JPH0225623B2 - - Google Patents
Info
- Publication number
- JPH0225623B2 JPH0225623B2 JP59226202A JP22620284A JPH0225623B2 JP H0225623 B2 JPH0225623 B2 JP H0225623B2 JP 59226202 A JP59226202 A JP 59226202A JP 22620284 A JP22620284 A JP 22620284A JP H0225623 B2 JPH0225623 B2 JP H0225623B2
- Authority
- JP
- Japan
- Prior art keywords
- deodorant
- odor
- water
- ammonia
- deodorizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002781 deodorant agent Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 241000196324 Embryophyta Species 0.000 claims description 5
- 235000007173 Abies balsamea Nutrition 0.000 claims description 4
- 244000283070 Abies balsamea Species 0.000 claims description 4
- 240000007019 Oxalis corniculata Species 0.000 claims description 4
- 235000016499 Oxalis corniculata Nutrition 0.000 claims description 4
- 241001070941 Castanea Species 0.000 claims description 3
- 235000014036 Castanea Nutrition 0.000 claims description 3
- 240000000161 Lagerstroemia indica Species 0.000 claims description 3
- 235000000283 Lagerstroemia parviflora Nutrition 0.000 claims description 3
- 240000007695 Nandina domestica Species 0.000 claims description 3
- 235000000405 Pinus densiflora Nutrition 0.000 claims description 3
- 240000008670 Pinus densiflora Species 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 235000002020 sage Nutrition 0.000 claims description 2
- 235000019645 odor Nutrition 0.000 description 15
- 238000000034 method Methods 0.000 description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- 239000000284 extract Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000004332 deodorization Methods 0.000 description 6
- 230000001877 deodorizing effect Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 230000001953 sensory effect Effects 0.000 description 5
- 239000012046 mixed solvent Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000004445 quantitative analysis Methods 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- 240000001548 Camellia japonica Species 0.000 description 1
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 241001062872 Cleyera japonica Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000018597 common camellia Nutrition 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 235000019640 taste Nutrition 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Description
〔技術分野〕
この発明は、生活環境汚染要因の一つである臭
気の除去に関わる技術分野である。
〔背景技術〕
近年生活環境の見直しが進むにつれ、生活環境
における臭気も、生活環境汚染要因の1つとして
その除去に関わる技術が注目されてきている。臭
気を除去するには、芳香性物質のマスキング効果
による感覚的消臭法、換気や臭気物質の吸収吸着
による物理的消臭法、中和、付加、縮合、酸化等
の化学反応により臭気物質を無臭化する化学的消
臭法及び、臭気物質を産生する微生物を滅殺し臭
気の発生を阻止する生物的消臭法がある。
感覚的消臭法は、芳香性物質により臭気を除去
し得ても、臭気物質を除去し得ず、又芳香といえ
ども、個人の好みにとつては不快と感じる場合が
あるという欠点を有する。
物理的消臭法は、古くから汎用されているが、
換気では装置化が必要であること、吸収吸着剤で
は、吸収吸着された臭気物質が、温度上昇によつ
て再放出されるという欠点を有する。
〔発明の目的〕
この発明は、人間に不快さを生じせしめる臭気
の1つであるアンモニア臭を効果的に除去する性
能を有する消臭剤を提供することをその目的とす
るものである。
〔発明の開示〕
この発明は、カタバミ、ツガ、サルスベリ、ナ
ンテン、クリ、サネカズラ、ミズメ、ニシキマ
ツ、イチヨウから成る群の中の植物体より、水あ
るいは親水性有機溶媒単独で、あるいはそれらを
組み合わせた溶剤で抽出を行ない、抽出物あるい
はそれらの抽出物を組み合わせたものが特にアン
モニアに対して消臭効果を有する消臭剤であるこ
とを特徴とするものである。
植物体の使用部位は特に限定されないが、葉、
樹皮、心材、果実が適当である。
抽出時に使用する溶媒は、アルコール類、ケト
ン類といつた親水性有機溶媒及び水単独で、ある
いはそれらの混合溶媒であればよいが水とメタノ
ール混合溶媒が望ましい。
消臭剤として使用する際には、液体、個体状の
いずれの形状で使用してもよく、特に限定される
ものではないが、たとえば水溶液として使用する
場合、0.1〜1%の濃度範囲で使用すればよい。
つぎに実施例を挙げて説明する。
〔実施例 1〜10〕
カタバミ、ツガ、サルスベリ、ナンテン、ク
リ、サネカズラ、ミズメ、ニシキマツ、イチヨウ
の葉を採取し、おのおのの葉を粉砕後、水・メタ
ノール混合溶媒で常温で1晩、80℃で5時間抽出
し、抽出液を濃縮し粉末状の抽出物をおのおのの
植物について得た。抽出物を各々1%の溶液と調
整し、消臭剤とした。
〔実施例 11〕
カタバミ、ツガの1%溶液を各々同部づつ混合
し、消臭剤とした。
以上の操作によつて得られた消臭剤のアンモニ
アに対する消臭評価を官能法及び定量法によつて
行なつた。
官能法は、希薄アンモニア溶液に消臭剤を一定
量添加した試料の臭気強度を10人のパネラーによ
つて6段階で評価した。その結果を第1表に示
す。
定量法は、希薄アンモニア溶液に消臭剤を一定
量添加後、直ちに密栓し振した後、ヘツドスペー
スガスをとり、ガスを水に溶解しそのアンモニア
量をネスラー法によつて比色定量し、消臭剤無添
加のものに対しての臭気残存率を求め、臭気除去
率を算出した。その結果を第2表に示す。
なお、ツバキ、サカキ、クスノキ、チヤノキ、
ゲツケイジユにつき、実施例1と同様にして抽出
液を得て、消臭効果を比較した。その結果を第3
表に示した。
[Technical Field] This invention is a technical field related to the removal of odor, which is one of the factors that pollute the living environment. [Background Art] As the living environment has been reconsidered in recent years, technologies related to the removal of odors from the living environment as one of the factors that pollute the living environment are attracting attention. To remove odors, there are sensory deodorization methods using the masking effect of aromatic substances, physical deodorization methods through ventilation and absorption and adsorption of odorous substances, and chemical reactions such as neutralization, addition, condensation, and oxidation. There are chemical deodorization methods that eliminate odor, and biological deodorization methods that kill odor-producing microorganisms and prevent the generation of odors. Sensory deodorization methods have the disadvantage that even though they can remove odors using aromatic substances, they cannot remove odorous substances, and even though they are fragrant, they may be unpleasant to individual tastes. . Physical deodorization methods have been widely used for a long time, but
Ventilation requires equipment, and absorbent adsorbents have the disadvantage that absorbed and adsorbed odorous substances are re-released as the temperature rises. [Object of the Invention] An object of the present invention is to provide a deodorant having the ability to effectively remove ammonia odor, which is one of the odors that cause discomfort to humans. [Disclosure of the Invention] The present invention relates to the use of plants in the group consisting of oxalis, hemlock, crape myrtle, nandina, chestnut, staghorn vine, mizume, Japanese pine, and staghorn, using water or a hydrophilic organic solvent alone, or a combination thereof. Extraction is performed with a solvent, and the extract or a combination of these extracts is a deodorizing agent that has a deodorizing effect, particularly against ammonia. The part of the plant used is not particularly limited, but leaves,
Bark, heartwood, and fruit are suitable. The solvent used during extraction may be a hydrophilic organic solvent such as an alcohol or a ketone, water alone, or a mixed solvent thereof, but preferably a mixed solvent of water and methanol. When used as a deodorant, it may be used in either liquid or solid form, and is not particularly limited; for example, when used as an aqueous solution, it may be used in a concentration range of 0.1 to 1%. do it. Next, an example will be given and explained. [Examples 1 to 10] Collect leaves of oxalis, hemlock, crape myrtles, nandina, chestnut, Japanese sage, Japanese pine, and staghorn. After crushing each leaf, soak in a water/methanol mixed solvent overnight at room temperature at 80°C. The extracts were extracted for 5 hours, and the extracts were concentrated to obtain powdered extracts for each plant. Each extract was prepared as a 1% solution and used as a deodorant. [Example 11] Equal parts of 1% solutions of oxalis and hemlock were mixed together to prepare a deodorant. The deodorizing agent obtained by the above procedure was evaluated for deodorizing ammonia using a sensory method and a quantitative method. In the sensory method, ten panelists evaluated the odor intensity of a sample prepared by adding a certain amount of deodorant to a dilute ammonia solution on a six-point scale. The results are shown in Table 1. The quantitative method involves adding a certain amount of deodorant to a dilute ammonia solution, immediately sealing the solution, shaking it, removing the headspace gas, dissolving the gas in water, and colorimetrically quantifying the amount of ammonia using the Nessler method. The odor residual rate was determined compared to that without the addition of deodorant, and the odor removal rate was calculated. The results are shown in Table 2. In addition, camellia, sakaki, camphor tree, tea tree,
Extracts of C. elegans were obtained in the same manner as in Example 1, and the deodorizing effects were compared. The result is the third
Shown in the table.
【表】【table】
【表】【table】
【表】【table】
【表】
註1 消臭効力官能評価は、6段階臭気強度法
を用いた。6段階臭気強度表示法[Table] Note 1: The 6-step odor intensity method was used for the sensory evaluation of deodorizing efficacy. 6-level odor intensity display method
この発明は、植物から得られる抽出成分を消臭
剤とすることを特徴とするもので、特にアンモニ
ア臭を除去する効果がある。
This invention is characterized by using an extracted component obtained from plants as a deodorant, and is particularly effective in removing ammonia odor.
Claims (1)
リ、サネカズラ、ミズメ、ニシキマツ、イチヨウ
からなる群の中の植物体より、水あるいは親水性
有機溶媒単独で、あるいはそれらを組み合わせた
溶媒で抽出したものであることを特徴とする消臭
剤。1. Extracted from plants in the group consisting of oxalis, hemlock, crape myrtle, nandina, chestnut, sage vine, mizume, Japanese pine, and staghorn, using water or a hydrophilic organic solvent alone, or a combination of these solvents. A deodorant featuring:
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59226202A JPS61103447A (en) | 1984-10-25 | 1984-10-25 | Deodorant |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59226202A JPS61103447A (en) | 1984-10-25 | 1984-10-25 | Deodorant |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS61103447A JPS61103447A (en) | 1986-05-21 |
JPH0225623B2 true JPH0225623B2 (en) | 1990-06-05 |
Family
ID=16841486
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59226202A Granted JPS61103447A (en) | 1984-10-25 | 1984-10-25 | Deodorant |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS61103447A (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61143065A (en) * | 1984-12-15 | 1986-06-30 | 松下電工株式会社 | Deodorant |
JPS6290167A (en) * | 1985-10-15 | 1987-04-24 | 松下電工株式会社 | Deodorant |
US5240699A (en) * | 1985-10-15 | 1993-08-31 | Matsushita Electric Works, Ltd. | Deodorant and filter using same, as well as method of producing the deodorant |
JPS6321061A (en) * | 1986-07-16 | 1988-01-28 | ダイセル化学工業株式会社 | Deodorant |
CA2428921A1 (en) * | 2000-11-28 | 2002-06-06 | Avon Products, Inc. | Anti-aging cosmetic composition and method of application |
JP2004307396A (en) | 2003-04-07 | 2004-11-04 | Kao Corp | Deodorant preparation |
WO2006011541A1 (en) * | 2004-07-29 | 2006-02-02 | Mitsubishi Paper Mills Limited | Air filter and air processing device using same |
JP5980512B2 (en) * | 2012-01-30 | 2016-08-31 | 学校法人東日本学園 | Body odor suppressor |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5366434A (en) * | 1976-11-26 | 1978-06-13 | Tanabe Seiyaku Co Ltd | Deodorant |
JPS5766757A (en) * | 1980-10-09 | 1982-04-23 | Shiraimatsu Shinyaku Co | Continuous deodorant using unglazed material as medium |
-
1984
- 1984-10-25 JP JP59226202A patent/JPS61103447A/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5366434A (en) * | 1976-11-26 | 1978-06-13 | Tanabe Seiyaku Co Ltd | Deodorant |
JPS5766757A (en) * | 1980-10-09 | 1982-04-23 | Shiraimatsu Shinyaku Co | Continuous deodorant using unglazed material as medium |
Also Published As
Publication number | Publication date |
---|---|
JPS61103447A (en) | 1986-05-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EXPY | Cancellation because of completion of term |