MX362867B - Tioeterificacion de mercaptanos en mezclas de hidrocarburos c4. - Google Patents
Tioeterificacion de mercaptanos en mezclas de hidrocarburos c4.Info
- Publication number
- MX362867B MX362867B MX2015000363A MX2015000363A MX362867B MX 362867 B MX362867 B MX 362867B MX 2015000363 A MX2015000363 A MX 2015000363A MX 2015000363 A MX2015000363 A MX 2015000363A MX 362867 B MX362867 B MX 362867B
- Authority
- MX
- Mexico
- Prior art keywords
- thioetherification
- mercaptanes
- hydrogen
- hydrocarbon mixtures
- aim
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
- C07C319/18—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by addition of thiols to unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
- C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
La invención se refiere a un proceso para la tioeterificación de mercaptanos con hidrocarburos poliinsaturados, llevado a cabo en un reactor con adición de hidrógeno, utilizándose un catalizador heterogéneo y en la presencia de 1-buteno. Es un objetivo de la invención configurar un proceso de este tipo de tal manera que el valor derivado de la corriente de C4 bruto se incremente. Este objetivo se logra por el hecho de introducir el hidrógeno en la reacción de tal manera que la relación molar entre hidrógeno y los hidrocarburos poliinsaturados no sea mayor de uno.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102012212317.2A DE102012212317A1 (de) | 2012-07-13 | 2012-07-13 | Thioveretherung von Mercaptanen in C4-Kohlenwasserstoffgemischen |
PCT/EP2013/063300 WO2014009148A1 (de) | 2012-07-13 | 2013-06-25 | Thioveretherung von mercaptanen in c4-kohlenwasserstoffgemischen |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2015000363A MX2015000363A (es) | 2015-04-14 |
MX362867B true MX362867B (es) | 2019-02-20 |
Family
ID=48748184
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2015000363A MX362867B (es) | 2012-07-13 | 2013-06-25 | Tioeterificacion de mercaptanos en mezclas de hidrocarburos c4. |
Country Status (18)
Country | Link |
---|---|
US (1) | US9260386B2 (es) |
EP (1) | EP2872484B1 (es) |
JP (1) | JP6095776B2 (es) |
KR (1) | KR102009548B1 (es) |
CN (1) | CN104583180B (es) |
AR (1) | AR092028A1 (es) |
BR (1) | BR112015000737B1 (es) |
CA (1) | CA2878983C (es) |
DE (1) | DE102012212317A1 (es) |
ES (1) | ES2690058T3 (es) |
IN (1) | IN2015DN00745A (es) |
MX (1) | MX362867B (es) |
MY (1) | MY160118A (es) |
PL (1) | PL2872484T3 (es) |
RU (1) | RU2628085C2 (es) |
TW (1) | TWI588122B (es) |
WO (1) | WO2014009148A1 (es) |
ZA (1) | ZA201500965B (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102013225724A1 (de) | 2013-12-12 | 2015-06-18 | Evonik Industries Ag | Reinigung flüssiger Kohlenwasserstoffströme mittels kupferhaltiger Sorptionsmittel |
EP3023131A1 (de) | 2014-11-18 | 2016-05-25 | Evonik Degussa GmbH | Zweistufige Feinentschwefelung von Olefingemischen |
SG10201604013RA (en) | 2015-05-28 | 2016-12-29 | Evonik Degussa Gmbh | Hydrogen-assisted adsorption of sulphur compounds from olefin mixtures |
WO2019233961A1 (en) * | 2018-06-07 | 2019-12-12 | Bp P.L.C. | Selective hydrogenation of polyunsaturates |
PL3680224T3 (pl) * | 2019-01-08 | 2023-09-11 | Evonik Operations Gmbh | Sposób usuwania wielonienasyconych węglowodorów ze strumieni węglowodorowych C4 w obecności merkaptanów, disiarczków i węglowodorów C5 |
US11186782B2 (en) * | 2019-01-08 | 2021-11-30 | Evonik Operations Gmbh | Catalyst and process for removing mercaptans from hydrocarbon streams |
Family Cites Families (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE740247C (de) * | 1939-06-29 | 1943-10-19 | Bataafsche Petroleum | Verfahren zur Herstellung von Thioathern und bzw. oder Mercaptanen |
DE864866C (de) * | 1949-06-08 | 1953-01-29 | Karl Dr Ziegler | Verfahren zur Darstellung von Anlagerungsverbindungen |
FR2482953A1 (fr) | 1980-05-22 | 1981-11-27 | Inst Francais Du Petrole | Procede d'hydrogenation selective d'une di-olefine dans un melange d'hydrocarbures renfermant au moins 4 atomes de carbone et contenant une olefine -a |
DE3143647A1 (de) * | 1981-11-04 | 1983-05-11 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur selektiven hydrierung von mehrfach ungesaettigten kohlenwasserstoffen in kohlenwasserstoff-gemischen |
US4695560A (en) * | 1985-10-01 | 1987-09-22 | Uop Inc. | Catalyst for the selective hydrogenation of diolefinic hydrocarbons |
CN1016165B (zh) * | 1987-09-21 | 1992-04-08 | 环球油品公司 | 用于烯烃选择性加氢的富含大孔的催化剂 |
DE3825169A1 (de) | 1988-07-23 | 1990-02-01 | Huels Chemische Werke Ag | Verfahren zur feinentschwefelung von kohlenwasserstoffen |
DE3914817C2 (de) | 1989-05-05 | 1995-09-07 | Huels Chemische Werke Ag | Verfahren zur Oligomerisierung von Olefinen |
DE4123246A1 (de) | 1991-07-13 | 1993-01-14 | Basf Ag | Verfahren zur selektiven hydrierung von butadienreichen roh-c(pfeil abwaerts)4(pfeil abwaerts)-schnitten |
US5338889A (en) * | 1992-12-29 | 1994-08-16 | Uop | Alkane rejection in C4 etherification and isomerization process |
DE4339713A1 (de) | 1993-11-22 | 1995-05-24 | Basf Ag | Verfahren zur Oligomerisierung von Olefinen zu hochlinearen Oligomeren und Katalysatoren dafür |
US5463134A (en) | 1994-05-04 | 1995-10-31 | Uop | Paraffin treating process for mercaptan and olefin removal |
FR2742679B1 (fr) | 1995-12-22 | 1998-01-16 | Inst Francais Du Petrole | Catalyseur d'hydrogenation selective et procede utilisant ce catalyseur |
US5759386A (en) * | 1997-01-09 | 1998-06-02 | Uop | Process for thioetherification and selective hydrogenation of light hydrocarbons |
US5851383A (en) | 1997-01-09 | 1998-12-22 | Uop Llc | Process for thioetherification and selective hydrogenation of light olefins |
DE19839459A1 (de) | 1998-08-29 | 2000-03-02 | Basf Ag | Katalysator und Verfahren zur Selektivhydrierung ungesättigter Verbindungen in Kohlenwasserstoffströmen |
DE19845857A1 (de) | 1998-10-05 | 2000-04-06 | Basf Ag | Verfahren zur katalytischen Oligomerisierung von Monoolefinen |
DE19906518A1 (de) | 1999-02-17 | 2000-08-31 | Oxeno Olefinchemie Gmbh | Verfahren zur Fraktionierung von Dibuten |
US6231752B1 (en) * | 1999-09-17 | 2001-05-15 | Catalytic Distillation Technologies | Process for the removal of mercaptans |
DE19957173A1 (de) | 1999-11-27 | 2001-05-31 | Basf Ag | Oligomerisierungskatalysator, Verfahren zu seiner Herstellung und seine Verwendung |
DE10102082A1 (de) | 2000-10-19 | 2002-05-02 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von hochreinem Raffinat II und Methyl-tert.-butylether |
US6930206B1 (en) | 2001-07-05 | 2005-08-16 | Catalytic Distillation Technologies | Process and apparatus for catalytic distillations |
DE10152842A1 (de) | 2001-10-25 | 2003-05-08 | Oxeno Olefinchemie Gmbh | Hydroisomerisierung von Olefinen mit 4-6 Kohlenstoffatomen |
US6849773B2 (en) | 2002-01-23 | 2005-02-01 | Catalytic Distillation Technologies | Process for the utilization of refinery C4 streams |
US7153415B2 (en) * | 2002-02-13 | 2006-12-26 | Catalytic Distillation Technologies | Process for the treatment of light naphtha hydrocarbon streams |
EP1513791B1 (en) * | 2002-06-11 | 2011-06-15 | Catalytic Distillation Technologies | Process and apparatus for catalytic distillations |
CN1294238C (zh) * | 2002-12-31 | 2007-01-10 | 中国石油化工股份有限公司齐鲁分公司 | 一种脱除汽油中硫醇的方法 |
DE102004018753A1 (de) | 2004-04-17 | 2005-11-03 | Oxeno Olefinchemie Gmbh | Kohlenwasserstoffgemisch aliphatischer gesättigter Kohlenwasserstoffe mit 16 C-Atomen |
DE102005062700A1 (de) | 2005-12-28 | 2007-07-05 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Buten aus technischen Mischungen von C4-Kohlenwasserstoffen |
DE102005062699A1 (de) | 2005-12-28 | 2007-09-06 | Oxeno Olefinchemie Gmbh | Verfahren zur Feinreinigung von 1-Buten-haltigen Strömen |
US8197674B2 (en) * | 2008-09-09 | 2012-06-12 | Lummus Technology Inc. | Thioetherification processes for the removal of mercaptans from gas streams |
CN101885660B (zh) | 2009-05-13 | 2013-07-31 | 中国石油化工股份有限公司 | 碳四烃催化分离异丁烯和丁烯-2的方法 |
DE102010030990A1 (de) | 2010-07-06 | 2012-01-12 | Evonik Oxeno Gmbh | Verfahren zur selektiven Hydrierung von mehrfach ungesättigten Kohlenwasserstoffen in olefinhaltigen Kohlenwasserstoffgemischen |
DE102012212316A1 (de) | 2012-07-13 | 2014-01-16 | Evonik Industries Ag | Schwefeladsoption vor Oligomerisierungsanlagen |
-
2012
- 2012-07-13 DE DE102012212317.2A patent/DE102012212317A1/de not_active Withdrawn
-
2013
- 2013-05-31 MY MYPI2013001991A patent/MY160118A/en unknown
- 2013-06-25 EP EP13734699.5A patent/EP2872484B1/de active Active
- 2013-06-25 US US14/414,540 patent/US9260386B2/en active Active
- 2013-06-25 CA CA2878983A patent/CA2878983C/en active Active
- 2013-06-25 JP JP2015520884A patent/JP6095776B2/ja active Active
- 2013-06-25 BR BR112015000737-6A patent/BR112015000737B1/pt active IP Right Grant
- 2013-06-25 WO PCT/EP2013/063300 patent/WO2014009148A1/de active Application Filing
- 2013-06-25 PL PL13734699T patent/PL2872484T3/pl unknown
- 2013-06-25 KR KR1020157003870A patent/KR102009548B1/ko active IP Right Grant
- 2013-06-25 RU RU2015104808A patent/RU2628085C2/ru active
- 2013-06-25 CN CN201380043667.3A patent/CN104583180B/zh active Active
- 2013-06-25 IN IN745DEN2015 patent/IN2015DN00745A/en unknown
- 2013-06-25 ES ES13734699.5T patent/ES2690058T3/es active Active
- 2013-06-25 MX MX2015000363A patent/MX362867B/es active IP Right Grant
- 2013-07-10 TW TW102124746A patent/TWI588122B/zh active
- 2013-07-12 AR ARP130102484A patent/AR092028A1/es active IP Right Grant
-
2015
- 2015-02-11 ZA ZA2015/00965A patent/ZA201500965B/en unknown
Also Published As
Publication number | Publication date |
---|---|
EP2872484A1 (de) | 2015-05-20 |
ZA201500965B (en) | 2016-01-27 |
TW201420557A (zh) | 2014-06-01 |
IN2015DN00745A (es) | 2015-07-10 |
PL2872484T3 (pl) | 2019-01-31 |
US20150166475A1 (en) | 2015-06-18 |
RU2015104808A (ru) | 2016-09-10 |
CA2878983A1 (en) | 2014-01-16 |
MY160118A (en) | 2017-02-28 |
BR112015000737B1 (pt) | 2020-11-10 |
KR20150032580A (ko) | 2015-03-26 |
EP2872484B1 (de) | 2018-08-08 |
BR112015000737A2 (pt) | 2017-06-27 |
CN104583180B (zh) | 2017-05-17 |
CN104583180A (zh) | 2015-04-29 |
US9260386B2 (en) | 2016-02-16 |
DE102012212317A1 (de) | 2014-01-16 |
WO2014009148A1 (de) | 2014-01-16 |
ES2690058T3 (es) | 2018-11-19 |
AR092028A1 (es) | 2015-03-18 |
MX2015000363A (es) | 2015-04-14 |
CA2878983C (en) | 2017-01-17 |
TWI588122B (zh) | 2017-06-21 |
KR102009548B1 (ko) | 2019-08-09 |
RU2628085C2 (ru) | 2017-08-14 |
JP6095776B2 (ja) | 2017-03-15 |
JP2015525750A (ja) | 2015-09-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
MX2015000363A (es) | Tioeterificacion de mercaptanos en mezclas de hidrocarburos c4. | |
AU2015243014B2 (en) | Fischer-tropsch process in a microchannel reactor | |
WO2015081122A3 (en) | Reactors and systems for oxidative coupling of methane | |
MY173214A (en) | Natural gas processing and systems cross-reference | |
MX2015010737A (es) | Procesos de polietileno y sus composiciones. | |
PH12014501550A1 (en) | Process and system for generating synthesis gas | |
MX2017004996A (es) | Metodos para conversion de etanol a hidrocarburos inferiores funcionalizados e hidrocarburos de corriente abajo. | |
MY171520A (en) | Process for converting hydrocarbon feeds by thermal steamcracking | |
WO2012050748A3 (en) | Processes for transalkylating aromatic hydrocarbons | |
EA201690133A1 (ru) | Способ крекинга углеводородного сырья в установке парового крекинга | |
MX2018009385A (es) | Metodos de produccion de carbono e hidrogeno a partir de gas natural y otros hidrocarburos. | |
WO2013043287A3 (en) | Hydrocarbon conversion process | |
BR112016010838A8 (pt) | métodos para controlar propriedades de polímero | |
PH12015500279B1 (en) | Process for preparing olefins by thermal steamcracking | |
WO2014058663A8 (en) | Polymerization process | |
IN2013MU04116A (es) | ||
MY183920A (en) | Process for co-oligomerization of olefins | |
MX2017009129A (es) | Proceso para convertir metanol a hidrocarburos adecuados para el uso como gasolina o componente de mezcla. | |
WO2014035919A3 (en) | Transport of dissolved species through a barrier | |
WO2012050749A3 (en) | Processes for transalkylating aromatic hydrocarbons | |
MX2023010522A (es) | Proceso para deshidrogenacion catalitica. | |
MY173217A (en) | Hydroisomerization catalysts based on fe containing molecular sieves | |
MX350643B (es) | Procedimiento para la produccion de acetato de vinilo. | |
WO2012099672A3 (en) | Hydrocarbon conversion process | |
WO2014184287A3 (en) | Process for converting a solid biomass material |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
GB | Transfer or rights |
Owner name: EVONIK DEGUSSA GMBH.* |
|
FG | Grant or registration |