CN105920987A - Plant source deodorization spray and application thereof - Google Patents

Plant source deodorization spray and application thereof Download PDF

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Publication number
CN105920987A
CN105920987A CN201610341623.4A CN201610341623A CN105920987A CN 105920987 A CN105920987 A CN 105920987A CN 201610341623 A CN201610341623 A CN 201610341623A CN 105920987 A CN105920987 A CN 105920987A
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China
Prior art keywords
extracting solution
plant
plant source
source deodorization
foul smell
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Pending
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CN201610341623.4A
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Chinese (zh)
Inventor
杨广群
曹丽萍
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Foshan Jucheng Biochemical Technology Research and Development Co Ltd
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Foshan Jucheng Biochemical Technology Research and Development Co Ltd
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Priority to CN201610341623.4A priority Critical patent/CN105920987A/en
Publication of CN105920987A publication Critical patent/CN105920987A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • A61L9/013Deodorant compositions containing animal or plant extracts, or vegetable material
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/14Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/52Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/58Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8603Removing sulfur compounds
    • B01D53/8612Hydrogen sulfide

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biomedical Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Epidemiology (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Botany (AREA)
  • Zoology (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention discloses a plant source deodorization spray. The plant source deodorization spray is prepared from, by weight, 50-60 parts of 95% alcohol, 25-35 parts of plant combined extracting solution and 20-30 parts of distilled water. The plant combined extracting solution is a combined solution of a dianthus chinensis extracting solution, a sculellaria barbata extracting solution, a polygala tenuifolia extracting solution, a white birch extracting solution and a cortex albiziae extracting solution. The invention further discloses a method for dissolving stink through the plant source deodorization spray. According to the method, the stink is pumped through a sucking pump, dilution is conducted 2-4 times, and then the plant source deodorization spray is used for carrying out continuous spraying for 3-8 h. The plant source deodorization spray has the advantages that the new plant source deodorization spray is developed, cost is low, consumed time is short, the deodorization effect is good, bacteria can be restrained and killed, and the spray is safe and free of toxins, and does not generate secondary pollution to the environment.

Description

A kind of plant source deodorization spraying and application thereof
Technical field
The invention belongs to environmental conservation and air purification field, be specifically related to a kind of plant source deodorization Spraying.
Background technology
Odorant refers to that all stimulate organum olfactorium cause people unhappy and damage life cycle Border and the gaseous matter of health, its chemical composition mainly has hydrogen sulfide, thio-alcohol, thioether Class, ammonia, amine, indoles, nitro compound, hydro carbons, aldehydes, fatty acid, phenols, Ketone, esters and organic halogen system derivant etc..As one of big public hazards in the world seven, malodor source has Industrial source and life source, be concentrated mainly in production process, to labourer's respiratory system, circulation The aspects such as system, digestive system, hormonal system, nervous system, mental status are very harmful. It is in work in the working environment that stench is serious for a long time and can lose olfactory sensation, cerebral cortex regulatory function Imbalance, make people's anorexia, feel sick, dysphoria, absent-minded, efficiency is low, judgment, Hypomnesis, has a great impact health.Therefore the research of deodorization technology is carried out, Eliminate stench and the harm of health is had major and immediate significance.
The common method processing industry stench at present has WATER-WASHING METHOD, medicinal liquid ablution, activated carbon to inhale Attached method, Ozonation, electrostatic deodorization process, soil deodorization method, combustion method and biological odor removal method Deng, wherein, plant extraction liquid deodorization process has non-secondary pollution, processing cost is low, operate dimension Protect convenience, odor removal efficient advantages of higher, increasingly receive publicity in foul gas processes.So And, plant source deodorizer is due to the most often effect meeting of effective ingredient, component ratio and dosage form There is bigger difference.
Chinese patent CN105412967A discloses a kind of novel vegetalitas deodorizer, its group Divide and be by mass percentage: Camphor Tree Seeds extract 50%-60%, Folium perillae extract 10%-15%, Chinese catalpa lemon extract 5%-10%, Folium Menthae extract 5%-10%, Laurel extract 5%-10%, Ilex extract 10%-20%.Vegetalitas deodorizer disclosed in the present invention is to NH3And H2S Clearance be respectively 92.7% and 90.9%.
Summary of the invention
It is an object of the invention to provide a kind of plant source deodorization spraying, this plant source deodorization spraying Complete deodorization, cost of manufacture is low, abnormal smells from the patient delicate fragrance, safety and environmental protection.
For achieving the above object, the technical solution used in the present invention is for providing a kind of plant source deodorization Spraying, described plant source deodorization spraying is made up of the raw material of following weight part ratio: 95% ethanol 50-60 part, plant society extracting solution 25-35 part, distilled water 20-30 part;Described plant group Close extracting solution be Dianthus chinensis extracting solution, Herba Scutellariae Barbatae extracting solution, Radix Polygalae extracting solution, Betula platyphylla Suk. extracting solution, The combination liquid of Cortex Albiziae extracting solution.
Preferably, the particle diameter of above-mentioned plant source deodorization spraying is 5-35um.
Preferably, the weight of each raw material in plant society extracting solution in above-mentioned plant source deodorization spraying Part ratio is: Dianthus chinensis extracting solution 30-40 part, Herba Scutellariae Barbatae extracting solution 20-30 part, Radix Polygalae extracting solution 20-30 part, Betula platyphylla Suk. extracting solution 32-46 part, Cortex Albiziae extracting solution 25-35 part.
Dianthus chinensis (Dianthus chinensis L.) belong to pinkwort, another name China Dianthus chinensis, in State natural pond bamboo, Dianthus chinensis flower, Diranthus chinensis, Shi Ju, Herba Dianthi grass etc..Diranthus chinensis is Chinese tradition name One of flower, originates in Northeast China, North China, the Yangtze river basin and south east asia, and distribution is very wide, In addition to south China more thermally district, the most all there is distribution.Dianthus chinensis is rich in volatile oil, volatilization Oil is mainly phenethanol, benzyl benzoate.Leukocyte cell is then had the highest by Dianthus chinensis extract Suppression ratio, can prevent and treat dermatitis and prevention skin allergy.
Herba Scutellariae Barbatae (Scutellaria barbata) belong to Labiatae Scutellaria plant, have another name called toothbrush grass, Narrow leaf Herba Scutellariae indicae, is distributed in south China, the west and south and middle part each province, mainly in Anhui, Zhejiang River and area, Bozhou.Herba Scutellariae Barbatae contains alkaloid, predominantly diterpene alkaloid, Herba Scutellariae Barbatae alkali etc.. Herba Scutellariae Barbatae extract has good anti-inflammatory.
Radix Polygalae (Polygala tenuifolie) is Polygalaceae polygala, has another name called Roots of Polygala tenuifolia, Main product is in the southwest of China and South China, and resource is abundanter.Radix Polygalae rich in triterpene saponin, The Multiple components such as alkaloid, oligosaccharide ester type compound and coumarin.Radix Polygalae extract has antibacterial Property, to dysentery bacterium, Bacillus tuberculosis, Bacillus typhi, escherichia coli, degeneration bacillus and The growth of staphylococcus aureus significantly inhibits effect.
Betula platyphylla Suk. (Betulaplatyphylla) is a kind of deciduous tree of Betulaceae Betula, not Name Betula, birch, Hua Pishu.Betula platyphylla Suk. is mainly distributed on Japan, Korea, Russian and Chinese. It is concentrated mainly on three provinces in the northeast of China and forest zone, the Inner Mongol in China.Cortex Betulae Pendulae contains volatile oil, containing three The multiple compounds such as terpenoid (betulinol), lactone.The extract of Cortex Betulae Pendulae and white birch leaf is equal There is antifungal activity.Cortex Betulae Pendulae extract can suppress the release of histamine, has antianaphylactic effect.
Cortex Albiziae (Albiziajulibrissin) is the dry bark of leguminous plant Herba Albiziae, China master Originate in Hubei, Jiangsu, zhejiang and other places, strip in spring, season in autumn two.Cortex Albiziae contains triterpene, life The multiple chemical compositions such as alkaloids, fatty glyceride, flavone and polysaccharide.Cortex Albiziae water extract Staphylococcus aureus, bacillus pyocyaneus, escherichia coli and dysentery bacterium there is strong suppression Effect, also has anti-inflammatory.
Another technical scheme of the present invention is for providing above-mentioned plant source deodorization spraying molten at foul smell Application in solution.
Another technical scheme of the present invention is dissolved for providing a kind of above-mentioned plant source deodorization spraying The method of foul smell, described method for aspirate foul smell with air pump, dilutes 2-4 times, then uses State plant source deodorization spraying and persistently spray 3-8h.
Preferably, foul smell described in the method for above-mentioned plant source deodorization spraying dissolving foul smell is that fish is rotten Lose foul smell.
Plant extract deodorant is formed, containing substantial amounts of multiple by a series of plant extraction liquids are compounding Miscellaneous compound, is simply segmented into terpenes, straight chain compound, benzene derivate and perfume (or spice) The compounds such as oxalaldehyde, cinnamic acid, geranyl formate, the odor molecules in foul smell by various instead The plant extraction liquid drop absorption in space should be dispersed in, various reaction occurs at normal temperatures, raw Become tasteless nontoxic molecule.Such as acid-base reaction: the alkaloid that deodorization spraying contains can be with sulfuration The reaction of the foul smell molecule such as hydrogen, hydrocyanic acid radical ion, corpse ammonia, being different from that general alkali is poisonous can not Edible, natural alkaloid degradable;Catalytic oxidation, under the catalysis of deodorization spraying, one As can not react with the oxygen in air with the hydrogen sulfide that the oxygen in air carries out reacting;Warp Crossing the drop of atomization, its diameter is at 0.04mm, it is sufficient to destroys the key in foul smell molecule, makes it Unstable, easily decompose;Redox reaction: the reproducibility molecule in plant extraction liquid is direct React with the oxidisability molecule in foul smell.Plant extraction liquid there are acidity, alkalescence and neutrality multiple Molecule, wherein effectively molecule contains conjugated double bond isoreactivity group, and chemistry, physical property are stable. Nontoxic corrosion-free pollution-free non-stimulated to skin.Surface energy is increased by atomization, can be from different Abnormal flavour is had an effect.
The present invention provide plant source deodorization spraying contain substantial amounts of alkaloid, terpenes, esters, Benzene derivate and straight chain compound, can be fully contacted with various foul smell molecules, generation soda acid, The reactions such as catalysis oxidation, oxidoreduction, plant the most of the present invention is respectively provided with antibacterial killing Bacterium and antianaphylactic effect, can carry out disinfection to equipment, place etc. while dissolving foul smell, Also skin will not be produced discomfort impact.
Beneficial effects of the present invention is to develop a kind of new plant source deodorization spraying, low cost, The shortest, good deodorization effect, energy is antibacterial, sterilization, and safety non-toxic does not produce secondary to environment Pollute.
Accompanying drawing explanation
Accompanying drawing 1 plant source deodorization spraying dissolves the schematic flow sheet of foul smell.
Detailed description of the invention
For making those skilled in the art be better understood when technical scheme, under Technical solution of the present invention is described in detail by face in conjunction with the embodiments.
Experimental technique used in following embodiment if no special instructions, is conventional method.
Material used in following embodiment, reagent etc., if no special instructions, all can be from business Approach obtains, and wherein Dianthus chinensis extracting solution, Herba Scutellariae Barbatae extracting solution, Radix Polygalae extracting solution, Betula platyphylla Suk. are extracted Liquid, Cortex Albiziae extracting solution are purchased from Li Nuo bio tech ltd, Zhengzhou
Embodiment 1
5um plant source deodorization spraying of the present invention is made up of the raw material of following weight part ratio: 95% Ethanol 50 parts, plant extraction liquid 25 parts, distilled water 20 parts;Described plant extraction liquid is stone Bamboo extracting solution 30 parts, Herba Scutellariae Barbatae extracting solution 20 parts, Radix Polygalae extracting solution 20 parts, Betula platyphylla Suk. are extracted Liquid 32 parts, the combination liquid of Cortex Albiziae extracting solution 25 parts.
Comparative example 1
5um plant source deodorization spraying of the present invention is made up of the raw material of following weight part ratio: 95% Ethanol 50 parts, plant extraction liquid 25 parts, distilled water 20 parts;Described plant extraction liquid is stone Bamboo extracting solution 30 parts, the combination liquid of Betula platyphylla Suk. extracting solution 32 parts.
Embodiment 2
20um plant source deodorization spraying of the present invention is made up of the raw material of following weight part ratio: 95% Ethanol 55 parts, plant extraction liquid 30 parts, distilled water 25 parts;Described plant extraction liquid is stone Bamboo extracting solution 35 parts, Herba Scutellariae Barbatae extracting solution 25 parts, Radix Polygalae extracting solution 25 parts, Betula platyphylla Suk. are extracted Liquid 39 parts, the combination liquid of Cortex Albiziae extracting solution 30 parts.
Comparative example 2
20um plant source deodorization spraying of the present invention is made up of the raw material of following weight part ratio: 95% Ethanol 55 parts, plant extraction liquid 30 parts, distilled water 25 parts;Described plant extraction liquid is stone Bamboo extracting solution 35 parts, Betula platyphylla Suk. extracting solution 39 parts, the combination liquid of Cortex Albiziae extracting solution 30 parts.
Embodiment 3
35um plant source deodorization spraying of the present invention is made up of the raw material of following weight part ratio: 95% Ethanol 60 parts, plant extraction liquid 35 parts, distilled water 30 parts;Described plant extraction liquid is stone Bamboo extracting solution 40 parts, Herba Scutellariae Barbatae extracting solution 30 parts, Radix Polygalae extracting solution 30 parts, Betula platyphylla Suk. are extracted Liquid 46 parts, the combination liquid of Cortex Albiziae extracting solution 35 parts.
Comparative example 3
35um plant source deodorization spraying of the present invention is made up of the raw material of following weight part ratio: 95% Ethanol 60 parts, plant extraction liquid 35 parts, distilled water 30 parts;Described plant extraction liquid is stone Bamboo extracting solution 40 parts, Herba Scutellariae Barbatae extracting solution 30 parts, Betula platyphylla Suk. extracting solution 46 parts, Cortex Albiziae carry Take the combination liquid of liquid 35 parts.
Plant source deodorization spraying dissolves fish corruption foul smell, as shown in Figure 1.
Embodiment 4
Aspirate fish corruption foul smell with air pump, dilute 2 times, then with planting that embodiment 1 prepares Thing source deodorization spraying persistently sprays 3h, H remaining in detection foul smell2S、NH3, TMA dense Degree, the results are shown in Table 1.
Comparative example 4
Aspirate fish corruption foul smell with air pump, dilute 2 times, then with planting that comparative example 1 prepares Thing source deodorization spraying persistently sprays 3h, H remaining in detection foul smell2S、NH3, TMA dense Degree, the results are shown in Table 1.
Embodiment 5
Aspirate fish corruption foul smell with air pump, dilute 3 times, then with planting that embodiment 2 prepares Thing source deodorization spraying persistently sprays 5.5h, H remaining in detection foul smell2S、NH3、TMA Concentration, the results are shown in Table 1.
Comparative example 5
Aspirate fish corruption foul smell with air pump, dilute 3 times, then with planting that comparative example 2 prepares Thing source deodorization spraying persistently sprays 5.5h, H remaining in detection foul smell2S、NH3、TMA Concentration, the results are shown in Table 1.
Embodiment 6
Aspirate fish corruption foul smell with air pump, dilute 4 times, then with planting that embodiment 3 prepares Thing source deodorization spraying persistently sprays 8h, H remaining in detection foul smell2S、NH3, TMA dense Degree, the results are shown in Table 1.
Comparative example 6
Aspirate fish corruption foul smell with air pump, dilute 4 times, then with planting that comparative example 3 prepares Thing source deodorization spraying persistently sprays 8h, H remaining in detection foul smell2S、NH3, TMA dense Degree, the results are shown in Table 1.
In above-described embodiment 4-6 and comparative example 4-6, the unit of gas concentration is mg/m3, absorption Rate represents with %, and blank refers to the spraying without plant society extracting solution.
Table 1 embodiment 4-6 and the comparative example 4-6 deodorizing effect to fish corruption foul smell
Embodiment 4-6 is to H as known from Table 12S、NH3, the deodorizing effect of TMA all reach 99% Above, below comparative example 4-657.33% and the sky without any plant extraction liquid it are significantly higher than The deodorizing effect of white comparison less than 2.4%, shows the plant source deodorization spraying tool that the present invention provides Have each plant extraction liquid in efficient deodorizing effect, and the plant society extracting solution added it Between there is synergism, deodorizing effect is substantially better than and only adds wherein 2 kinds, 3 kinds or 4 kinds and plant The deodorization spraying of thing extracting solution.
Obviously, above-mentioned 6 embodiments are only the section Example of the present invention rather than all real Execute example.Enlightenment based on the present invention, those of ordinary skill in the art are not making creative labor Other embodiments all obtained by the premise of Dong, broadly fall into the model that present aspect is protected Enclose.

Claims (6)

1. a plant source deodorization spraying, it is characterised in that described plant source deodorization spraying by The raw material composition of following weight part ratio: 95% ethanol 50-60 part, plant society extracting solution 25-35 Part, distilled water 20-30 part;Described plant society extracting solution is that Dianthus chinensis extracting solution, Herba Scutellariae Barbatae carry Take the combination liquid of liquid, Radix Polygalae extracting solution, Betula platyphylla Suk. extracting solution, Cortex Albiziae extracting solution.
Plant source deodorization spraying the most according to claim 1, it is characterised in that described in plant The particle diameter of thing source deodorization spraying is 5-35um.
Plant source deodorization spraying the most according to claim 1, it is characterised in that described in plant In thing combination extracting solution, the weight part ratio of each raw material is: Dianthus chinensis extracting solution 30-40 part, Herba Scutellariae Barbatae Extracting solution 20-30 part, Radix Polygalae extracting solution 20-30 part, Betula platyphylla Suk. extracting solution 32-46 part, Herba Albiziae Skin extracting solution 25-35 part.
4. according to plant source deodorization spraying described in any one of claim 1-3 in foul smell dissolves Application.
5. the method that a plant source deodorization spraying dissolves foul smell, it is characterised in that described side Method, for aspirate foul smell with air pump, dilutes 2-4 times, then with any one of claim 1-3 institute State plant source deodorization spraying and persistently spray 3-8h.
The method that the most according to claim 5, plant source deodorization spraying dissolves foul smell, it is special Levying and be, described foul smell is fish corruption foul smell.
CN201610341623.4A 2016-05-20 2016-05-20 Plant source deodorization spray and application thereof Pending CN105920987A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112439316A (en) * 2020-11-06 2021-03-05 广州小众环保科技有限公司 Composite deodorant containing plant extract and preparation method thereof

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