CN104725140A - Amino acid fertilizer synergist with ammonia volatilization inhibiting effect and manufacture method thereof - Google Patents
Amino acid fertilizer synergist with ammonia volatilization inhibiting effect and manufacture method thereof Download PDFInfo
- Publication number
- CN104725140A CN104725140A CN201510132405.5A CN201510132405A CN104725140A CN 104725140 A CN104725140 A CN 104725140A CN 201510132405 A CN201510132405 A CN 201510132405A CN 104725140 A CN104725140 A CN 104725140A
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- CN
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- Prior art keywords
- amino acid
- water
- parts
- agent
- ammonia volatilization
- Prior art date
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 55
- 238000000034 method Methods 0.000 title claims abstract description 36
- 229910021529 ammonia Inorganic materials 0.000 title claims abstract description 34
- 230000002401 inhibitory effect Effects 0.000 title claims abstract description 33
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Classifications
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Abstract
The invention discloses an amino acid fertilizer synergist with an ammonia volatilization inhibiting effect and a manufacture method thereof. The amino acid fertilizer synergist is characterized by comprising the following components in parts by weight: 70-85 parts of starch, 6-7 parts of strain, 5-10 parts of carbon source, 3-5 parts of nitrogen source, 30-50 parts of water, 1.6-1.8 parts of medium trace element, 6-8 parts of seaweed hydrolysate, 3-4 parts of water soluble nutrient antibiotics and 2-4 parts of root growth promoting agent. The amino acid synergy solution is obtained through a solid fermentation method, wherein the solid content is greater than or equal to 12%, the amino acid content is greater than or equal to 8, the ammonia volatilization inhibiting rate is greater than or equal to 25%, and the amino acid deposition rate is less than or equal to 65%; the amino acid synergy solution is applied to the synergist for promoting the nutrient absorption of the plant in the soil; the nitrogen fertilizer apparent utilization rate is increased to greater than 40%, each component is pure natural substance and can be completely degraded to reduce the morbidity of the plant diseases and insect pests; the potato control efficiency is respectively 92.5% and the water absorbency is 350-450 g/g; the soil caking can be prevented, the root activity in the seedling stage can be increased to greater than 43% and the amino acid fertilizer synergist has an obvious yield-increasing effect.
Description
Technical field
The invention belongs to fertilizer synergist technical field, be specifically related to one and there is inhibiting amino acid fertilizer synergistic agent of ammonia volatilization and preparation method thereof.
Background technology
The chemical fertilizer utilization ratio of China is general lower, nitrogenous fertilizer average utilization about 30%, phosphate fertilizer this season utilization ratio about 25%, potassium utilization rate about 50%.In prior art research focus mostly on the investigation and application of the chemicals such as urease inhibitor and nitrification inhibitor, for crude substance and the research of modified natural materials on fertilizer auxiliary agent less.Amino acid is the organic carbon source of crop, again organic nitrogen source simultaneously, organic acid, sugar, sugar alcohol, gsh etc. all can be used as organic carbon source by crop and directly absorb, metabolic process can be participated in directly after absorption, save the energy of crop organic synthesis, and can crop root growth be promoted, improve improving activity of root system; There is the degeneration-resistant diseases and insect pests resistance of crop simultaneously, all have more significant effect of increasing production to various crop, and there is the toxic action alleviating plant heavy metal ion.The nutrient substance of existing promotion tubers, exists that composition activeconstituents is more not to be saved, and activeconstituents proportioning is reasonable not, and purposes is problem not widely.
Traditionally trace element is supplemented and use its inorganic salt form; as zinc sulfate, ferrous sulfate and manganous sulfate etc.; but also exist that range of application is narrower, inefficiency, be easy to form indissoluble salt, be unfavorable for the problems such as Crop in the soil system of complexity; reduce its biologic activity; not only do not have the effect of trace element supplement; but also can soil compaction be caused, be unfavorable for the Sustainable development of environment protection and agricultural.Based on traditional chemical fertilizer, be equipped with some required synergistic component, it with the addition of multiple inorganic or organic compound to some extent, and synthesising preparation and biochemical product, but consider few to the diseases and insect pests resistance improving crop, or the compositions such as the sterilant added have severe side effect to soil and crop, insect pest is caused to make a variation, the generation of the problems such as soil pollution.In addition, existing amino acid synergistic agent comparison of ingredients is single, not there is comprehensive nutrition, therefore, how to invent one and there is inhibiting amino acid fertilizer synergistic agent of ammonia volatilization and preparation method thereof, make full use of existing resource, improve ammonia volatilization restraining effect, improve crop quality, promote volume increase, have important practical significance.
Summary of the invention
For problems of the prior art, one is the object of the present invention is to provide to have inhibiting amino acid fertilizer synergistic agent of ammonia volatilization and preparation method thereof, amino acid synergistic liquid of the present invention is applied in synergistic agent, can promote that plant is to the absorption of nutrient in soil, Nitrogen apparent recovery fraction brings up to more than 40%, each composition is pure natural substance, can very degrade, reduce the sickness rate of disease and pest, potato prevention effect is respectively 92.5%, its water absorbent rate is 350-450g/g, soil block can be prevented, the improving activity of root system that can significantly improve seedling stage reaches more than 43%, there is more significant effect of increasing production.
The technical scheme that the present invention takes is:
One has the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization, and it is characterized in that, feed components is composed as follows according to weight part:
Starch 70-85 part, bacterial classification 6-7 part, carbon source 5-10 part, nitrogenous source 3-5 part, water 30-50 part, medium trace element 1.6-1.8 part, hydrolyzing seaweed liquid 6-8 part, water-soluble nutrition antibiotic 3-4 part, promoter 2-4 part.
Further, be describedly no less than the Lactobacterium acidophilum of 2.0 × 1011cfu, the colloid bacillus cereus being no less than 1.0 × 1011cfu containing effective gemma number and effective gemma number be no less than 2.0 × 10 containing effective gemma number
11the mix bacterium agent of the Bacillus licheniformis composition of cfu.
Further, the mixture that described carbon source is percentage composition is 30-40% fragrant plant mentioned in ancient texts dish, the stone honey of 15-25%, the sweet potato starch of 50-75% form.
Further, described nitrogenous source is percentage composition is the mixture that 25-35% dried silkworm chrysalis meal, 15-20% peptone and 55-75% wheat bran form.
Further, described promoter is consisted of by weight part: the mixture of 3-5 part naphthylacetic acid, 2-4 part vitamins B phosphoric acid ester, 2-4 part Vitamin E acetate, 3-5 part vitamin C phosphoric ester, 5-7 part chitosan.
Further, the preparation method of described water-soluble nutrition antibiotic comprises the steps:
(1) chitin colloid solution I processed: get glycolic acid, citric acid mixing according to weight proportion 2:3, be made into deionized water the aqueous solution that concentration is 12-15wt%, add chitosan, be heated to 60-65 DEG C and stir;
(2) thick gel II processed: get seaweed gel according to weight ratio 3:4, guar gum coordinates, be made into deionized water the aqueous solution that concentration is 6-8wt%, raised temperature is 40 DEG C-50 DEG C and stirs;
(3) aqueous solution III: Shrubalthea Bark and temperature are that the water of 90 DEG C mixes according to 1:3, lixiviate 3-4h, filtration obtains vat liquor, adds percentage composition than tea saponin, the matrine of 6-8%, the azone of 4-6%, the nicotine of 2-5% for 3-5%, stir in vat liquor;
(4) make water-soluble nutrition antibiotic: mixed by the solution of step (1) and step (2) and step (3), add the deionized water solution that mixture 2 times of volumes contain 30% xanthohumic acid, stir.
Further, described medium trace element be by percentage composition be the EDTA chelated copper of 0.01-0.03%, the Chelating state element that forms of the EDTA chelated iron of 0.3-0.5%, the EDTA Chelated Manganese of 0.06-0.08%, the EDTA chelated zinc of 0.7-0.9%, the EDTA chelated magnesium of 0.2-0.4%, the EDTA chelating calcium of 0.7-0.9%.
There is a making method for the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization, it is characterized in that, specifically comprise the steps:
(1) starch adhesive processed: the mixing starch getting peanut starch, rice flour composition according to weight proportion 4:1, adds the water grinding machine defibrination of 2-3 times of volume, adjustment starch adhesive concentration is 16-20 Baume;
(2) enzymolysis: regulate pH for 6-7 according to the mixture that mol ratio 1:3 forms with sodium carbonate and sodium hydroxide, and add the polyphenoloxidase of starch weight 0.3-0.5% and the trypsinase of 0.2-0.4%, starch adhesive is heated to 38-42 DEG C, and enzymolysis time is 5-6h;
(3) ferment: get the mixing of bacterial classification, carbon source, nitrogenous source, water and medium trace element according to weight proportion and add in the obtained enzymolysis solution of step (2), stir and stack fermentation 15-18 days;
(4) chelating extracts: in the material after fermentation ends, add the water of 3 times of volumes, stir, first use acetic acid as acidic extraction agent, control temperature is 45-50 DEG C, extract 12-14h, regulate pH to be between 6.5-7 with the alkaline extraction agent that sodium carbonate and sodium hydroxide form according to mol ratio 1:3, solution is 65-75 DEG C by automatic steam control temperature and stirs extraction 7-9h;
(5) amino acid synergistic liquid processed: solution carries out press filtration by pressure filter, the boric acid of 2-5 part is added in the filtrate obtained, be 6-7 with vinegar acid for adjusting pH, evaporation concentration obtains solid substance >=12%, aminoacids content >=8, ammonia volatilization inhibiting rate >=25%, the amino acid synergistic liquid of amino acid deposition rate≤65%;
(6) hydrolyzing seaweed liquid processed: choose fresh marine alga and rub, pull an oar, add the cellulase of 1-3% and the middle temperature α-amylase of 2-4%, control temperature is 35-37 DEG C, regulate hydrolyzed solution pH value to 6-7 with acetic acid, hydrolysis 4-5h, filter, in filtrate, add the water-holding agent that 4-8% is made up of according to weight ratio 3:2:2 cross-linked polysaccharides acetic ester, Artemisinin, Viscogum BE, homogeneous;
(7) synergistic agent processed: mixed according to weight proportion by the hydrolyzing seaweed liquid in the amino acid synergistic liquid in step (5) and step (6), adds water-soluble nutrition antibiotic and the promoter of corresponding weight proportion, stirs.
Further, described step (7) adds the liquid calcium nutrition agent of 2-3% in the process stirred, the making method of described liquid calcium nutrition agent is, amino acid is got and calcium lignin sulphonate is dissolved in the water of 3 times of volumes according to weight ratio 5:3, weight ratio 1:2 is by concentration the mixture that the nitrocalcite of 2mol/L and calcium carbonate forms to be dissolved in the above-mentioned aqueous solution, add 1.2 normal atmosphere, control temperature is 95oC, stirs 2h.
Beneficial effect of the present invention is:
The present invention adopts peanut starch, the mixing starch that rice flour forms is as the main raw material of solid state fermentation, coordinate nitrogenous source, carbon source, the compositions such as special bacterial classification, solid substance >=12% is obtained by solid fermentation method, aminoacids content >=8, ammonia volatilization inhibiting rate >=25%, the amino acid synergistic liquid of amino acid deposition rate≤65%, the preliminary enzymolysis of starch can active substance in activated Starch, for high-efficiency fermenting is laid a good foundation, organic acid is rich in amino acid synergistic liquid, sugar, sugar alcohol, gsh etc. all can be used as the composition that organic carbon source is directly absorbed by crop, be applied in synergistic agent, can promote that plant is to the absorption of nutrient in soil, significantly can increase grain number per spike and the 100-grain weight of crop, Nitrogen apparent recovery fraction improves more than 40%, each composition is pure natural substance, the feature of environmental protection is excellent, can very degrade, metabolic process can be participated in directly after absorption, and can crop root growth be promoted, improve improving activity of root system, there is more significant effect of increasing production.
Compound chitin colloid solution I and thick gel II in water-soluble nutrition antibiotic in the present invention, as the added ingredients of synergistic agent, glycolic acid, as the added ingredients of synergistic agent in citric acid, the Multiple components in synergistic agent can be made to have good dispersiveness and stability, the cooperation of seaweed gel and guar gum can promote the growth of crop, as microbial polysaccharide, microbial polysaccharide composition can be increased, be conducive to recovering soil fertility, improve cultivation power, improve the yield and quality of crop, tea saponin is added with in the vat liquor of Shrubalthea Bark, matrine, the composition such as azone and nicotine, improve the diseases and insect pests resistance of crop, there is sterilization, the effects such as repellent insect pest, reduce the sickness rate of disease and pest, the prevention effect of potato reaches more than 92%, reach the effect reducing agricultural chemicals and chemical fertilizer, and there is the toxic action alleviating plant heavy metal ion, environment protecting is good.
The mixture that promoter of the present invention is made up of naphthylacetic acid, vitamins B phosphoric acid ester, Vitamin E acetate, vitamin C phosphoric ester, chitosan, add the activeconstituents of enhancer composition, activeconstituents reasonable ratio, crop root growth can be promoted, improve improving activity of root system, obtained synergistic agent can significantly improve the improving activity of root system in seedling stage and reach more than 43%, has more significant effect of increasing production.
Composite in synergistic agent of the present invention have hydrolyzing seaweed liquid, and marine alga obtains amino acid synergistic composition by enzymolysis, is conducive to crop yield, water-holding agent is added in filtrate, its water absorbent rate is 350-450g/g, can prevent soil block, improves crop water absorption, effective fertilizer composition utilising efficiency.
The present invention adds medium trace element in composition of raw materials, boric acid is added in filtrate again after weak base extracts, crop for want of trace element generation disease can be prevented, crop root growth can be promoted, improve improving activity of root system, thus promote aerobic beneficial microorganism to grow and activity, strengthen the ability of Crop nutrient, increase soil organic matter content.
In manufacture craft of the present invention, the liquid calcium nutrition agent of 2-3% is added in the process in the end stirred, the compositions such as amino acid, calcium lignin sulphonate, nitrocalcite and calcium carbonate are rich in described liquid calcium nutrition agent, can for farm crop supplement its growth needed for amino acid and calcium constituent, indirectly supplement the calcium constituent of needed by human body, have the effect improving crop quality, market application foreground is wide.
Embodiment
The present invention is further illustrated below in conjunction with specific embodiment.
Embodiment 1
One has the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization, and it is characterized in that, feed components is composed as follows according to weight part:
Starch 70 parts, bacterial classification 6 parts, carbon source 5 parts, 3 parts, nitrogenous source, 30 parts, water, medium trace element 1.6 parts, hydrolyzing seaweed liquid 6 parts, 3 parts, water-soluble nutrition antibiotic, promoter 2 parts.
Further, be describedly no less than the Lactobacterium acidophilum of 2.0 × 1011cfu, the colloid bacillus cereus being no less than 1.0 × 1011cfu containing effective gemma number and effective gemma number be no less than 2.0 × 10 containing effective gemma number
11the mix bacterium agent of the Bacillus licheniformis composition of cfu.
Further, the mixture that described carbon source is percentage composition is 30% fragrant plant mentioned in ancient texts dish, the stone honey of 15%, the sweet potato starch of 55% form.
Further, described nitrogenous source is percentage composition is the mixture that 25% dried silkworm chrysalis meal, 15% peptone and 60% wheat bran form.
Further, described promoter is consisted of by weight part: the mixture of 3 parts of naphthylacetic acids, 2 parts of vitamins B phosphoric acid ester, 2 parts of Vitamin E acetates, 3 parts of vitamin C phosphoric esters, 5 parts of chitosan.
Further, the preparation method of described water-soluble nutrition antibiotic comprises the steps:
(1) chitin colloid solution I processed: get glycolic acid, citric acid mixing according to weight proportion 2:3, be made into deionized water the aqueous solution that concentration is 12wt%, add chitosan, be heated to 60 DEG C and stir;
(2) thick gel II processed: get seaweed gel according to weight ratio 3:4, guar gum coordinates, be made into deionized water the aqueous solution that concentration is 6wt%, raised temperature is 40 DEG C and stirs;
(3) aqueous solution III: Shrubalthea Bark and temperature are that the water of 90 DEG C mixes according to 1:3, lixiviate 3h, filters and obtains vat liquor, adding percentage composition than being the tea saponin of 3%, matrine, the azone of 4%, the nicotine of 2% of 6%, stirring in vat liquor;
(4) make water-soluble nutrition antibiotic: mixed by the solution of step (1) and step (2) and step (3), add the deionized water solution that mixture 2 times of volumes contain 30% xanthohumic acid, stir.
Further, described medium trace element be by percentage composition be the EDTA chelated copper of 0.01-0.03%, the Chelating state element that forms of the EDTA chelated iron of 0.3-0.5%, the EDTA Chelated Manganese of 0.06-0.08%, the EDTA chelated zinc of 0.7-0.9%, the EDTA chelated magnesium of 0.2-0.4%, the EDTA chelating calcium of 0.7-0.9%.
There is a making method for the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization, it is characterized in that, specifically comprise the steps:
(1) starch adhesive processed: the mixing starch getting peanut starch, rice flour composition according to weight proportion 4:1, adds the water grinding machine defibrination of 2 times of volumes, adjustment starch adhesive concentration is 16-20 Baume;
(2) enzymolysis: regulate pH for 6-7 with sodium carbonate and sodium hydroxide according to the mixture that mol ratio 1:3 forms, and add polyphenoloxidase and 0.2% trypsinase of starch weight 0.3%, starch adhesive is heated to 38 DEG C, enzymolysis time is 6h;
(3) ferment: get the mixing of bacterial classification, carbon source, nitrogenous source, water and medium trace element according to weight proportion and add in the obtained enzymolysis solution of step (2), stir and stack fermentation 15 days;
(4) chelating extracts: in the material after fermentation ends, add the water of 3 times of volumes, stir, first use acetic acid as acidic extraction agent, control temperature is 45-50 DEG C, extract 12-14h, regulate pH to be between 6.5-7 with the alkaline extraction agent that sodium carbonate and sodium hydroxide form according to mol ratio 1:3, solution is 65 DEG C by automatic steam control temperature and stirs extraction 9h;
(5) amino acid synergistic liquid processed: solution carries out press filtration by pressure filter, in the filtrate obtained, add the boric acid of 3 parts, be 6-7 with vinegar acid for adjusting pH, evaporation concentration obtains solid substance >=12%, aminoacids content >=8, ammonia volatilization inhibiting rate >=25%, the amino acid synergistic liquid of amino acid deposition rate≤65%;
(6) hydrolyzing seaweed liquid processed: choose fresh marine alga and rub, pull an oar, add the cellulase of 1% and the middle temperature α-amylase of 2%, control temperature is 35 DEG C, regulate hydrolyzed solution pH value to 6-7 with acetic acid, hydrolysis 5h, filter, in filtrate, add 4% water-holding agent be made up of according to weight ratio 3:2:2 cross-linked polysaccharides acetic ester, Artemisinin, Viscogum BE, homogeneous;
(7) synergistic agent processed: mixed according to weight proportion by the hydrolyzing seaweed liquid in the amino acid synergistic liquid in step (5) and step (6), adds water-soluble nutrition antibiotic and the promoter of corresponding weight proportion, stirs.
Embodiment 2
One has the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization, and it is characterized in that, feed components is composed as follows according to weight part:
Starch 75 parts, bacterial classification 6.5 parts, carbon source 8 parts, 4 parts, nitrogenous source, 40 parts, water, medium trace element 1.7 parts, hydrolyzing seaweed liquid 7 parts, 3.5 parts, water-soluble nutrition antibiotic, promoter 3 parts.
Further, be describedly no less than the Lactobacterium acidophilum of 2.0 × 1011cfu, the colloid bacillus cereus being no less than 1.0 × 1011cfu containing effective gemma number and effective gemma number be no less than 2.0 × 10 containing effective gemma number
11the mix bacterium agent of the Bacillus licheniformis composition of cfu.
Further, the mixture that described carbon source is percentage composition is 35% fragrant plant mentioned in ancient texts dish, the stone honey of 15%, the sweet potato starch of 50% form.
Further, described nitrogenous source is percentage composition is the mixture that 30% dried silkworm chrysalis meal, 15% peptone and 55% wheat bran form.
Further, described promoter is consisted of by weight part: the mixture of 4 parts of naphthylacetic acids, 3 parts of vitamins B phosphoric acid ester, 3 parts of Vitamin E acetates, 4 parts of vitamin C phosphoric esters, 6 parts of chitosan.
Further, the preparation method of described water-soluble nutrition antibiotic comprises the steps:
(1) chitin colloid solution I processed: get glycolic acid, citric acid mixing according to weight proportion 2:3, be made into deionized water the aqueous solution that concentration is 13wt%, add chitosan, be heated to 63 DEG C and stir;
(2) thick gel II processed: get seaweed gel according to weight ratio 3:4, guar gum coordinates, be made into deionized water the aqueous solution that concentration is 7wt%, raised temperature is 45 DEG C and stirs;
(3) aqueous solution III: Shrubalthea Bark and temperature are that the water of 90 DEG C mixes according to 1:3, lixiviate 3.2h, filters and obtains vat liquor, adding percentage composition than being the tea saponin of 4%, matrine, the azone of 5%, the nicotine of 3% of 7%, stirring in vat liquor;
(4) make water-soluble nutrition antibiotic: mixed by the solution of step (1) and step (2) and step (3), add the deionized water solution that mixture 2 times of volumes contain 30% xanthohumic acid, stir.
Further, described medium trace element be by percentage composition be the EDTA chelated copper of 0.01-0.03%, the Chelating state element that forms of the EDTA chelated iron of 0.3-0.5%, the EDTA Chelated Manganese of 0.06-0.08%, the EDTA chelated zinc of 0.7-0.9%, the EDTA chelated magnesium of 0.2-0.4%, the EDTA chelating calcium of 0.7-0.9%.
There is a making method for the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization, it is characterized in that, specifically comprise the steps:
(1) starch adhesive processed: the mixing starch getting peanut starch, rice flour composition according to weight proportion 4:1, adds the water grinding machine defibrination of 2.5 times of volumes, adjustment starch adhesive concentration is 16-20 Baume;
(2) enzymolysis: regulate pH for 6-7 with sodium carbonate and sodium hydroxide according to the mixture that mol ratio 1:3 forms, and add polyphenoloxidase and 0.3% trypsinase of starch weight 0.4%, starch adhesive is heated to 40 DEG C, enzymolysis time is 5.5h;
(3) ferment: get the mixing of bacterial classification, carbon source, nitrogenous source, water and medium trace element according to weight proportion and add in the obtained enzymolysis solution of step (2), stir and stack fermentation 16 days;
(4) chelating extracts: in the material after fermentation ends, add the water of 3 times of volumes, stir, first use acetic acid as acidic extraction agent, control temperature is 48 DEG C, extract 13h, regulate pH to be between 6.5-7 with the alkaline extraction agent that sodium carbonate and sodium hydroxide form according to mol ratio 1:3, solution is 70 DEG C by automatic steam control temperature and stirs extraction 8h;
(5) amino acid synergistic liquid processed: solution carries out press filtration by pressure filter, in the filtrate obtained, add the boric acid of 2 parts, be 6-7 with vinegar acid for adjusting pH, evaporation concentration obtains solid substance >=12%, aminoacids content >=8, ammonia volatilization inhibiting rate >=25%, the amino acid synergistic liquid of amino acid deposition rate≤65%;
(6) hydrolyzing seaweed liquid processed: choose fresh marine alga and rub, pull an oar, add the cellulase of 2% and the middle temperature α-amylase of 3%, control temperature is 36 DEG C, regulate hydrolyzed solution pH value to 6-7 with acetic acid, hydrolysis 4.8h, filter, in filtrate, add 6% water-holding agent be made up of according to weight ratio 3:2:2 cross-linked polysaccharides acetic ester, Artemisinin, Viscogum BE, homogeneous;
(7) synergistic agent processed: mixed according to weight proportion by the hydrolyzing seaweed liquid in the amino acid synergistic liquid in step (5) and step (6), adds water-soluble nutrition antibiotic and the promoter of corresponding weight proportion, stirs.
Embodiment 3
One has the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization, and it is characterized in that, feed components is composed as follows according to weight part:
Starch 80 parts, bacterial classification 6.5 parts, carbon source 7 parts, 4.5 parts, nitrogenous source, 45 parts, water, medium trace element 1.7 parts, hydrolyzing seaweed liquid 6.5 parts, 3.8 parts, water-soluble nutrition antibiotic, promoter 3.5 parts.
Further, be describedly no less than the Lactobacterium acidophilum of 2.0 × 1011cfu, the colloid bacillus cereus being no less than 1.0 × 1011cfu containing effective gemma number and effective gemma number be no less than 2.0 × 10 containing effective gemma number
11the mix bacterium agent of the Bacillus licheniformis composition of cfu.
Further, the mixture that described carbon source is percentage composition is 32% fragrant plant mentioned in ancient texts dish, the stone honey of 18%, the sweet potato starch of 50% form.
Further, described nitrogenous source is percentage composition is the mixture that 25% dried silkworm chrysalis meal, 15% peptone and 60% wheat bran form.
Further, described promoter is consisted of by weight part: the mixture of 4 parts of naphthylacetic acids, 2.5 parts of vitamins B phosphoric acid ester, 3.5 parts of Vitamin E acetates, 4.5 parts of vitamin C phosphoric esters, 5.5 parts of chitosan.
Further, the preparation method of described water-soluble nutrition antibiotic comprises the steps:
(1) chitin colloid solution I processed: get glycolic acid, citric acid mixing according to weight proportion 2:3, be made into deionized water the aqueous solution that concentration is 14wt%, add chitosan, be heated to 64 DEG C and stir;
(2) thick gel II processed: get seaweed gel according to weight ratio 3:4, guar gum coordinates, be made into deionized water the aqueous solution that concentration is 7wt%, raised temperature is 48 DEG C and stirs;
(3) aqueous solution III: Shrubalthea Bark and temperature are that the water of 90 DEG C mixes according to 1:3, lixiviate 3.8h, filters and obtains vat liquor, adding percentage composition than being the tea saponin of 4%, matrine, the azone of 5%, the nicotine of 4.8% of 7%, stirring in vat liquor;
(4) make water-soluble nutrition antibiotic: mixed by the solution of step (1) and step (2) and step (3), add the deionized water solution that mixture 2 times of volumes contain 30% xanthohumic acid, stir.
Further, described medium trace element be by percentage composition be the EDTA chelated copper of 0.01-0.03%, the Chelating state element that forms of the EDTA chelated iron of 0.3-0.5%, the EDTA Chelated Manganese of 0.06-0.08%, the EDTA chelated zinc of 0.7-0.9%, the EDTA chelated magnesium of 0.2-0.4%, the EDTA chelating calcium of 0.7-0.9%.
There is a making method for the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization, it is characterized in that, specifically comprise the steps:
(1) starch adhesive processed: the mixing starch getting peanut starch, rice flour composition according to weight proportion 4:1, adds the water grinding machine defibrination of 3 times of volumes, adjustment starch adhesive concentration is 16-20 Baume;
(2) enzymolysis: regulate pH for 6-7 with sodium carbonate and sodium hydroxide according to the mixture that mol ratio 1:3 forms, and add the polyphenoloxidase of starch weight 0.4% and the trypsinase of 0.3%, starch adhesive is heated to 40 DEG C, enzymolysis time is 5.8h;
(3) ferment: get the mixing of bacterial classification, carbon source, nitrogenous source, water and medium trace element according to weight proportion and add in the obtained enzymolysis solution of step (2), stir and stack fermentation 16 days;
(4) chelating extracts: in the material after fermentation ends, add the water of 3 times of volumes, stir, first use acetic acid as acidic extraction agent, control temperature is 48 DEG C, extract 13h, regulate pH to be between 6.5-7 with the alkaline extraction agent that sodium carbonate and sodium hydroxide form according to mol ratio 1:3, solution is 70 DEG C by automatic steam control temperature and stirs extraction 8h;
(5) amino acid synergistic liquid processed: solution carries out press filtration by pressure filter, in the filtrate obtained, add the boric acid of 4 parts, be 6-7 with vinegar acid for adjusting pH, evaporation concentration obtains solid substance >=12%, aminoacids content >=8, ammonia volatilization inhibiting rate >=25%, the amino acid synergistic liquid of amino acid deposition rate≤65%;
(6) hydrolyzing seaweed liquid processed: choose fresh marine alga and rub, pull an oar, add the cellulase of 3% and the middle temperature α-amylase of 3%, control temperature is 36 DEG C, regulate hydrolyzed solution pH value to 6-7 with acetic acid, hydrolysis 4.7h, filter, in filtrate, add 6% water-holding agent be made up of according to weight ratio 3:2:2 cross-linked polysaccharides acetic ester, Artemisinin, Viscogum BE, homogeneous;
(7) synergistic agent processed: the hydrolyzing seaweed liquid in the amino acid synergistic liquid in step (5) and step (6) is mixed according to weight proportion, add water-soluble nutrition antibiotic and the promoter of corresponding weight proportion, stir, the liquid calcium nutrition agent of 2-3% is added in the process stirred, the making method of described liquid calcium nutrition agent is, amino acid is got and calcium lignin sulphonate is dissolved in the water of 3 times of volumes according to weight ratio 5:3, weight ratio 1:2 is by concentration the mixture that the nitrocalcite of 2mol/L and calcium carbonate forms to be dissolved in the above-mentioned aqueous solution, add 1.2 normal atmosphere, control temperature is 95oC, stir 2h.
Embodiment 4
One has the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization, and it is characterized in that, feed components is composed as follows according to weight part:
Starch 85 parts, bacterial classification 7 parts, carbon source 10 parts, 5 parts, nitrogenous source, 50 parts, water, medium trace element 1.8 parts, hydrolyzing seaweed liquid 8 parts, 4 parts, water-soluble nutrition antibiotic, promoter 4 parts.
Further, be describedly no less than the Lactobacterium acidophilum of 2.0 × 1011cfu, the colloid bacillus cereus being no less than 1.0 × 1011cfu containing effective gemma number and effective gemma number be no less than 2.0 × 10 containing effective gemma number
11the mix bacterium agent of the Bacillus licheniformis composition of cfu.
Further, the mixture that described carbon source is percentage composition is 34% fragrant plant mentioned in ancient texts dish, the stone honey of 16%, the sweet potato starch of 50% form.
Further, described nitrogenous source is percentage composition is the mixture that 25% dried silkworm chrysalis meal, 20% peptone and 55% wheat bran form.
Further, described promoter is consisted of by weight part: the mixture of 5 parts of naphthylacetic acids, 4 parts of vitamins B phosphoric acid ester, 4 parts of Vitamin E acetates, 5 parts of vitamin C phosphoric esters, 7 parts of chitosan.
Further, the preparation method of described water-soluble nutrition antibiotic comprises the steps:
(1) chitin colloid solution I processed: get glycolic acid, citric acid mixing according to weight proportion 2:3, be made into deionized water the aqueous solution that concentration is 15wt%, add chitosan, be heated to 65 DEG C and stir;
(2) thick gel II processed: get seaweed gel according to weight ratio 3:4, guar gum coordinates, be made into deionized water the aqueous solution that concentration is 8wt%, raised temperature is 50 DEG C and stirs;
(3) aqueous solution III: Shrubalthea Bark and temperature are that the water of 90 DEG C mixes according to 1:3, lixiviate 4h, filters and obtains vat liquor, adding percentage composition than being the tea saponin of 5%, matrine, the azone of 6%, the nicotine of 5% of 8%, stirring in vat liquor;
(4) make water-soluble nutrition antibiotic: mixed by the solution of step (1) and step (2) and step (3), add the deionized water solution that mixture 2 times of volumes contain 30% xanthohumic acid, stir.
Further, described medium trace element be by percentage composition be the EDTA chelated copper of 0.01-0.03%, the Chelating state element that forms of the EDTA chelated iron of 0.3-0.5%, the EDTA Chelated Manganese of 0.06-0.08%, the EDTA chelated zinc of 0.7-0.9%, the EDTA chelated magnesium of 0.2-0.4%, the EDTA chelating calcium of 0.7-0.9%.
There is a making method for the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization, it is characterized in that, specifically comprise the steps:
(1) starch adhesive processed: the mixing starch getting peanut starch, rice flour composition according to weight proportion 4:1, adds the water grinding machine defibrination of 2-3 times of volume, adjustment starch adhesive concentration is 16-20 Baume;
(2) enzymolysis: regulate pH for 6-7 with sodium carbonate and sodium hydroxide according to the mixture that mol ratio 1:3 forms, and add the polyphenoloxidase of starch weight 0.5% and the trypsinase of 0.4%, starch adhesive is heated to 42 DEG C, enzymolysis time is 5h;
(3) ferment: get the mixing of bacterial classification, carbon source, nitrogenous source, water and medium trace element according to weight proportion and add in the obtained enzymolysis solution of step (2), stir and stack fermentation 18 days;
(4) chelating extracts: in the material after fermentation ends, add the water of 3 times of volumes, stir, first use acetic acid as acidic extraction agent, control temperature is 50 DEG C, extract 12h, regulate pH to be between 6.5-7 with the alkaline extraction agent that sodium carbonate and sodium hydroxide form according to mol ratio 1:3, solution is 75 DEG C by automatic steam control temperature and stirs extraction 7h;
(5) amino acid synergistic liquid processed: solution carries out press filtration by pressure filter, in the filtrate obtained, add the boric acid of 5 parts, be 6-7 with vinegar acid for adjusting pH, evaporation concentration obtains solid substance >=12%, aminoacids content >=8, ammonia volatilization inhibiting rate >=25%, the amino acid synergistic liquid of amino acid deposition rate≤65%;
(6) hydrolyzing seaweed liquid processed: choose fresh marine alga and rub, pull an oar, add the cellulase of 3% and the middle temperature α-amylase of 4%, control temperature is 37 DEG C, regulate hydrolyzed solution pH value to 6-7 with acetic acid, hydrolysis 4h, filter, in filtrate, add 8% water-holding agent be made up of according to weight ratio 3:2:2 cross-linked polysaccharides acetic ester, Artemisinin, Viscogum BE, homogeneous;
(7) synergistic agent processed: the hydrolyzing seaweed liquid in the amino acid synergistic liquid in step (5) and step (6) is mixed according to weight proportion, add water-soluble nutrition antibiotic and the promoter of corresponding weight proportion, stir, the liquid calcium nutrition agent of 2-3% is added in the process stirred, the making method of described liquid calcium nutrition agent is, amino acid is got and calcium lignin sulphonate is dissolved in the water of 3 times of volumes according to weight ratio 5:3, weight ratio 1:2 is by concentration the mixture that the nitrocalcite of 2mol/L and calcium carbonate forms to be dissolved in the above-mentioned aqueous solution, add 1.2 normal atmosphere, control temperature is 95oC, stir 2h.
Specific experiment process is:
Synergistic agent is tested
Test example 1: aminoacids complex fertilizer synergistic agent of the present invention is on the impact of Peanut Root System vigor in seedling stage
Routine control (CK) and aminoacids complex fertilizer synergistic agent (A-1, A-2, A-3) 4 process of the present invention are established in test, and A-1, A-2, A-3 are aminoacids complex fertilizer synergistic agent of the present invention prepared by embodiment 1,2,3 respectively, repeat 6 times.
Test method is as follows:
First quartz sand clear water is cleaned, put into stainless steel pallet, keep certain humidity, Ecological Property of Peanut Seeds is put into dish, cover on it with wet cloth, nursery is carried out under the condition of temperature 25 ± 1 DEG C, grow to when peanut sprouts, during 1.2-1.5cm, peanut is taken out and puts into the cultivation cup filling with quartz sand, water 25mL concentration 0.2 % by weight aminoacids complex fertilizer synergistic agent of the present invention every day, CK waters 25mL water.When flower growth is to about 8-12cm, take out root system, clean with clear water, adopt TTC method, measure the improving activity of root system of peanut.
Its test-results is listed in the table below in 1.
Table 1 Peanut Root System vigor (mg/gh, TTC method)
| Process | Improving activity of root system |
| CK | 1.033 |
| A-1 | 1.486 |
| A-2 | 1.478 |
| A-2 | 1.481 |
Above-mentioned test-results shows, compared with Routine control, aminoacids complex fertilizer synergistic agent of the present invention can significantly improve the improving activity of root system of peanut in seedling stage, and A-1, A-2, A-3 exceed 43.8%, 43.0% and 43.3% than contrast respectively.
Test example 2:
The impact test of the amino acid urea adding aminoacids complex fertilizer synergistic agent of the present invention on soybean yields and yield component establishes CK(not apply fertilizer), common urea (U) and 6, amino acid urea (AU-1, AU-2, AU-3) process that utilizes amino acid fertilizer auxiliary agent of the present invention to produce, nitrogen amount applied is that every post executes purity nitrogen 1g(by 25cm topsoil, is equivalent to 0.053gN/kg soil).
Fertilization mode: to water water-soluble to U and AU-1, AU-2, AU-3 when large bean seedlings grow to 35-45cm respectively afterwards, repeat 2 times, random alignment.Leaving and taking earth pillar upper strata 25cm is clay fertilizer mixolimnion, applies, calcium superphosphate (P for examination fertilizer as base manure
2o
516%) every post executes 12.50g, Repone K (K
2o 60%) every post executes 3g, disposablely when filling post to apply.Each soybean earth pillar all sows 3 soybean seeds.
Table 2: soybean yields, constituent element and Nitrogen apparent recovery fraction
| Process | Output (g/ strain) | 100-grain weight (g) | Nitrogen apparent recovery fraction (%) |
| CK | 18.35 | 13.52 | |
| U | 25.83 | 13.56 | 33.25 |
| A-1 | 27.82 | 13.89 | 42.60 |
| A-2 | 28.01 | 13.88 | 42.18 |
| A-2 | 28.30 | 13.90 | 43.01 |
Above-mentioned test-results: compared with common urea, amino acid synergistic agent urea significantly can increase the 100-grain weight of soybean, increases by 2.6%, 2.7%, 2.8% respectively, and Nitrogen apparent recovery fraction improves more than 26%.As can be seen here, at Dripping simulation test conditions, when nitrogen consumption is identical, compared with common urea process, aminoacids complex fertilizer synergistic agent of the present invention adds in urea and can significantly increase soybean kernel output.
The above is not limitation of the present invention; be noted that for those skilled in the art; under the prerequisite not departing from essential scope of the present invention; can also make some changes, remodeling, interpolation or replacement, these improvements and modifications also should be considered as protection scope of the present invention.
Test example 3:
Nursery: choose healthy sandy loam as nursery soil.Nutrition pot adopts disposal plastic cup, every cup soil 300g, Single fertilizer (CK), singly executes common fertilizer (OF), uses 6g treatment capacity used by the amino acid fertilizer synergistic agent obtained containing specific embodiment 1-3 fertilizer (B-1, B-2, B-3) according to every glass.
Potted plant: by the nursery of above-mentioned nursery process soil plantation potato, nutrient chemical fertilizer fertilizer (urea, calcium superphosphate, Repone K) equivalent polishing everywhere, when potato seedling grows to 4-5 sheet true leaf, the potato seedling in nutrition pot being transplanted to every alms bowl together with nursery soil fills in the large basin alms bowl of 5 kg, 5 process are set altogether, often process repetition 25 times.When transplanting 35 days, find bacterial wilt disease plant, observe plant incidence every day subsequently, record sickness rate.The plant and the soil sample that gather each process take back lab analysis mensuration.
Test-results is as following table 3:
Microorganism in potato rhizosphere soil and sickness rate, prevention effect and output
| Process | Pathogenic bacteria 10 5cfu/g | Bacterium 10 5cfu/g | Actinomycetes 10 5cfu/g | Sickness rate % | Prevention effect % | Output kg/ hectare |
| CK | 13.2±3.20a | 3.12±3.27c | 2±1.34b | 34 | 15853.4±70 | |
| OF | 8.7±1.31b | 5.22±1.26c | 3±3.20b | 18 | 50 | 17853.4±80 |
| B-1 | 1.63±0.35a | 9.68±1.27b | 6±3.22b | 5 | 92.5 | 19853.4±80 |
| B-2 | 1.06±0.65b | 10.21±3.52a | 6±3.06a | 4 | 93.0 | 19863.5±90 |
| B-3 | 1.04±0.48c | 10.34±2.24a | 6±2.53a | 4 | 92.8 | 19923.5±80 |
Test-results is as follows:
Use the sickness rate that microbial organic fertilizer of the present invention significantly can reduce potato bacterial wilt, 92.5%, 93.0%, 92.8% is respectively containing the prevention effect of amino acid synergistic agent B-1, B-2, B-3 process potato in the present invention, sickness rate reduces greatly, and the fertilizer using synergistic agent of the present invention significantly can increase the output (table 3) of potato.The potato yield of Single fertilizer process is 15853.4 ± 70 kg.ha-1, singly executing the potato yield that common fertilizer (OF) processes is 17853.4 ± 80kg.ha-1, using the amino acid fertilizer synergistic agent obtained containing specific embodiment 1-3 is 19853.4 ± 80 kg.ha-1 according to the output that every glass is used the fertilizer (B-1, B-2, B-3) of 6g treatment capacity, 19863.5 ± 90 kg.ha-1,19923.5 ± 80 kg.ha-1, result shows to use microbial organic fertilizer obvious effect of increasing production.
The above is not limitation of the present invention; be noted that for those skilled in the art; under the prerequisite not departing from essential scope of the present invention; can also make some changes, remodeling, interpolation or replacement, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (9)
1. have the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization, it is characterized in that, feed components is composed as follows according to weight part:
Starch 70-85 part, bacterial classification 6-7 part, carbon source 5-10 part, nitrogenous source 3-5 part, water 30-50 part, medium trace element 1.6-1.8 part, hydrolyzing seaweed liquid 6-8 part, water-soluble nutrition antibiotic 3-4 part, promoter 2-4 part.
2. one has the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization according to claim 1, it is characterized in that, be describedly no less than the Lactobacterium acidophilum of 2.0 × 1011cfu, the colloid bacillus cereus being no less than 1.0 × 1011cfu containing effective gemma number and effective gemma number be no less than 2.0 × 10 containing effective gemma number
11the mix bacterium agent of the Bacillus licheniformis composition of cfu.
3. one has the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization according to claim 1, it is characterized in that, the mixture that described carbon source is percentage composition is 30-40% fragrant plant mentioned in ancient texts dish, the stone honey of 15-25%, the sweet potato starch of 50-75% form.
4. one has the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization according to claim 1, it is characterized in that, described nitrogenous source is percentage composition is the mixture that 25-35% dried silkworm chrysalis meal, 15-20% peptone and 55-75% wheat bran form.
5. one has the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization according to claim 1, it is characterized in that, described promoter is consisted of by weight part: the mixture of 3-5 part naphthylacetic acid, 2-4 part vitamins B phosphoric acid ester, 2-4 part Vitamin E acetate, 3-5 part vitamin C phosphoric ester, 5-7 part chitosan.
6. one has the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization according to claim 1, it is characterized in that, the preparation method of described water-soluble nutrition antibiotic comprises the steps:
(1) chitin colloid solution I processed: get glycolic acid, citric acid mixing according to weight proportion 2:3, be made into deionized water the aqueous solution that concentration is 12-15wt%, add chitosan, be heated to 60-65 DEG C and stir;
(2) thick gel II processed: get seaweed gel according to weight ratio 3:4, guar gum coordinates, be made into deionized water the aqueous solution that concentration is 6-8wt%, raised temperature is 40 DEG C-50 DEG C and stirs;
(3) aqueous solution III: Shrubalthea Bark and temperature are that the water of 90 DEG C mixes according to 1:3, lixiviate 3-4h, filtration obtains vat liquor, adds percentage composition than tea saponin, the matrine of 6-8%, the azone of 4-6%, the nicotine of 2-5% for 3-5%, stir in vat liquor;
(4) make water-soluble nutrition antibiotic: mixed by the solution of step (1) and step (2) and step (3), add the deionized water solution that mixture 2 times of volumes contain 30% xanthohumic acid, stir.
7. one has the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization according to claim 1, it is characterized in that, described medium trace element be by percentage composition be the EDTA chelated copper of 0.01-0.03%, the Chelating state element that forms of the EDTA chelated iron of 0.3-0.5%, the EDTA Chelated Manganese of 0.06-0.08%, the EDTA chelated zinc of 0.7-0.9%, the EDTA chelated magnesium of 0.2-0.4%, the EDTA chelating calcium of 0.7-0.9%.
8. there is a making method for the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization, it is characterized in that, specifically comprise the steps:
(1) starch adhesive processed: the mixing starch getting peanut starch, rice flour composition according to weight proportion 4:1, adds the water grinding machine defibrination of 2-3 times of volume, adjustment starch adhesive concentration is 16-20 Baume;
(2) enzymolysis: regulate pH for 6-7 according to the mixture that mol ratio 1:3 forms with sodium carbonate and sodium hydroxide, and add the polyphenoloxidase of starch weight 0.3-0.5% and the trypsinase of 0.2-0.4%, starch adhesive is heated to 38-42 DEG C, and enzymolysis time is 5-6h;
(3) ferment: get the mixing of bacterial classification, carbon source, nitrogenous source, water and medium trace element according to weight proportion and add in the obtained enzymolysis solution of step (2), stir and stack fermentation 15-18 days;
(4) chelating extracts: in the material after fermentation ends, add the water of 3 times of volumes, stir, first use acetic acid as acidic extraction agent, control temperature is 45-50 DEG C, extract 12-14h, regulate pH to be between 6.5-7 with the alkaline extraction agent that sodium carbonate and sodium hydroxide form according to mol ratio 1:3, solution is 65-75 DEG C by automatic steam control temperature and stirs extraction 7-9h;
(5) amino acid synergistic liquid processed: solution carries out press filtration by pressure filter, the boric acid of 2-5 part is added in the filtrate obtained, be 6-7 with vinegar acid for adjusting pH, evaporation concentration obtains solid substance >=12%, aminoacids content >=8, ammonia volatilization inhibiting rate >=25%, the amino acid synergistic liquid of amino acid deposition rate≤65%;
(6) hydrolyzing seaweed liquid processed: choose fresh marine alga and rub, pull an oar, add the cellulase of 1-3% and the middle temperature α-amylase of 2-4%, control temperature is 35-37 DEG C, regulate hydrolyzed solution pH value to 6-7 with acetic acid, hydrolysis 4-5h, filter, in filtrate, add the water-holding agent that 4-8% is made up of according to weight ratio 3:2:2 cross-linked polysaccharides acetic ester, Artemisinin, Viscogum BE, homogeneous;
(7) synergistic agent processed: mixed according to weight proportion by the hydrolyzing seaweed liquid in the amino acid synergistic liquid in step (5) and step (6), adds water-soluble nutrition antibiotic and the promoter of corresponding weight proportion, stirs.
9. a kind of making method with the inhibiting amino acid fertilizer synergistic agent of ammonia volatilization according to claim 8, it is characterized in that, described step (7) adds the liquid calcium nutrition agent of 2-3% in the process stirred, the making method of described liquid calcium nutrition agent is, amino acid is got and calcium lignin sulphonate is dissolved in the water of 3 times of volumes according to weight ratio 5:3, weight ratio 1:2 is by concentration the mixture that the nitrocalcite of 2mol/L and calcium carbonate forms to be dissolved in the above-mentioned aqueous solution, add 1.2 normal atmosphere, control temperature is 95oC, stirs 2h.
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| CN108083893A (en) * | 2017-12-07 | 2018-05-29 | 深圳市芭田生态工程股份有限公司 | Improve the fertilizer synergist and New-type Anti-drought Fertilizer of drought-resistant ability |
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