CN104277198B - 一种石墨烯基导电阻燃型水性聚氨酯涂料和胶黏剂的制备方法 - Google Patents
一种石墨烯基导电阻燃型水性聚氨酯涂料和胶黏剂的制备方法 Download PDFInfo
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- CN104277198B CN104277198B CN201410575831.1A CN201410575831A CN104277198B CN 104277198 B CN104277198 B CN 104277198B CN 201410575831 A CN201410575831 A CN 201410575831A CN 104277198 B CN104277198 B CN 104277198B
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Abstract
Description
实例一 | 实例二 | 实例三 | 实例四 | 实例五 | 市场PU-1 | |
最大烟密度 | 22 | 26 | 28 | 14 | 6 | 43 |
达到最大烟密度时间/s | 161 | 165 | 186 | 210 | 211 | 121 |
氧指数 | 26.6 | 25.8 | 25.9 | 26.8 | 278 | 24 |
有焰燃烧时间/s | 22.5 | 22.6 | 13.4 | 10.8 | 10.2 | 25 |
无焰燃烧时间/s | 0 | 0 | 0 | 0 | 0 | 0 |
实例一 | 实例二 | 实例三 | 实例四 | 实例五 | 市场PU-1 | |
体积电阻/Ω | 7.75^109 | 4.62^108 | 3.50^107 | 6.70^106 | 2.80^105 | 8.00^109 |
电阻率/Ω·cm | 7.75^109 | 1.04^1010 | 1.33^109 | 1.27^107 | 1.01^106 | 7.20^1010 |
Claims (9)
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CN116004110A (zh) * | 2023-01-13 | 2023-04-25 | 上海正欧实业有限公司 | 一种具有自润滑作用的耐磨聚氨酯地坪涂料及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103254400A (zh) * | 2013-05-20 | 2013-08-21 | 常州大学 | 一种氧化石墨烯/水性聚氨酯纳米复合材料的制备方法 |
CN103804625A (zh) * | 2014-01-07 | 2014-05-21 | 浙江伟星新型建材股份有限公司 | 一种石墨烯/水性聚氨酯纳米复合材料的制备方法 |
CN103805046A (zh) * | 2014-01-26 | 2014-05-21 | 陕西科技大学 | 原位法制备含石墨烯的水性聚氨酯复合导电涂料及其方法 |
-
2014
- 2014-10-25 CN CN201410575831.1A patent/CN104277198B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103254400A (zh) * | 2013-05-20 | 2013-08-21 | 常州大学 | 一种氧化石墨烯/水性聚氨酯纳米复合材料的制备方法 |
CN103804625A (zh) * | 2014-01-07 | 2014-05-21 | 浙江伟星新型建材股份有限公司 | 一种石墨烯/水性聚氨酯纳米复合材料的制备方法 |
CN103805046A (zh) * | 2014-01-26 | 2014-05-21 | 陕西科技大学 | 原位法制备含石墨烯的水性聚氨酯复合导电涂料及其方法 |
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