CN104204277B - 金色硬质装饰构件 - Google Patents

金色硬质装饰构件 Download PDF

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Publication number
CN104204277B
CN104204277B CN201380015093.9A CN201380015093A CN104204277B CN 104204277 B CN104204277 B CN 104204277B CN 201380015093 A CN201380015093 A CN 201380015093A CN 104204277 B CN104204277 B CN 104204277B
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CN
China
Prior art keywords
film
layer
gradient
golden
alloy
Prior art date
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CN201380015093.9A
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English (en)
Chinese (zh)
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CN104204277A (zh
Inventor
高崎康太郎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Citizen Holdings Co Ltd
Original Assignee
Citizen Watch Co Ltd
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Publication date
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Publication of CN104204277A publication Critical patent/CN104204277A/zh
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/0015—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterized by the colour of the layer
    • A—HUMAN NECESSITIES
    • A44—HABERDASHERY; JEWELLERY
    • A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
    • A44C27/00—Making jewellery or other personal adornments
    • A44C27/001—Materials for manufacturing jewellery
    • A44C27/005—Coating layers for jewellery
    • A44C27/007—Non-metallic coatings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/0021—Reactive sputtering or evaporation
    • C23C14/0036—Reactive sputtering
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/02—Pretreatment of the material to be coated
    • C23C14/024—Deposition of sublayers, e.g. to promote adhesion of the coating
    • C23C14/025—Metallic sublayers
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0641—Nitrides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0676—Oxynitrides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14—Metallic material, boron or silicon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34—Sputtering
    • C23C14/3407—Cathode assembly for sputtering apparatus, e.g. Target
    • C23C14/3414—Metallurgical or chemical aspects of target preparation, e.g. casting, powder metallurgy
    • G—PHYSICS
    • G04—HOROLOGY
    • G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
    • G04B37/00—Cases
    • G04B37/22—Materials or processes of manufacturing pocket watch or wrist watch cases
    • A—HUMAN NECESSITIES
    • A44—HABERDASHERY; JEWELLERY
    • A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
    • A44C27/00—Making jewellery or other personal adornments
    • A44C27/001—Materials for manufacturing jewellery
    • A44C27/005—Coating layers for jewellery
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
    • Y10T428/264—Up to 3 mils
    • Y10T428/265—1 mil or less

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Physical Vapour Deposition (AREA)
CN201380015093.9A 2012-03-19 2013-02-28 金色硬质装饰构件 Active CN104204277B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2012062218A JP5979927B2 (ja) 2012-03-19 2012-03-19 金色硬質装飾部材
JP2012-062218 2012-03-19
PCT/JP2013/055486 WO2013140988A1 (ja) 2012-03-19 2013-02-28 金色硬質装飾部材

Publications (2)

Publication Number Publication Date
CN104204277A CN104204277A (zh) 2014-12-10
CN104204277B true CN104204277B (zh) 2018-12-04

Family

ID=49222451

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380015093.9A Active CN104204277B (zh) 2012-03-19 2013-02-28 金色硬质装饰构件

Country Status (5)

Country Link
US (1) US9469765B2 (enExample)
EP (1) EP2829632B1 (enExample)
JP (1) JP5979927B2 (enExample)
CN (1) CN104204277B (enExample)
WO (1) WO2013140988A1 (enExample)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2667265A1 (fr) * 2012-05-22 2013-11-27 The Swatch Group Research and Development Ltd. Composant d'habillage d'horlogerie bi-métal brasé
JP6440866B2 (ja) * 2016-03-25 2018-12-19 Ｊｘ金属株式会社 Ｔｉ−Ｎｂ合金スパッタリングターゲット及びその製造方法
US11408066B2 (en) 2016-03-31 2022-08-09 Citizen Watch Co., Ltd. Decorative member and method for producing the same
CN107684202A (zh) * 2016-08-03 2018-02-13 周生生珠宝金行有限公司 足金及其制造方法
JP6862793B2 (ja) * 2016-11-24 2021-04-21 セイコーエプソン株式会社 時計用部品および時計
JP6834632B2 (ja) * 2017-03-14 2021-02-24 セイコーエプソン株式会社 時計用部品および時計
CN112458417A (zh) * 2020-11-24 2021-03-09 创隆实业(深圳)有限公司 一种多元层状加硬涂层生长工艺
CN112877642B (zh) * 2021-04-29 2021-07-20 蓝思科技（长沙）有限公司 防指纹膜、玻璃制品及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1380856A (zh) * 2000-04-19 2002-11-20 西铁城钟表股份有限公司 餐具及其表面处理方法、有硬质装饰镀膜的基材、基材的制造方法和刀叉餐具
WO2010150411A1 (ja) * 2009-06-26 2010-12-29 オーエスジー株式会社 硬質被膜、および硬質被膜被覆工具
JP2011256424A (ja) * 2010-06-08 2011-12-22 Citizen Holdings Co Ltd 硬質装飾部材
EP2463398A1 (en) * 2009-08-04 2012-06-13 Tungaloy Corporation Coated member

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5485214A (en) * 1977-12-21 1979-07-06 Suwa Seikosha Kk Armor for personal watch
JPH02138460A (ja) 1989-07-20 1990-05-28 Seikosha Co Ltd 金色を呈する物品の製造方法
JPH0417665A (ja) * 1990-05-10 1992-01-22 Kowa Eng Kk 銀白色装飾品
ATE195354T1 (de) * 1992-02-27 2000-08-15 Hauzer Ind Bv Verbesserungen von verfahren der physikalischen dampfphasen-abscheidung
JP4171099B2 (ja) * 1998-04-24 2008-10-22 株式会社神戸製鋼所 耐摩耗性に優れる硬質皮膜
JP2003082452A (ja) 2001-09-13 2003-03-19 Citizen Watch Co Ltd 装飾用金色被膜
US7081186B2 (en) * 2003-11-20 2006-07-25 Sheffield Hallam University Combined coating process comprising magnetic field-assisted, high power, pulsed cathode sputtering and an unbalanced magnetron
DE102004044919A1 (de) * 2004-09-14 2006-03-30 Martin Balzer Dekorative Beschichtung zum Korrosionsschutz auf Basis von Refraktärmetall-Magnesium-Nitriden sowie Verfahren zur Herstellung derselben
US20080014420A1 (en) * 2006-07-11 2008-01-17 Ion Technology (Hong Kong) Limited Surface treatment for titanium or titanium-alloys
EP2620526B1 (en) * 2010-09-21 2018-05-02 Citizen Watch Co., Ltd. White rigid decorative member

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1380856A (zh) * 2000-04-19 2002-11-20 西铁城钟表股份有限公司 餐具及其表面处理方法、有硬质装饰镀膜的基材、基材的制造方法和刀叉餐具
WO2010150411A1 (ja) * 2009-06-26 2010-12-29 オーエスジー株式会社 硬質被膜、および硬質被膜被覆工具
EP2463398A1 (en) * 2009-08-04 2012-06-13 Tungaloy Corporation Coated member
JP2011256424A (ja) * 2010-06-08 2011-12-22 Citizen Holdings Co Ltd 硬質装飾部材

Also Published As

Publication number Publication date
EP2829632B1 (en) 2019-11-27
EP2829632A1 (en) 2015-01-28
JP5979927B2 (ja) 2016-08-31
US9469765B2 (en) 2016-10-18
JP2013194276A (ja) 2013-09-30
US20150044453A1 (en) 2015-02-12
WO2013140988A1 (ja) 2013-09-26
EP2829632A4 (en) 2015-11-04
CN104204277A (zh) 2014-12-10

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C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C41 Transfer of patent application or patent right or utility model
CB02 Change of applicant information

Address after: Japan Tokyo Tozai Tokyo city Tanashi town six chome 1 No. 12

Applicant after: CITIZEN WATCH Co.,Ltd.

Address before: Japan Tokyo Tozai Tokyo city Tanashi town six chome 1 No. 12

Applicant before: CITIZEN HOLDINGS Co.,Ltd.

COR Change of bibliographic data
TA01 Transfer of patent application right

Effective date of registration: 20170228

Address after: Japan Tokyo Tozai Tokyo city Tanashi town six chome 1 No. 12

Applicant after: CITIZEN HOLDINGS Co.,Ltd.

Address before: Japan Tokyo Tozai Tokyo city Tanashi town six chome 1 No. 12

Applicant before: CITIZEN HOLDINGS Co.,Ltd.

Applicant before: CITIZEN WATCH Co.,Ltd.

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GR01 Patent grant