CN104583180B - 硫醇在c4烃混合物中的硫醚化 - Google Patents

硫醇在c4烃混合物中的硫醚化 Download PDF

Info

Publication number
CN104583180B
CN104583180B CN201380043667.3A CN201380043667A CN104583180B CN 104583180 B CN104583180 B CN 104583180B CN 201380043667 A CN201380043667 A CN 201380043667A CN 104583180 B CN104583180 B CN 104583180B
Authority
CN
China
Prior art keywords
butene
process according
distillation
hydrogen
thioetherification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201380043667.3A
Other languages
English (en)
Chinese (zh)
Other versions
CN104583180A (zh
Inventor
S·佩特兹
M·温特伯格
D·马奇梅伊尔
F·盖伦
R·布克尔
J·沙伦伯格
A·里克斯
A·沃尔夫
M·雷珀德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Evonik Degussa GmbH
Evonik Industries AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Degussa GmbH, Evonik Industries AG filed Critical Evonik Degussa GmbH
Publication of CN104583180A publication Critical patent/CN104583180A/zh
Application granted granted Critical
Publication of CN104583180B publication Critical patent/CN104583180B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/18—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by addition of thiols to unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
    • C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CN201380043667.3A 2012-07-13 2013-06-25 硫醇在c4烃混合物中的硫醚化 Active CN104583180B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102012212317.2A DE102012212317A1 (de) 2012-07-13 2012-07-13 Thioveretherung von Mercaptanen in C4-Kohlenwasserstoffgemischen
DE102012212317.2 2012-07-13
PCT/EP2013/063300 WO2014009148A1 (de) 2012-07-13 2013-06-25 Thioveretherung von mercaptanen in c4-kohlenwasserstoffgemischen

Publications (2)

Publication Number Publication Date
CN104583180A CN104583180A (zh) 2015-04-29
CN104583180B true CN104583180B (zh) 2017-05-17

Family

ID=48748184

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380043667.3A Active CN104583180B (zh) 2012-07-13 2013-06-25 硫醇在c4烃混合物中的硫醚化

Country Status (18)

Country Link
US (1) US9260386B2 (https=)
EP (1) EP2872484B1 (https=)
JP (1) JP6095776B2 (https=)
KR (1) KR102009548B1 (https=)
CN (1) CN104583180B (https=)
AR (1) AR092028A1 (https=)
BR (1) BR112015000737B1 (https=)
CA (1) CA2878983C (https=)
DE (1) DE102012212317A1 (https=)
ES (1) ES2690058T3 (https=)
IN (1) IN2015DN00745A (https=)
MX (1) MX362867B (https=)
MY (1) MY160118A (https=)
PL (1) PL2872484T3 (https=)
RU (1) RU2628085C2 (https=)
TW (1) TWI588122B (https=)
WO (1) WO2014009148A1 (https=)
ZA (1) ZA201500965B (https=)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013225724A1 (de) 2013-12-12 2015-06-18 Evonik Industries Ag Reinigung flüssiger Kohlenwasserstoffströme mittels kupferhaltiger Sorptionsmittel
EP3023131A1 (de) 2014-11-18 2016-05-25 Evonik Degussa GmbH Zweistufige Feinentschwefelung von Olefingemischen
SG10201604013RA (en) 2015-05-28 2016-12-29 Evonik Degussa Gmbh Hydrogen-assisted adsorption of sulphur compounds from olefin mixtures
CN112739669B (zh) * 2018-06-07 2024-08-16 英国石油有限公司 多不饱和物的选择性加氢
EP3680224B1 (de) * 2019-01-08 2023-05-24 Evonik Operations GmbH Verfahren zur entfernung mehrfach ungesättigter kohlenwasserstoffe aus c4-kohlenwasserstoffströmen in anwesenheit von mercaptanen, disulfiden und c5-kohlenwasserstoffen
US11186782B2 (en) * 2019-01-08 2021-11-30 Evonik Operations Gmbh Catalyst and process for removing mercaptans from hydrocarbon streams
EP4660179A1 (de) 2024-06-03 2025-12-10 Evonik Oxeno GmbH & Co. KG Verfahren zur herstellung von hochreinem 1-buten und von hochreinem isobutan

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4517395A (en) * 1981-11-04 1985-05-14 Chemische Werke Huls Aktiengesellschaft Process for the selective hydrogenation of polyunsaturated hydrocarbons in hydrocarbon mixtures
CN1032157A (zh) * 1987-09-21 1989-04-05 环球油品公司 用于烯烃选择性加氢的富含大孔的催化剂
US5338889A (en) * 1992-12-29 1994-08-16 Uop Alkane rejection in C4 etherification and isomerization process
US5851383A (en) * 1997-01-09 1998-12-22 Uop Llc Process for thioetherification and selective hydrogenation of light olefins
WO2003062178A1 (en) * 2002-01-23 2003-07-31 Catalytic Distillation Technologies Process for the utilization of refinery c4 streams
CN1511925A (zh) * 2002-12-31 2004-07-14 中国石油化工股份有限公司齐鲁分公司 一种脱除汽油中硫醇的方法
CN1246424C (zh) * 1999-09-17 2006-03-22 催化蒸馏技术公司 去除硫醇的方法
CN102149793A (zh) * 2008-09-09 2011-08-10 鲁姆斯科技公司 用于从气体物流中去除硫醇的硫醚化方法

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE740247C (de) * 1939-06-29 1943-10-19 Bataafsche Petroleum Verfahren zur Herstellung von Thioathern und bzw. oder Mercaptanen
DE864866C (de) * 1949-06-08 1953-01-29 Karl Dr Ziegler Verfahren zur Darstellung von Anlagerungsverbindungen
FR2482953A1 (fr) 1980-05-22 1981-11-27 Inst Francais Du Petrole Procede d'hydrogenation selective d'une di-olefine dans un melange d'hydrocarbures renfermant au moins 4 atomes de carbone et contenant une olefine -a
US4695560A (en) * 1985-10-01 1987-09-22 Uop Inc. Catalyst for the selective hydrogenation of diolefinic hydrocarbons
DE3825169A1 (de) 1988-07-23 1990-02-01 Huels Chemische Werke Ag Verfahren zur feinentschwefelung von kohlenwasserstoffen
DE3914817C2 (de) 1989-05-05 1995-09-07 Huels Chemische Werke Ag Verfahren zur Oligomerisierung von Olefinen
DE4123246A1 (de) 1991-07-13 1993-01-14 Basf Ag Verfahren zur selektiven hydrierung von butadienreichen roh-c(pfeil abwaerts)4(pfeil abwaerts)-schnitten
DE4339713A1 (de) 1993-11-22 1995-05-24 Basf Ag Verfahren zur Oligomerisierung von Olefinen zu hochlinearen Oligomeren und Katalysatoren dafür
US5463134A (en) 1994-05-04 1995-10-31 Uop Paraffin treating process for mercaptan and olefin removal
FR2742679B1 (fr) 1995-12-22 1998-01-16 Inst Francais Du Petrole Catalyseur d'hydrogenation selective et procede utilisant ce catalyseur
US5759386A (en) * 1997-01-09 1998-06-02 Uop Process for thioetherification and selective hydrogenation of light hydrocarbons
DE19839459A1 (de) 1998-08-29 2000-03-02 Basf Ag Katalysator und Verfahren zur Selektivhydrierung ungesättigter Verbindungen in Kohlenwasserstoffströmen
DE19845857A1 (de) 1998-10-05 2000-04-06 Basf Ag Verfahren zur katalytischen Oligomerisierung von Monoolefinen
DE19906518A1 (de) 1999-02-17 2000-08-31 Oxeno Olefinchemie Gmbh Verfahren zur Fraktionierung von Dibuten
DE19957173A1 (de) 1999-11-27 2001-05-31 Basf Ag Oligomerisierungskatalysator, Verfahren zu seiner Herstellung und seine Verwendung
DE10102082A1 (de) 2000-10-19 2002-05-02 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von hochreinem Raffinat II und Methyl-tert.-butylether
US6930206B1 (en) 2001-07-05 2005-08-16 Catalytic Distillation Technologies Process and apparatus for catalytic distillations
DE10152842A1 (de) 2001-10-25 2003-05-08 Oxeno Olefinchemie Gmbh Hydroisomerisierung von Olefinen mit 4-6 Kohlenstoffatomen
US7153415B2 (en) * 2002-02-13 2006-12-26 Catalytic Distillation Technologies Process for the treatment of light naphtha hydrocarbon streams
ATE512946T1 (de) * 2002-06-11 2011-07-15 Catalytic Distillation Tech Verfahren und vorrichtung für katalytische destillierungen
DE102004018753A1 (de) 2004-04-17 2005-11-03 Oxeno Olefinchemie Gmbh Kohlenwasserstoffgemisch aliphatischer gesättigter Kohlenwasserstoffe mit 16 C-Atomen
DE102005062700A1 (de) 2005-12-28 2007-07-05 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Buten aus technischen Mischungen von C4-Kohlenwasserstoffen
DE102005062699A1 (de) 2005-12-28 2007-09-06 Oxeno Olefinchemie Gmbh Verfahren zur Feinreinigung von 1-Buten-haltigen Strömen
CN101885660B (zh) 2009-05-13 2013-07-31 中国石油化工股份有限公司 碳四烃催化分离异丁烯和丁烯-2的方法
DE102010030990A1 (de) 2010-07-06 2012-01-12 Evonik Oxeno Gmbh Verfahren zur selektiven Hydrierung von mehrfach ungesättigten Kohlenwasserstoffen in olefinhaltigen Kohlenwasserstoffgemischen
DE102012212316A1 (de) 2012-07-13 2014-01-16 Evonik Industries Ag Schwefeladsoption vor Oligomerisierungsanlagen

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4517395A (en) * 1981-11-04 1985-05-14 Chemische Werke Huls Aktiengesellschaft Process for the selective hydrogenation of polyunsaturated hydrocarbons in hydrocarbon mixtures
CN1032157A (zh) * 1987-09-21 1989-04-05 环球油品公司 用于烯烃选择性加氢的富含大孔的催化剂
US5338889A (en) * 1992-12-29 1994-08-16 Uop Alkane rejection in C4 etherification and isomerization process
US5851383A (en) * 1997-01-09 1998-12-22 Uop Llc Process for thioetherification and selective hydrogenation of light olefins
CN1246424C (zh) * 1999-09-17 2006-03-22 催化蒸馏技术公司 去除硫醇的方法
WO2003062178A1 (en) * 2002-01-23 2003-07-31 Catalytic Distillation Technologies Process for the utilization of refinery c4 streams
CN1511925A (zh) * 2002-12-31 2004-07-14 中国石油化工股份有限公司齐鲁分公司 一种脱除汽油中硫醇的方法
CN102149793A (zh) * 2008-09-09 2011-08-10 鲁姆斯科技公司 用于从气体物流中去除硫醇的硫醚化方法

Also Published As

Publication number Publication date
KR102009548B1 (ko) 2019-08-09
KR20150032580A (ko) 2015-03-26
MX2015000363A (es) 2015-04-14
IN2015DN00745A (https=) 2015-07-10
BR112015000737A2 (pt) 2017-06-27
PL2872484T3 (pl) 2019-01-31
JP2015525750A (ja) 2015-09-07
RU2015104808A (ru) 2016-09-10
EP2872484B1 (de) 2018-08-08
US20150166475A1 (en) 2015-06-18
CA2878983A1 (en) 2014-01-16
MX362867B (es) 2019-02-20
EP2872484A1 (de) 2015-05-20
US9260386B2 (en) 2016-02-16
RU2628085C2 (ru) 2017-08-14
JP6095776B2 (ja) 2017-03-15
TW201420557A (zh) 2014-06-01
AR092028A1 (es) 2015-03-18
TWI588122B (zh) 2017-06-21
CN104583180A (zh) 2015-04-29
WO2014009148A1 (de) 2014-01-16
BR112015000737B1 (pt) 2020-11-10
ZA201500965B (en) 2016-01-27
ES2690058T3 (es) 2018-11-19
MY160118A (en) 2017-02-28
DE102012212317A1 (de) 2014-01-16
CA2878983C (en) 2017-01-17

Similar Documents

Publication Publication Date Title
CN104583180B (zh) 硫醇在c4烃混合物中的硫醚化
JP5298195B2 (ja) 統合されたプロピレン生成
CN111410597B (zh) 在硫醇、二硫化物和c5烃存在下从c4烃料流中去除多不饱和烃的方法
TW467880B (en) Process for preparing olefins from steam cracker or refinery C4 streams
US10221111B2 (en) Method for separating propylene from dehydrogenation reaction products of propane-containing feedstock
TWI429741B (zh) 使用催化蒸餾之超低苯重組油的方法
CN102811988B (zh) 四聚物生产设备及其相关方法
US7556728B2 (en) Process for the manufacture of a gasoline blending component
CN111408367A (zh) 从烃料流中去除硫醇的催化剂和方法
CN101519337B (zh) 一种炼厂高硫碳四精脱硫的方法
CN112143519A (zh) 异构烷烃与烯烃的固体酸烷基化方法
CN112143518B (zh) 一种生产汽油的固体酸烷基化方法
CN112143523B (zh) 一种烷基化汽油原料的预处理方法
CN111748374B (zh) 一种混合碳四原料加氢精制的方法及其系统
CN101597509B (zh) 重组烷基化催化蒸馏脱硫方法
MXPA98000233A (en) Improved process for selective hydrogenation of highly unsaturated compounds and isomerization of olefins in hydrocarbon currents

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
EXSB Decision made by sipo to initiate substantive examination
SE01 Entry into force of request for substantive examination
C41 Transfer of patent application or patent right or utility model
TA01 Transfer of patent application right

Effective date of registration: 20160107

Address after: essen

Applicant after: EVONIK DEGUSSA GmbH

Address before: essen

Applicant before: Evonik Industries AG

GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20231107

Address after: mAhR

Patentee after: Evonik Oxenor Co.,Ltd.

Address before: essen

Patentee before: Evonik Operations Ltd.

TR01 Transfer of patent right