CN105272741A - Biological organic pesticide-containing fertilizer and preparation method thereof - Google Patents
Biological organic pesticide-containing fertilizer and preparation method thereof Download PDFInfo
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- CN105272741A CN105272741A CN201510701684.2A CN201510701684A CN105272741A CN 105272741 A CN105272741 A CN 105272741A CN 201510701684 A CN201510701684 A CN 201510701684A CN 105272741 A CN105272741 A CN 105272741A
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Abstract
The invention discloses a biological organic pesticide-containing fertilizer and a preparation method thereof and belongs to the technical field of preparation of biological organic pesticide-containing fertilizers. The biological organic pesticide-containing fertilizer comprises raw materials as follows: 40-90 parts of leaves of weeping willows, 50-90 parts of piper methysticum forst, 60-90 parts of leaves of tea trees, 25-40 parts of waste residues, 15-30 parts of earthworm powder, 4-8 parts of biological bacteria, 2-6 parts of microelements, 1-3 parts of a water-retaining agent, 1-3 parts of a wetting dispersant and 1-3 parts of a penetrant. The biological organic pesticide-containing fertilizer is prepared in steps of crushing, fermentation, concentration, drying and the like, can effectively prevent diseases and pests and can also balance nutrition, promote quick and healthy growth of crops and increase the yield of the crops, is ecological and environment-friendly, improves soil environment and is free from pollution to the environment.
Description
[technical field]
The invention belongs to fertilizer preparing technical field, be specifically related to a kind of bioorganic pesticide fertilizer and preparation method thereof.
[background technology]
China is a large agricultural country, and agricultural chemicals and chemical fertilizer play very important effect in agriculture production, and along with the raising of people's living standard and health perception, people pay much attention to the security of agricultural-food, increase year by year demand that is nuisanceless, green food.
Current cultural control disease and pest and farm crop institute are to fertilize, mainly use chemicals and toxic pesticides through mix and blend, to be manured into soil or on farm crop, the agricultural chemicals that life-time service is a large amount of year in year out and chemical fertilizer, cause insect to produce resistance, soil compaction, water source soil and farm crop are polluted, agricultural product quality declines, and pesticide residue exceed standard, and have a strong impact on physical and mental health and the competitive power of agricultural products in China in world market of people.Therefore the bioorganic pesticide fertilizer developing a kind of Biocidal type is development trend.
[summary of the invention]
The invention provides a kind of bioorganic pesticide fertilizer and preparation method thereof, use a large amount of agricultural chemicals and chemical fertilizer to cause insect to produce resistance, soil compaction to solve, water source soil and farm crop contaminated, agricultural product quality declines, and pesticide residue exceed standard serious and cause the problems such as food safety.Bioorganic pesticide fertilizer of the present invention can not only preventing disease and pest effectively, and can be balanced nutritious, promotes that farm crop grow up healthy and sound fast, improves crop yield.
For solving above technical problem, the present invention by the following technical solutions:
A kind of bioorganic pesticide fertilizer, in units of weight part, comprise following raw material: weeping willow leaf 40-90 part, piper methysticum 50-90 part, leaf of tea tree 60-90 part, waste residue 25-40 part, earthworm powder 15-30 part, biological bacteria 4-8 part, micro-2-6 part, water-holding agent 1-3 part, wetting dispersing agent 1-3 part, permeate agent 1-3 part.
Preferably, described bioorganic pesticide fertilizer, in units of weight part, comprise following raw material: weeping willow leaf 50-90 part, piper methysticum 60-90 part, leaf of tea tree 70-90 part, waste residue 30-40 part, earthworm powder 20-30 part, biological bacteria 5-7 part, micro-3-5 part, water-holding agent 2-3 part, wetting dispersing agent 2-3 part, permeate agent 2-3 part.
Preferably, described bioorganic pesticide fertilizer, in units of weight part, comprise following raw material: 70 parts, weeping willow leaf, piper methysticum 75 parts, leaf of tea tree 80 parts, 32 parts, waste residue, earthworm powder 22 parts, biological bacteria 6 parts, trace element 4 parts, water-holding agent 2 parts, wetting dispersing agent 2 parts, permeate agent 2 parts.
Preferably, described waste residue comprises one or more in marc, bagasse, edible fungi residues, sugared slag, acid-sludge, fecula, manioc waste, citric acid waste, soy sauce residues, residue of monosodium glutamate, residue from beans after making.
Preferably, described biological bacteria comprises one or more in vinelandii, genus bacillus, enzymatic microorganism, yeast, actinomycetes, root nodule bacterium, phosphorus bacteria, B. mucilaginocus, phosphate solubilizing bacteria.
Preferably, described trace element comprises one or more in iron, boron, manganese, copper, zinc, molybdenum.
Preferably, described water-holding agent comprises one or more in polyacrylamide, sodium polyacrylate, polyacrylic acid potassium, ammonium polyacrylate, starch graft acrylic acid sodium.
Preferably, described wetting dispersing agent comprises one or more in calcium lignin sulphonate, N-sodium lauroyl glutamate, sodium laurylsulfate.
Preferably, described permeate agent comprises one or more in soap powder, sodium lignosulfonate, alkyl sodium sulfonate, sodium alkyl benzene sulfonate, alkyl sulfuric ester sodium.
The present invention also provides a kind of preparation method of bioorganic pesticide fertilizer, comprises the following steps:
S1: by weeping willow leaf, piper methysticum, leaf of tea tree co-grinding, obtains mixture A after crossing 100-200 mesh sieve, adds waste residue, earthworm powder, biological bacteria, ferment at 60-80 DEG C in mixture A, ferments after 10-20 days and obtains fermented liquid;
S2: fermented liquid obtained for step S1 is left standstill and abandons precipitation, and remaining ferment liquid is concentrated at 50-60 DEG C, obtain enriched material, described enriched material is dried to water content≤6% at 90-105 DEG C, obtained mixture B;
S3: the mixture B that step S2 is obtained pulverizes, mixes with trace element, water-holding agent, wetting dispersing agent, permeate agent after crossing 100-300 mesh sieve, obtained bioorganic pesticide fertilizer.
Weeping willow leaf has the effect such as clearing heat and detoxicating, expelling wind and removing dampness, antisepsis and anti-inflammation, maggot of going out, infanticide Jue.
Piper methysticum contains multiple Ginkgolide Component, has the multiple physiological and pharmacological effects such as spasmolytic, anti-top epilepsy, toponarcosis, anti-inflammatory, Antifungi, desinsection, has stronger restraining effect to dysentery bacterium, Corynebacterium diphtheriae and intestinal bacteria.
The extract of leaf of tea tree has potent germicidal action, and tea tree can effectively tackle for various fungal infection, can kill streptococcus aureus, diphtheria corynebacterium.
Containing numerous nutritive ingredients in waste residue, the nutrition of demand of plant growth can be provided as bioorganic pesticide fertilizer, Promoting plant growth.
Earthworm strong adaptability, growth and breeding are fast, output is high, low price, earthworm powder contains all amino acid, and content is high, and phosphorus, calcium, mineral substance, vitamin contents are also very abundant, amino acid can promote root growth, strong sprout, healthy tree, the photosynthetic function of enhancing blade and the degeneration-resistant of crop.
The bioorganic pesticide fertilizer that biological bacteria is made has the function of volume increase, oil recovery enhancement, also has and significantly reduces nitrate in plant materials, nitrite and heavy metal content, improves the effect such as chemical fertilizer utilization ratio and fertilizing soil.
Boron compares and concentrates in stem apex, the tip of a root, blade and floral organ in plant materials, and the content in dicotyledons is usually higher than monocotyledons.Boron can improve the nitrogenase activity of leguminous crop root nodule bacterium, and increase amount of nitrogen fixation, during boron deficiency, root stays undeveloped, affects amount of nitrogen fixation.Boron can also strengthen crop anti-adversity.
Iron is that chlorophyll formation is indispensable, and in plant body, be difficult to transfer, so blade " chlorosis " is the performance of plant iron deficiency, and first this chlorosis shows on young leaflet tablet.
Copper participates in the resistance of the photosynthesis of plant, respiration, nitrogen metabolism, enhancing plant.During scarce copper, plant strain growth is thin and weak, and young leaves turns to be yellow, and wilting withered, blade tip is curling to turn white, and has necrotic spot.
Zinc can promote that crop carries out photosynthesis, and it is the moiety of multiple enzyme, and during scarce zinc, stagnating appears in crop growth.
Containing manganese in plant chloroplast, manganese can promote seed germination and seedling growth in period, affects the accumulation in vivo of the photosynthesis of crop, respiration, nitric nitrogen during manganese deficiency.Show as chlorosis yellow between blade arteries and veins, have brown spot.
Molybdenum is nitrogen-fixing microorganism, necessary when particularly fixing air nitrogen with the root nodule bacterium of leguminous crop symbiosis, can promote leaf photosynthesis intensity again simultaneously, and when lacking molybdenum, plant is short and small, and chlorosis between blade arteries and veins, leaf margin is dried-up, inwardly curling, becomes wilting state.
Water-holding agent can strengthen soil water-retaining performance, improvement Soil structure, the deep percolation reducing water and loss of soil nutrient, raising efficiency of water application.
Dispersion agent can reduce the viscosity of bioorganic pesticide fertilizer particle and high molecular polymer, and bioorganic pesticide fertilizer particle can be made to be quickly dispersed in water, and high molecular polymer also can be made to play its dispersiveness simultaneously.
Permeate agent has fixing hydrophilic and oleophilic group, aligns in the surface energy of solution, and can make the material that surface tension significantly declines, and has the effect making fertilizer efficiency and drug effect synergy simultaneously.
The present invention has following beneficial effect:
(1) bioorganic pesticide fertilizer of the present invention uses water-holding agent, can strengthen soil water-retaining performance, improvement Soil structure, the deep percolation reducing water and loss of soil nutrient, raising efficiency of water application;
(2) bioorganic pesticide fertilizer of the present invention uses dispersion agent, can reduce the viscosity of bioorganic pesticide fertilizer particle and high molecular polymer, bioorganic pesticide fertilizer particle can be made to be quickly dispersed in water, be conducive to plant absorption;
(3) bioorganic pesticide fertilizer of the present invention uses permeate agent to have the effect making fertilizer efficiency and drug effect synergy;
(4) bioorganic pesticide fertilizer of the present invention can not only preventing disease and pest effectively, and can be balanced nutritious, promotes that farm crop grow up healthy and sound fast, improves crop yield;
(5) bioorganic pesticide fertilizer ecological, environmental protective of the present invention, improves edatope, environmentally safe;
(6) bioorganic pesticide fertilizer preparation method of the present invention is simple to operate, and preparation cost is low, is conducive to applying.
[embodiment]
Be specifically described below in conjunction with specific embodiment.
Embodiment 1
A kind of bioorganic pesticide fertilizer, in units of weight part, comprise following raw material: 90 parts, weeping willow leaf, piper methysticum 90 parts, leaf of tea tree 90 parts, marc 8 parts, bagasse 8 parts, edible fungi residues 8 parts, sugar slag 8 parts, acid-sludge 8 parts, earthworm powder 30 parts, genus bacillus 2 parts, enzymatic microorganism 2 parts, 2 parts, yeast, 2 parts, actinomycetes, ferro element 2 parts, boron 2 parts, manganese element 2 parts, sodium polyacrylate ammonium polyacrylate 1 part, polyacrylic acid potassium ammonium polyacrylate 1 part, ammonium polyacrylate 1 part, calcium lignin sulphonate 1 part, N-sodium lauroyl glutamate 1 part, sodium laurylsulfate 1 part, sodium lignosulfonate 1 part, alkyl sodium sulfonate 1 part, sodium alkyl benzene sulfonate 1 part.
The preparation method of described bioorganic pesticide fertilizer, comprises the following steps:
S1: by weeping willow leaf, piper methysticum, leaf of tea tree co-grinding, obtains mixture A after crossing 200 mesh sieve, adds waste residue, earthworm powder, biological bacteria, ferment at 80 DEG C in mixture A, ferments after 10 days and obtains fermented liquid;
S2: fermented liquid obtained for step S1 is left standstill and abandons precipitation, and remaining ferment liquid is concentrated at 60 DEG C, and obtain enriched material, described enriched material being dried at 105 DEG C water content is 4%, obtained mixture B;
S3: the mixture B that step S2 is obtained pulverizes, mixes with trace element, water-holding agent, wetting dispersing agent, permeate agent after crossing 300 mesh sieve, obtained bioorganic pesticide fertilizer.
Embodiment 2
A kind of bioorganic pesticide fertilizer; in units of weight part, comprise following raw material: 70 parts, weeping willow leaf, piper methysticum 75 parts, leaf of tea tree 80 parts, fecula 6 parts, manioc waste 6 parts, citric acid waste 5 parts, soy sauce residues 5 parts, residue of monosodium glutamate 5 parts, earthworm powder 22 parts, 2 parts, actinomycetes, root nodule bacterium 2 parts, phosphorus bacteria 2 parts, copper 2 parts, zinc element 2 parts, ammonium polyacrylate 1 part, 1 part, starch graft acrylic acid sodium, N-sodium lauroyl glutamate 1 part, sodium laurylsulfate 1 part, sodium alkyl benzene sulfonate 1 part, 1 part, alkyl sulfuric ester sodium.
The preparation method of described bioorganic pesticide fertilizer, comprises the following steps:
S1: by weeping willow leaf, piper methysticum, leaf of tea tree co-grinding, obtains mixture A after crossing 200 mesh sieve, adds waste residue, earthworm powder, biological bacteria, ferment at 70 DEG C in mixture A, ferments after 15 days and obtains fermented liquid;
S2: fermented liquid obtained for step S1 is left standstill and abandons precipitation, and remaining ferment liquid is concentrated at 55 DEG C, and obtain enriched material, described enriched material being dried at 100 DEG C water content is 5%, obtained mixture B;
S3: the mixture B that step S2 is obtained pulverizes, mixes with trace element, water-holding agent, wetting dispersing agent, permeate agent after crossing 200 mesh sieve, obtained bioorganic pesticide fertilizer.
Embodiment 3
A kind of bioorganic pesticide fertilizer; in units of weight part, comprise following raw material: 50 parts, weeping willow leaf, piper methysticum 60 parts, leaf of tea tree 70 parts, residue of monosodium glutamate 15 parts, residue from beans after making 15 parts, earthworm powder 20 parts, genus bacillus 1 part, root nodule bacterium 1 part, phosphorus bacteria 1 part, B. mucilaginocus 1 part, phosphate solubilizing bacteria 1 part, copper 1 part, zinc element 1 part, molybdenum element 1 part, polyacrylic acid potassium 1 part, ammonium polyacrylate 1 part, calcium lignin sulphonate 1 part, N-sodium lauroyl glutamate 1 part, sodium lignosulfonate 1 part, alkyl sodium sulfonate 1 part.
The preparation method of described bioorganic pesticide fertilizer, comprises the following steps:
S1: by weeping willow leaf, piper methysticum, leaf of tea tree co-grinding, obtains mixture A after crossing 100 mesh sieve, adds waste residue, earthworm powder, biological bacteria, ferment at 80 DEG C in mixture A, ferments after 10 days and obtains fermented liquid;
S2: fermented liquid obtained for step S1 is left standstill and abandons precipitation, and remaining ferment liquid is concentrated at 50 DEG C, and obtain enriched material, described enriched material being dried at 105 DEG C water content is 6%, obtained mixture B;
S3: the mixture B that step S2 is obtained pulverizes, mixes with trace element, water-holding agent, wetting dispersing agent, permeate agent after crossing 100 mesh sieve, obtained bioorganic pesticide fertilizer.
Embodiment 4
A kind of bioorganic pesticide fertilizer; in units of weight part, comprise following raw material: 90 parts, weeping willow leaf, piper methysticum 90 parts, leaf of tea tree 90 parts, edible fungi residues 15 parts, sugared slag 15 parts, acid-sludge 10 parts, earthworm powder 30 parts, 2 parts, vinelandii, genus bacillus 2 parts, phosphorus bacteria 1 part, B. mucilaginocus 1 part, phosphate solubilizing bacteria 1 part, boron 1 part, manganese element 1 part, copper 1 part, zinc element 1 part, molybdenum element 1 part, sodium polyacrylate 3 parts, N-sodium lauroyl glutamate 3 parts, alkyl sodium sulfonate 3 parts.
The preparation method of described bioorganic pesticide fertilizer, comprises the following steps:
S1: by weeping willow leaf, piper methysticum, leaf of tea tree co-grinding, obtains mixture A after crossing 200 mesh sieve, adds waste residue, earthworm powder, biological bacteria, ferment at 70 DEG C in mixture A, ferments after 15 days and obtains fermented liquid;
S2: fermented liquid obtained for step S1 is left standstill and abandons precipitation, and remaining ferment liquid is concentrated at 60 DEG C, and obtain enriched material, described enriched material being dried at 100 DEG C water content is 5%, obtained mixture B;
S3: the mixture B that step S2 is obtained pulverizes, mixes with trace element, water-holding agent, wetting dispersing agent, permeate agent after crossing 200 mesh sieve, obtained bioorganic pesticide fertilizer.
Embodiment 5
A kind of bioorganic pesticide fertilizer, in units of weight part, comprise following raw material: 40 parts, weeping willow leaf, piper methysticum 50 parts, leaf of tea tree 60 parts, marc 25 parts, earthworm powder 15 parts, genus bacillus 4 parts, boron 2 parts, polyacrylamide 1 part, calcium lignin sulphonate 1 part, soap powder 1 part.
The preparation method of described bioorganic pesticide fertilizer, comprises the following steps:
S1: by weeping willow leaf, piper methysticum, leaf of tea tree co-grinding, obtains mixture A after crossing 100 mesh sieve, adds waste residue, earthworm powder, biological bacteria, ferment at 60 DEG C in mixture A, ferments after 20 days and obtains fermented liquid;
S2: fermented liquid obtained for step S1 is left standstill and abandons precipitation, and remaining ferment liquid is concentrated at 50 DEG C, and obtain enriched material, described enriched material being dried at 90 DEG C water content is 6%, obtained mixture B;
S3: the mixture B that step S2 is obtained pulverizes, mixes with trace element, water-holding agent, wetting dispersing agent, permeate agent after crossing 100 mesh sieve, obtained bioorganic pesticide fertilizer.
Embodiment 6
A kind of bioorganic pesticide fertilizer, in units of weight part, comprise following raw material: 55 parts, weeping willow leaf, piper methysticum 65 parts, leaf of tea tree 75 parts, fecula 32 parts, earthworm powder 22 parts, genus bacillus 6 parts, molybdenum element 4 parts, 2 parts, starch graft acrylic acid sodium, sodium laurylsulfate 2 parts, alkyl sodium sulfonate 2 parts.
The preparation method of described bioorganic pesticide fertilizer, comprises the following steps:
S1: by weeping willow leaf, piper methysticum, leaf of tea tree co-grinding, obtains mixture A after crossing 100 mesh sieve, adds waste residue, earthworm powder, biological bacteria, ferment at 80 DEG C in mixture A, ferments after 10 days and obtains fermented liquid;
S2: fermented liquid obtained for step S1 is left standstill and abandons precipitation, and remaining ferment liquid is concentrated at 50 DEG C, and obtain enriched material, described enriched material being dried at 105 DEG C water content is 6%, obtained mixture B;
S3: the mixture B that step S2 is obtained pulverizes, mixes with trace element, water-holding agent, wetting dispersing agent, permeate agent after crossing 100 mesh sieve, obtained bioorganic pesticide fertilizer.
For verifying the effect of bioorganic pesticide fertilizer of the present invention, by following experimental verification.
The fragrant taro ground that six block specifications are basically identical is chosen in agricultural base, Fu Chuan county of south china, be set to fragrant taro ground a, fragrant taro ground b, fragrant taro ground c, fragrant taro ground d, fragrant taro ground e, fragrant taro ground f, fragrant taro is planted on six pieces of ground, wherein fragrant taro ground a, fragrant taro ground b, fragrant taro ground c use same not have the common fertilizer of Biocidal, fragrant taro ground d, fragrant taro ground e, fragrant taro ground f use the fertilizer of embodiment 1,2,3 respectively, calculate with every mu of fertilising 120kg, observe the fragrant taro growing state on six pieces of fragrant taro ground.Result shows: fragrant taro ground a, fragrant taro ground b, the fragrant taro plant gloss difference that fragrant taro ground c kind is planted, unhealthy, the speed of growth is slow, plant is little, yield poorly, and fragrant taro ground d, fragrant taro ground e, the fragrant taro plant good luster that fragrant taro ground f kind is planted, healthy, fast growth, plant is large, output is high, with do not use product of the present invention fragrant taro compared with, every mu of volume increase 726.5-791.2kg, and use the disease and pest in the fragrant taro ground of product of the present invention substantially not have, visible bioorganic pesticide fertilizer of the present invention can not only preventing disease and pest effectively, and can be balanced in nutrition, improve edatope, promote that farm crop grow up healthy and sound fast, shorten growth cycle, improve crop yield.
Above content can not assert that the present invention specifically implements to be confined to these explanations; for general technical staff of the technical field of the invention; do not departing under concept thereof of the present invention; some simple deduction or replace can also be made, all should be considered as belonging to the scope of patent protection that the present invention is determined by submitted to claims.
Claims (10)
1. a bioorganic pesticide fertilizer, it is characterized in that, in units of weight part, comprise following raw material: weeping willow leaf 40-90 part, piper methysticum 50-90 part, leaf of tea tree 60-90 part, waste residue 25-40 part, earthworm powder 15-30 part, biological bacteria 4-8 part, micro-2-6 part, water-holding agent 1-3 part, wetting dispersing agent 1-3 part, permeate agent 1-3 part.
2. bioorganic pesticide fertilizer according to claim 1, it is characterized in that, in units of weight part, comprise following raw material: weeping willow leaf 50-90 part, piper methysticum 60-90 part, leaf of tea tree 70-90 part, waste residue 30-40 part, earthworm powder 20-30 part, biological bacteria 5-7 part, micro-3-5 part, water-holding agent 2-3 part, wetting dispersing agent 2-3 part, permeate agent 2-3 part.
3. bioorganic pesticide fertilizer according to claim 2, it is characterized in that, in units of weight part, comprise following raw material: 70 parts, weeping willow leaf, piper methysticum 75 parts, leaf of tea tree 80 parts, 32 parts, waste residue, earthworm powder 22 parts, biological bacteria 6 parts, trace element 4 parts, water-holding agent 2 parts, wetting dispersing agent 2 parts, permeate agent 2 parts.
4. the bioorganic pesticide fertilizer according to any one of claim 1-3, it is characterized in that, described waste residue comprise in marc, bagasse, edible fungi residues, sugared slag, acid-sludge, fecula, manioc waste, citric acid waste, soy sauce residues, residue of monosodium glutamate, residue from beans after making one or more.
5. the bioorganic pesticide fertilizer according to any one of claim 1-3, is characterized in that, described biological bacteria comprise in vinelandii, genus bacillus, enzymatic microorganism, yeast, actinomycetes, root nodule bacterium, phosphorus bacteria, B. mucilaginocus, phosphate solubilizing bacteria one or more.
6. the bioorganic pesticide fertilizer according to any one of claim 1-3, is characterized in that, described trace element comprise in iron, boron, manganese, copper, zinc, molybdenum one or more.
7. the bioorganic pesticide fertilizer according to any one of claim 1-3, is characterized in that, described water-holding agent comprise in polyacrylamide, sodium polyacrylate, polyacrylic acid potassium, ammonium polyacrylate, starch graft acrylic acid sodium one or more.
8. the bioorganic pesticide fertilizer according to any one of claim 1-3, is characterized in that, described wetting dispersing agent comprise in calcium lignin sulphonate, N-sodium lauroyl glutamate, sodium laurylsulfate one or more.
9. the bioorganic pesticide fertilizer according to any one of claim 1-3, is characterized in that, described permeate agent comprise in soap powder, sodium lignosulfonate, alkyl sodium sulfonate, sodium alkyl benzene sulfonate, alkyl sulfuric ester sodium one or more.
10. a preparation method for the bioorganic pesticide fertilizer according to any one of claim 1-9, is characterized in that, comprises the following steps:
S1: by weeping willow leaf, piper methysticum, leaf of tea tree co-grinding, obtains mixture A after crossing 100-200 mesh sieve, adds waste residue, earthworm powder, biological bacteria, ferment at 60-80 DEG C in mixture A, ferments after 10-20 days and obtains fermented liquid;
S2: fermented liquid obtained for step S1 is left standstill and abandons precipitation, and remaining ferment liquid is concentrated at 50-60 DEG C, obtain enriched material, described enriched material is dried to water content≤6% at 90-105 DEG C, obtained mixture B;
S3: the mixture B that step S2 is obtained pulverizes, mixes with trace element, water-holding agent, wetting dispersing agent, permeate agent after crossing 100-300 mesh sieve, obtained bioorganic pesticide fertilizer.
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Application publication date: 20160127 |