CN108083893A - Improve the fertilizer synergist and New-type Anti-drought Fertilizer of drought-resistant ability - Google Patents
Improve the fertilizer synergist and New-type Anti-drought Fertilizer of drought-resistant ability Download PDFInfo
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- CN108083893A CN108083893A CN201711285723.0A CN201711285723A CN108083893A CN 108083893 A CN108083893 A CN 108083893A CN 201711285723 A CN201711285723 A CN 201711285723A CN 108083893 A CN108083893 A CN 108083893A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C11/00—Other nitrogenous fertilisers
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
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Abstract
The invention discloses a kind of fertilizer synergists for improving drought-resistant ability, are made of 45%~60% fulvic acid, 10%~25% microelement chelate, 10%~20% proline and 15%~25% marine algae extract.The present invention also proposes a kind of New-type Anti-drought Fertilizer of the fertilizer synergist comprising above-mentioned raising drought-resistant ability.The fertilizer synergist of the raising drought-resistant ability of the present invention, it is intended to which on the one hand bioenergizer and various active ingredients by external source improve soil activation, enhance the activity of Soil Microorganism and enzyme, promote plant root growth, in external increase plant drought ability;Another aspect stimulates in crop body and the activation of water resistant stress factors such as amino acid, carbohydrate etc., common to cooperate to improve the drought-resistant ability of plant in itself.
Description
Technical field
The present invention relates to fertilizer additive technical field more particularly to a kind of fertilizer synergist for improving drought-resistant ability and resist
Non-irrigated fertilizer.
Background technology
China's gross amount of water resources occupies the world the 6th, but water occupancy volume is only 2400 cubic metres per capita, is that the world is per capita
The 1/4 of amount.China is faced with more serious water shortage problem, and agricultural water accounts for 70% of total water consumption or so, the serious system of arid
The raising of Yue Zhe China crop yield.Research shows that under drought condition osmotic adjustment is such as soluble in plant
The substances such as sugar, inorganic ions, free amino acid etc., some Protective enzymes, endogenous hormones have different degrees of increase, directly
Or plant is played regulatory role indirectly, to enhance the drought resistance of wheat.Accordingly, it is capable to no pass through seed soaking or blade face using these substances
It sprays and other external method of administration is to improve the drought resistance of plant, the lower crop yield of the stress that moisturizes is always people's concern
Focus.
Drought resisting ingredient also has application in production in fertilizer adding technique at present, more typically using with strong absorptive
High molecular polymer added as water-retaining agent in fertilizer, order of soaking seed or dress seed for crop promotes drought resisting effect, but only
It can work in crops seedling stage;Also have using antitranspirant, by with foliar fertilizer add after crop foliage-spray, make
For pharmacy effect in stomata, to reduce moisture loss, but drought resistance is unstable, and also leaf photosynthesis can be impacted.In recent years
Come, although also occurring that seedling stage processing can be used in the market, can be used for the drought resistance agent type that Adult plant sprays, it is this kind of to add
It is mostly that a variety of chemical compositions compound to add agent, and complicated component needs to be inquired into the security of crop, and application cost compared with
It is high.Therefore the drought resisting effect of existing drought resisting additive is very limited, and effect is single, can not improve the nutrition condition of plant.
The content of the invention
It is a primary object of the present invention to provide a kind of fertilizer synergist for improving drought-resistant ability, it is intended to by changing arid
Under the conditions of root growth the outer nutrient environment of soil, activate with water resistant stress factors with reference to stimulating in crop body, collaboration, which is promoted, plants
The strain drought-resistant ability of itself.
To achieve the above object, the fertilizer synergist of raising drought-resistant ability of the invention, by 45%~60% fulvic acid,
10%~25% microelement chelate, 10%~20% proline and 15%~25% marine algae extract composition.
On the basis of the fertilizer synergist of above-mentioned raising drought-resistant ability, the present invention further also proposes that more than one are stated and carries
The fertilizer synergist of high drought-resistant ability is the New-type Anti-drought Fertilizer of functional additive.
Drought-resistant and synergistic agent using the present invention, the additive as a large amount of fertilizer, which supplements, to be used, and makes an addition to a great number of elements
When in base fertilizer, it is intended to which on the one hand bioenergizer and various active ingredients by external source improve soil activation, enhancing soil
The activity of microorganism and enzyme in earth promotes plant root growth, in external increase plant drought ability;On the other hand crop is stimulated
Internal and water resistant stress factors such as amino acid, carbohydrate etc. activation;Between each functional component on the different Coping style of each leisure
It plays a role, while can also be conducive to repair the cell damage of crop under drought environment by directly or indirectly biostimulation
Wound, it is common to cooperate to improve the drought-resistant ability of plant in itself.
Specific embodiment
The realization, the function and the advantages of the object of the present invention will be described further in conjunction with the embodiments.It should be appreciated that this
Locate described specific embodiment to be only used to explain the present invention, be not intended to limit the present invention.
The present invention provide it is a kind of improve drought-resistant ability fertilizer synergist, synergist by 45%~60% fulvic acid,
10%~25% microelement chelate, 10%~20% proline and 15%~25% marine algae extract composition.
In four kinds of functional components of the drought-resistant and synergistic agent of above-mentioned fertilizer, fulvic acid is biochemical fulvic acid powder;As fertilizer
Itself it is on the one hand exogenous estrogen in a kind of similar plants body after synergistic component addition, the work for promoting polysaccharase can be stimulated
Property, make young cell membrane pectic substance enzyme hydrolysis, softening of the cell wall so that cell is easy to elongation division, may finally make crop
Secondary root increases, root amount increases, root elongation, improves the absorption of the moisture and nutrient ability under drought environment.Second party
Face fulvic acid promotes the absorption and transhipment of plant centering trace element, and this some in trace element such as Fe, Cu, Zn, Mn, B, Mo
Deng being all the component that participates in the synthesis of crop anti-adversity enzyme, the effect of this aspect can be by promoting crop in arid item
Resistance functional enzyme under part is metabolized to promote the drought-resistant ability of crop;Also, it synthesizes and expresses in fulvic acid promotion
In enzyme, this some enzyme such as SOD (superoxide dismutase), CAT (catalase), POD (peroxidase) can be removed
The activity of oxygen radical substance, reduce drought environment in this some active oxygen to the extent of the destruction of cell membrane lipid and membrane damage journey
Degree makes the vital movement of crop is few to be able to more normally carry out by drought impact.Third aspect fulvic acid can be used as external source
Sexual stimulus object promotes the expression quantity of the expression, especially abscisic acid (ABA) of crop hormone in vivo;Abscisic acid is a kind of crop in itself
Growth inhibitor, great expression can reduce stomatal aperture, reduce that moisture content is rising, promote the product of the Osmoprotectants such as proline
It is tired, plant is made to keep more moisture content;This effect promotes root system development with fulvic acid itself, improves root activity, and crop is made to exist
More moisture content can be absorbed under drought condition and nutriment is combined, there is the effect increased income and decreased expenditure and complemented each other, so that crop exists
There can be higher resistance under drought condition.
Proline is as additive component, its own is the most strong amino acid of hydratability, as exogenous amino acid
After addition is absorbed by crops, on the one hand its extremely strong hydrophily binding ability, can stablize the metabolism in plasm colloid and tissue
Process, thus solidification point can be reduced, it prevents cell dehydration, moisture is reduced so as to the preservation of the moisture beneficial to crop
It scatters and disappears;On the other hand, itself it is to play osmotic adjustment as osmoticum in crop body, as the plant under drought condition
The storage form of object nitrogen source is used for participating in the synthesis of chlorophyll after plant drouhgt stress releasing.Meanwhile proline hydrophilic group with
Protein hydrophilic group interaction make protein stability improve so that severe water stress under crop root nodule metabolic enzyme and structure
The proline that protein may be accumulated is protected, and mitigates the extent of injury of the severe drought to tissue.
With reference under drought stress environment, after crop metabolism and above two functional component, mended in further synergist
Filled with microelement chelate, micro- function is above-mentioned to be had been described above, and is all the group for participating in the synthesis of crop anti-adversity enzyme
Into part;Herein as collaboration collocation addition, can under the function of fulvic acid and the exogenous bioenergizer of proline,
It is rapidly absorbed by crops and transports, promote the activity and expression quantity of resistance enzyme of the crop under drought environment, so as to whole
Enhance the crop anti-adversity under drought environment.Certainly, trace element can be included as in Fe, Cu, Zn, Mn, B, Mo, Ni etc.
It is a variety of.
Wherein in order to promote its crop anti-adversity effect under drought condition, microelement chelate uses in the present invention
Chelating agent to trace element is small molecule chelators, this kind of small molecule chelators is such as:Oxalic acid, histidine, malic acid,
The compound of this small molecule such as citric acid, glutathione or the complexones of small molecule, Aminodithioformate and
Xanthates, such as EDTA, sodium dimethyl dithiocarbamate.These small molecule chelators are in use, due to its small point
The ability that minor structure is freely transported in crop lays the foundation for the absorption and efficient transhipment of element, and promotion makees object for this
The transport of across root cells plasma membrane, xylem long-distance transportation, leaf cell plasma membrane and the vacuole of the trace element of a little enzyme activity important compositions
Film transports, and root absorption trace element is transported to aerial part and is present in epidermal cell in the form of chelate or mesophyll is thin
Born of the same parents, vacuole are attached on cell membrane.Therefore after being absorbed by crops, trace element region in the cell can on the one hand be promoted
Distribution equilibrium, reduce cell matrix matrix Trace Element Imbalance under drought stress situation;On the other hand, by transport
The activation of ability, so that the ability to express of crop anti-adversity enzyme and active General Promotion.
Marine algae extract in last synergistic component, be will seaweed products carry out after Cell wall digestion the intracellular extracted into
Point, it is the biostimulant for belonging to extraction rich in substances such as alginic acid, mannitol, organized enzymes, there is similar cell mitogen
With the activity of similar auxin;Comparison of ingredients is complicated, and the bio-stimulant that these and other in effect include hormone material can
Can adjust crop to switch system of defense in time to tackle adverse circumstances, plant growth and the activation abiotic side of body of crop can be induced
Urgent mechanism, so as to improve the defence capability of crop and osmotic protection function and water resistant stress ability.
And further marine algae extract can directly buy acquisition, certainly due to extraction seaweed raw material classification and method mistake
Cheng Butong, the product quality of final marine algae extract accordingly can also have any different;It is promoted based on the present invention as fertilizer synergist
Crop resists the conception of drought environment, and in order to which guaranteed quality is stablized, technical staff may be employed following process and obtain in implementing:
S10 will be crushed after fresh seaweed cleaning, drying;
Seaweed after crushing in the sodium bicarbonate solution of 5wt% is impregnated 30~50min, then adds in complex enzyme by S20
It is digested, hydrolysis temperature is 30~40 DEG C, pH is 5.0~7.5;
During the step is implemented complex enzyme be cellulase, zytase, the mixture of pectase and papain, mesh
Be digest the cellulose of alginic cell wall, pectin, memebrane protein etc. a variety of enzymes of ingredient compound, common cooperation makes digestion
Completely, recovery rate is promoted.
S30, rise temperature makes complex enzyme deactivation after enzymolysis, then filters, and is that seaweed carries by filtrate spray drying
Take object.
Contain polysaccharide, alginic acid, the seaweed compounded amino in seaweed in the extract obtained essentially as described above
A large amount of beneficiating ingredients such as acid, protein, vitamin, and amino-oligosaccharide is to nutrition under the resistance and drought condition of crop
It is unbalance etc. to have good action.
The fertilizer synergist of the raising drought-resistant ability of the present invention, the additive as a large amount of fertilizer, which supplements, to be used, and is made an addition to
When in the base fertilizer of a great number of elements, it is intended to which on the one hand bioenergizer and various active ingredients by external source improve soil
Activity enhances the activity of Soil Microorganism and enzyme, promotes plant root growth, in external increase plant drought ability;It is another
Aspect stimulates in crop body and the activation of water resistant stress factors such as amino acid, carbohydrate etc.;It is each comfortable different between each functional component
Coping style on play a role, while can also be conducive to through directly or indirectly biostimulation, repair under drought environment
The cellular damage of crop, it is common to cooperate to improve the drought-resistant ability of plant in itself.
On the basis of the fertilizer synergist of above-mentioned raising drought-resistant ability, the present invention further also proposes that more than one are stated and carries
The fertilizer synergist of high drought-resistant ability is the New-type Anti-drought Fertilizer of functional additive, and synergist is according to usual weight of fertilizer in implementation
0.2~2% addition.Further for the cooperation convenient for additive and fertilizer, more than improve the fertilizer synergistic of drought-resistant ability
Agent ingredient is all prepared using powdered components, for example fulvic acid choice of powder shape biochemical fulvic acid carries out.In implementation, will now it improve anti-
The fertilizer synergist ingredient of non-irrigated ability is mixed according to the above mentioned proportion, is re-used as functional additive afterwards and is added in fertilizer.
Fertilizer using the present invention on the basis of a large amount of nutritious fertilizers, adds the fertilizer of above-mentioned raising drought-resistant ability
On the one hand synergist, bioenergizer and various active ingredients by external source improve soil activation, enhance Soil Microorganism
With the activity of enzyme, promote plant root growth, in external increase plant drought ability;Another aspect stimulates in crop body and water resistant
The activation of stress factors such as amino acid, carbohydrate etc.;It plays a role between each functional component on the different Coping style of each leisure, together
When can also be conducive to through directly or indirectly biostimulation, repair the cellular damage of crop under drought environment, it is common to cooperate
To improve the drought-resistant ability of plant in itself.
Details to make the fertilizer synergist of the above-mentioned raising drought-resistant ability of the present invention is more conducive to the reason of those skilled in the art
Solution and the progressive effect for implementing and protruding this case fertilizer, carry out the above to this case below by way of specific embodiment
It is illustrated.
Embodiment 1
S10, according to fulvic acid 40%, microelement chelate 20% (trace element include equal proportion add Fe,
Cu, Zn, Mn, B, to trace element cheland use), proline 20%, marine algae extract 20% ratio, after mixing
The as fertilizer synergist of the raising drought-resistant ability of the present embodiment 1;Wherein, all directly commercially available purchase of more than raw material obtains.
For verification the verifying results, above-mentioned synergist is mixed with macroelement fertilizer ingredient by S20, and the drought resisting of the present invention is made
After fertilizer, for planting experiment:Brassica rapa L is planted using pot experiment, sets 6 processing altogether, each handles 5 repetitions, amounts to 30
Basin sows 3 plants per basin, is colonized 1 plant.The soil moisture that simulating drought soil control basin is plucked in plantation, after plantation is completed, statistics
Wilting degree, wilted percent, wilting rank and the yield of plant.
Embodiment 2
S10, according to fulvic acid 45%, microelement chelate 15% (trace element include equal proportion add Fe,
Cu, Zn, Mn, B, Mo, Ni, to trace element cheland using sodium dimethyl dithiocarbamate, oxalic acid, histidine,
Malic acid these types), proline 20%, the ratio of marine algae extract 20%, mixing after be the present embodiment 2 raising drought resisting
The fertilizer synergist of ability;Wherein, all directly commercially available purchase of more than raw material obtains
S20, further for verification the verifying results, according to the same manner as in Example 1, by above-mentioned synergist and a great number of elements
Fertilizer component mixes, after the New-type Anti-drought Fertilizer of the present invention is made, for planting experiment:Brassica rapa L is planted using pot experiment, sets 6 altogether
A processing each handles 5 repetitions, amounts to 30 basins, and 3 plants are sowed per basin, is colonized 1 plant.Simulating drought soil controls basin in plantation
The soil moisture plucked after plantation is completed, counts wilting degree, wilted percent, wilting rank and the yield of plant.
Embodiment 3
S10, selects good kelp, agar, fragrant plant mentioned in ancient texts, seaweed 1Kg, add in 7L water impregnate 3 it is small when after, washing of stirring,
Draining;And wash 4 extremely cleanings repeatedly again by this method, and it is fine crushing to 2~5mm after dry, it is transferred in digestion vessel;
S20 is added in the sodium bicarbonate solution of 100mL 5wt% into digestion vessel after impregnating 30~50min, is added in fine
The mixed enzyme solution of plain enzyme, zytase, pectase and papain is tieed up, stirring stops after carrying out enzymolysis 3h, will digest slurries
Carrying out usual heating treatment makes compound enzyme-deactivating;Then, slurries are centrifuged, discard insoluble precipitation, take the supernatant to be
Enzymolysis liquid, then spray drying is marine algae extract manufactured in the present embodiment;
S30, according to fulvic acid 50%, microelement chelate 10% (trace element include equal proportion add Fe,
Zn, B, Mo, Ni, to trace element cheland using EDTA, dimethyl disulfide for sodium formate, histidine these types), dried meat ammonia
Acid 20%, the ratio of marine algae extract 20% are the fertilizer synergist of the raising drought-resistant ability of the present embodiment 3 after mixing;.
S40, further for verification the verifying results, according to the same manner as in Example 1, by above-mentioned synergist and a great number of elements
Fertilizer component mixes, after the New-type Anti-drought Fertilizer of the present invention is made, for planting experiment:Brassica rapa L is planted using pot experiment, sets 6 altogether
A processing each handles 5 repetitions, amounts to 30 basins, and 3 plants are sowed per basin, is colonized 1 plant.Simulating drought soil controls basin in plantation
The soil moisture plucked after plantation is completed, counts wilting degree, wilted percent, wilting rank and the yield of plant.
For prominent and verification synergist effect, compareed using the macroelement fertilizer for not adding synergist as CK
Carry out planting experiment comparison, whole result such as following table:
Wilting degree | Wilted percent | Wilting rank | Yield (g) | |
CK | 60 | 1 | 3.2 | 24.38 |
Embodiment 1 | 36 | 0.6 | 0.6 | 35.96 |
Embodiment 2 | 8 | 0.4 | 0.4 | 33.7 |
Embodiment 3 | 4 | 0.2 | 0.2 | 29.66 |
Wherein, the calculation of wilting degree/wilted percent/wilting rank in above table is:Under drought stress conditions,
According to the symptom that each plant shows, stress level classification is carried out with reference to standard once, and the 0th, 7,10 day after stress is to each
Processing plant withered here rate, wither and here spend statistics:It withers here to spend and is classified as 0, health;1, here withering occur in a small number of blades;2, half leaf
Here withering occurs in piece;3, here withering occur in blades more than half;4, here whole strain withers.
Wither here rate (%)=(occur here wither symptom strain number/processing strain number) × 100%;
It withers and here spends=[(here wither value of series × strain number) × 100]/(here wither highest value of series × total strain number).
After the New-type Anti-drought Fertilizer that can be seen that using the present invention from the result of the test planted above, plant wilting rank declines
Reach 80%~90%, yield increases by 20%~45%, and drought resisting effect is apparent.Each leisure is different between illustrating each functional component
It plays a role on Coping style, improves soil activation and stimulate in crop body telling on jointly with water resistant stress factors, can have
There is the drought resisting value that comparison is actual.
It these are only the preferred embodiment of the present invention, be not intended to limit the scope of the invention, it is every to utilize this hair
The equivalent structure or equivalent flow shift that bright description is made directly or indirectly is used in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (8)
1. a kind of fertilizer synergist for improving drought-resistant ability, which is characterized in that by 45%~60% fulvic acid, 10%~25%
Microelement chelate, 10%~20% proline and 15%~25% marine algae extract composition.
2. the fertilizer synergist of drought-resistant ability is improved as described in claim 1, which is characterized in that the microelement chelate
In trace element at least one of for Fe, Cu, Zn, Mn, B, Mo, Ni.
3. the fertilizer synergist of drought-resistant ability is improved as claimed in claim 1 or 2, which is characterized in that the trace element chela
Cheland micro- in object is closed as oxalic acid, histidine, malic acid, citric acid, glutathione, complexones, amino
At least one of dithio formate and xanthates.
4. the fertilizer synergist of drought-resistant ability is improved as claimed in claim 3, which is characterized in that the complexones is
EDTA。
5. the fertilizer synergist of the raising drought-resistant ability as described in right will require 3, which is characterized in that the two thio first of amino
Hydrochlorate is sodium dimethyl dithiocarbamate.
6. the fertilizer synergist of drought-resistant ability is improved as claimed in claim 1 or 2, which is characterized in that the marine algae extract
Acquisition is made by the steps:
Fresh seaweed is started the cleaning processing, then dry, crushing;
Seaweed after crushing in the sodium bicarbonate solution of 5wt% is impregnated into 30~50min, complex enzyme is then added in and is digested
Afterwards, filter to take filtrate and carry out spray drying acquisition;Wherein, complex enzyme includes cellulase, zytase, pectin in enzymolysis process
Enzyme and papain, temperature is 30~40 DEG C in enzymolysis process, pH is 5.0~7.5.
7. a kind of New-type Anti-drought Fertilizer, which is characterized in that the fertilizer of drought-resistant ability is improved including claim 1 to 6 any one of them
Synergist.
8. New-type Anti-drought Fertilizer as claimed in claim 7, which is characterized in that the fertilizer synergist for improving drought-resistant ability accounts for fertilizer
The 0.2~2% of weight.
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CN114395607B (en) * | 2022-03-28 | 2022-07-12 | 卡力(烟台)农业发展有限公司 | Seaweed oligopeptide powder and preparation method thereof |
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