BR112015014121B1 - Copolímero de etileno, processo de polimerização de olefina para produzir um copolímero de etileno e camada de película - Google Patents
Copolímero de etileno, processo de polimerização de olefina para produzir um copolímero de etileno e camada de película Download PDFInfo
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- BR112015014121B1 BR112015014121B1 BR112015014121-8A BR112015014121A BR112015014121B1 BR 112015014121 B1 BR112015014121 B1 BR 112015014121B1 BR 112015014121 A BR112015014121 A BR 112015014121A BR 112015014121 B1 BR112015014121 B1 BR 112015014121B1
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- Brazil
- Prior art keywords
- ethylene copolymer
- catalyst
- fact
- weight
- ethylene
- Prior art date
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- 229920001038 ethylene copolymer Polymers 0.000 title claims abstract description 225
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 81
- 239000000203 mixture Substances 0.000 claims abstract description 121
- 229920001577 copolymer Polymers 0.000 claims abstract description 70
- 238000010828 elution Methods 0.000 claims abstract description 67
- 239000003054 catalyst Substances 0.000 claims description 345
- 238000009826 distribution Methods 0.000 claims description 128
- 238000000034 method Methods 0.000 claims description 100
- 239000003607 modifier Substances 0.000 claims description 100
- 239000002685 polymerization catalyst Substances 0.000 claims description 80
- -1 amine compound Chemical class 0.000 claims description 73
- 239000003446 ligand Substances 0.000 claims description 72
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 66
- 239000005977 Ethylene Substances 0.000 claims description 66
- QLNAVQRIWDRPHA-UHFFFAOYSA-N iminophosphane Chemical compound P=N QLNAVQRIWDRPHA-UHFFFAOYSA-N 0.000 claims description 64
- 229910052723 transition metal Inorganic materials 0.000 claims description 64
- 150000003624 transition metals Chemical class 0.000 claims description 64
- 230000008569 process Effects 0.000 claims description 61
- 125000004432 carbon atom Chemical group C* 0.000 claims description 59
- 239000012190 activator Substances 0.000 claims description 48
- 229910052751 metal Inorganic materials 0.000 claims description 46
- 125000003118 aryl group Chemical group 0.000 claims description 44
- 239000004711 α-olefin Substances 0.000 claims description 43
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 42
- 239000002184 metal Substances 0.000 claims description 42
- 125000000217 alkyl group Chemical group 0.000 claims description 40
- 239000000155 melt Substances 0.000 claims description 40
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 38
- 238000002844 melting Methods 0.000 claims description 34
- 230000008018 melting Effects 0.000 claims description 34
- 230000002441 reversible effect Effects 0.000 claims description 31
- 125000005843 halogen group Chemical group 0.000 claims description 25
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 25
- 238000004458 analytical method Methods 0.000 claims description 24
- 150000001336 alkenes Chemical class 0.000 claims description 22
- 125000001424 substituent group Chemical group 0.000 claims description 21
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 20
- 229910052799 carbon Inorganic materials 0.000 claims description 11
- 125000003545 alkoxy group Chemical group 0.000 claims description 10
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 claims description 9
- 125000004104 aryloxy group Chemical group 0.000 claims description 9
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 8
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 8
- 238000001125 extrusion Methods 0.000 abstract description 15
- 238000005194 fractionation Methods 0.000 abstract description 15
- 230000002829 reductive effect Effects 0.000 abstract description 7
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- 239000011347 resin Substances 0.000 description 139
- 239000000178 monomer Substances 0.000 description 119
- 239000012071 phase Substances 0.000 description 78
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 72
- 229920000642 polymer Polymers 0.000 description 67
- 239000007789 gas Substances 0.000 description 56
- 239000000243 solution Substances 0.000 description 39
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 33
- 239000002002 slurry Substances 0.000 description 31
- 230000000052 comparative effect Effects 0.000 description 29
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 26
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- 238000001035 drying Methods 0.000 description 22
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 22
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- 238000010348 incorporation Methods 0.000 description 21
- 239000004698 Polyethylene Substances 0.000 description 20
- 238000006243 chemical reaction Methods 0.000 description 19
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 19
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- 230000002902 bimodal effect Effects 0.000 description 18
- 239000012968 metallocene catalyst Substances 0.000 description 18
- 239000010936 titanium Substances 0.000 description 18
- 239000003085 diluting agent Substances 0.000 description 17
- 125000001183 hydrocarbyl group Chemical group 0.000 description 17
- 238000004519 manufacturing process Methods 0.000 description 17
- 229910052757 nitrogen Inorganic materials 0.000 description 17
- 239000000463 material Substances 0.000 description 16
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 14
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 14
- 239000000377 silicon dioxide Substances 0.000 description 14
- 239000002904 solvent Substances 0.000 description 14
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 238000004587 chromatography analysis Methods 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 12
- 229910052735 hafnium Inorganic materials 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- 239000001257 hydrogen Substances 0.000 description 11
- 229910052809 inorganic oxide Inorganic materials 0.000 description 11
- 230000000704 physical effect Effects 0.000 description 11
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 10
- 229910052796 boron Inorganic materials 0.000 description 10
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 10
- 239000011148 porous material Substances 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- 238000012545 processing Methods 0.000 description 10
- 238000007789 sealing Methods 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 9
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical class CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 9
- 238000005227 gel permeation chromatography Methods 0.000 description 9
- 229930195733 hydrocarbon Natural products 0.000 description 9
- 230000000670 limiting effect Effects 0.000 description 9
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical class CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 8
- 239000000654 additive Substances 0.000 description 8
- 239000003426 co-catalyst Substances 0.000 description 8
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical group C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 150000003254 radicals Chemical class 0.000 description 8
- 238000000518 rheometry Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 229910052726 zirconium Inorganic materials 0.000 description 8
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 238000007334 copolymerization reaction Methods 0.000 description 7
- 150000002430 hydrocarbons Chemical class 0.000 description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 7
- XPPWLXNXHSNMKC-UHFFFAOYSA-N phenylboron Chemical compound [B]C1=CC=CC=C1 XPPWLXNXHSNMKC-UHFFFAOYSA-N 0.000 description 7
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 7
- 229910052719 titanium Inorganic materials 0.000 description 7
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- 238000007792 addition Methods 0.000 description 6
- 239000003963 antioxidant agent Substances 0.000 description 6
- 125000004429 atom Chemical group 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 239000008187 granular material Substances 0.000 description 6
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 6
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 6
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 239000002808 molecular sieve Substances 0.000 description 6
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 6
- 239000002516 radical scavenger Substances 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 6
- 125000000041 C6-C10 aryl group Chemical group 0.000 description 5
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 5
- 239000002168 alkylating agent Substances 0.000 description 5
- 229940100198 alkylating agent Drugs 0.000 description 5
- 235000006708 antioxidants Nutrition 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 239000012954 diazonium Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-O diazynium Chemical compound [NH+]#N IJGRMHOSHXDMSA-UHFFFAOYSA-O 0.000 description 5
- 238000000113 differential scanning calorimetry Methods 0.000 description 5
- 230000009977 dual effect Effects 0.000 description 5
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 125000001153 fluoro group Chemical group F* 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 125000002524 organometallic group Chemical group 0.000 description 5
- 238000005453 pelletization Methods 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- NDLNTMNRNCENRZ-UHFFFAOYSA-N 2-[2-hydroxyethyl(octadecyl)amino]ethanol Chemical compound CCCCCCCCCCCCCCCCCCN(CCO)CCO NDLNTMNRNCENRZ-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 4
- 239000002734 clay mineral Substances 0.000 description 4
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 4
- 150000001993 dienes Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 4
- 230000004927 fusion Effects 0.000 description 4
- 238000012685 gas phase polymerization Methods 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 125000004433 nitrogen atom Chemical group N* 0.000 description 4
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- 125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 4
- OJJVPGJEBAZOIF-UHFFFAOYSA-N (2,3,4,5-tetrafluorophenoxy)boronic acid Chemical compound OB(O)OC1=CC(F)=C(F)C(F)=C1F OJJVPGJEBAZOIF-UHFFFAOYSA-N 0.000 description 3
- OCJGSAJPSURHFR-UHFFFAOYSA-N 1,2,2-trifluoroethoxyboronic acid Chemical compound OB(O)OC(F)C(F)F OCJGSAJPSURHFR-UHFFFAOYSA-N 0.000 description 3
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- 150000001412 amines Chemical class 0.000 description 3
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- IDASTKMEQGPVRR-UHFFFAOYSA-N cyclopenta-1,3-diene;zirconium(2+) Chemical class [Zr+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 IDASTKMEQGPVRR-UHFFFAOYSA-N 0.000 description 3
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- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 3
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- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 2
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Images
Classifications
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- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
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- Chemical Kinetics & Catalysis (AREA)
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- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2798855A CA2798855C (en) | 2012-06-21 | 2012-12-14 | Ethylene copolymers having reverse comonomer incorporation |
| CA2798855 | 2012-12-14 | ||
| PCT/CA2013/001002 WO2014089671A1 (en) | 2012-12-14 | 2013-12-04 | Ethylene copolymer compositions, film and polymerization processes |
Publications (2)
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| BR112015014121A2 BR112015014121A2 (pt) | 2017-07-11 |
| BR112015014121B1 true BR112015014121B1 (pt) | 2021-04-06 |
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| BR112015014121-8A BR112015014121B1 (pt) | 2012-12-14 | 2013-12-04 | Copolímero de etileno, processo de polimerização de olefina para produzir um copolímero de etileno e camada de película |
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| JP (1) | JP6231579B2 (enExample) |
| KR (1) | KR102121298B1 (enExample) |
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| ES (1) | ES2663020T3 (enExample) |
| MX (1) | MX374326B (enExample) |
| NO (1) | NO2931763T3 (enExample) |
| WO (1) | WO2014089671A1 (enExample) |
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| CA2798855C (en) * | 2012-06-21 | 2021-01-26 | Nova Chemicals Corporation | Ethylene copolymers having reverse comonomer incorporation |
| ES2632549T3 (es) * | 2013-03-28 | 2017-09-14 | Dow Global Technologies Llc | Composición de interpolímero de etileno/alfa-olefina |
| US10253121B2 (en) * | 2014-02-11 | 2019-04-09 | Univation Technologies, Llc | Method of producing polyethylene and polyethylene thereof |
| US20170152377A1 (en) * | 2014-06-26 | 2017-06-01 | Dow Global Technologies Llc | Breathable films and articles incorporating same |
| JP6825917B2 (ja) * | 2014-06-26 | 2021-02-03 | ダウ グローバル テクノロジーズ エルエルシー | 改善された靭性を有するブローフィルム |
| CA2952031C (en) * | 2014-06-26 | 2022-10-04 | Dow Global Technologies Llc | Cast films with improved toughness |
| TWI557140B (zh) * | 2014-08-19 | 2016-11-11 | 努發化工（國際）公司 | 使用單活性中心催化劑產生之乙烯共聚物 |
| KR101617870B1 (ko) | 2014-09-05 | 2016-05-03 | 주식회사 엘지화학 | 가공성이 우수한 올레핀계 중합체 |
| KR101889598B1 (ko) | 2015-12-08 | 2018-08-17 | 주식회사 엘지화학 | 올레핀계 중합체 |
| EP3472240B1 (en) * | 2016-06-17 | 2020-04-01 | Borealis AG | Bi- or multimodal polyethylene terpolymer with enhanced rheological properties |
| JP7004679B2 (ja) | 2016-06-23 | 2022-01-21 | ボレアリス エージー | 触媒不活性化のためのプロセス |
| US10000594B2 (en) | 2016-11-08 | 2018-06-19 | Chevron Phillips Chemical Company Lp | Dual catalyst system for producing LLDPE copolymers with a narrow molecular weight distribution and improved processability |
| US11384228B2 (en) * | 2017-09-22 | 2022-07-12 | Dow Global Technologies Llc | Thermoformed film compositions with enhanced toughness after thermoforming processes |
| US10358506B2 (en) * | 2017-10-03 | 2019-07-23 | Chevron Phillips Chemical Company Lp | Dual catalyst system for producing LLDPE copolymers with improved processability |
| WO2019094131A1 (en) * | 2017-11-13 | 2019-05-16 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions and articles made therefrom |
| CN111465626B (zh) * | 2017-11-28 | 2022-10-18 | 埃克森美孚化学专利公司 | 聚乙烯组合物和由其制成的膜 |
| CN111433229B (zh) * | 2017-12-01 | 2022-12-13 | 埃克森美孚化学专利公司 | 催化剂体系和使用其的聚合方法 |
| CN111683979B (zh) | 2017-12-26 | 2024-08-23 | 陶氏环球技术有限责任公司 | 用于生产多峰型乙烯类聚合物的工艺 |
| JP7326283B2 (ja) | 2017-12-26 | 2023-08-15 | ダウ グローバル テクノロジーズ エルエルシー | マルチモーダルエチレン系ポリマーの製造のための二重反応器溶液プロセス |
| JP7328965B2 (ja) * | 2017-12-26 | 2023-08-17 | ダウ グローバル テクノロジーズ エルエルシー | 低温での靱性が改善された多峰性エチレン系ポリマーを有する組成物 |
| EP3732213B1 (en) | 2017-12-26 | 2022-01-12 | Dow Global Technologies LLC | Multimodal ethylene-based polymer compositions having improved toughness |
| KR102013170B1 (ko) | 2018-04-05 | 2019-08-22 | 대림산업 주식회사 | 폴리올레핀 수지 조성물 및 이의 제조방법 |
| WO2020078932A1 (en) * | 2018-10-15 | 2020-04-23 | Total Research & Technology Feluy | Polyethylene resins |
| KR102116476B1 (ko) * | 2019-01-18 | 2020-05-28 | 대림산업 주식회사 | 폴리올레핀 중합 촉매 조성물, 폴리올레핀의 제조 방법 및 폴리올레핀 수지 |
| US12104026B2 (en) * | 2019-09-03 | 2024-10-01 | Sabic Global Technologies B.V. | Package comprising a bi-directionally oriented polyethylene film |
| KR102525719B1 (ko) * | 2019-11-28 | 2023-04-26 | 한화솔루션 주식회사 | 올레핀계 중합체 필름 및 그 제조방법 |
| WO2021126448A1 (en) | 2019-12-17 | 2021-06-24 | Exxonmobil Chemical Patents Inc. | Broad orthogonal distribution polyethylenes for films |
| US12577334B2 (en) | 2019-12-17 | 2026-03-17 | Exxonmobil Chemical Patents Inc. | Broad orthogonal distribution polyethylenes for films |
| EP4129671A4 (en) * | 2020-03-31 | 2024-04-24 | Prime Polymer Co., Ltd. | COMPOSITION OF ETHYLENE RESIN AND FILM |
| BR112022019747A2 (pt) * | 2020-04-01 | 2022-11-16 | Dow Global Technologies Llc | Copolímero de polietileno de baixa densidade linear bimodal, e, artigo fabricado |
| KR102608616B1 (ko) * | 2020-11-23 | 2023-12-04 | 한화솔루션 주식회사 | 올레핀계 중합체, 그로부터 제조된 필름 및 그 제조방법 |
| KR102608612B1 (ko) * | 2020-11-23 | 2023-12-04 | 한화솔루션 주식회사 | 올레핀계 중합체 및 그 제조방법 |
| EP4261237A4 (en) * | 2020-12-08 | 2024-11-13 | Hanwha Solutions Corporation | OLEFIN-BASED POLYMER, FILM PREPARED THEREFROM AND RELATED PREPARATION METHODS |
| KR102611686B1 (ko) * | 2020-12-17 | 2023-12-08 | 한화솔루션 주식회사 | 올레핀계 중합체 및 그 제조방법 |
| MX2023007849A (es) | 2021-01-26 | 2023-07-07 | Dow Global Technologies Llc | Composiciones, peliculas y articulos de polietileno. |
| WO2023060075A1 (en) | 2021-10-04 | 2023-04-13 | Exxonmobil Chemical Patents Inc. | Polyethylene blends, films thereof, and methods thereof |
| DE112022005556T5 (de) * | 2021-12-23 | 2024-09-19 | Daicel Corporation | Verfahren zur Herstellung eines zyklischen Olefincopolymers und Katalysatorzusammensetzung |
| US20250243332A1 (en) * | 2022-05-07 | 2025-07-31 | Dow Global Technologies Llc | A breathable, biaxially-oriented polyethylene film |
| CN121464161A (zh) * | 2023-05-23 | 2026-02-03 | 埃克森美孚技术与工程公司 | 具有改进的加工性的聚乙烯及其膜 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4553924B2 (ja) * | 1996-05-17 | 2010-09-29 | ザ ダウ ケミカル カンパニー | 共重合体の製造方法およびそれを含有するブレンド組成物 |
| ATE212648T1 (de) | 1996-05-17 | 2002-02-15 | Bp Chem Int Ltd | Polyolefinzusammensetzung, deren molekulargewichtsmaximum sich in dem teil der zusammensetzung mit dem höheren comonomergehalt befindet |
| US6255426B1 (en) | 1997-04-01 | 2001-07-03 | Exxon Chemical Patents, Inc. | Easy processing linear low density polyethylene |
| CA2210131C (en) * | 1997-07-09 | 2005-08-02 | Douglas W. Stephan | Supported phosphinimine-cp catalysts |
| WO2006085051A1 (en) | 2005-02-09 | 2006-08-17 | Ineos Europe Limited | Copolymers and films thereof |
| CN101472964B (zh) | 2006-06-27 | 2012-09-05 | 尤尼威蒂恩技术有限责任公司 | 使用茂金属催化剂的改进聚合方法、其聚合产物及最终用途 |
| WO2008002379A2 (en) * | 2006-06-27 | 2008-01-03 | Univation Technologies, Llc | Polymers made with metallocene catalysts, for use in rotomolding and injection molding products |
| GB2458160A (en) * | 2008-03-07 | 2009-09-09 | Exxonmobil Chem Patents Inc | High MIR linear polyethylene, in co-extruded films |
| EP2177548A1 (en) | 2008-10-14 | 2010-04-21 | Ineos Europe Limited | Copolymers and films thereof |
| US8114946B2 (en) | 2008-12-18 | 2012-02-14 | Chevron Phillips Chemical Company Lp | Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches |
| US20110003940A1 (en) | 2009-07-01 | 2011-01-06 | Dow Global Technologies Inc. | Ethylene-based polymer compositions for use as a blend component in shrinkage film applications |
| US8383754B2 (en) * | 2010-04-19 | 2013-02-26 | Chevron Phillips Chemical Company Lp | Catalyst compositions for producing high Mz/Mw polyolefins |
| CA2734167C (en) * | 2011-03-15 | 2018-03-27 | Nova Chemicals Corporation | Polyethylene film |
| CA2742454C (en) * | 2011-06-09 | 2018-06-12 | Nova Chemicals Corporation | Methods for controlling ethylene copolymer properties |
| CN103781838B (zh) | 2011-07-08 | 2016-04-06 | 道达尔研究技术弗吕公司 | 由茂金属催化的聚乙烯 |
| CA2798855C (en) * | 2012-06-21 | 2021-01-26 | Nova Chemicals Corporation | Ethylene copolymers having reverse comonomer incorporation |
| CA2780508A1 (en) * | 2012-06-21 | 2013-12-21 | Nova Chemicals Corporation | Polyethylene composition, film and polymerization process |
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2013
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- 2013-12-04 ES ES13862866.4T patent/ES2663020T3/es active Active
- 2013-12-04 EP EP13862866.4A patent/EP2931763B1/en active Active
- 2013-12-04 CA CA2835740A patent/CA2835740C/en active Active
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- 2013-12-04 DK DK13862866.4T patent/DK2931763T3/en active
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| WO2014089671A1 (en) | 2014-06-19 |
| NO2931763T3 (enExample) | 2018-06-30 |
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| EP2931763B1 (en) | 2018-01-31 |
| BR112015014121A2 (pt) | 2017-07-11 |
| CN104918972B (zh) | 2018-01-02 |
| EP2931763A1 (en) | 2015-10-21 |
| ES2663020T3 (es) | 2018-04-10 |
| KR20150096665A (ko) | 2015-08-25 |
| CA2835740A1 (en) | 2014-06-14 |
| EP2931763A4 (en) | 2016-07-20 |
| MX2015007292A (es) | 2015-09-10 |
| JP6231579B2 (ja) | 2017-11-15 |
| CA2835740C (en) | 2020-12-29 |
| CN104918972A (zh) | 2015-09-16 |
| JP2016504442A (ja) | 2016-02-12 |
| KR102121298B1 (ko) | 2020-06-11 |
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