CN104246606B - 复合树脂组合物及其用途、用立体石印术制备牙组件的方法 - Google Patents

复合树脂组合物及其用途、用立体石印术制备牙组件的方法 Download PDF

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Publication number
CN104246606B
CN104246606B CN201380018791.4A CN201380018791A CN104246606B CN 104246606 B CN104246606 B CN 104246606B CN 201380018791 A CN201380018791 A CN 201380018791A CN 104246606 B CN104246606 B CN 104246606B
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China
Prior art keywords
wavelength
photopolymerization initiator
maximum
composite resin
resin composition
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Chinese (zh)
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CN104246606A (zh
Inventor
W·瓦赫特
J·艾伯特
D·沃瑟
N·莫斯奈尔
V·莱因伯格尔
J·斯代姆普夫尔
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TU Wien
Ivoclar Vivadent AG
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TU Wien
Ivoclar Vivadent AG
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C13/00—Dental prostheses; Making same
    • A61C13/0003—Making bridge-work, inlays, implants or the like
    • A61C13/0006—Production methods
    • A61C13/0013—Production methods using stereolithographic techniques
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C13/00—Dental prostheses; Making same
    • A61C13/08—Artificial teeth; Making same
    • A61C13/082—Cosmetic aspects, e.g. inlays; Determination of the colour
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C13/00—Dental prostheses; Making same
    • A61C13/225—Fastening prostheses in the mouth
    • A61C13/26—Dentures without palates; Partial dentures, e.g. bridges
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
    • A61C5/00—Filling or capping teeth
    • A61C5/70—Tooth crowns; Making thereof
    • A61C5/77—Methods or devices for making crowns
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/60—Preparations for dentistry comprising organic or organo-metallic additives
    • A61K6/62—Photochemical radical initiators
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10—Processes of additive manufacturing
    • B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B29C64/124—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
    • B29C64/129—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
    • B29C64/135—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0037—Production of three-dimensional images
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
    • G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00—Processes of additive manufacturing

Landscapes

  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Dentistry (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Manufacturing & Machinery (AREA)
  • Optics & Photonics (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Biophysics (AREA)
  • Dental Preparations (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
CN201380018791.4A 2012-04-11 2013-04-11 复合树脂组合物及其用途、用立体石印术制备牙组件的方法 Active CN104246606B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12163824.1 2012-04-11
EP12163824 2012-04-11
PCT/EP2013/057635 WO2013153183A2 (de) 2012-04-11 2013-04-11 Kompositharz-zusammensetzung und verfahren zur herstellung dentaler bauteile mittels stereolithographie

Publications (2)

Publication Number Publication Date
CN104246606A CN104246606A (zh) 2014-12-24
CN104246606B true CN104246606B (zh) 2019-05-10

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Country Status (7)

Country Link
US (1) US9387056B2 (enExample)
EP (1) EP2751618B1 (enExample)
JP (1) JP6438385B2 (enExample)
CN (1) CN104246606B (enExample)
IL (1) IL234805A0 (enExample)
IN (1) IN2014DN08124A (enExample)
WO (1) WO2013153183A2 (enExample)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013153183A2 (de) 2012-04-11 2013-10-17 Ivoclar Vivadent Ag Kompositharz-zusammensetzung und verfahren zur herstellung dentaler bauteile mittels stereolithographie
US10357334B2 (en) * 2013-12-26 2019-07-23 Hegland LLC Dental devices and methods for treating one or more teeth
US11299569B2 (en) * 2014-04-30 2022-04-12 Institute Of Chemistry, Chinese Academy Of Sciences Material for 3D printing, process for preparing the same and article thereof
DE102014107330A1 (de) * 2014-05-23 2015-11-26 Heraeus Kulzer Gmbh Druckbare und sinterbare dentale Zusammensetzungen zur Herstellung von Teilen dentaler Prothesen sowie Verfahren zu deren Herstellung
DE102014116389A1 (de) 2014-11-11 2016-05-12 Voco Gmbh Radikalisch härtbare dentale Zusammensetzungen
DE102014116402A1 (de) 2014-11-11 2016-05-12 Voco Gmbh Verwendung radikalisch härtbarer Zusammensetzungen in generativen Fertigungsverfahren
US10709530B2 (en) * 2015-02-03 2020-07-14 Mitsui Chemicals, Inc. Photocurable composition, denture base, and plate denture
EP3124509A1 (en) * 2015-07-31 2017-02-01 Afinitica Technologies, S. L. Fast light curing cyanoacrylate compositions
ES2695237T3 (es) * 2015-09-29 2019-01-02 Ivoclar Vivadent Ag Fotoiniciadores de acilgermanio y procedimiento para su preparación
EP3173062A1 (de) * 2015-11-30 2017-05-31 Philipps-Universität Marburg Polymerisationslampe und komposite zur füllung von zahnkavitäten
US10221284B2 (en) * 2016-01-15 2019-03-05 Hrl Laboratories, Llc Resin formulations for polymer-derived ceramic materials
KR102629906B1 (ko) * 2016-06-15 2024-01-30 닛토덴코 가부시키가이샤 점착제층을 갖는 편광 필름, 및 화상 표시 장치
CN109641264A (zh) 2016-08-25 2019-04-16 3M创新有限公司 用于增材制造方法的着色可固化组合物、三维复合制品及其用途
JP7017514B2 (ja) * 2016-10-21 2022-02-08 クラレノリタケデンタル株式会社 光学的立体造形用組成物
RU2646088C1 (ru) * 2016-12-27 2018-03-01 Федеральное государственное бюджетное учреждение науки Байкальский институт природопользования Сибирского отделения Российской академии наук (БИП СО РАН) Фотополимерная композиция для изготовления термостойких объектов методом лазерной стереолитографии
WO2018182821A1 (en) * 2017-03-28 2018-10-04 Ford Global Technologies, Llc Stabilized additive manufacturing articles
CN110461886B (zh) * 2017-03-29 2022-03-22 三井化学株式会社 光固化性组合物、义齿基托及带托义齿
WO2018231583A1 (en) 2017-06-14 2018-12-20 3M Innovative Properties Company Curable composition for producing a dental composite crown and process of production
CN110799168B (zh) 2017-06-20 2023-06-23 3M创新有限公司 用于增材制造方法的可辐射固化组合物
CN110831735B (zh) * 2017-06-28 2021-12-14 3M创新有限公司 用于粘合剂和粘合剂制品的增材制造方法
EP3658068B1 (en) * 2017-07-25 2025-04-09 Solventum Intellectual Properties Company Water-resistant polymer-based dental articles
EP3713536A1 (en) 2017-11-22 2020-09-30 3M Innovative Properties Company Photopolymerizable compositions including a urethane component and a monofunctional reactive diluent, articles, and methods
US11904031B2 (en) 2017-11-22 2024-02-20 3M Innovative Properties Company Orthodontic articles comprising polymerized composition comprising at least two free-radical initiators
KR101835539B1 (ko) * 2018-01-17 2018-04-19 에이온 주식회사 인공 치아 성형 장치 및 그 방법
EP3765537A4 (en) 2018-03-15 2021-12-29 3M Innovative Properties Company Photopolymerizable compositions including a polypropylene oxide component, articles, and methods
EP3752123A1 (en) 2018-06-29 2020-12-23 3M Innovative Properties Company Photopolymerizable compositions including a polyurethane methacrylate polymer prepared using a polycarbonate diol, articles, and methods
US11584817B2 (en) 2018-06-29 2023-02-21 3M Innovative Properties Company Orthodontic articles comprising cured free-radically polymerizable composition with improved strength in aqueous environment
EP3660085B1 (de) 2018-11-29 2026-07-01 Ivoclar Vivadent AG Stützmaterial für den energieimpuls-induzierten transferdruck
EP3660087B1 (de) 2018-11-29 2024-05-29 Ivoclar Vivadent AG Verfahren und werkstoff zur herstellung von 3d objekten durch energieimpuls-induzierten transferdruck
EP3669856A1 (de) 2018-12-21 2020-06-24 Ivoclar Vivadent AG Zusammensetzungen für die herstellung von transparenten dentalwerkstücken mittels stereolithographie
RU2723427C1 (ru) * 2018-12-26 2020-06-11 ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ УНИТАРНОЕ ПРЕДПРИЯТИЕ "ИНСТИТУТ ХИМИЧЕСКИХ РЕАКТИВОВ И ОСОБО ЧИСТЫХ ХИМИЧЕСКИХ ВЕЩЕСТВ НАЦИОНАЛЬНОГО ИССЛЕДОВАТЕЛЬСКОГО ЦЕНТРА "КУРЧАТОВСКИЙ ИНСТИТУТ" (НИЦ "Курчатовский институт - ИРЕА) Композиция на основе стабилизированного диоксида циркония для 3D печати методом стереолитографии (Варианты)
DE102019105816A1 (de) 2019-03-07 2020-09-10 Mühlbauer Technology Gmbh Stereolithographisch hergestellte dentale Formteile und Verfahren zur Herstellung aus photopolymerisierbaren Kompositharz-Zusammensetzungen
JP7692841B2 (ja) * 2019-12-25 2025-06-16 クラレノリタケデンタル株式会社 エネルギー線硬化性立体造形物用コーティング材及びそれを含むエネルギー線硬化性立体造形用材料キット並びにそれを用いた立体造形物及びその製造方法
US20210284572A1 (en) * 2020-03-13 2021-09-16 Corning Incorporated Low temperature laser bleaching of polychromatic glass ceramics
IT202000014725A1 (it) * 2020-06-19 2021-12-19 Mat3D S R L Composizione di resine foto-polimerizzabili, metodo di fabbricazione di un manufatto impiegante la stessa e manufatto cosi’ ottenuto
ES3071032T3 (en) * 2022-05-10 2026-06-19 Ivoclar Vivadent Ag Dental hand tool for curing a polymer
DE102022123585A1 (de) 2022-09-15 2024-03-21 Voco Gmbh Unreaktive Transferschienen
DE102022123586A1 (de) 2022-09-15 2024-03-21 Voco Gmbh Opazitätsumschlag bei Druckharzen
CN120187382A (zh) * 2022-11-25 2025-06-20 舒万诺知识产权公司 在处理患者口腔中的牙齿状况的方法中使用的可固化组合物
KR102575220B1 (ko) * 2023-02-17 2023-09-06 송은영 치과용 하이브리드 복합 레진블록의 제작을 위한 광 중합기
CN122055123A (zh) 2023-11-13 2026-05-15 舒万诺知识产权公司 用于增材制造方法的可辐射固化组合物
CN117681438B (zh) * 2024-02-02 2024-04-05 北京航空航天大学 基于灰度调控的3d打印矫治器的方法和系统

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1153794A (zh) * 1995-10-19 1997-07-09 株式会社三键 可光固化组合物
WO2001012679A1 (de) * 1999-08-13 2001-02-22 Deltamed Medizinprodukte Gmbh Mit sichtbarem licht aushärtende zusammensetzung und deren verwendung
WO2004108799A1 (en) * 2003-06-06 2004-12-16 Ciba Specialty Chemicals Holding Inc. Novel surface-active polysiloxane photoinitiators
WO2009032228A2 (en) * 2007-08-31 2009-03-12 Dentsply International Inc. Three-dimensional printing methods and materials for making dental products
CN101689019A (zh) * 2007-06-27 2010-03-31 帝斯曼知识产权资产管理有限公司 通过立体光刻制成的澄清无色三维制品以及这种制品的制造方法

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3801511C2 (de) * 1988-01-20 1996-11-14 Espe Stiftung Verwendung von Photoinitiatoren zur Herstellung von in zwei Schritten härtbaren Dentalmassen
US5607985A (en) * 1992-12-21 1997-03-04 Adell Co., Ltd. Photopolymerization initiator for visible light-polymerizing adhesive
BE1008372A3 (nl) 1994-04-19 1996-04-02 Materialise Nv Werkwijze voor het vervaardigen van een geperfektioneerd medisch model uitgaande van digitale beeldinformatie van een lichaamsdeel.
AUPN023294A0 (en) 1994-12-22 1995-01-27 Commonwealth Scientific And Industrial Research Organisation Polymerisable monomers and polymers
BE1009947A6 (nl) 1996-02-15 1997-11-04 Materialise Nv Werkwijze en inrichting voor het vervaardigen van een driedimensionaal voorwerp uit een hardbaar vloeibaar medium.
DE19616183C2 (de) 1996-03-20 1999-05-12 Ivoclar Ag Funktionalisiertes und polymerisierbares Polymer
DE19903177C5 (de) 1999-01-21 2010-09-16 Ivoclar Vivadent Ag Verwendung von Materialien auf der Basis von Polysiloxanen als Dentalmaterialien
DE19938463A1 (de) 1999-08-13 2001-02-22 Deltamed Medizinprodukte Gmbh Mit sichtbarem Licht aushärtende Zusammensetzung und deren Verwendung
DE19950284A1 (de) 1999-10-19 2001-04-26 Deltamed Medizinprodukte Gmbh Mit sichtbarem Licht aushärtende Zusammensetzung und deren Verwendung
NL1016815C2 (nl) * 1999-12-15 2002-05-14 Ciba Sc Holding Ag Oximester-fotoinitiatoren.
DE10114290B4 (de) 2001-03-23 2004-08-12 Ivoclar Vivadent Ag Desktop-Verfahren zur Herstellung von Dentalprodukten unter Verwendung des 3D-Plottings
DE10249324A1 (de) 2002-10-22 2004-06-24 Ivoclar Vivadent Ag Polymerisationsfähige bicyclische Cyclopropanderivate und deren Verwendung zur Herstellung von Dentalmaterialien
US7166651B2 (en) * 2003-05-19 2007-01-23 Kerr Corporation Two-part self-adhering dental compositions
US20070259309A1 (en) * 2006-05-08 2007-11-08 Den-Mat Corporation Dental curing device and method with real-time cure indication
US20110033887A1 (en) * 2007-09-24 2011-02-10 Fang Nicholas X Three-Dimensional Microfabricated Bioreactors with Embedded Capillary Network
EP2151214B1 (de) * 2008-07-30 2013-01-23 Ivoclar Vivadent AG Lichthärtende Schlicker für die stereolithographische Herstellung von Dentalkeramiken
JP5669386B2 (ja) * 2009-01-15 2015-02-12 富士フイルム株式会社 新規化合物、重合性組成物、カラーフィルタ、及びその製造方法、固体撮像素子、並びに、平版印刷版原版
ES2711759T3 (es) 2012-04-11 2019-05-07 Ivoclar Vivadent Ag Composiciones polimerizables con profundidad de polimerización elevada
WO2013153183A2 (de) 2012-04-11 2013-10-17 Ivoclar Vivadent Ag Kompositharz-zusammensetzung und verfahren zur herstellung dentaler bauteile mittels stereolithographie

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1153794A (zh) * 1995-10-19 1997-07-09 株式会社三键 可光固化组合物
WO2001012679A1 (de) * 1999-08-13 2001-02-22 Deltamed Medizinprodukte Gmbh Mit sichtbarem licht aushärtende zusammensetzung und deren verwendung
WO2004108799A1 (en) * 2003-06-06 2004-12-16 Ciba Specialty Chemicals Holding Inc. Novel surface-active polysiloxane photoinitiators
CN101689019A (zh) * 2007-06-27 2010-03-31 帝斯曼知识产权资产管理有限公司 通过立体光刻制成的澄清无色三维制品以及这种制品的制造方法
WO2009032228A2 (en) * 2007-08-31 2009-03-12 Dentsply International Inc. Three-dimensional printing methods and materials for making dental products

Also Published As

Publication number Publication date
CN104246606A (zh) 2014-12-24
WO2013153183A3 (de) 2013-12-12
IL234805A0 (en) 2014-12-31
IN2014DN08124A (enExample) 2015-05-01
EP2751618A2 (de) 2014-07-09
JP6438385B2 (ja) 2018-12-12
WO2013153183A2 (de) 2013-10-17
US9387056B2 (en) 2016-07-12
JP2015515327A (ja) 2015-05-28
EP2751618B1 (de) 2019-05-29
US20150111176A1 (en) 2015-04-23

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