CN104307019A - Plant extract deodorizer for removing harmful gases - Google Patents
Plant extract deodorizer for removing harmful gases Download PDFInfo
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- CN104307019A CN104307019A CN201410605716.4A CN201410605716A CN104307019A CN 104307019 A CN104307019 A CN 104307019A CN 201410605716 A CN201410605716 A CN 201410605716A CN 104307019 A CN104307019 A CN 104307019A
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Abstract
The invention discloses a plant extract deodorizer for removing harmful gases. The plant extract deodorizer comprises the following components in percentage by mass: 35-50% of plant extract, 1-2.5% of a stabilizer, and the balance of deionized water. The plant extract deodorizer for removing harmful gases can be used after being diluted by water, the amount of which is 1000 times than that of the plant extract deodorizer, can rapidly reduce the concentrations of harmful gases during the removal process of hydrogen sulfide, ammonia, methyl mercaptan and volatile organic gases, can eliminate the odor and peculiar smell brought by the harmful gases, and meanwhile, further has the effects of sterilization and bacteriostasis.
Description
Technical field
The present invention relates to municipal administration, industrial waste gas processing technology field, being specially a kind of vegetables extractive type deodorant agent for removing harmful gas.
Background technology
Along with the raising of living standards of the people, the expansion of economical production activity, the harm of harmful gas gets more and more, and is also more and more taken seriously.Harmful gas refers to and has a negative impact to the health of human or animal, though in other words on enter and the health of animal without impact, human or animal is felt under the weather, affects the gas of human or animal's comfort level.As NH
3, H
2s and volatile organic gas.Harmful gas is usually with foul smelling or abnormal flavour, and the occasion more often producing harmful gas has municipal garbage transfer, garbage loading embeading, dumping, public lavatory, sewage pumping station, municipal sewage plant, sludge treating block, plant, industrial undertaking's Production Regional, industrial waste processing unit, Industrial Wastewater Treatment unit, industrial sludge processing unit etc., but also there are Liao hotel building at present, or in domestic environment, occur the situation of high concentration harmful gas.Harmful gas can be divided into five classes by its composition: (1) sulfur-containing compound, as H
2s, SO
2, mercaptan etc.; (2) nitrogen-containing compound, as ammonia, amine, indole etc.; (3) halogen and derivant, as chlorine, halogenated hydrocarbons etc.; (4) hydro carbons and aromatic hydrocarbon; (5) oxygen-bearing organic matter, as alcohol, phenol, aldehyde, ketone etc.
Plant extract is applied in industry-by-industry very early, wherein mainly contains alkaloid, flavonoid, organic acid, plants essential oil etc.Phenolic hydroxyl group Numerous on their molecular structure, each construction unit is made up of multi-ring fragrant core and active function groups, its active function groups comprises: phenolic hydroxyl group, hydroxyl, carboxyl etc., there is rapid-action performance for the most Toxic in volatile organic matter and ozone, ammonia etc., be translated into harmless object.
Plants essential oil is the large class of one in natural plant extracts, and plants essential oil is polyphenols, the plants essential oil class material used preferably is had to the plant extract of hydroquinone and adjacent diphenol structure in the present invention.The activity of this kind of material is stronger.
Plants essential oil class material also can with protein generation association reaction, therefore the antibacterial in air is had and necessarily kills and inhibitory action.When vegetables extractive type deodorant agent becomes small drop by atomizer, just can be adsorbed onto the harmful gas molecule in air, fast various reaction occurs at normal temperatures, generate tasteless nontoxic molecule, thus reach the object removing harmful gas.
Vegetables extractive type deodorant agent has following features in removal harmful gas: 1. high efficiency.Under equal consumption, its treatment effeciency is apparently higher than traditional chemosorbent.2. safety non-toxic.Through strict test and a large amount of facts have proved, it is harmless, nontoxic to human body and animal, can not cause skin or respiratory system allergy, can not cause various untoward reaction.3. non-secondary pollution.Vegetables extractive type deodorant agent is organic principle, has biodegradability, namely can degrade voluntarily, thus can not bring secondary pollution.4. of many uses, effect is unique.Vegetables extractive type deodorant agent can be used for the purification of air in the places such as hotel, hotel, station, City Hall, meeting room and office; More be usually used in the Deodor in the places such as all types of factory, soot, sewage treatment plant, dung yard, slaughterhouse, food factory; Also can be used for the odor purification in the civilian place such as family, automobile.5. injected volume is relatively few.More than 1000 times can be diluted when vegetables extractive type deodorant agent uses, just can realize the purification of large area air.
Summary of the invention
The object of the invention is to the present invention and aim to provide a kind of vegetables extractive type deodorant agent for removing harmful gas, more than 1000 times can be diluted with removing hydrogen sulfide, ammonia, methanthiol, volatile organic gas, the concentration of quick these harmful gass of reduction, eliminates the stench abnormal flavour that it brings, also has the effect of bactericidal simultaneously.
For removing a vegetables extractive type deodorant agent for harmful gas, mixed by the raw material of following mass percent:
1) plant extract of 35-50%, comprising 5-9% plant flavonoids material, 5-7% plant organic acid substance and 20-35% plants essential oil class material;
2) 1-2.5% stabilizing agent, wherein comprises 0.5-1% surfactant, 0.2-0.6% acid-base modifier, 0.2-0.6% emulsifying agent, 0.1-0.3 fixastive;
3) all the other are supplied with water, and water used is deionized water.
Described plant extract can be from fruit, the root of vegetable and these plants of Chinese herbal medicine, leaf, flower and fruit parts.Described is Herba Apii graveolentis aglycon containing plant flavonoids material, Radix Scutellariae flavin, Tangeretin, Quercetin, catechin, Dai, anthocyanidin, fragrant glycosides, hesperidin, quercimentin, green tea polyphenol, pattern glucosides, pattern thuja acid wherein one or both;
Described containing plant organic acid substance for being selected from citric acid, lactic acid, malic acid, oxalic acid, caffeic acid, one or both of chlorogenic acid;
Described containing plants essential oil class material for being selected from Oleum Camphora, Cortex Cinnamomi leaf oil, Cedar oil, Oleum menthae, Eucalyptus oil, citronella oil, Fructus Citri Limoniae oil, oil of rosemary, three kinds in Oleum Menthae Rotundifoliae or five kinds;
Described surfactant is the one in sorbitan oleate, sucrose fatty acid ester, alkyl polyglucoside surfactant;
Described acid-base modifier is potassium carbonate, sodium carbonate, the one in sodium bicarbonate;
Described emulsifying agent is one or both in fatty acid glyceride, glycerol citric acid fatty acid ester, methyl glycol fatty acid ester;
Described fixastive is one or both in vetiver oil, patchouli oil, Oleum Santali albi, orris oil.
The above-mentioned vegetables extractive type deodorant agent for removing harmful gas, more than 1000 times can be diluted by common atomizer in the municipal garbage transfer often producing harmful gas, garbage loading embeading, dumping, public lavatory, sewage pumping station, municipal sewage plant, sludge treating block, plant, industrial undertaking's Production Regional, industrial waste processing unit, Industrial Wastewater Treatment unit, the places such as industrial sludge processing unit use, remove hydrogen sulfide, ammonia, methanthiol, volatile organic gas, the concentration of quick these harmful gass of reduction, eliminate the stench abnormal flavour that it brings, also there is the effect of bactericidal simultaneously.Can adjust sprinkling frequency according to the concentration of harmful gas and deenergized period during concrete use, the frequency of recommendation is at interval of spray in 2 minutes 15 seconds, can reduce harmful gas concentration rapidly.Spray 15 seconds to hydrogen sulfide, the clearance of Ammonia more than 95%, to the clearance of volatile organic matter more than 50%.
Mode at present for harmful gas process is mainly: Physical, chemical neutralization method, bioanalysis, synthetic method etc.What Physical was multiplex is non-thermal plasma trap, and equipment investment is higher, is subject to processing gas quantitative limitation.Chemical neutralization method mostly is the mode of soda acid medicament washing, also needs the equipment of specialty, there is potential safety hazard, and not good to volatile organic gas treatment effect.Bioanalysis needs professional equipment, and process large-minded, operating cost is low, but can not thoroughly solve volatile organic waste gas.Can maximize favourable factors and minimize unfavourable ones in conjunction with above three kinds or two kinds of methods synthetic method together, but also have problems in the removal and running in control of volatile organic waste gas.
The present invention has the following advantages for the vegetables extractive type deodorant agent and above four kinds of Measures compare of removing harmful gas:
1. be mainly natural plant extracts and water, to human body, animal, environment is nontoxic, can be used in confined space or have the region of the mankind or animal activity, not by the restriction of place to use;
2. can fast and harmful gas react, reduce harmful gas concentration, reduce all kinds of injury and loss;
3. natural plant extracts carries plant fragrance, also eliminates stink abnormal flavour while purifying air;
4. natural plant extracts is for tool adsorptions such as the virus in air, various bacteria, fungus, yeast, so can sterilize, antibacterial;
5. instructions for use is simple, and easily operate, using dosage can adjust flexibly, and cost is easy to control, and does not limit, does not produce secondary pollution, environmental protection by tolerance.
The mechanism of action of the present invention is:
Vegetables extractive type deodorant agent for removing harmful gas provided by the present invention, principle active component is wherein natural plant extracts.Organic acid wherein, flavonoids and plants essential oil are all polyphenol substances.They, all with a large amount of phenolic hydroxyl group functional group, have characteristic and the reproducibility of very strong phenol, therefore very fast in the response speed with volatile organic matter.
Harmful gas molecule is dispersed in the natural plant extracts deodorizer drop absorption in space, following reaction occurs at normal temperatures, generates tasteless nontoxic molecule:
Alkali reaction.Vegetables extractive type deodorant agent shows as alkalescence by ph regulator, and it can react with hydrogen sulfide, hydrocyanic acid radical ion, ammonia equimolecular.
Catalytic oxidation.As hydrogen sulfide, can not react with the oxygen in air in the ordinary course of things, but under the catalytic action of natural plant extracts deodorizer, can react with the oxygen in air.
Lewis acid alkali reaction.In organic chemistry, molecule or the atomic group that can absorb electron cloud are called lewis acid, and in the compound of organic sulfur, the skin of sulphur atom has unoccupied orbital, can accept external electron cloud, and the compound of this kind of organic sulfur therefore can be claimed to be lewis acid.On the contrary, the molecule of electron cloud or atomic group can be provided to be called lewis base.Generally electronegative atomic group, nitrogenous Organic substance belong to lewis base.Acid-base neutralization reaction can be there is in both.
Redox reaction.Such as, formaldehyde has oxidisability, and the effective molecule had in vegetables extractive type deodorant agent has reproducibility, and they can directly react.
Natural plant essential oils has resistance of wide spectrum (comprising the suppression to filamentous fungi, yeast, antibacterial, virus) to microorganism.Its mechanism of action be protein high binding capacity, by with the metabolism of cell membrane Binding change microorganism and to coefficient results of many factors such as the chelations of metal.
After vegetables extractive type deodorant dilution agent in the present invention through the liquid-drop diameter of atomization at 0.04mm, its surface energy can reach 1/3 and 1/2 of some organic compound bond energys, at this moment can destroy the key in harmful gas molecule, makes that their are unstable, easily decomposes.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail and completely:
Embodiment 1
Prepare following raw materials according:
1) tea polyphenols 70g
2) chlorogenic acid 50g
3) Cypress ethereal oil, Peppermint essential oil, each 100g of eucalyptus oil
4) sorbitan oleate 7g
5) potassium carbonate 6g
6) glycerine fatty acid fat 5g
7) Oleum Santali albi 3g
8) deionized water 559g
First by 5) potassium carbonate and 8) deionized water mixes, and adds 1 successively), 2), 3), 4), 6), 7), then continuous stirring 1 hour.
Embodiment 2
Prepare following raw materials according:
1) grape pip procyanidin 80g
2) chlorogenic acid 50g
3) Camphora quintessence oil 80g, oil of Cymbopogon winterianus 130g, Fructus Citri Limoniae quintessence oil 110g
4) APG 10g
5) sodium bicarbonate 5g
6) glycerine fatty acid fat 5g
7) patchouli oil 3g
8) deionized water 527g
First by 5) sodium bicarbonate and 8) deionized water mixes, and adds 1 successively), 2), 3), 4), 6), 7), then continuous stirring 1 hour.
Embodiment 3
1) glucoside hesperidin 75g
2) citric acid 50g
3) oil of Cymbopogon winterianus 100g, eucalyptus oil 90g, Fructus Citri Limoniae quintessence oil 120g
4) APG 10g
5) sodium bicarbonate 4g
6) glycerine fatty acid fat 5g
7) patchouli oil 3g
8) deionized water 543g
First by 5) sodium bicarbonate and 8) deionized water mixes, and adds 1 successively), 2), 3), 4), 6), 7), then continuous stirring 1 hour.
Embodiment 4
1) catechin 60g
2) chlorogenic acid 70g
3) basyleaves quintessence oil, Cypress ethereal oil, Peppermint essential oil, oil of Cymbopogon winterianus, each 70g of Fructus Citri Limoniae quintessence oil
4) sorbitan oleate 8g
5) sodium bicarbonate 5g
6) glycerine fatty acid fat 6g
7) Oleum Santali albi 3g
8) deionized water 498g
First by 5) sodium bicarbonate and 8) deionized water mixes, and adds 1 successively), 2), 3), 4), 6), 7), then continuous stirring 1 hour.
Embodiment 5
After embodiment 1 vegetables extractive type deodorant dilution agent 1000 times, atomizer is used to spray 20 seconds at the waste gas confined space gathered.The data of the volatile organic matter concentration (VOC) detected are table 1.
Table 1
As shown in table 1, when VOC concentration is at 260ppm, only spray 20 seconds, clearance just can be reached for 53.8%, illustrates that this vegetables extractive type deodorant agent is fast to the removal speed of VCO, Be very effective.
Embodiment 6
After embodiment 2 vegetables extractive type deodorant dilution agent 1000 times, atomizer is used to spray 15 seconds at the waste gas confined space gathered.The hydrogen sulfide detected and the data of ammonia are table 2.
Table 2
As shown in table 2, in confined space, the concentration of hydrogen sulfide and ammonia is all higher, after spraying vegetables extractive type deodorant agent in 15 seconds, harmful gas concentration declines rapidly, clearance clearance all reaches more than 95%, and illustrate that this vegetables extractive type deodorant agent is to hydrogen sulfide, the removal of ammonia is faster and better.
Above-described embodiment is interpreted as only being not used in for illustration of the present invention limiting the scope of the invention.After the content of having read the present invention's record, those skilled in the art can make various changes or modifications the present invention, and these equivalence changes and modification fall into the scope of the claims in the present invention equally.
Claims (8)
1. for removing a vegetables extractive type deodorant agent for harmful gas, it is characterized in that, being mixed by the component of following mass percent:
1) plant extract of 35-50%, comprising 5-9% plant flavonoids material, 5-7% plant organic acid substance and 20-35% plants essential oil class material;
2) 1-2.5% stabilizing agent, wherein comprises 0.5-1% surfactant, 0.2-0.6% acid-base modifier, 0.2-0.6% emulsifying agent, 0.1-0.3 fixastive;
3) all the other are deionized water.
2. a kind of vegetables extractive type deodorant agent for removing harmful gas according to claim 1, it is characterized in that, described plant flavonoids material is Herba Apii graveolentis aglycon, Radix Scutellariae flavin, Tangeretin, Quercetin, catechin, Dai, anthocyanidin, fragrant glycosides, hesperidin, quercimentin, green tea polyphenol, pattern glucosides, pattern thuja acid wherein one or both.
3. a kind of vegetables extractive type deodorant agent for removing harmful gas according to claim 1, it is characterized in that, described plant organic acid substance is citric acid, lactic acid, malic acid, oxalic acid, caffeic acid, one or both of chlorogenic acid.
4. a kind of vegetables extractive type deodorant agent for removing harmful gas according to claim 1, is characterized in that, described plants essential oil class material is Oleum Camphora, Cortex Cinnamomi leaf oil, Cedar oil, Oleum menthae, Eucalyptus oil, citronella oil, Fructus Citri Limoniae oil, oil of rosemary, three kinds in Oleum Menthae Rotundifoliae or five kinds.
5. a kind of vegetables extractive type deodorant agent for removing harmful gas according to claim 1, it is characterized in that, described surfactant is the one in sorbitan oleate, sucrose fatty acid ester, alkyl polyglucoside surfactant.
6. a kind of vegetables extractive type deodorant agent for removing harmful gas according to claim 1, it is characterized in that, described acid-base modifier is potassium carbonate, sodium carbonate, the one in sodium bicarbonate.
7. a kind of vegetables extractive type deodorant agent for removing harmful gas according to claim 1, is characterized in that, described emulsifying agent is one or both in fatty acid glyceride, glycerol citric acid fatty acid ester, methyl glycol fatty acid ester.
8. a kind of vegetables extractive type deodorant agent for removing harmful gas according to claim 1, is characterized in that, described fixastive is one or both in vetiver oil, patchouli oil, Oleum Santali albi, orris oil.
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