CN104078243A - 一种基于石墨烯复合聚苯胺的固态电解电容器 - Google Patents
一种基于石墨烯复合聚苯胺的固态电解电容器 Download PDFInfo
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- CN104078243A CN104078243A CN201410319836.8A CN201410319836A CN104078243A CN 104078243 A CN104078243 A CN 104078243A CN 201410319836 A CN201410319836 A CN 201410319836A CN 104078243 A CN104078243 A CN 104078243A
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- electrolytic capacitor
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- 239000003990 capacitor Substances 0.000 title claims abstract description 55
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 17
- 239000007787 solid Substances 0.000 title claims abstract description 16
- 239000002131 composite material Substances 0.000 title claims abstract description 10
- 229920000767 polyaniline Polymers 0.000 title abstract description 10
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 48
- 238000000034 method Methods 0.000 claims abstract description 34
- 239000000178 monomer Substances 0.000 claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 239000007800 oxidant agent Substances 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims description 69
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 56
- 239000006185 dispersion Substances 0.000 claims description 49
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 38
- 229910002804 graphite Inorganic materials 0.000 claims description 29
- 239000010439 graphite Substances 0.000 claims description 29
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 20
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 19
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- 239000007864 aqueous solution Substances 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 9
- 230000001590 oxidative effect Effects 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- 229920000265 Polyparaphenylene Polymers 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- -1 polyphenylene Polymers 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 2
- 239000002019 doping agent Substances 0.000 abstract 1
- 238000005538 encapsulation Methods 0.000 abstract 1
- 230000002794 monomerizing effect Effects 0.000 abstract 1
- 238000004804 winding Methods 0.000 abstract 1
- 239000011888 foil Substances 0.000 description 31
- 238000007789 sealing Methods 0.000 description 17
- 238000003763 carbonization Methods 0.000 description 11
- 230000008859 change Effects 0.000 description 10
- 239000004411 aluminium Substances 0.000 description 9
- 238000004140 cleaning Methods 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- 239000003792 electrolyte Substances 0.000 description 7
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 230000004888 barrier function Effects 0.000 description 4
- 229920001940 conductive polymer Polymers 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229920000128 polypyrrole Polymers 0.000 description 3
- 239000011241 protective layer Substances 0.000 description 3
- 239000007784 solid electrolyte Substances 0.000 description 3
- 239000005030 aluminium foil Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000002322 conducting polymer Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000008393 encapsulating agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- ZRSKSQHEOZFGLJ-UHFFFAOYSA-N ammonium adipate Chemical compound [NH4+].[NH4+].[O-]C(=O)CCCCC([O-])=O ZRSKSQHEOZFGLJ-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
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- 125000000623 heterocyclic group Chemical group 0.000 description 1
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- 238000011065 in-situ storage Methods 0.000 description 1
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- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
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- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410319836.8A CN104078243B (zh) | 2014-07-07 | 2014-07-07 | 一种基于石墨烯复合聚苯胺的固态电解电容器 |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410319836.8A CN104078243B (zh) | 2014-07-07 | 2014-07-07 | 一种基于石墨烯复合聚苯胺的固态电解电容器 |
Publications (2)
| Publication Number | Publication Date |
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| CN104078243A true CN104078243A (zh) | 2014-10-01 |
| CN104078243B CN104078243B (zh) | 2016-11-16 |
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| CN201410319836.8A Active CN104078243B (zh) | 2014-07-07 | 2014-07-07 | 一种基于石墨烯复合聚苯胺的固态电解电容器 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105405657A (zh) * | 2014-09-16 | 2016-03-16 | 立隆电子工业股份有限公司 | 电解电容器的制造方法及其制品 |
| CN106558418A (zh) * | 2015-09-28 | 2017-04-05 | 无锡市惠诚石墨烯技术应用有限公司 | 一种固态电解电容器及其固态电解质的制备方法 |
| CN108231434A (zh) * | 2017-12-27 | 2018-06-29 | 益阳艾华富贤电子有限公司 | 固态电容制备方法 |
| CN110676059A (zh) * | 2019-08-14 | 2020-01-10 | 湖南艾华集团股份有限公司 | 聚苯胺基固态电解电容器电极材料的制备方法 |
| CN112038095A (zh) * | 2020-09-24 | 2020-12-04 | 湖南艾华集团股份有限公司 | 一种基于导电聚苯铵-聚酰亚胺膜的固态铝电解电容器及其制备方法 |
| CN113436892A (zh) * | 2021-06-08 | 2021-09-24 | 湖南艾华集团股份有限公司 | 一种基于MoS2-PANI的固态铝电解电容器及制备方法 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08330191A (ja) * | 1995-05-27 | 1996-12-13 | Nec Corp | 固体電解コンデンサ及びその製造方法 |
| JPH11191518A (ja) * | 1997-12-26 | 1999-07-13 | Sanyo Electric Co Ltd | 有機固体電解コンデンサ及びその製造方法 |
| JP2001307958A (ja) * | 2000-04-26 | 2001-11-02 | Nichicon Corp | 固体電解コンデンサ |
| JP2002015956A (ja) * | 2000-06-29 | 2002-01-18 | Nichicon Corp | 固体電解コンデンサ |
| CN101916671A (zh) * | 2010-07-01 | 2010-12-15 | 南通江海电容器股份有限公司 | 可降低esr、提高静电容量固体电解电容器的制备方法 |
| CN102219390A (zh) * | 2011-03-18 | 2011-10-19 | 南京邮电大学 | 一种层状石墨烯聚苯胺复合物膜及其制备方法 |
| CN102768902A (zh) * | 2012-08-02 | 2012-11-07 | 电子科技大学 | 一种制造有机电解质电解电容器的方法 |
-
2014
- 2014-07-07 CN CN201410319836.8A patent/CN104078243B/zh active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08330191A (ja) * | 1995-05-27 | 1996-12-13 | Nec Corp | 固体電解コンデンサ及びその製造方法 |
| JPH11191518A (ja) * | 1997-12-26 | 1999-07-13 | Sanyo Electric Co Ltd | 有機固体電解コンデンサ及びその製造方法 |
| JP2001307958A (ja) * | 2000-04-26 | 2001-11-02 | Nichicon Corp | 固体電解コンデンサ |
| JP2002015956A (ja) * | 2000-06-29 | 2002-01-18 | Nichicon Corp | 固体電解コンデンサ |
| CN101916671A (zh) * | 2010-07-01 | 2010-12-15 | 南通江海电容器股份有限公司 | 可降低esr、提高静电容量固体电解电容器的制备方法 |
| CN102219390A (zh) * | 2011-03-18 | 2011-10-19 | 南京邮电大学 | 一种层状石墨烯聚苯胺复合物膜及其制备方法 |
| CN102768902A (zh) * | 2012-08-02 | 2012-11-07 | 电子科技大学 | 一种制造有机电解质电解电容器的方法 |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105405657A (zh) * | 2014-09-16 | 2016-03-16 | 立隆电子工业股份有限公司 | 电解电容器的制造方法及其制品 |
| CN106558418A (zh) * | 2015-09-28 | 2017-04-05 | 无锡市惠诚石墨烯技术应用有限公司 | 一种固态电解电容器及其固态电解质的制备方法 |
| CN106558418B (zh) * | 2015-09-28 | 2019-08-23 | 无锡市惠诚石墨烯技术应用有限公司 | 一种固态电解电容器及其固态电解质的制备方法 |
| CN108231434A (zh) * | 2017-12-27 | 2018-06-29 | 益阳艾华富贤电子有限公司 | 固态电容制备方法 |
| CN108231434B (zh) * | 2017-12-27 | 2021-10-08 | 益阳艾华富贤电子有限公司 | 固态电容制备方法 |
| CN110676059A (zh) * | 2019-08-14 | 2020-01-10 | 湖南艾华集团股份有限公司 | 聚苯胺基固态电解电容器电极材料的制备方法 |
| CN110676059B (zh) * | 2019-08-14 | 2021-07-30 | 湖南艾华集团股份有限公司 | 聚苯胺基固态电解电容器电极材料的制备方法 |
| CN112038095A (zh) * | 2020-09-24 | 2020-12-04 | 湖南艾华集团股份有限公司 | 一种基于导电聚苯铵-聚酰亚胺膜的固态铝电解电容器及其制备方法 |
| CN112038095B (zh) * | 2020-09-24 | 2022-03-01 | 湖南艾华集团股份有限公司 | 一种基于导电聚苯铵-聚酰亚胺膜的固态铝电解电容器及其制备方法 |
| CN113436892A (zh) * | 2021-06-08 | 2021-09-24 | 湖南艾华集团股份有限公司 | 一种基于MoS2-PANI的固态铝电解电容器及制备方法 |
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| Publication number | Publication date |
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| CN104078243B (zh) | 2016-11-16 |
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Inventor after: Xiao Zhongliang Inventor after: Xia Kaixiang Inventor after: Cai Jinfeng Inventor after: Li Xianqing Inventor after: Zhou Qingqing Inventor after: Wang Shuting Inventor after: Wang Liyuan Inventor before: Xiao Zhongliang Inventor before: Xia Kaixiang Inventor before: Cai Jinfeng Inventor before: Li Xianqing Inventor before: Zhou Qingqing |
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Denomination of invention: Solid electrolytic capacitor based on graphene composite polyaniline Effective date of registration: 20191024 Granted publication date: 20161116 Pledgee: Qiliqiao sub branch of Yiyang Rural Commercial Bank Co.,Ltd. Pledgor: YIYANG WANJINGYUAN ELECTRONICS Co.,Ltd. Registration number: Y2019430000031 |
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