CN104918972B - 乙烯共聚物组合物、膜和聚合方法 - Google Patents
乙烯共聚物组合物、膜和聚合方法 Download PDFInfo
- Publication number
- CN104918972B CN104918972B CN201380065313.9A CN201380065313A CN104918972B CN 104918972 B CN104918972 B CN 104918972B CN 201380065313 A CN201380065313 A CN 201380065313A CN 104918972 B CN104918972 B CN 104918972B
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- China
- Prior art keywords
- ethylene copolymer
- catalyst
- ethylene
- cdbi
- tref
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2798855 | 2012-12-14 | ||
| CA2798855A CA2798855C (en) | 2012-06-21 | 2012-12-14 | Ethylene copolymers having reverse comonomer incorporation |
| PCT/CA2013/001002 WO2014089671A1 (en) | 2012-12-14 | 2013-12-04 | Ethylene copolymer compositions, film and polymerization processes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104918972A CN104918972A (zh) | 2015-09-16 |
| CN104918972B true CN104918972B (zh) | 2018-01-02 |
Family
ID=50929151
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380065313.9A Active CN104918972B (zh) | 2012-12-14 | 2013-12-04 | 乙烯共聚物组合物、膜和聚合方法 |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP2931763B1 (enExample) |
| JP (1) | JP6231579B2 (enExample) |
| KR (1) | KR102121298B1 (enExample) |
| CN (1) | CN104918972B (enExample) |
| BR (1) | BR112015014121B1 (enExample) |
| CA (1) | CA2835740C (enExample) |
| DK (1) | DK2931763T3 (enExample) |
| ES (1) | ES2663020T3 (enExample) |
| MX (1) | MX374326B (enExample) |
| NO (1) | NO2931763T3 (enExample) |
| WO (1) | WO2014089671A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2819827C2 (ru) * | 2019-03-25 | 2024-05-27 | Шеврон Филлипс Кемикал Компани Лп | Двухкомпонентные сополимеры lldpe с улучшенной ударопрочностью и сопротивлением раздиру и способы их получения |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2798855C (en) * | 2012-06-21 | 2021-01-26 | Nova Chemicals Corporation | Ethylene copolymers having reverse comonomer incorporation |
| WO2014159844A1 (en) * | 2013-03-28 | 2014-10-02 | Dow Global Technologies Llc | An ethylene/alpha-olefin interpolymer composition |
| ES2918979T3 (es) | 2014-02-11 | 2022-07-21 | Univation Tech Llc | Métodos para preparar copolímeros de etileno |
| US20170152377A1 (en) * | 2014-06-26 | 2017-06-01 | Dow Global Technologies Llc | Breathable films and articles incorporating same |
| US20170129229A1 (en) * | 2014-06-26 | 2017-05-11 | Dow Global Technologies Llc | Blown films with improved toughness |
| CA2952031C (en) * | 2014-06-26 | 2022-10-04 | Dow Global Technologies Llc | Cast films with improved toughness |
| TWI557140B (zh) * | 2014-08-19 | 2016-11-11 | 努發化工(國際)公司 | 使用單活性中心催化劑產生之乙烯共聚物 |
| KR101617870B1 (ko) | 2014-09-05 | 2016-05-03 | 주식회사 엘지화학 | 가공성이 우수한 올레핀계 중합체 |
| KR101889598B1 (ko) * | 2015-12-08 | 2018-08-17 | 주식회사 엘지화학 | 올레핀계 중합체 |
| KR20190021324A (ko) * | 2016-06-17 | 2019-03-05 | 보레알리스 아게 | 향상된 유동학적 특성을 갖는 바이모달 또는 멀티모달 폴리에틸렌 삼원공중합체 |
| WO2017220724A1 (en) | 2016-06-23 | 2017-12-28 | Borealis Ag | Process for catalyst deactivation |
| US10000594B2 (en) | 2016-11-08 | 2018-06-19 | Chevron Phillips Chemical Company Lp | Dual catalyst system for producing LLDPE copolymers with a narrow molecular weight distribution and improved processability |
| EP3684850B1 (en) * | 2017-09-22 | 2024-04-10 | Dow Global Technologies LLC | Thermoformed film compositions with enhanced toughness after thermoforming processes |
| US10358506B2 (en) * | 2017-10-03 | 2019-07-23 | Chevron Phillips Chemical Company Lp | Dual catalyst system for producing LLDPE copolymers with improved processability |
| US10927202B2 (en) * | 2017-11-13 | 2021-02-23 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions and articles made therefrom |
| US10934376B2 (en) | 2017-11-28 | 2021-03-02 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions and films made therefrom |
| CN115850552B (zh) * | 2017-12-01 | 2024-08-06 | 埃克森美孚化学专利公司 | 催化剂体系和使用其的聚合方法 |
| JP7278286B2 (ja) | 2017-12-26 | 2023-05-19 | ダウ グローバル テクノロジーズ エルエルシー | 靭性が改善された多峰性エチレン系ポリマー組成物 |
| SG11202005765YA (en) | 2017-12-26 | 2020-07-29 | Dow Global Technologies Llc | Dual reactor solution process for the production of multimodal ethylene-based polymer |
| WO2019133400A1 (en) * | 2017-12-26 | 2019-07-04 | Dow Global Technologies Llc | Compositions with multimodal ethylene-based polymers having improved toughness at low temperatures |
| ES2946586T3 (es) | 2017-12-26 | 2023-07-21 | Dow Global Technologies Llc | Procedimiento para la producción de polímeros a base de etileno multimodales |
| KR102013170B1 (ko) * | 2018-04-05 | 2019-08-22 | 대림산업 주식회사 | 폴리올레핀 수지 조성물 및 이의 제조방법 |
| KR102842316B1 (ko) * | 2018-10-15 | 2025-08-05 | 토탈에너지스 원테크 벨지움 | 폴리에틸렌 수지 |
| KR102116476B1 (ko) * | 2019-01-18 | 2020-05-28 | 대림산업 주식회사 | 폴리올레핀 중합 촉매 조성물, 폴리올레핀의 제조 방법 및 폴리올레핀 수지 |
| EP4025634A1 (en) * | 2019-09-03 | 2022-07-13 | SABIC Global Technologies, B.V. | Package comprising a bi-directionally oriented polyethylene film |
| KR102525719B1 (ko) * | 2019-11-28 | 2023-04-26 | 한화솔루션 주식회사 | 올레핀계 중합체 필름 및 그 제조방법 |
| EP4077423A1 (en) | 2019-12-17 | 2022-10-26 | ExxonMobil Chemical Patents Inc. | Broad orthogonal distribution polyethylenes for films |
| WO2021200991A1 (ja) * | 2020-03-31 | 2021-10-07 | 株式会社プライムポリマー | エチレン系樹脂組成物及びフィルム |
| MX2022011103A (es) | 2020-04-01 | 2022-10-03 | Dow Global Technologies Llc | Copolimero de polietileno lineal bimodal de baja densidad. |
| KR102608616B1 (ko) * | 2020-11-23 | 2023-12-04 | 한화솔루션 주식회사 | 올레핀계 중합체, 그로부터 제조된 필름 및 그 제조방법 |
| KR102608612B1 (ko) * | 2020-11-23 | 2023-12-04 | 한화솔루션 주식회사 | 올레핀계 중합체 및 그 제조방법 |
| WO2022124694A1 (ko) * | 2020-12-08 | 2022-06-16 | 한화솔루션 주식회사 | 올레핀계 중합체, 그로부터 제조된 필름 및 그 제조방법 |
| KR102611686B1 (ko) * | 2020-12-17 | 2023-12-08 | 한화솔루션 주식회사 | 올레핀계 중합체 및 그 제조방법 |
| JP2024506510A (ja) | 2021-01-26 | 2024-02-14 | ダウ グローバル テクノロジーズ エルエルシー | ポリエチレン組成物、フィルム、及び物品 |
| WO2023060075A1 (en) | 2021-10-04 | 2023-04-13 | Exxonmobil Chemical Patents Inc. | Polyethylene blends, films thereof, and methods thereof |
| JP7329720B1 (ja) * | 2021-12-23 | 2023-08-18 | ポリプラスチックス株式会社 | 環状オレフィン共重合体の製造方法及び触媒組成物 |
| US20250243332A1 (en) * | 2022-05-07 | 2025-07-31 | Dow Global Technologies Llc | A breathable, biaxially-oriented polyethylene film |
| WO2024242949A1 (en) * | 2023-05-23 | 2024-11-28 | ExxonMobil Technology and Engineering Company | Polyethylenes having improved processability and films thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1206015A (zh) * | 1997-07-09 | 1999-01-27 | 诺瓦化学品(国际)股份有限公司 | 膦亚胺-Cp载体催化剂 |
| CN101472964A (zh) * | 2006-06-27 | 2009-07-01 | 尤尼威蒂恩技术有限责任公司 | 使用茂金属催化剂的改进聚合方法、共聚合产物及最终用途 |
| CN101516932A (zh) * | 2006-06-27 | 2009-08-26 | 尤尼威蒂恩技术有限责任公司 | 乙烯α-烯烃共聚物及制备该共聚物的聚合方法 |
| CN101959907A (zh) * | 2008-03-07 | 2011-01-26 | 埃克森美孚化学专利公司 | 高mir线性聚乙烯和采用这样的聚乙烯制备的复合薄膜 |
| WO2012122624A1 (en) * | 2011-03-15 | 2012-09-20 | Nova Chemicals (International) S.A. | Polyethylene film |
| WO2012167347A1 (en) * | 2011-06-09 | 2012-12-13 | Nova Chemicals (International) S.A. | Methods for controlling ethylene copolymer properties |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6462161B1 (en) | 1996-05-17 | 2002-10-08 | Bp Chemicals Limited | Polyolefin composition with molecular weight maximum occurring in that part of the composition that has the highest comonomer content |
| JP4553924B2 (ja) * | 1996-05-17 | 2010-09-29 | ザ ダウ ケミカル カンパニー | 共重合体の製造方法およびそれを含有するブレンド組成物 |
| US6255426B1 (en) | 1997-04-01 | 2001-07-03 | Exxon Chemical Patents, Inc. | Easy processing linear low density polyethylene |
| EP1848750B2 (en) | 2005-02-09 | 2024-12-25 | Ineos Sales (UK) Limited | Copolymers and films thereof |
| EP2177548A1 (en) | 2008-10-14 | 2010-04-21 | Ineos Europe Limited | Copolymers and films thereof |
| US8114946B2 (en) * | 2008-12-18 | 2012-02-14 | Chevron Phillips Chemical Company Lp | Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches |
| US20110003940A1 (en) | 2009-07-01 | 2011-01-06 | Dow Global Technologies Inc. | Ethylene-based polymer compositions for use as a blend component in shrinkage film applications |
| US8383754B2 (en) * | 2010-04-19 | 2013-02-26 | Chevron Phillips Chemical Company Lp | Catalyst compositions for producing high Mz/Mw polyolefins |
| EA027509B1 (ru) | 2011-07-08 | 2017-08-31 | Тотал Ресерч & Технолоджи Фелай | Металлоцен-катализированный полиэтилен |
| CA2780508A1 (en) * | 2012-06-21 | 2013-12-21 | Nova Chemicals Corporation | Polyethylene composition, film and polymerization process |
| CA2798855C (en) * | 2012-06-21 | 2021-01-26 | Nova Chemicals Corporation | Ethylene copolymers having reverse comonomer incorporation |
-
2013
- 2013-12-04 NO NO13862866A patent/NO2931763T3/no unknown
- 2013-12-04 BR BR112015014121-8A patent/BR112015014121B1/pt active IP Right Grant
- 2013-12-04 DK DK13862866.4T patent/DK2931763T3/en active
- 2013-12-04 JP JP2015546784A patent/JP6231579B2/ja active Active
- 2013-12-04 WO PCT/CA2013/001002 patent/WO2014089671A1/en not_active Ceased
- 2013-12-04 KR KR1020157016006A patent/KR102121298B1/ko active Active
- 2013-12-04 CN CN201380065313.9A patent/CN104918972B/zh active Active
- 2013-12-04 MX MX2015007292A patent/MX374326B/es active IP Right Grant
- 2013-12-04 ES ES13862866.4T patent/ES2663020T3/es active Active
- 2013-12-04 CA CA2835740A patent/CA2835740C/en active Active
- 2013-12-04 EP EP13862866.4A patent/EP2931763B1/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1206015A (zh) * | 1997-07-09 | 1999-01-27 | 诺瓦化学品(国际)股份有限公司 | 膦亚胺-Cp载体催化剂 |
| CN101472964A (zh) * | 2006-06-27 | 2009-07-01 | 尤尼威蒂恩技术有限责任公司 | 使用茂金属催化剂的改进聚合方法、共聚合产物及最终用途 |
| CN101516932A (zh) * | 2006-06-27 | 2009-08-26 | 尤尼威蒂恩技术有限责任公司 | 乙烯α-烯烃共聚物及制备该共聚物的聚合方法 |
| CN101959907A (zh) * | 2008-03-07 | 2011-01-26 | 埃克森美孚化学专利公司 | 高mir线性聚乙烯和采用这样的聚乙烯制备的复合薄膜 |
| WO2012122624A1 (en) * | 2011-03-15 | 2012-09-20 | Nova Chemicals (International) S.A. | Polyethylene film |
| WO2012167347A1 (en) * | 2011-06-09 | 2012-12-13 | Nova Chemicals (International) S.A. | Methods for controlling ethylene copolymer properties |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2819827C2 (ru) * | 2019-03-25 | 2024-05-27 | Шеврон Филлипс Кемикал Компани Лп | Двухкомпонентные сополимеры lldpe с улучшенной ударопрочностью и сопротивлением раздиру и способы их получения |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20150096665A (ko) | 2015-08-25 |
| ES2663020T3 (es) | 2018-04-10 |
| MX374326B (es) | 2025-03-06 |
| CA2835740C (en) | 2020-12-29 |
| KR102121298B1 (ko) | 2020-06-11 |
| CN104918972A (zh) | 2015-09-16 |
| WO2014089671A1 (en) | 2014-06-19 |
| EP2931763A1 (en) | 2015-10-21 |
| MX2015007292A (es) | 2015-09-10 |
| EP2931763B1 (en) | 2018-01-31 |
| BR112015014121B1 (pt) | 2021-04-06 |
| DK2931763T3 (en) | 2018-04-16 |
| CA2835740A1 (en) | 2014-06-14 |
| JP2016504442A (ja) | 2016-02-12 |
| NO2931763T3 (enExample) | 2018-06-30 |
| EP2931763A4 (en) | 2016-07-20 |
| JP6231579B2 (ja) | 2017-11-15 |
| BR112015014121A2 (pt) | 2017-07-11 |
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| GR01 | Patent grant |