CN104078243B - 一种基于石墨烯复合聚苯胺的固态电解电容器 - Google Patents
一种基于石墨烯复合聚苯胺的固态电解电容器 Download PDFInfo
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- CN104078243B CN104078243B CN201410319836.8A CN201410319836A CN104078243B CN 104078243 B CN104078243 B CN 104078243B CN 201410319836 A CN201410319836 A CN 201410319836A CN 104078243 B CN104078243 B CN 104078243B
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- 239000003990 capacitor Substances 0.000 title claims abstract description 47
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 26
- 239000007787 solid Substances 0.000 title claims abstract description 17
- 150000001412 amines Chemical class 0.000 title claims abstract description 9
- -1 polyphenylene Polymers 0.000 title claims abstract description 8
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- 230000001590 oxidative effect Effects 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims description 64
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 52
- 239000006185 dispersion Substances 0.000 claims description 48
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 38
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 19
- 238000007789 sealing Methods 0.000 claims description 19
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 238000005868 electrolysis reaction Methods 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 239000001117 sulphuric acid Substances 0.000 claims description 2
- 235000011149 sulphuric acid Nutrition 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims 1
- 235000011130 ammonium sulphate Nutrition 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 20
- 229910002804 graphite Inorganic materials 0.000 abstract description 19
- 239000010439 graphite Substances 0.000 abstract description 19
- 238000003763 carbonization Methods 0.000 abstract description 12
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- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 18
- 238000006087 Brown hydroboration reaction Methods 0.000 description 9
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 9
- 238000004140 cleaning Methods 0.000 description 9
- 239000003792 electrolyte Substances 0.000 description 7
- 229920000767 polyaniline Polymers 0.000 description 7
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- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 5
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- 239000005030 aluminium foil Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000002322 conducting polymer Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000008393 encapsulating agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
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- ZRSKSQHEOZFGLJ-UHFFFAOYSA-N ammonium adipate Chemical compound [NH4+].[NH4+].[O-]C(=O)CCCCC([O-])=O ZRSKSQHEOZFGLJ-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
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- 125000000623 heterocyclic group Chemical group 0.000 description 1
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- 238000011056 performance test Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
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- 230000000630 rising effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
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- 239000002904 solvent Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
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- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
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Families Citing this family (6)
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CN105405657A (zh) * | 2014-09-16 | 2016-03-16 | 立隆电子工业股份有限公司 | 电解电容器的制造方法及其制品 |
CN106558418B (zh) * | 2015-09-28 | 2019-08-23 | 无锡市惠诚石墨烯技术应用有限公司 | 一种固态电解电容器及其固态电解质的制备方法 |
CN108231434B (zh) * | 2017-12-27 | 2021-10-08 | 益阳艾华富贤电子有限公司 | 固态电容制备方法 |
CN110676059B (zh) * | 2019-08-14 | 2021-07-30 | 湖南艾华集团股份有限公司 | 聚苯胺基固态电解电容器电极材料的制备方法 |
CN112038095B (zh) * | 2020-09-24 | 2022-03-01 | 湖南艾华集团股份有限公司 | 一种基于导电聚苯铵-聚酰亚胺膜的固态铝电解电容器及其制备方法 |
CN113436892B (zh) * | 2021-06-08 | 2022-10-25 | 湖南艾华集团股份有限公司 | 一种基于MoS2-PANI的固态铝电解电容器及制备方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08330191A (ja) * | 1995-05-27 | 1996-12-13 | Nec Corp | 固体電解コンデンサ及びその製造方法 |
JPH11191518A (ja) * | 1997-12-26 | 1999-07-13 | Sanyo Electric Co Ltd | 有機固体電解コンデンサ及びその製造方法 |
JP2001307958A (ja) * | 2000-04-26 | 2001-11-02 | Nichicon Corp | 固体電解コンデンサ |
JP2002015956A (ja) * | 2000-06-29 | 2002-01-18 | Nichicon Corp | 固体電解コンデンサ |
CN101916671A (zh) * | 2010-07-01 | 2010-12-15 | 南通江海电容器股份有限公司 | 可降低esr、提高静电容量固体电解电容器的制备方法 |
CN102219390A (zh) * | 2011-03-18 | 2011-10-19 | 南京邮电大学 | 一种层状石墨烯聚苯胺复合物膜及其制备方法 |
CN102768902A (zh) * | 2012-08-02 | 2012-11-07 | 电子科技大学 | 一种制造有机电解质电解电容器的方法 |
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2014
- 2014-07-07 CN CN201410319836.8A patent/CN104078243B/zh active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08330191A (ja) * | 1995-05-27 | 1996-12-13 | Nec Corp | 固体電解コンデンサ及びその製造方法 |
JPH11191518A (ja) * | 1997-12-26 | 1999-07-13 | Sanyo Electric Co Ltd | 有機固体電解コンデンサ及びその製造方法 |
JP2001307958A (ja) * | 2000-04-26 | 2001-11-02 | Nichicon Corp | 固体電解コンデンサ |
JP2002015956A (ja) * | 2000-06-29 | 2002-01-18 | Nichicon Corp | 固体電解コンデンサ |
CN101916671A (zh) * | 2010-07-01 | 2010-12-15 | 南通江海电容器股份有限公司 | 可降低esr、提高静电容量固体电解电容器的制备方法 |
CN102219390A (zh) * | 2011-03-18 | 2011-10-19 | 南京邮电大学 | 一种层状石墨烯聚苯胺复合物膜及其制备方法 |
CN102768902A (zh) * | 2012-08-02 | 2012-11-07 | 电子科技大学 | 一种制造有机电解质电解电容器的方法 |
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