effects 0.000 claims 2
- 241000790917 Dioxys <bee> Species 0.000 claims 1
- 229910003978 SiClx Inorganic materials 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 229910000420 cerium oxide Inorganic materials 0.000 claims 1
- 239000004744 fabric Substances 0.000 claims 1
- 229910000480 nickel oxide Inorganic materials 0.000 claims 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 claims 1
- 239000004408 titanium dioxide Substances 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- 229910052596 spinel Inorganic materials 0.000 abstract description 101
- 239000011029 spinel Substances 0.000 abstract description 101
- 230000003197 catalytic effect Effects 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000007787 solid Substances 0.000 description 56
- 239000012071 phase Substances 0.000 description 52
- 239000000243 solution Substances 0.000 description 41
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 27
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 26
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 26
- 239000007864 aqueous solution Substances 0.000 description 25
- 238000005470 impregnation Methods 0.000 description 23
- 229910052710 silicon Inorganic materials 0.000 description 21
- 150000002739 metals Chemical class 0.000 description 20
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 18
- 239000002243 precursor Substances 0.000 description 18
- 239000010703 silicon Substances 0.000 description 18
- 150000004645 aluminates Chemical class 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 14
- 239000002002 slurry Substances 0.000 description 14
- CRHLEZORXKQUEI-UHFFFAOYSA-N dialuminum;cobalt(2+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Co+2].[Co+2] CRHLEZORXKQUEI-UHFFFAOYSA-N 0.000 description 13
- 239000000543 intermediate Substances 0.000 description 13
- 238000009826 distribution Methods 0.000 description 12
- 239000000843 powder Substances 0.000 description 12
- 239000002245 particle Substances 0.000 description 11
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 10
- 229910001593 boehmite Inorganic materials 0.000 description 10
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 10
- 235000011007 phosphoric acid Nutrition 0.000 description 10
- 229910052566 spinel group Inorganic materials 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 238000003837 high-temperature calcination Methods 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 229910004298 SiO 2 Inorganic materials 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 229910052681 coesite Inorganic materials 0.000 description 5
- 229910052906 cristobalite Inorganic materials 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- 229910052682 stishovite Inorganic materials 0.000 description 5
- 229910052905 tridymite Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000004517 catalytic hydrocracking Methods 0.000 description 4
- 239000003245 coal Substances 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- -1 preferably cobalt Chemical compound 0.000 description 4
- 239000002028 Biomass Substances 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 230000002902 bimodal effect Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000010981 drying operation Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 150000002823 nitrates Chemical class 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 2
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 150000003841 chloride salts Chemical class 0.000 description 2
- 229940011182 cobalt acetate Drugs 0.000 description 2
- MULYSYXKGICWJF-UHFFFAOYSA-L cobalt(2+);oxalate Chemical compound [Co+2].[O-]C(=O)C([O-])=O MULYSYXKGICWJF-UHFFFAOYSA-L 0.000 description 2
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000011066 ex-situ storage Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 150000003891 oxalate salts Chemical class 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000007519 polyprotic acids Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- 229910017119 AlPO Inorganic materials 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910002515 CoAl Inorganic materials 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 159000000021 acetate salts Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- OFHCOWSQAMBJIW-AVJTYSNKSA-N alfacalcidol Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C\C=C1\C[C@@H](O)C[C@H](O)C1=C OFHCOWSQAMBJIW-AVJTYSNKSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 238000002453 autothermal reforming Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
- B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/005—Spinels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0209—Impregnation involving a reaction between the support and a fluid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/088—Decomposition of a metal salt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/28—Phosphorising
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1452311 | 2014-03-20 | ||
| FR1452311A FR3018702B1 (fr) | 2014-03-20 | 2014-03-20 | Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104923270A CN104923270A (zh) | 2015-09-23 |
| CN104923270B true CN104923270B (zh) | 2019-07-09 |
Family
ID=50933354
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510124262.3A Active CN104923270B (zh) | 2014-03-20 | 2015-03-20 | 基于viiib族金属和包含氧化铝、二氧化硅、尖晶石和磷的氧化物载体的费托催化剂 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9486789B2 (enExample) |
| EP (1) | EP2921227B1 (enExample) |
| JP (1) | JP6511305B2 (enExample) |
| CN (1) | CN104923270B (enExample) |
| CA (1) | CA2885633C (enExample) |
| DK (1) | DK2921227T3 (enExample) |
| FR (1) | FR3018702B1 (enExample) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3018702B1 (fr) * | 2014-03-20 | 2017-10-20 | Ifp Energies Now | Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore |
| FR3028770B1 (fr) * | 2014-11-26 | 2016-12-02 | Ifp Energies Now | Procede de preparation d'un catalyseur fischer-tropsch avec traitement a la vapeur |
| FR3035007B1 (fr) * | 2015-04-16 | 2019-04-19 | IFP Energies Nouvelles | Catalyseur comprenant une phase active dopee au bore |
| US10066169B2 (en) * | 2015-07-14 | 2018-09-04 | Research & Business Foundation Sungkyunkwan University | Mesoporous cobalt-metal oxide catalyst for Fischer-Tropsch synthesis reactions and a preparing method thereof |
| FR3041270A1 (fr) * | 2015-09-17 | 2017-03-24 | Ifp Energies Now | Catalyseur fischer-tropsch a base d'un metal du groupe viiib, de bore et d'un support contenant du phosphore introduit sous forme d'un sel |
| EP3441380A4 (en) * | 2016-04-04 | 2020-02-26 | Kao Corporation | Method for producing alcohol |
| FR3053260B1 (fr) * | 2016-06-30 | 2020-12-11 | Ifp Energies Now | Masse de captation constitue d'une phase active sous forme cristalline |
| CN106268888B (zh) * | 2016-07-21 | 2019-06-11 | 中国科学院广州能源研究所 | 一种水相催化糖醇原料制取c5、c6烷烃的催化剂及其应用 |
| CN106268894A (zh) * | 2016-07-28 | 2017-01-04 | 中国科学院广州能源研究所 | 一种用于低碳烷烃脱氢制乙烯和丙烯的催化剂、其制备方法及其应用 |
| FR3057472B1 (fr) | 2016-10-17 | 2018-11-16 | IFP Energies Nouvelles | Catalyseur de cobalt a base d'un support contenant une phase d'oxyde mixte contenant du cobalt et/ou du nickel prepare par l'utilisation d'un compose hydrogenocarbone. |
| CN108144643B (zh) * | 2016-12-05 | 2020-03-10 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制低碳烯烃的方法 |
| CN108212162B (zh) * | 2016-12-22 | 2021-03-16 | 成功大学 | 纳米镍触媒及碳氧化物的氢化方法 |
| CN108654654B (zh) * | 2017-04-01 | 2021-09-03 | 国家能源投资集团有限责任公司 | 沉淀铁费托催化剂及其制备方法和应用 |
| KR102324239B1 (ko) * | 2017-11-06 | 2021-11-08 | 한화솔루션 주식회사 | 방향족 화합물의 수소화 반응용 촉매 및 이의 제조방법 |
| CN112533697A (zh) * | 2018-06-05 | 2021-03-19 | 沙特基础全球技术有限公司 | 铁-镁二氧化硅负载的催化剂、其制备方法及其用途 |
| CN110773189A (zh) * | 2018-07-31 | 2020-02-11 | 中国石油化工股份有限公司 | 一种加氢活性保护催化剂及其制备与应用 |
| US11110438B2 (en) | 2018-07-31 | 2021-09-07 | Board Of Regents, The University Of Texas System | Methods for preparation and use of liquid synthesis catalysts |
| CN110773182A (zh) * | 2018-07-31 | 2020-02-11 | 中国石油化工股份有限公司 | 一种加氢活性保护催化剂及其制备与应用 |
| FR3085382B1 (fr) * | 2018-09-04 | 2020-08-14 | Ifp Energies Now | Procede fischer-tropsch en presence d'un catalyseur prepare a partir d'un sel fondu |
| FR3085284B1 (fr) | 2018-09-04 | 2021-05-07 | Ifp Energies Now | Procede de preparation d'un catalyseur ou d'une masse de captation a partir de sels fondus |
| CN111318293B (zh) * | 2018-12-13 | 2023-09-01 | 中国石油化工股份有限公司 | 一种快速提高单环芳烃含量的加氢处理催化剂及其制备方法 |
| FR3104461B1 (fr) | 2019-12-17 | 2022-06-17 | Ifp Energies Now | Catalyseur d’hydrogenation selective obtenu a partir de sels fondus et d’un additif organique |
| FR3104463B1 (fr) | 2019-12-17 | 2021-12-17 | Ifp Energies Now | Catalyseur d’hydrogenolyse obtenu a partir de sels fondus et d’un additif organique |
| CN113117691A (zh) * | 2020-01-16 | 2021-07-16 | 中国科学院大连化学物理研究所 | 一种钴基催化剂在费托合成反应中的应用 |
| FR3112088B1 (fr) | 2020-07-03 | 2022-09-30 | Ifp Energies Now | Procede de preparation d’un catalyseur d’hydrogenation selective obtenu a partir de sels fondus et un alliage nickel cuivre |
| FR3112087B1 (fr) | 2020-07-03 | 2022-09-30 | Ifp Energies Now | Procede de preparation d’un catalyseur d’hydrogenation de composes aromatiques obtenu a partir de sels fondus et un alliage nickel cuivre |
| FR3125438A1 (fr) | 2021-07-22 | 2023-01-27 | IFP Energies Nouvelles | Procede de preparation d’un catalyseur a partir de sels fondus et d’un support particulier |
| CN116020497B (zh) * | 2021-10-27 | 2024-07-12 | 中国石油化工股份有限公司 | 复合载体、加氢催化剂及其制备方法和应用 |
| CN116020498B (zh) * | 2021-10-27 | 2024-10-15 | 中国石油化工股份有限公司 | 加氢催化剂的制备方法、由该方法制备的催化剂及应用 |
| CN119034743B (zh) * | 2024-08-21 | 2025-03-28 | 宁夏千锋科技有限公司 | 一种经济环保型氯酸盐分解工艺用添加剂 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103249481A (zh) * | 2010-08-09 | 2013-08-14 | Gtl.F1公司 | 费托催化剂 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4931433B1 (enExample) * | 1970-02-25 | 1974-08-21 | ||
| US4172810A (en) * | 1978-05-08 | 1979-10-30 | Exxon Research & Engineering Co. | Catalysts for the conversion of relatively low molecular weight hydrocarbons to high molecular weight hydrocarbons and the regeneration of the catalysts |
| ES2132728T3 (es) * | 1994-11-02 | 1999-08-16 | Anglo American Res Lab Pty Ltd | Catalizador con soporte de oxido de zirconio/oxido de cerio. |
| US6368997B2 (en) * | 1998-05-22 | 2002-04-09 | Conoco Inc. | Fischer-Tropsch processes and catalysts using fluorided supports |
| JP5072136B2 (ja) * | 1998-07-24 | 2012-11-14 | 千代田化工建設株式会社 | 多孔性スピネル型複合酸化物の製造方法 |
| GB2410449B (en) | 2004-01-28 | 2008-05-21 | Statoil Asa | Fischer-Tropsch catalysts |
| JP4472556B2 (ja) * | 2004-03-26 | 2010-06-02 | コスモ石油株式会社 | 炭化水素油の水素化処理触媒及びその製造方法並びに炭化水素油の水素化処理方法 |
| RU2389548C2 (ru) * | 2004-09-23 | 2010-05-20 | Статоил Аса | Промотированный катализатор синтеза фишера-тропша, способ его получения и способ синтеза углеводородов фишера-тропша |
| FR2879478B1 (fr) | 2004-12-17 | 2007-10-26 | Inst Francais Du Petrole | Catalyseur a base de cobalt pour la synthese fisher-tropsch |
| KR100885310B1 (ko) | 2007-07-26 | 2009-02-24 | 한국화학연구원 | 피셔-트롭쉬 합성용 코발트／인―알루미나 촉매와 이의제조방법 |
| KR100918105B1 (ko) | 2008-03-27 | 2009-09-22 | 한국화학연구원 | 피셔-트롭쉬 합성용 코발트／지르코늄-인/실리카 촉매와이의 제조방법 |
| FR2991199B1 (fr) * | 2012-05-30 | 2015-05-15 | IFP Energies Nouvelles | Procede de preparation d'un catalyseur mettant en oeuvre une etape de sechage rapide et son utilisation pour la synthese fischer-tropsch |
| FR2991198B1 (fr) * | 2012-05-30 | 2015-05-15 | IFP Energies Nouvelles | Procede de preparation d'un catalyseur mettant en oeuvre au moins une etape de sechage rapide et au moins une etape de sechage en lit fluidise et son utilisation pour la synthese fischer-tropsch |
| FR3018810B1 (fr) * | 2014-03-20 | 2017-06-09 | Ifp Energies Now | Procede fischer-tropsch utilisant un catalyseur a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice et du phosphore |
| FR3018702B1 (fr) * | 2014-03-20 | 2017-10-20 | Ifp Energies Now | Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore |
-
2014
- 2014-03-20 FR FR1452311A patent/FR3018702B1/fr active Active
-
2015
- 2015-02-19 EP EP15305245.1A patent/EP2921227B1/fr active Active
- 2015-02-19 DK DK15305245.1T patent/DK2921227T3/en active
- 2015-03-18 JP JP2015054085A patent/JP6511305B2/ja active Active
- 2015-03-19 CA CA2885633A patent/CA2885633C/fr active Active
- 2015-03-20 US US14/663,731 patent/US9486789B2/en active Active
- 2015-03-20 CN CN201510124262.3A patent/CN104923270B/zh active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103249481A (zh) * | 2010-08-09 | 2013-08-14 | Gtl.F1公司 | 费托催化剂 |
Also Published As
| Publication number | Publication date |
|---|---|
| DK2921227T3 (en) | 2017-07-31 |
| JP6511305B2 (ja) | 2019-05-15 |
| FR3018702B1 (fr) | 2017-10-20 |
| US20150266006A1 (en) | 2015-09-24 |
| CA2885633C (fr) | 2021-10-26 |
| US9486789B2 (en) | 2016-11-08 |
| CN104923270A (zh) | 2015-09-23 |
| EP2921227A1 (fr) | 2015-09-23 |
| JP2015182077A (ja) | 2015-10-22 |
| FR3018702A1 (fr) | 2015-09-25 |
| EP2921227B1 (fr) | 2017-04-12 |
| CA2885633A1 (fr) | 2015-09-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104923270B (zh) | 基于viiib族金属和包含氧化铝、二氧化硅、尖晶石和磷的氧化物载体的费托催化剂 | |
| CA2500646C (en) | Fischer-tropsch processes and catalysts using stabilized supports | |
| US8071655B2 (en) | Cobalt-based catalyst for fischer-tropsch synthesis | |
| US11020728B2 (en) | Catalyst comprising a boron-doped active phase | |
| KR100918105B1 (ko) | 피셔-트롭쉬 합성용 코발트／지르코늄-인/실리카 촉매와이의 제조방법 | |
| US9512365B2 (en) | Fischer-tropsch process using a catalyst based on a metal of group VIIIB and an oxides support comprising alumina, silica and phosphorus | |
| Zeng et al. | Ni–Ce–Al composite oxide catalysts synthesized by solution combustion method: Enhanced catalytic activity for CO methanation | |
| JP2010524681A (ja) | フィッシャー・トロプシュ合成用コバルト／リン−アルミナ触媒及びその製造方法 | |
| KR101648949B1 (ko) | 피셔-트롭쉬 합성반응용 코어-쉘 구조의 코발트 촉매와 이의 제조방법 | |
| US10066169B2 (en) | Mesoporous cobalt-metal oxide catalyst for Fischer-Tropsch synthesis reactions and a preparing method thereof | |
| JP2010532245A (ja) | ゾル・ゲル法によるフィッシャー・トロプシュ合成用リン含有アルミナ支持体の製造及びその触媒の製造 | |
| US20170304807A1 (en) | Method for preparation of a fischer-tropsch catalyst with vapor treatment | |
| CN101098752B (zh) | 用于费托合成的钴基催化剂 | |
| US11596929B2 (en) | Fischer-tropsch process in the presence of a catalyst prepared from a molten salt | |
| JP6769769B2 (ja) | フィッシャー・トロプシュ反応における使用を意図した触媒の調製方法 | |
| Shoganbek et al. | Dry methane reforming over lanthanide-doped Co–Al catalysts prepared via a solution combustion method | |
| JP7012596B2 (ja) | 合成ガスから炭化水素を製造する触媒の製造方法、及び合成ガスから炭化水素を製造する方法 | |
| FR3041270A1 (fr) | Catalyseur fischer-tropsch a base d'un metal du groupe viiib, de bore et d'un support contenant du phosphore introduit sous forme d'un sel | |
| Park et al. | Pore-size controlled Ni/Al2O3 catalyst for methane reforming via mechanochemical one-pot synthesis | |
| Grzybek et al. | Robust ethanol steam reforming catalysts with strong cobalt-alumina support interaction | |
| Silmina et al. | Steam Reforming of Acetic Acid Using Ni Nanoparticle Encapsulated on CeO2/Al2O3/SBA-15 | |
| Alharbi | Dry Reforming of Methane by Ni-In-Ce Supported Catalysts |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |