CN104745972B - 具有高延展性、高加工性的高磁通密度软磁铁基非晶合金 - Google Patents
具有高延展性、高加工性的高磁通密度软磁铁基非晶合金 Download PDFInfo
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- CN104745972B CN104745972B CN201410834174.8A CN201410834174A CN104745972B CN 104745972 B CN104745972 B CN 104745972B CN 201410834174 A CN201410834174 A CN 201410834174A CN 104745972 B CN104745972 B CN 104745972B
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- 229910000808 amorphous metal alloy Inorganic materials 0.000 title claims abstract description 81
- 230000005291 magnetic effect Effects 0.000 title claims abstract description 52
- 230000004907 flux Effects 0.000 title claims abstract description 39
- 230000005389 magnetism Effects 0.000 title claims abstract description 29
- 230000003245 working effect Effects 0.000 title claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 186
- 239000000956 alloy Substances 0.000 claims abstract description 76
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 73
- 229910052742 iron Inorganic materials 0.000 claims abstract description 37
- 229910052796 boron Inorganic materials 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims abstract description 24
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 23
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 21
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 14
- 230000035699 permeability Effects 0.000 claims abstract description 14
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000010703 silicon Substances 0.000 claims abstract description 13
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011574 phosphorus Substances 0.000 claims abstract description 11
- 238000005275 alloying Methods 0.000 claims abstract description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
- 238000010791 quenching Methods 0.000 claims description 8
- 230000000171 quenching effect Effects 0.000 claims description 8
- 230000015572 biosynthetic process Effects 0.000 abstract description 8
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract description 6
- 238000007496 glass forming Methods 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 description 33
- 239000000463 material Substances 0.000 description 28
- 125000004429 atom Chemical group 0.000 description 22
- 239000005300 metallic glass Substances 0.000 description 21
- 238000002441 X-ray diffraction Methods 0.000 description 14
- 238000002425 crystallisation Methods 0.000 description 13
- 230000008025 crystallization Effects 0.000 description 13
- 238000007711 solidification Methods 0.000 description 13
- 230000008023 solidification Effects 0.000 description 13
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 11
- 239000011521 glass Substances 0.000 description 9
- 238000009826 distribution Methods 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000002184 metal Substances 0.000 description 7
- 229910000676 Si alloy Inorganic materials 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 6
- 239000011162 core material Substances 0.000 description 6
- 229910018540 Si C Inorganic materials 0.000 description 5
- 238000000137 annealing Methods 0.000 description 5
- 229910010271 silicon carbide Inorganic materials 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 150000001875 compounds Chemical group 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 230000005496 eutectics Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000012300 argon atmosphere Substances 0.000 description 3
- 230000006837 decompression Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 238000004663 powder metallurgy Methods 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000003708 ampul Substances 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000010955 niobium Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 238000007088 Archimedes method Methods 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910001021 Ferroalloy Inorganic materials 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 229910000846 In alloy Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910008423 Si—B Inorganic materials 0.000 description 1
- 229910006367 Si—P Inorganic materials 0.000 description 1
- 229910001037 White iron Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
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- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000006355 external stress Effects 0.000 description 1
- 230000005307 ferromagnetism Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 239000000700 radioactive tracer Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000008771 sex reversal Effects 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000010875 treated wood Substances 0.000 description 1
Landscapes
- Soft Magnetic Materials (AREA)
- Continuous Casting (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013-272759 | 2013-12-27 | ||
| JP2013272759A JP6347606B2 (ja) | 2013-12-27 | 2013-12-27 | 高延性・高加工性を持つ高磁束密度軟磁性鉄基非晶質合金 |
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| Publication Number | Publication Date |
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| CN104745972A CN104745972A (zh) | 2015-07-01 |
| CN104745972B true CN104745972B (zh) | 2018-03-27 |
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| CN201410834174.8A Active CN104745972B (zh) | 2013-12-27 | 2014-12-26 | 具有高延展性、高加工性的高磁通密度软磁铁基非晶合金 |
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| Country | Link |
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| JP (1) | JP6347606B2 (enExample) |
| CN (1) | CN104745972B (enExample) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104946962B (zh) * | 2015-06-10 | 2018-01-23 | 中国科学院宁波材料技术与工程研究所 | 一种含磷和碳的母合金的熔炼工艺 |
| CN105177469A (zh) * | 2015-09-25 | 2015-12-23 | 天津大学 | 一种高铁含量的非晶软磁合金及其制备方法 |
| CN107103976A (zh) * | 2016-02-22 | 2017-08-29 | 天津大学 | 一种铁钴基韧性纳米晶软磁合金及其制备方法 |
| CN106636984A (zh) * | 2017-01-25 | 2017-05-10 | 青岛云路先进材料技术有限公司 | 一种铁基非晶合金 |
| CN106636982B (zh) * | 2017-01-25 | 2018-02-09 | 青岛云路先进材料技术有限公司 | 一种铁基非晶合金及其制备方法 |
| CN106636983A (zh) * | 2017-01-25 | 2017-05-10 | 青岛云路先进材料技术有限公司 | 一种铁基非晶合金的制备方法 |
| CN106702291A (zh) * | 2017-01-25 | 2017-05-24 | 青岛云路先进材料技术有限公司 | 一种铁基非晶合金及其制备方法 |
| CN106906431A (zh) * | 2017-04-06 | 2017-06-30 | 青岛云路先进材料技术有限公司 | 一种铁基非晶合金及其制备方法 |
| CN107309408B (zh) * | 2017-06-28 | 2019-04-05 | 黄毅 | 低成本生产高导磁非晶纳米晶合金带材的方法 |
| CN107236911A (zh) * | 2017-07-31 | 2017-10-10 | 青岛云路先进材料技术有限公司 | 一种铁基非晶合金 |
| CN109576609B (zh) * | 2018-11-26 | 2021-07-27 | 清华大学 | 软磁性FeCoNiBCP高熵非晶合金及其制备方法 |
| CN109468425A (zh) * | 2018-12-11 | 2019-03-15 | 武汉桂坤科技有限公司 | 一种非真空下生产非晶态带材新工艺 |
| JP7637341B2 (ja) * | 2020-02-25 | 2025-02-28 | 大同特殊鋼株式会社 | Ｆｅ基アモルファス合金及びその製造方法 |
| JP7584780B2 (ja) * | 2020-06-08 | 2024-11-18 | ネクストコアテクノロジーズ株式会社 | Ｆｅ－Ｓｉ－Ｂ系急冷凝固合金およびその製造方法 |
| JP2021195579A (ja) | 2020-06-10 | 2021-12-27 | 株式会社Bmg | 高磁束密度軟磁性Ｆｅ系非晶質合金 |
| CN112469257A (zh) * | 2020-10-14 | 2021-03-09 | 北京航空航天大学 | 一种低噪声和高屏蔽系数的铁基非晶材料电磁屏蔽桶 |
| CN112143985B (zh) * | 2020-10-15 | 2022-03-15 | 太原理工大学 | 一种低矫顽力的铁基非晶合金及其成分设计方法 |
| CN114058810B (zh) * | 2021-11-18 | 2023-06-23 | 安徽中环晶研新材料有限公司 | 一种高性能铁基非晶纳米晶合金的热处理方法 |
| CN114420435B (zh) * | 2022-01-25 | 2023-11-24 | 沈阳工业大学 | 一种变压器用混合材料卷铁心截面设计方法 |
| CN115786823B (zh) * | 2022-12-02 | 2025-05-06 | 新疆大学 | 一种具有明显塑性和优异耐蚀性的高熵块体非晶合金及制备方法 |
| CN116083772B (zh) * | 2022-12-28 | 2024-09-17 | 钢研纳克检测技术股份有限公司 | 一种具有900k高温抗性软磁高熵合金 |
| CN116445790B (zh) * | 2023-03-17 | 2024-07-16 | 中国科学院宁波材料技术与工程研究所 | 一种软磁高熵合金及其制备的软磁复合材料和制备方法 |
| CN116607085B (zh) * | 2023-05-24 | 2025-06-13 | 长三角物理研究中心有限公司 | 一种高电阻率的非晶合金带材及其制备方法 |
| CN120188926B (zh) * | 2025-05-26 | 2025-07-22 | 杭州电子科技大学 | 低韧性气溶胶加热器、制备方法、应用及气溶胶生成制品 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1721563A (zh) * | 2004-07-05 | 2006-01-18 | 日立金属株式会社 | Fe基非晶态合金带 |
| CN101167145A (zh) * | 2005-02-17 | 2008-04-23 | 梅特格拉斯公司 | 铁基高饱和感应非晶态合金 |
| CN101595237A (zh) * | 2006-12-04 | 2009-12-02 | 东北泰克诺亚奇股份有限公司 | 非晶态合金组合物 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001279387A (ja) * | 2000-03-28 | 2001-10-10 | Nippon Steel Corp | 急冷凝固薄帯製造用の安価なＦｅ基母合金 |
| JP3634286B2 (ja) * | 2000-11-27 | 2005-03-30 | 新日本製鐵株式会社 | Ｆｅ基非晶質合金薄帯とそれを用いて製造した鉄心 |
| WO2003085150A1 (fr) * | 2002-04-05 | 2003-10-16 | Nippon Steel Corporation | Bande mince en alliage amorphe a base de fer presentant de remarquables caracteristiques d'aimantation temporaire, noyau de fer obtenu a partir de cette bande et alliage mere pour production de bande mince a solidification par trempe |
| JP4319206B2 (ja) * | 2006-07-20 | 2009-08-26 | 独立行政法人科学技術振興機構 | 軟磁性Ｆｅ基金属ガラス合金 |
| JP2009174034A (ja) * | 2008-01-28 | 2009-08-06 | Hitachi Metals Ltd | アモルファス軟磁性合金、アモルファス軟磁性合金薄帯、アモルファス軟磁性合金粉末およびそれを用いた磁心並びに磁性部品 |
| CN102741437B (zh) * | 2008-08-22 | 2014-12-10 | 牧野彰宏 | 合金组合物、Fe基纳米晶合金及其制造方法和磁性部件 |
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2013
- 2013-12-27 JP JP2013272759A patent/JP6347606B2/ja active Active
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- 2014-12-26 CN CN201410834174.8A patent/CN104745972B/zh active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1721563A (zh) * | 2004-07-05 | 2006-01-18 | 日立金属株式会社 | Fe基非晶态合金带 |
| CN101167145A (zh) * | 2005-02-17 | 2008-04-23 | 梅特格拉斯公司 | 铁基高饱和感应非晶态合金 |
| CN101595237A (zh) * | 2006-12-04 | 2009-12-02 | 东北泰克诺亚奇股份有限公司 | 非晶态合金组合物 |
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| Publication number | Publication date |
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| JP6347606B2 (ja) | 2018-06-27 |
| CN104745972A (zh) | 2015-07-01 |
| JP2015127436A (ja) | 2015-07-09 |
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