CN104080792A - 用于制备茂金属络合物的方法 - Google Patents
用于制备茂金属络合物的方法 Download PDFInfo
- Publication number
- CN104080792A CN104080792A CN201280068053.6A CN201280068053A CN104080792A CN 104080792 A CN104080792 A CN 104080792A CN 201280068053 A CN201280068053 A CN 201280068053A CN 104080792 A CN104080792 A CN 104080792A
- Authority
- CN
- China
- Prior art keywords
- formula
- indenyl
- compound
- group
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 0 CC1(C)OB(C(C2*)=C(*)C3=C2C(*)=C(*)C(*)C3*)OC1(C)C Chemical compound CC1(C)OB(C(C2*)=C(*)C3=C2C(*)=C(*)C(*)C3*)OC1(C)C 0.000 description 3
- DRKHIWKXLZCAKP-UHFFFAOYSA-N Brc(cccc1)c1-c1ccccc1Br Chemical compound Brc(cccc1)c1-c1ccccc1Br DRKHIWKXLZCAKP-UHFFFAOYSA-N 0.000 description 1
- WQONPSCCEXUXTQ-UHFFFAOYSA-N Brc1ccccc1Br Chemical compound Brc1ccccc1Br WQONPSCCEXUXTQ-UHFFFAOYSA-N 0.000 description 1
- XYBOTSLRNVRNBM-UHFFFAOYSA-N C(C(c(cccc1)c1C(C1)=Cc2c1cccc2)=C1)c2c1cccc2 Chemical compound C(C(c(cccc1)c1C(C1)=Cc2c1cccc2)=C1)c2c1cccc2 XYBOTSLRNVRNBM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
- C07C1/321—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/04—One of the condensed rings being a six-membered aromatic ring
- C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/09—Cyclic bridge, i.e. Cp or analog where the bridging unit linking the two Cps or analogs is part of a cyclic group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11009974.4 | 2011-12-19 | ||
| EP11009974 | 2011-12-19 | ||
| PCT/EP2012/005232 WO2013091837A1 (en) | 2011-12-19 | 2012-12-13 | Process for the preparation of metallocene complexes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104080792A true CN104080792A (zh) | 2014-10-01 |
Family
ID=47428557
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280068053.6A Pending CN104080792A (zh) | 2011-12-19 | 2012-12-13 | 用于制备茂金属络合物的方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9000200B2 (https=) |
| EP (1) | EP2800754B1 (https=) |
| JP (1) | JP6454549B2 (https=) |
| CN (1) | CN104080792A (https=) |
| IN (1) | IN2014DN04977A (https=) |
| PT (1) | PT2800754T (https=) |
| WO (1) | WO2013091837A1 (https=) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104093730A (zh) * | 2011-12-19 | 2014-10-08 | 沙特基础工业公司 | 用于制备茂金属络合物的方法 |
| EP2832739A1 (en) * | 2013-08-01 | 2015-02-04 | Saudi Basic Industries Corporation | Bridged metallocene complex for olefin polymerization |
| EA032159B1 (ru) * | 2013-08-20 | 2019-04-30 | Сауди Бейсик Индастриз Корпорейшн | Способ получения 2,2'-бис-инденилбифенильных лигандов и их металлоценовых комплексов |
| US9815917B2 (en) | 2013-08-30 | 2017-11-14 | Saudi Basic Industries Corporation | Bridged metallocene complex for olefin polymerization |
| WO2015132346A1 (en) * | 2014-03-06 | 2015-09-11 | Saudi Basic Industries Corporation | Catalyst comprising a metallocene complex and a co-catalyst |
| GB2533770B (en) | 2014-12-22 | 2021-02-10 | Norner Verdandi As | Polyethylene for pipes |
| GB201611295D0 (en) | 2016-06-29 | 2016-08-10 | Norner Verdandi As | Polyethylene for pipes |
| CN110650965B (zh) | 2017-04-04 | 2022-10-04 | Sabic环球技术有限责任公司 | 用于烯烃聚合的二烃基-甲硅烷基-桥连-1,3二取代-2-茚基茂金属络合物 |
| CN110650978B (zh) * | 2017-04-04 | 2022-09-23 | Sabic环球技术有限责任公司 | 用于烯烃聚合的二甲基-甲硅烷基-桥连的-1-取代-2-茚基茂金属复合物 |
| WO2025202139A1 (en) * | 2024-03-26 | 2025-10-02 | Sabic Global Technologies B.V. | Olefin-based copolymers and process for production thereof |
| WO2025201795A1 (en) * | 2024-03-26 | 2025-10-02 | Sabic Global Technologies B.V. | Catalyst system for use in olefin polymerisation |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1291986A (zh) * | 1998-11-18 | 2001-04-18 | 蒙特尔技术有限公司 | 双(四氢茚基)金属茂作为烯烃聚合催化剂 |
| US6342622B1 (en) * | 1999-06-11 | 2002-01-29 | Dsm B.V. | Indenyl compounds for the polymerization of olefins |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3443087A1 (de) * | 1984-11-27 | 1986-05-28 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von polyolefinen |
| US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
| PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
| ATE137770T1 (de) | 1989-10-10 | 1996-05-15 | Fina Technology | Metallocenkatalysator mit lewissäure und alkylaluminium |
| DK0426637T4 (da) | 1989-10-30 | 2002-01-14 | Fina Technology | Fremgangsmåde til fremstilling af metallocenkatalysatorer til polymerisation af olefiner |
| EP0500944B1 (en) | 1990-07-24 | 1998-10-07 | Mitsui Chemicals, Inc. | Catalyst for alpha-olefin polymerization and production of poly-alpha-olefin therewith |
| NL9101502A (nl) | 1991-09-06 | 1993-04-01 | Dsm Nv | Werkwijze voor het bereiden van een gebrugde metalloceenverbinding alsmede een katalysatorcomponent en een werkwijze voor de polymerisatie van een olefinen. |
| NL9201970A (nl) * | 1992-11-11 | 1994-06-01 | Dsm Nv | Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen. |
| JPH08188610A (ja) * | 1995-01-12 | 1996-07-23 | Mitsui Petrochem Ind Ltd | 新規な遷移金属化合物、オレフィン重合用触媒成分、オレフィン重合用触媒およびオレフィンの重合方法 |
| IT1275777B1 (it) * | 1995-07-06 | 1997-10-17 | Enichem Spa | Catalizzatore metallocenico per la (co)polimerizzazione delle olefine |
| ES2188047T3 (es) * | 1998-03-09 | 2003-06-16 | Basell Polyolefine Gmbh | Compuestos de circonoceno puenteados, procedimiento para su preparacion y su empleo como componentes catalizadores en la polimerizacion de olefinas. |
| IT1298616B1 (it) * | 1998-03-10 | 2000-01-12 | Enichem Spa | Complesso metallocenico pontato per la (co) polimerizzazione delle olefine |
| DE19922020A1 (de) * | 1999-05-12 | 2000-11-16 | Targor Gmbh | Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| EP1059300A1 (en) | 1999-06-11 | 2000-12-13 | Dsm N.V. | Indenyl compounds for the polymerisation of olefins |
| US20060116400A1 (en) * | 2002-11-28 | 2006-06-01 | Astrazeneca Ab | Oxazolidinone and/or isoxazoline derivatives as antibacterial agents |
| MXPA06000933A (es) * | 2003-07-25 | 2006-03-30 | Pfizer | Compuestos de aminopirazol y uso como inhibidores de chk1. |
| ATE361323T1 (de) * | 2004-03-12 | 2007-05-15 | Saudi Basic Ind Corp | Katalysatorzusammensetzung für die polymerisation von olefinen und polymerisationsverfahren unter dessen verwendung |
| US20080146612A1 (en) * | 2005-01-27 | 2008-06-19 | Astrazeneca Ab | Novel Biaromatic Compounds, Inhibitors of the P2X7-Receptor |
| EP1731535A1 (en) * | 2005-06-07 | 2006-12-13 | Saudi Basic Industries Corporation Inc. | Process for polymerization of olefins |
| PL1764378T3 (pl) * | 2005-08-17 | 2009-08-31 | Saudi Basic Ind Corp | Kompozycja katalizatorowa do polimeryzacji olefin, sposób polimeryzacji z zastosowaniem tej kompozycji, oraz sposób jej wytwarzania |
| EP2183228B1 (en) * | 2007-07-26 | 2014-08-20 | Vitae Pharmaceuticals, Inc. | CYCLIC INHIBITORS OF 11ß -HYDROXYSTERIOD DEHYDROGENASE 1 |
| JP5529496B2 (ja) * | 2009-11-02 | 2014-06-25 | 東ソー株式会社 | 1,3,5−トリアジン誘導体とその製造方法及びそれを含有する有機電界発光素子 |
| US9062015B2 (en) * | 2009-12-14 | 2015-06-23 | Merck Patent Gmbh | Inhibitors of sphingosine kinase |
| CN102382148B (zh) * | 2011-08-02 | 2014-04-02 | 海门瑞一医药科技有限公司 | 双三苯基膦二氯化钯生产工艺 |
| CN104093730A (zh) * | 2011-12-19 | 2014-10-08 | 沙特基础工业公司 | 用于制备茂金属络合物的方法 |
-
2012
- 2012-12-13 JP JP2014546362A patent/JP6454549B2/ja not_active Expired - Fee Related
- 2012-12-13 IN IN4977DEN2014 patent/IN2014DN04977A/en unknown
- 2012-12-13 EP EP12805598.5A patent/EP2800754B1/en not_active Not-in-force
- 2012-12-13 PT PT128055985T patent/PT2800754T/pt unknown
- 2012-12-13 CN CN201280068053.6A patent/CN104080792A/zh active Pending
- 2012-12-13 US US14/366,691 patent/US9000200B2/en not_active Expired - Fee Related
- 2012-12-13 WO PCT/EP2012/005232 patent/WO2013091837A1/en not_active Ceased
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1291986A (zh) * | 1998-11-18 | 2001-04-18 | 蒙特尔技术有限公司 | 双(四氢茚基)金属茂作为烯烃聚合催化剂 |
| US6342622B1 (en) * | 1999-06-11 | 2002-01-29 | Dsm B.V. | Indenyl compounds for the polymerization of olefins |
Non-Patent Citations (2)
| Title |
|---|
| DONG-WON LEE等,: "A Convenient Approach to 2-Arylindenes via Suzuki Coupling Reaction of 2-Indenylboronate with Aryl Bromides", 《BULL. KOREAN CHEM. SOC.》, vol. 25, no. 1, 31 December 2004 (2004-12-31), XP002578589 * |
| EDWIN G. IJPEIJ等,: "A Suzuki Coupling Based Route to 2,2′-Bis(2-indenyl)biphenyl Derivatives", 《J. ORG. CHEM.》, vol. 67, no. 1, 13 December 2001 (2001-12-13), pages 169 - 176 * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2800754A1 (en) | 2014-11-12 |
| WO2013091837A1 (en) | 2013-06-27 |
| JP6454549B2 (ja) | 2019-01-16 |
| EP2800754B1 (en) | 2017-06-28 |
| US20140378694A1 (en) | 2014-12-25 |
| JP2015505846A (ja) | 2015-02-26 |
| IN2014DN04977A (https=) | 2015-05-15 |
| US9000200B2 (en) | 2015-04-07 |
| PT2800754T (pt) | 2017-08-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20141001 |
|
| RJ01 | Rejection of invention patent application after publication |