CN104755661B - 碳纤维制造方法、该方法所用的前体材料和所得的碳纤维 - Google Patents
碳纤维制造方法、该方法所用的前体材料和所得的碳纤维 Download PDFInfo
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- CN104755661B CN104755661B CN201380054732.2A CN201380054732A CN104755661B CN 104755661 B CN104755661 B CN 104755661B CN 201380054732 A CN201380054732 A CN 201380054732A CN 104755661 B CN104755661 B CN 104755661B
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- Prior art keywords
- fiber
- carbon
- cellulose
- precursor material
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- Expired - Fee Related
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 129
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 81
- 238000000034 method Methods 0.000 title claims abstract description 69
- 239000002243 precursor Substances 0.000 title claims abstract description 59
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 56
- 239000000463 material Substances 0.000 title claims abstract description 51
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 43
- 229920002678 cellulose Polymers 0.000 claims abstract description 48
- 239000001913 cellulose Substances 0.000 claims abstract description 48
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 44
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 44
- 239000004917 carbon fiber Substances 0.000 claims description 43
- 238000011049 filling Methods 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 19
- 229920005610 lignin Polymers 0.000 claims description 17
- 229910021389 graphene Inorganic materials 0.000 claims description 16
- 241000196324 Embryophyta Species 0.000 claims description 15
- 229920003043 Cellulose fiber Polymers 0.000 claims description 14
- 238000009955 starching Methods 0.000 claims description 14
- -1 siloxanes Chemical class 0.000 claims description 13
- 238000005087 graphitization Methods 0.000 claims description 12
- 230000007062 hydrolysis Effects 0.000 claims description 11
- 238000006460 hydrolysis reaction Methods 0.000 claims description 11
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 10
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 8
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 8
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 8
- 239000011425 bamboo Substances 0.000 claims description 8
- 241001649247 Boehmeria Species 0.000 claims description 7
- 241000218236 Cannabis Species 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 6
- 235000007164 Oryza sativa Nutrition 0.000 claims description 5
- 235000019270 ammonium chloride Nutrition 0.000 claims description 5
- 239000003365 glass fiber Substances 0.000 claims description 5
- 235000009566 rice Nutrition 0.000 claims description 5
- 229920000742 Cotton Polymers 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 241000209094 Oryza Species 0.000 claims 3
- 244000082204 Phyllostachys viridis Species 0.000 claims 1
- 239000000470 constituent Substances 0.000 abstract 1
- 235000010980 cellulose Nutrition 0.000 description 39
- 230000008569 process Effects 0.000 description 19
- 239000002071 nanotube Substances 0.000 description 18
- 230000004048 modification Effects 0.000 description 13
- 238000012986 modification Methods 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 11
- 238000003763 carbonization Methods 0.000 description 10
- 229910002804 graphite Inorganic materials 0.000 description 10
- 239000010439 graphite Substances 0.000 description 10
- 229920002239 polyacrylonitrile Polymers 0.000 description 10
- 238000005229 chemical vapour deposition Methods 0.000 description 9
- 235000013877 carbamide Nutrition 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 241001330002 Bambuseae Species 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 229920002522 Wood fibre Polymers 0.000 description 6
- 239000007799 cork Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 150000003672 ureas Chemical class 0.000 description 6
- 239000002025 wood fiber Substances 0.000 description 6
- 239000010408 film Substances 0.000 description 5
- 238000000227 grinding Methods 0.000 description 5
- 239000010902 straw Substances 0.000 description 5
- 239000002028 Biomass Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 238000001000 micrograph Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 229920000433 Lyocell Polymers 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000002041 carbon nanotube Substances 0.000 description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 238000007380 fibre production Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 238000002604 ultrasonography Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 229910019093 NaOCl Inorganic materials 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000002372 labelling Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000003229 sclerosing agent Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229910017061 Fe Co Inorganic materials 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920002488 Hemicellulose Polymers 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 241001274660 Modulus Species 0.000 description 1
- 241000549556 Nanos Species 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 239000011852 carbon nanoparticle Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000002079 double walled nanotube Substances 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000005021 gait Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000002121 nanofiber Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000002074 nanoribbon Substances 0.000 description 1
- 239000002135 nanosheet Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000001149 thermolysis Methods 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/16—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from products of vegetable origin or derivatives thereof, e.g. from cellulose acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/26—Cellulose ethers
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Fibers (AREA)
- Carbon And Carbon Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1260032A FR2997097B1 (fr) | 2012-10-22 | 2012-10-22 | Procede de fabrication d'une fibre de carbone, materiau precurseur utilise par le procede et fibre de carbone obtenue. |
| FR1260032 | 2012-10-22 | ||
| PCT/FR2013/052495 WO2014064373A1 (fr) | 2012-10-22 | 2013-10-18 | Procede de fabrication d'une fibre de carbone, materiau precurseur utilise par le procede et fibre de carbone obtenue |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104755661A CN104755661A (zh) | 2015-07-01 |
| CN104755661B true CN104755661B (zh) | 2017-04-26 |
Family
ID=47429916
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380054732.2A Expired - Fee Related CN104755661B (zh) | 2012-10-22 | 2013-10-18 | 碳纤维制造方法、该方法所用的前体材料和所得的碳纤维 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9909235B2 (enExample) |
| EP (1) | EP2909366A1 (enExample) |
| JP (1) | JP6368716B2 (enExample) |
| KR (1) | KR20150077465A (enExample) |
| CN (1) | CN104755661B (enExample) |
| FR (1) | FR2997097B1 (enExample) |
| WO (1) | WO2014064373A1 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104264260B (zh) * | 2014-07-28 | 2016-04-13 | 四川大学 | 一种石墨烯/纳米纤维素复合纤维及其制备方法 |
| CN104831389B (zh) * | 2015-05-22 | 2017-04-19 | 济南圣泉集团股份有限公司 | 一种多功能粘胶纤维及其制备方法 |
| KR101689861B1 (ko) * | 2015-05-26 | 2016-12-26 | 한국과학기술연구원 | 나노카본 복합 고성능 저가 탄소섬유 및 그 제조방법 |
| CN106328945A (zh) * | 2015-06-24 | 2017-01-11 | 中国科学院金属研究所 | 一种柔性高导电复合碳质纤维的制备方法 |
| KR101791948B1 (ko) | 2015-10-28 | 2017-11-01 | 한국과학기술연구원 | 리그닌 코팅 조성물 및 이를 포함하는 초극세 섬유 |
| JP6663991B2 (ja) * | 2015-11-20 | 2020-03-13 | 済南聖泉集団股▲ふん▼有限公司Ｊｉｎａｎ Ｓｈｅｎｇｑｕａｎ Ｇｒｏｕｐ Ｓｈａｒｅ Ｈｏｌｄｉｎｇ Ｃｏ．， Ｌｔｄ | 機能性再生セルロース繊維及びその調製方法と使用 |
| CN105633424A (zh) * | 2015-12-31 | 2016-06-01 | 广东省生态环境与土壤研究所 | 一种基于蜘蛛丝的多孔活性碳纤维材料及应用 |
| CN106211388A (zh) * | 2016-07-05 | 2016-12-07 | 安徽吉安特种线缆制造有限公司 | 一种耐候性好的自限温电缆材料 |
| FR3058167B1 (fr) * | 2016-10-28 | 2019-11-22 | Arkema France | Nouveau procede de fabrication de materiaux hautement carbones et materiau hautement carbone obtenu |
| FR3058166B1 (fr) * | 2016-10-28 | 2018-11-23 | Arkema France | Procede de fabrication de fibres de carbone a partir de precurseurs biosources et fibres de carbone obtenues |
| FR3075227B1 (fr) * | 2017-12-18 | 2020-11-13 | Association Pour Le Developpement De Lenseignement Et Des Recherches Aupres Des Univ Des Centres De | Procede de fabrication d’une fibre de carbone a partir de coton recycle et utilisation de la fibre ainsi obtenue pour la formation d’un article en materiau composite |
| CN108532029B (zh) * | 2018-04-17 | 2021-04-02 | 浙江理工大学 | 采用服用或废弃服用腈纶制备纳米碳纤维的方法 |
| FR3095819B1 (fr) * | 2019-05-10 | 2021-06-18 | Inst De Rech Tech Jules Verne | Procédé de fabrication d’une fibre de carbone à partir d’un produit en papier |
| KR102075114B1 (ko) * | 2019-06-21 | 2020-02-07 | 국방과학연구소 | 라이오셀계 탄소섬유 제조를 위한 탄소 나노 튜브 코팅 및 열처리 |
| CN114423816B (zh) * | 2019-09-23 | 2024-10-11 | 阿莫绿色技术有限公司 | 射频散热塑料、其制备方法及利用其的中继器盒体 |
| US12053908B2 (en) | 2021-02-01 | 2024-08-06 | Regen Fiber, Llc | Method and system for recycling wind turbine blades |
| JP7018237B1 (ja) * | 2021-12-02 | 2022-02-10 | 竹本油脂株式会社 | 炭素繊維前駆体用処理剤、炭素繊維前駆体用処理剤含有組成物、及び炭素繊維前駆体 |
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- 2013-10-18 US US14/437,701 patent/US9909235B2/en not_active Expired - Fee Related
- 2013-10-18 EP EP13792052.6A patent/EP2909366A1/fr not_active Withdrawn
- 2013-10-18 CN CN201380054732.2A patent/CN104755661B/zh not_active Expired - Fee Related
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| JP2010007216A (ja) * | 2008-06-30 | 2010-01-14 | Mitsubishi Rayon Co Ltd | 炭素繊維前駆体アクリル系繊維用油剤組成物、並びに炭素繊維前駆体アクリル系繊維束及びその製造方法 |
| WO2012066241A2 (fr) * | 2010-11-17 | 2012-05-24 | Arkema France | Procede de fabrication de materiau fibreux pre-impregne de polymere thermodurcissable |
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Also Published As
| Publication number | Publication date |
|---|---|
| FR2997097B1 (fr) | 2015-04-10 |
| US9909235B2 (en) | 2018-03-06 |
| WO2014064373A1 (fr) | 2014-05-01 |
| CN104755661A (zh) | 2015-07-01 |
| EP2909366A1 (fr) | 2015-08-26 |
| FR2997097A1 (fr) | 2014-04-25 |
| JP2015537125A (ja) | 2015-12-24 |
| KR20150077465A (ko) | 2015-07-07 |
| JP6368716B2 (ja) | 2018-08-01 |
| US20150292118A1 (en) | 2015-10-15 |
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