JPH0222669B2 - - Google Patents
Info
- Publication number
- JPH0222669B2 JPH0222669B2 JP59216994A JP21699484A JPH0222669B2 JP H0222669 B2 JPH0222669 B2 JP H0222669B2 JP 59216994 A JP59216994 A JP 59216994A JP 21699484 A JP21699484 A JP 21699484A JP H0222669 B2 JPH0222669 B2 JP H0222669B2
- Authority
- JP
- Japan
- Prior art keywords
- deodorant
- deodorizing
- japanese
- odors
- asparagus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002781 deodorant agent Substances 0.000 claims description 29
- 230000001877 deodorizing effect Effects 0.000 claims description 18
- 235000005340 Asparagus officinalis Nutrition 0.000 claims description 7
- 240000003296 Petasites japonicus Species 0.000 claims description 6
- 239000004480 active ingredient Substances 0.000 claims description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 5
- 241000588278 Osmanthus heterophyllus Species 0.000 claims description 5
- 235000010326 Osmanthus heterophyllus Nutrition 0.000 claims description 5
- 235000004338 Syringa vulgaris Nutrition 0.000 claims description 5
- 240000007313 Tilia cordata Species 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 244000003416 Asparagus officinalis Species 0.000 claims description 3
- 241000218691 Cupressaceae Species 0.000 claims description 3
- 241000555682 Forsythia x intermedia Species 0.000 claims 1
- 244000018633 Prunus armeniaca Species 0.000 claims 1
- 235000009827 Prunus armeniaca Nutrition 0.000 claims 1
- 244000297179 Syringa vulgaris Species 0.000 claims 1
- -1 apricot Chemical class 0.000 claims 1
- 235000019645 odor Nutrition 0.000 description 26
- 238000000034 method Methods 0.000 description 15
- 238000004332 deodorization Methods 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 230000009965 odorless effect Effects 0.000 description 6
- 244000024251 Aralia cordata Species 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 241000555712 Forsythia Species 0.000 description 4
- 241001092391 Sorbus Species 0.000 description 4
- 241001104043 Syringa Species 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 4
- 235000008345 mountainash Nutrition 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 235000003823 Petasites japonicus Nutrition 0.000 description 2
- 240000001142 Tilia japonica Species 0.000 description 2
- 235000017860 Tilia japonica Nutrition 0.000 description 2
- 235000001436 butterbur Nutrition 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 240000004731 Acer pseudoplatanus Species 0.000 description 1
- 235000002754 Acer pseudoplatanus Nutrition 0.000 description 1
- 235000014722 Aralia cordata Nutrition 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000565354 Fraxinus longicuspis Species 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 235000006485 Platanus occidentalis Nutrition 0.000 description 1
- 244000172533 Viola sororia Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000021028 berry Nutrition 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000010800 human waste Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000010806 kitchen waste Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 235000019640 taste Nutrition 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Description
〔技術分野〕
この発明は、悪臭や異臭を消す消臭剤に関す
る。
〔背景技術〕
一般に、悪臭や異臭としては、工場の排煙や廃
液、および煙草や屎尿、ならびに台所の厨芥等が
発生源となつており、その悪臭や異臭の種類も多
種多様である。特に、家庭内においては、冷暖房
装置の作動時には密室状態に保たれることが多い
ので、これらの悪臭異臭の対策が大きな問題とな
つてきている。
このような悪臭や異臭を消す方法には、大別し
て次の4つの方法がある。
感覚的消臭法…芳香性物質(香料等)によつ
て悪臭や異臭をマスクする方法。
物理的消臭法…換気・拡散によつて悪臭を希
釈,除去するか、あるいは活性炭などを利用し
て臭気を吸着させる方法。
化学的消臭法…悪臭や異臭成分と化学的に反
応(中和,付加,縮合,酸化等)させて無臭化
する方法。
生物的消臭法…腐敗を生起するバクテリアを
滅殺して、腐敗を防止し、悪臭の発生を阻止す
る方法。
の感覚的消臭法は、主に一般家庭で実施され
ている方法で、消臭剤自身の有する香気などによ
つて、悪臭や異臭を消臭するものである。しか
し、この方法では香気と臭気のバランスをとるこ
とが難しく、しかも、消臭剤の有する香気には人
の好みがあつて、時に嫌悪感を催させることがあ
り、一般的な消臭剤とは云い難い。の物理的方
法は広く使用されているが、装置化が必要であつ
たり、室温が変動したり、活性炭などでは悪臭や
異臭成分の吸着効果に持続性が無いという問題が
ある。また、化学的消臭法は、多種多様な悪臭
成分に対し、効果的に反応する物質の選定が極め
て困難であり、使用薬剤の取扱いに注意を要する
こともあつて、一般的ではない。さらに、の生
成物的消臭法も装置化が必要であり、効果の発現
が遅いという欠点があるなど、各消臭剤に各々一
長一短があるのが現状である。
このような現状に鑑み、発明者らは、それ自身
は無臭で、大がかりな設備も必要としない消臭剤
として、植物中の有効成分を用いることを案出
し、開発を進めた。その間において、対象とする
臭気によつて消臭効果にばらつきがあることが分
かつた。
〔発明の目的〕
この発明は、上のような事情に鑑みてなされた
ものであつて、それ自身は無臭であり、大がかり
な設備も必要としない消臭剤で、対象臭気を限定
し、それに対しては高い消臭効果を示す消臭剤を
提供することをその目的とする。
〔発明の開示〕
この発明は、メルカプタン類に対する消臭剤で
あつて、キリ,ライラツク,シナレンギヨウ,ヒ
イラギモクセイ,シナノキ,フキ,ツワブキ,カ
ナメモチ,ヤマナラシおよびアスパラガスからな
る群の少なくともひとつから抽出された抽出成分
を有効成分とすることを特徴とする消臭剤をその
要旨とする。
すなわち、この発明にかかる消臭剤は、キリ,
ライラツク,シナレンギヨウ,ヒイラギモクセ
イ,シナノキ,フキ,ツワブキ,カナメモチ,ヤ
マナラシ,およびアスパラガスからなる群の少な
くともひとつの、樹皮,心材,葉,茎および果実
などを、たとえば水あるいは親水性有機溶媒、あ
るいはそれらの組み合わせで抽出する等して得ら
れ、特にメカプタン類に対して消臭効果を有する
ものである。以下に、この発明を詳しく説明す
る。
この発明の消臭剤の原料としては、キリ,ライ
ラツク,シナレンギヨウ,ヒイラギモクセイ,シ
ナノキ,フキ,ツワブキ,カナメモチ,ヤマナラ
シおよびアスパラガスの、樹皮,心材,葉,茎お
よび果実等を使用することができる。
この発明において使用する抽出溶剤としては、
水および親水性有機溶剤、すなわちたとえば、メ
タノール,エタノール,プロパノール等のアルコ
ール類やアセトン,メチルエケトン等のケトン類
などを単独あるいは混合して用いる。
抽出方法は、たとえば水蒸気蒸留法を例にとる
と、前記の原料植物を水蒸気蒸留器にかけ、原料
中から有効成分以外の成分(香気成分)を除去し
て無臭化する。次に、原料残渣物を濾過器にかけ
て濾液を得る。この濾液中には消臭有効成分が含
まれている。したがつて、これを消臭剤としてそ
のまま用いてもよいし、もしくは濃縮して用いて
もよい。しかしながら、消臭成分の抽出法は、上
記の方法に限定されず、前述の熱水抽出後、濾過
して消臭有効成分が得られてもよい。
このようにして得られた消臭剤の使用態様につ
いては、とくに限定するものではないが、液剤、
スプレー型、あるいは担体への含浸,粉末,錠
剤,果粒剤への成型等、用途により多岐にわたつ
て使用されるものである。液状消臭剤として使用
する場合、消臭剤の有効濃度は0.25〜5%の範囲
である。当然のことながら、この範囲では濃度が
高いほど効果,持続性も大きいと言えるが、この
範囲を越えると消臭剤自体の臭いが出現し、消臭
剤としては、不向きとなる。
消臭液には、消臭液の飛散防止あるいは防腐剤
的な役割も加味して、通常、グリセリンやプロピ
レングリコールなどの多価アルコールが添加剤と
して使用される。
この消臭成分は固形状でも使用することができ
る。この場合は、上の消臭液を素焼陶土のような
多孔性(または浸透性)の無機物と混合し、消臭
成分を前記担体表面に吸着させ、これを容器等に
充填して使用したり、あるいは、ゼラチンと混合
して固形体で使用する等の方法がある。
このようにして製品化された消臭剤は、それ自
身無臭で、メルカプタン類の消臭に、有効かつ迅
速に寄与することができる。
以下、この発明をその実施例にもとづいて説明
する。
実施例 1
キリ,ライラツク,シナレンギヨウ,ヒイラギ
モクセイ,シナノキ,フキ,ツワブキ,カナメモ
チ,ヤマナラシの葉、シナレンギヨウの実および
アスパラガスの茎より水―メタノールの混合溶媒
を用いて、消臭有効成分を抽出した。これで1wt
%(以下、「%」と略)水溶液を作り消臭剤とし
た。
消臭剤の消臭効果をみるために、次のような評
価を行つた。すなわち、以下第1表に示す6段階
臭気レベルの内5に相当するメルカプタン類の水
溶液に、上記の消臭剤を一定量添加した。その臭
気を10人のパネラーに評価させた。比較例とし
て、消臭剤の代わりに水を同量添加した場合の臭
気も評価させた。結果は第2表に示す。
[Technical Field] This invention relates to a deodorant that eliminates bad odors and foreign odors. [Background Art] Generally, the sources of bad odors and strange odors are factory smoke and waste liquid, cigarettes, human waste, kitchen waste, etc., and there are a wide variety of types of bad odors and strange odors. Particularly in homes, where rooms are often kept closed when air-conditioning equipment is in operation, countermeasures against these foul odors have become a major problem. There are four ways to eliminate such bad odors and strange odors: Sensory deodorization method: A method of masking bad odors and foreign odors using aromatic substances (fragrances, etc.). Physical deodorization method: Diluting and removing bad odors through ventilation and diffusion, or using activated carbon to absorb odors. Chemical deodorization method: A method of chemically reacting (neutralization, addition, condensation, oxidation, etc.) with malodor and off-flavor components to make them odorless. Biological deodorization method: A method that kills bacteria that cause spoilage, prevents spoilage, and prevents the occurrence of bad odors. The sensory deodorization method is a method that is mainly practiced in ordinary households, and it uses the scent of the deodorant itself to eliminate bad odors and foreign odors. However, with this method, it is difficult to balance the scent and odor, and the scent of deodorants has different tastes and can sometimes make people feel disgusted. It's hard to say. Although this physical method is widely used, there are problems in that it requires equipment, that the room temperature fluctuates, and that activated carbon does not have a long-lasting adsorption effect on bad odors and off-flavor components. In addition, chemical deodorization methods are not common because it is extremely difficult to select substances that effectively react with a wide variety of malodorous components, and care must be taken in handling the chemicals used. Furthermore, the product-based deodorizing method also requires equipment, and has the drawbacks of slow onset of effects. At present, each deodorant has its own advantages and disadvantages. In view of this current situation, the inventors devised and proceeded with the development of a deodorant that is odorless itself and does not require large-scale equipment, using active ingredients found in plants. During this period, it was found that the deodorizing effect varied depending on the target odor. [Purpose of the invention] This invention was made in view of the above circumstances, and is a deodorizing agent that is odorless itself and does not require large-scale equipment. The purpose is to provide a deodorizing agent that exhibits a high deodorizing effect. [Disclosure of the Invention] The present invention provides a deodorant for mercaptans, which is a deodorizing agent extracted from at least one of the group consisting of thorn, lilac, Chinese forsythia, holly osmanthus, linden, Japanese butterbur, Japanese asparagus, Japanese violet, mountain ash, and asparagus. The gist of the invention is a deodorant characterized by having an extracted component as an active ingredient. That is, the deodorant according to the present invention has a sharp,
The bark, heartwood, leaves, stems, fruits, etc. of at least one of the group consisting of lilac, Chinese forsythia, holly osmanthus, linden, butterbur, Japanese linden, Japanese cypress, mountain ash, and asparagus, for example, with water or a hydrophilic organic solvent, or the like. It is obtained by extracting a combination of the following, and has a deodorizing effect particularly on mecaptans. This invention will be explained in detail below. As raw materials for the deodorant of the present invention, the bark, heartwood, leaves, stems, fruits, etc. of thorn, lilac, Chinese forsythia, holly osmanthus, linden, Japanese butterbur, Japanese linden, Japanese ash, mountain ash, asparagus, and asparagus can be used. . The extraction solvent used in this invention is
Water and a hydrophilic organic solvent, such as alcohols such as methanol, ethanol, and propanol, and ketones such as acetone and methyl etketone, are used alone or in combination. An example of an extraction method is steam distillation, in which the raw material plant is passed through a steam distiller to remove components other than the active ingredients (fragrant components) from the raw material to make it odorless. Next, the raw material residue is filtered to obtain a filtrate. This filtrate contains an effective deodorizing ingredient. Therefore, it may be used as a deodorant as it is, or it may be used after being concentrated. However, the method for extracting the deodorizing component is not limited to the above method, and the deodorizing active component may be obtained by filtration after the hot water extraction described above. The manner of use of the deodorizer obtained in this way is not particularly limited, but liquid,
It is used in a wide variety of ways depending on the application, such as in a spray form, impregnated into a carrier, and molded into powder, tablets, and granules. When used as a liquid deodorant, the effective concentration of the deodorant ranges from 0.25 to 5%. Naturally, within this range, it can be said that the higher the concentration, the greater the effect and sustainability, but if it exceeds this range, the odor of the deodorant itself will appear, making it unsuitable as a deodorant. Polyhydric alcohols such as glycerin and propylene glycol are usually used as additives in deodorant liquids to prevent the deodorant from scattering and to act as a preservative. This deodorizing component can also be used in solid form. In this case, the above deodorizing liquid may be mixed with a porous (or permeable) inorganic material such as unglazed china clay, the deodorizing component is adsorbed onto the surface of the carrier, and this is used by filling it into a container, etc. Alternatively, there are methods such as mixing it with gelatin and using it in a solid form. The deodorant produced in this way is itself odorless and can effectively and quickly contribute to the deodorization of mercaptans. Hereinafter, this invention will be explained based on its embodiments. Example 1 Deodorizing active ingredients were extracted from the leaves of thorn, lilac, forsythia, holly osmanthus, linden, butterbur, Japanese trumpet, Japanese cypress, mountain ash leaves, sycamore berries, and asparagus stems using a mixed solvent of water and methanol. . Now 1wt
% (hereinafter abbreviated as "%") aqueous solution was made and used as a deodorant. In order to examine the deodorizing effect of the deodorant, the following evaluation was performed. That is, a certain amount of the above deodorant was added to an aqueous solution of mercaptans corresponding to 5 of the 6 odor levels shown in Table 1 below. Ten panelists evaluated the odor. As a comparative example, the odor was also evaluated when the same amount of water was added instead of the deodorant. The results are shown in Table 2.
【表】【table】
【表】【table】
【表】
表からわかるように、消臭剤を添加することに
よつて臭気レベルは著しく低下した。
実施例 2
実施例1で得られた1%水溶液の消臭剤100μ
を10ppmエチルメルカプタン水溶液200μの
入つた密栓付ガラス容器に添加し、1分間震盪し
たあと、容器のヘツドスペースより注射器でガス
を2c.c.採取して、ガスクロマトグラフイによつ
て、エチルメルカプタンの濃度を測定した。検出
器はFPD(炎光光度検出器)を使用した。
消臭効果をみるために消臭剤添加前についても
同様に測定し、消臭剤添加前後の濃度比より臭気
除去率を求めた。比較のために、前記した本願発
明の原料植物群以外の植物についても、実施例と
同様の方法で消臭剤を製造して臭気除去率を求め
た。これらの結果は第3表に示す。[Table] As can be seen from the table, the odor level was significantly reduced by adding the deodorant. Example 2 100μ of the 1% aqueous deodorant solution obtained in Example 1
was added to a sealed glass container containing 200μ of a 10ppm ethyl mercaptan aqueous solution, and after shaking for 1 minute, 2 c.c. of gas was collected from the head space of the container with a syringe, and the ethyl mercaptan was determined by gas chromatography. The concentration was measured. The detector used was FPD (Flame Photometric Detector). In order to examine the deodorizing effect, measurements were made in the same manner before the addition of the deodorant, and the odor removal rate was determined from the concentration ratio before and after the addition of the deodorant. For comparison, deodorants were produced using plants other than the raw material plant groups of the present invention described above in the same manner as in the examples, and odor removal rates were determined. These results are shown in Table 3.
【表】【table】
【表】
実施例 3
実施例1で得られたキリ,ライラツク,シナレ
ンギヨウの1%水溶液を同量ずつ混合した液を、
実施例2同様、FPDを用いたガスクロマトグラ
フイに付した。結果を第4表に示す。[Table] Example 3 A liquid obtained by mixing equal amounts of 1% aqueous solutions of Kiri, Lilac, and Shinarengiyo obtained in Example 1,
As in Example 2, it was subjected to gas chromatography using FPD. The results are shown in Table 4.
以上に見たように、この発明では、前記特定の
植物体を消臭剤原料とし、このような原料から抽
出された成分を有効成分として用いているので、
消臭剤自体は無臭で、人体に対して危険性がな
く、安価で、あらゆる形態で使用できる、メルカ
プタン類消臭用として特に有効な消臭剤を得るこ
とができる。
As seen above, in this invention, the specific plant is used as a deodorant raw material, and the ingredients extracted from such raw material are used as active ingredients.
The deodorant itself is odorless, poses no danger to the human body, is inexpensive, can be used in any form, and is particularly effective for deodorizing mercaptans.
Claims (1)
リ,ライラツク,シナレンギヨウ,ヒイラギモク
セイ,シナノキ,フキ,ツワブキ,カナメモチ,
ヤマナラシおよびアスパラガスからなる群の少な
くともひとつから抽出された抽出成分を有効成分
とすることを特徴とする消臭剤。1 Deodorizing agents against mercaptans, such as apricot, lilac, Chinese forsythia, holly osmanthus, linden, Japanese butterbur, Japanese butterbur, Japanese cypress,
A deodorant characterized in that the active ingredient is an extracted component extracted from at least one of the group consisting of asparagus and asparagus.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59216994A JPS6194660A (en) | 1984-10-15 | 1984-10-15 | Deodorant |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59216994A JPS6194660A (en) | 1984-10-15 | 1984-10-15 | Deodorant |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6194660A JPS6194660A (en) | 1986-05-13 |
JPH0222669B2 true JPH0222669B2 (en) | 1990-05-21 |
Family
ID=16697143
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59216994A Granted JPS6194660A (en) | 1984-10-15 | 1984-10-15 | Deodorant |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6194660A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH046775U (en) * | 1990-04-28 | 1992-01-22 |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61193665A (en) * | 1985-02-25 | 1986-08-28 | 松下電工株式会社 | Deodorant |
US5240699A (en) * | 1985-10-15 | 1993-08-31 | Matsushita Electric Works, Ltd. | Deodorant and filter using same, as well as method of producing the deodorant |
JPS6290167A (en) * | 1985-10-15 | 1987-04-24 | 松下電工株式会社 | Deodorant |
JPH0282979A (en) * | 1988-09-19 | 1990-03-23 | Inabata Koryo Kk | Deodorant |
GB2312622A (en) * | 1996-05-03 | 1997-11-05 | Haitai Confectionery Company L | Deodorizing agents containing plant extracts as the effective ingredient |
JP4778813B2 (en) * | 2006-03-07 | 2011-09-21 | 株式会社ロッテ | Methioninase inhibitor |
CN107375757A (en) * | 2017-08-30 | 2017-11-24 | 四川汇诚药业有限公司 | A kind of asparagus tablet and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5366434A (en) * | 1976-11-26 | 1978-06-13 | Tanabe Seiyaku Co Ltd | Deodorant |
JPS5766757A (en) * | 1980-10-09 | 1982-04-23 | Shiraimatsu Shinyaku Co | Continuous deodorant using unglazed material as medium |
-
1984
- 1984-10-15 JP JP59216994A patent/JPS6194660A/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5366434A (en) * | 1976-11-26 | 1978-06-13 | Tanabe Seiyaku Co Ltd | Deodorant |
JPS5766757A (en) * | 1980-10-09 | 1982-04-23 | Shiraimatsu Shinyaku Co | Continuous deodorant using unglazed material as medium |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH046775U (en) * | 1990-04-28 | 1992-01-22 |
Also Published As
Publication number | Publication date |
---|---|
JPS6194660A (en) | 1986-05-13 |
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