CN104703681A - 具有均孔分离活性层的膜和制备膜的方法 - Google Patents

具有均孔分离活性层的膜和制备膜的方法 Download PDF

Info

Publication number
CN104703681A
CN104703681A CN201380041855.2A CN201380041855A CN104703681A CN 104703681 A CN104703681 A CN 104703681A CN 201380041855 A CN201380041855 A CN 201380041855A CN 104703681 A CN104703681 A CN 104703681A
Authority
CN
China
Prior art keywords
membrane
weight
polymer
block copolymer
solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201380041855.2A
Other languages
English (en)
Chinese (zh)
Inventor
V.阿贝茨
J.克洛德
M.V.菲里兹
K.布尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Helmholtz Zentrum Geesthachi Zentrum fur Material And Seacoast Research Center Co Ltd
Original Assignee
Helmholtz Zentrum Geesthachi Zentrum fur Material And Seacoast Research Center Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Helmholtz Zentrum Geesthachi Zentrum fur Material And Seacoast Research Center Co Ltd filed Critical Helmholtz Zentrum Geesthachi Zentrum fur Material And Seacoast Research Center Co Ltd
Publication of CN104703681A publication Critical patent/CN104703681A/zh
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/80—Block polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/0013—Casting processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/027—Nanofiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/145—Ultrafiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/00091—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching by evaporation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/0011—Casting solutions therefor
    • B01D67/00111—Polymer pretreatment in the casting solutions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B01D69/107—Organic support material
    • B01D69/1071—Woven, non-woven or net mesh
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/1213—Laminated layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/08—Polysaccharides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/28—Polymers of vinyl aromatic compounds
    • B01D71/281—Polystyrene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/28—Polymers of vinyl aromatic compounds
    • B01D71/283—Polyvinylpyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/12—Specific ratios of components used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/219—Specific solvent system
    • B01D2323/22—Specific non-solvents or non-solvent system
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/021—Pore shapes
    • B01D2325/0212—Symmetric or isoporous membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/0283—Pore size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/34—Molecular weight or degree of polymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
    • B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/66—Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
    • B01D71/68—Polysulfones; Polyethersulfones

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Water Supply & Treatment (AREA)
  • Nanotechnology (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
CN201380041855.2A 2012-08-09 2013-07-05 具有均孔分离活性层的膜和制备膜的方法 Pending CN104703681A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12179792.2 2012-08-09
EP12179792.2A EP2695669B1 (de) 2012-08-09 2012-08-09 Membran mit isoporöser trennaktiver Schicht und Verfahren zur Herstellung einer Membran
PCT/EP2013/001984 WO2014023379A1 (de) 2012-08-09 2013-07-05 Membran mit isoporöser trennaktiver schicht und verfahren zur herstellung einer membran

Publications (1)

Publication Number Publication Date
CN104703681A true CN104703681A (zh) 2015-06-10

Family

ID=48782268

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380041855.2A Pending CN104703681A (zh) 2012-08-09 2013-07-05 具有均孔分离活性层的膜和制备膜的方法

Country Status (8)

Country Link
US (1) US20150151256A1 (enExample)
EP (1) EP2695669B1 (enExample)
JP (1) JP2015529555A (enExample)
KR (1) KR20150041002A (enExample)
CN (1) CN104703681A (enExample)
IN (1) IN2015DN00750A (enExample)
RU (1) RU2015105311A (enExample)
WO (1) WO2014023379A1 (enExample)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106422817A (zh) * 2015-06-25 2017-02-22 帕尔公司 自润湿多孔膜
CN106422818A (zh) * 2015-06-25 2017-02-22 帕尔公司 自润湿多孔膜
CN108714373A (zh) * 2018-06-15 2018-10-30 南京工业大学 基于嵌段共聚物非溶剂诱导相分离制备多孔膜的方法
CN109908775A (zh) * 2019-02-01 2019-06-21 浙江大学 一种利用嵌段聚合物制备多孔分离膜的方法
CN110382093A (zh) * 2017-03-01 2019-10-25 亥姆霍兹中心盖斯特哈赫特材料及海岸研究中心有限公司 平板几何形状的整体不对称均孔嵌段共聚物膜
CN110913978A (zh) * 2017-07-27 2020-03-24 亥姆霍兹材料研究与海岸研究盖斯特哈赫特中心 制备均孔中空纤维复合膜的方法
CN111437733A (zh) * 2020-04-20 2020-07-24 贵州省材料产业技术研究院 一种低压聚合物脱色纳滤膜制备方法及其制品和应用
CN111971115A (zh) * 2018-03-12 2020-11-20 特拉波雷技术有限公司 具有大孔隙的均孔介孔不对称嵌段共聚物材料及其制造方法
CN113522037A (zh) * 2021-07-21 2021-10-22 江苏盈天化学有限公司 一种渗透汽化四氢呋喃脱水复合膜的制备方法

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG194779A1 (en) 2011-05-04 2013-12-30 Univ Cornell Multiblock copolymer films, methods of making same, and uses thereof
JP2015073980A (ja) * 2013-10-11 2015-04-20 富士フイルム株式会社 ガス分離膜およびガス分離膜モジュール
CN104028123B (zh) * 2014-05-14 2016-04-20 浙江大学 一种聚合物纳米纤维分离膜的制备方法
DE102014213027A1 (de) 2014-07-04 2016-01-07 Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung GmbH Verfahren zur Herstellung einer Membran mit isoporöser trennaktiver Schicht mit einstellbarer Porengröße, Membran, Filtrationsmodul und Verwendung
CN104607072B (zh) * 2015-01-08 2016-12-07 天津大学 壳聚糖修饰介孔二氧化硅填充杂化膜及制备方法和应用
EP3056260B1 (de) 2015-02-16 2020-02-12 Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung GmbH Verfahren zur Herstellung einer Trennmembran sowie mit dem Verfahren herstellbare Trennmembran
US11198103B2 (en) 2015-03-10 2021-12-14 Trustees Of Tufts College Two-layer nanofiltration membranes
CN105032220B (zh) * 2015-09-08 2017-05-10 南京工业大学 一种永久亲水型聚砜超滤膜的制备方法
SG10202010709UA (en) * 2016-04-28 2020-11-27 Terapore Tech Inc Charged isoporous materials for electrostatic separations
CN106310967B (zh) * 2016-08-23 2018-08-21 北京碧水源膜科技有限公司 一种制备亲水性纳米杂化增强型中空纤维膜的方法
EP3541500B1 (en) 2016-11-17 2021-12-08 Shethji, Jayraj K. Isoporous self-assembled block copolymer films containing high molecular weight hydrophilic additives and methods of making the same
CN109996598A (zh) 2016-11-22 2019-07-09 3M创新有限公司 包含五嵌段共聚物的多孔膜及其制备方法
US10781279B2 (en) 2016-11-22 2020-09-22 3M Innovative Properties Company Pentablock copolymers
US11567072B2 (en) 2017-02-22 2023-01-31 Terapore Technologies, Inc. Ligand bound MBP membranes, uses and method of manufacturing
CN106943895B (zh) * 2017-04-07 2019-07-05 华东师范大学 一种丙酮刺激响应的柔性仿生双层高分子薄膜及制备方法和应用
JP2020519734A (ja) * 2017-05-12 2020-07-02 テラポア テクノロジーズ，インコーポレイテッド 耐薬品性フッ素化マルチブロック重合体構造物、製造方法及びその使用
EP3697524A4 (en) * 2017-09-19 2021-09-01 Terapore Technologies, Inc. CHEMICALLY RESISTANT ISOPOROUS CROSS-LINKED BLOCK COPOLYMER STRUCTURE
CN108654409B (zh) * 2018-06-05 2021-07-27 南京工业大学 一种高分子胶束纳滤膜的制备及其应用
EP3772370A1 (en) * 2019-08-05 2021-02-10 Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung GmbH Method of producing a polymeric membrane
CN110585937A (zh) * 2019-08-13 2019-12-20 浙江工业大学 一种大分子共组装诱导低χ值聚合物制备均孔膜的方法
KR102299597B1 (ko) 2019-12-27 2021-09-08 연세대학교 산학협력단 복합 멤브레인 및 이의 제조방법
US12420238B2 (en) 2021-01-22 2025-09-23 Cornell University Asymmetric multiblock copolymer-homopolymer films, methods of making same, and uses thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101516481A (zh) * 2006-09-22 2009-08-26 Gkss-盖斯特哈赫特研究中心有限责任公司 均孔膜及其制备方法
WO2011098851A1 (en) * 2010-02-11 2011-08-18 King Abdullah University Of Science And Technology Self-assembled block copolymer membrane

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19738913B4 (de) * 1997-09-05 2004-03-18 MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. Blockcopolymerphasen als Template für strukturierte organisch-anorganische Hybridmaterialien
EP2108674A4 (en) * 2007-01-11 2011-04-20 Nitto Denko Corp METHOD FOR PRODUCING A MICROPOROUS POLYMERIC SUBSTANCE, MICRONIC POLYMERIC SUBSTANCE AND DISCONNECTED MEMBRANE

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101516481A (zh) * 2006-09-22 2009-08-26 Gkss-盖斯特哈赫特研究中心有限责任公司 均孔膜及其制备方法
WO2011098851A1 (en) * 2010-02-11 2011-08-18 King Abdullah University Of Science And Technology Self-assembled block copolymer membrane

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106422818B (zh) * 2015-06-25 2019-09-10 帕尔公司 自润湿多孔膜
CN106422818A (zh) * 2015-06-25 2017-02-22 帕尔公司 自润湿多孔膜
CN106422817B (zh) * 2015-06-25 2020-06-05 帕尔公司 自润湿多孔膜
TWI648319B (zh) * 2015-06-25 2019-01-21 美商帷幕公司 自潤濕多孔性薄膜（ｉｉ）
US10239023B2 (en) 2015-06-25 2019-03-26 Pall Corporation Self-wetting porous membranes (II)
CN106422817A (zh) * 2015-06-25 2017-02-22 帕尔公司 自润湿多孔膜
CN110382093A (zh) * 2017-03-01 2019-10-25 亥姆霍兹中心盖斯特哈赫特材料及海岸研究中心有限公司 平板几何形状的整体不对称均孔嵌段共聚物膜
CN110913978A (zh) * 2017-07-27 2020-03-24 亥姆霍兹材料研究与海岸研究盖斯特哈赫特中心 制备均孔中空纤维复合膜的方法
CN111971115A (zh) * 2018-03-12 2020-11-20 特拉波雷技术有限公司 具有大孔隙的均孔介孔不对称嵌段共聚物材料及其制造方法
CN108714373A (zh) * 2018-06-15 2018-10-30 南京工业大学 基于嵌段共聚物非溶剂诱导相分离制备多孔膜的方法
CN108714373B (zh) * 2018-06-15 2021-02-05 南京工业大学 基于嵌段共聚物非溶剂诱导相分离制备多孔膜的方法
CN109908775A (zh) * 2019-02-01 2019-06-21 浙江大学 一种利用嵌段聚合物制备多孔分离膜的方法
CN111437733A (zh) * 2020-04-20 2020-07-24 贵州省材料产业技术研究院 一种低压聚合物脱色纳滤膜制备方法及其制品和应用
CN111437733B (zh) * 2020-04-20 2022-03-08 贵州省材料产业技术研究院 一种低压聚合物脱色纳滤膜制备方法及其制品和应用
CN113522037A (zh) * 2021-07-21 2021-10-22 江苏盈天化学有限公司 一种渗透汽化四氢呋喃脱水复合膜的制备方法

Also Published As

Publication number Publication date
US20150151256A1 (en) 2015-06-04
EP2695669B1 (de) 2016-10-12
JP2015529555A (ja) 2015-10-08
WO2014023379A1 (de) 2014-02-13
KR20150041002A (ko) 2015-04-15
IN2015DN00750A (enExample) 2015-07-10
EP2695669A1 (de) 2014-02-12
RU2015105311A (ru) 2016-09-27

Similar Documents

Publication Publication Date Title
CN104703681A (zh) 具有均孔分离活性层的膜和制备膜的方法
CN110475602B (zh) 含有高分子量亲水性添加剂的均孔自组装嵌段共聚物膜及其制备方法
Han et al. Preparation and characterization of cellulose acetate/carboxymethyl cellulose acetate blend ultrafiltration membranes
DK2922620T3 (en) Process for the preparation of integral asymmetric hollow fiber polymer membrane consisting of amphiphilic block copolymer, the hollow fiber membrane obtained and use thereof
EP2695668B1 (de) Verfahren zum Herstellen einer thermoresponsiven Filtrationsmembran und thermoresponsive Filtrationsmembran
DE102014213027A1 (de) Verfahren zur Herstellung einer Membran mit isoporöser trennaktiver Schicht mit einstellbarer Porengröße, Membran, Filtrationsmodul und Verwendung
Soyekwo et al. Highly permeable cellulose acetate nanofibrous composite membranes by freeze-extraction
KR102456816B1 (ko) 평면 시트 기하구조의 일체형 비대칭, 이소다공성 블록 공중합체 멤브레인
DE102012207344A1 (de) Membran mit isoporöser trennaktiver Schicht und Verfahren zur Herstellung einer Membran
CN118341281A (zh) 一种具有沙漏结构的高通量聚醚砜嵌段共聚物多孔微滤膜及其制备方法和应用
Zhu et al. Surface wormlike morphology control of polysulfone/poly (N-isopropylacrylamide) membranes by tuning the two-stage phase separation and their thermo-responsive permselectivity
JP7030800B2 (ja) 中空繊維幾何形状のマクロポーラス又はメソポーラスポリマフィルム
KR20110076333A (ko) 정밀여과막의 제조방법 및 그로부터 제조되는 고수투성 정밀여과막
KR101778683B1 (ko) 유기 용매 및 수압을 이용한 고분자 필름에 기공을 형성하는 방법
JPS5959207A (ja) 選択性透過膜の製造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150610