CN104039704B - 用于制备cha型结构的沸石材料的无有机模板合成法 - Google Patents

用于制备cha型结构的沸石材料的无有机模板合成法 Download PDF

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Publication number
CN104039704B
CN104039704B CN201280066497.6A CN201280066497A CN104039704B CN 104039704 B CN104039704 B CN 104039704B CN 201280066497 A CN201280066497 A CN 201280066497A CN 104039704 B CN104039704 B CN 104039704B
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cha
zeolitic material
mixture
seed crystal
present
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CN104039704A (zh
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S·莫勒
H·金
J·杨
U·米勒
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BASF SE
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7015—CHA-type, e.g. Chabazite, LZ-218
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/10—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least phosphorus atoms
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Compositions Of Oxide Ceramics (AREA)
CN201280066497.6A 2011-11-11 2012-11-09 用于制备cha型结构的沸石材料的无有机模板合成法 Active CN104039704B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11188857 2011-11-11
EP11188857.4 2011-11-11
PCT/IB2012/056292 WO2013068976A1 (en) 2011-11-11 2012-11-09 Organotemplate-free synthetic process for the production of a zeolitic material of the cha-type structure

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CN104039704A CN104039704A (zh) 2014-09-10
CN104039704B true CN104039704B (zh) 2017-10-24

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EP (1) EP2776369B1 (enExample)
JP (1) JP6324895B2 (enExample)
KR (1) KR102032584B1 (enExample)
CN (1) CN104039704B (enExample)
BR (1) BR112014011308B1 (enExample)
CA (1) CA2855572C (enExample)
IN (1) IN2014CN03353A (enExample)
MX (1) MX375064B (enExample)
PL (1) PL2776369T3 (enExample)
RU (1) RU2612697C2 (enExample)
WO (1) WO2013068976A1 (enExample)
ZA (1) ZA201404210B (enExample)

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WO2019140750A1 (zh) * 2018-01-19 2019-07-25 山东齐鲁华信高科有限公司 一种高铁含量的Fe-ZSM-5分子筛的制备方法

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US20150118151A1 (en) 2012-12-10 2015-04-30 Exxonmobil Research And Engineering Company Seeded synthesis of aluminosilicate molecular sieves
WO2016099775A1 (en) * 2014-12-17 2016-06-23 Sabic Global Techologies B.V. Silicoaluminophosphate catalyst for chloromethane conversion
ES2574500B1 (es) * 2014-12-17 2017-03-31 Consejo Superior De Investigaciones Científicas (Csic) Síntesis de la zeolita con la estructura cristalina CHA, procedimiento de síntesis y su uso en aplicaciones catalíticas
WO2017109705A1 (en) * 2015-12-22 2017-06-29 Basf Corporation Process for preparing iron(iii)-exchanged zeolite composition
RU2740455C2 (ru) 2016-06-08 2021-01-14 Басф Корпорейшн Промотированный медью гмелинит и его применение в селективном каталитическом восстановлении nox
WO2017211236A1 (en) * 2016-06-08 2017-12-14 Basf Corporation Copper-promoted zeolitic materials of the cha framework structure from organotemplate-free synthesis and use thereof in the selective catalytic reduction of nox
CN106145138B (zh) * 2016-06-27 2018-05-08 杨晓波 一种合成具有菱沸石结构的沸石分子筛的方法
CN106145137B (zh) * 2016-06-27 2018-06-05 杨晓波 一种直接水热合成中硅铝比菱沸石的方法
WO2018102555A1 (en) * 2016-12-02 2018-06-07 Ecolab USA, Inc. Polyaluminum salts and their uses in preparation of high-purity colloidal aluminum-silica composite particles and zeolites
CN110621622B (zh) 2017-05-15 2024-11-19 巴斯夫公司 制备包含金属m并具有aei骨架类型的沸石材料的方法
JP7254715B2 (ja) 2017-05-15 2023-04-10 ビーエーエスエフ コーポレーション フレームワークタイプａｅｉを有するゼオライト系材料を製造する方法
EP3651900A1 (en) * 2017-07-11 2020-05-20 Shell Internationale Research Maatschappij B.V. A catalyst and method of use thereof
CA3074818A1 (en) * 2017-09-07 2019-03-14 Basf Corporation Zeolite with reduced extra-framework aluminum
CN108083292B (zh) * 2018-01-31 2020-12-29 吉林大学 一种磷掺杂cha分子筛、制备方法及其应用
WO2019223761A1 (en) 2018-05-25 2019-11-28 Basf Se Rare earth element containing aluminum-rich zeolitic material
US11554964B2 (en) 2018-07-27 2023-01-17 Basf Se Process for preparing a zeolitic material having a framework type FER
US12264076B2 (en) 2019-05-15 2025-04-01 Basf Mobile Emissions Catalysts Llc Process for the production of the CHA-AFT zeolite intergrowth COE-10 and use thereof in heterogeneous catalysis
CN111348660B (zh) * 2020-03-16 2022-08-09 江西师范大学 一种中硅cha型分子筛及其制备方法和应用
CN111762795B (zh) * 2020-07-13 2022-10-14 包头稀土研究院 含有稀土元素的分子筛及其生产方法
CN111762794B (zh) * 2020-07-13 2022-08-05 包头稀土研究院 分子筛及其制备方法
EP4015454A1 (en) * 2020-12-21 2022-06-22 Tosoh Corporation Cha-type zeolite and manufacturing method thereof
CN112919493B (zh) * 2021-02-05 2022-10-14 正大能源材料(大连)有限公司 一种低成本制备ssz-13分子筛的方法及应用

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EP2776369A4 (en) 2015-08-05
KR102032584B1 (ko) 2019-10-15
JP6324895B2 (ja) 2018-05-16
WO2013068976A1 (en) 2013-05-16
MX2014005537A (es) 2014-09-16
BR112014011308A2 (pt) 2017-05-09
ZA201404210B (en) 2015-08-26
CN104039704A (zh) 2014-09-10
BR112014011308B1 (pt) 2021-04-13
EP2776369B1 (en) 2022-02-23
JP2015511919A (ja) 2015-04-23
KR20140093982A (ko) 2014-07-29
CA2855572C (en) 2020-04-28
RU2612697C2 (ru) 2017-03-13
CA2855572A1 (en) 2013-05-16
PL2776369T3 (pl) 2022-06-20
IN2014CN03353A (enExample) 2015-07-03
MX375064B (es) 2025-03-06
EP2776369A1 (en) 2014-09-17
RU2014123614A (ru) 2015-12-20

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