CN104039704B - 用于制备cha型结构的沸石材料的无有机模板合成法 - Google Patents
用于制备cha型结构的沸石材料的无有机模板合成法 Download PDFInfo
- Publication number
- CN104039704B CN104039704B CN201280066497.6A CN201280066497A CN104039704B CN 104039704 B CN104039704 B CN 104039704B CN 201280066497 A CN201280066497 A CN 201280066497A CN 104039704 B CN104039704 B CN 104039704B
- Authority
- CN
- China
- Prior art keywords
- cha
- zeolitic material
- mixture
- seed crystal
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7015—CHA-type, e.g. Chabazite, LZ-218
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/10—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least phosphorus atoms
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Compositions Of Oxide Ceramics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11188857.4 | 2011-11-11 | ||
| EP11188857 | 2011-11-11 | ||
| PCT/IB2012/056292 WO2013068976A1 (en) | 2011-11-11 | 2012-11-09 | Organotemplate-free synthetic process for the production of a zeolitic material of the cha-type structure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104039704A CN104039704A (zh) | 2014-09-10 |
| CN104039704B true CN104039704B (zh) | 2017-10-24 |
Family
ID=48288615
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280066497.6A Active CN104039704B (zh) | 2011-11-11 | 2012-11-09 | 用于制备cha型结构的沸石材料的无有机模板合成法 |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP2776369B1 (cg-RX-API-DMAC10.html) |
| JP (1) | JP6324895B2 (cg-RX-API-DMAC10.html) |
| KR (1) | KR102032584B1 (cg-RX-API-DMAC10.html) |
| CN (1) | CN104039704B (cg-RX-API-DMAC10.html) |
| BR (1) | BR112014011308B1 (cg-RX-API-DMAC10.html) |
| CA (1) | CA2855572C (cg-RX-API-DMAC10.html) |
| IN (1) | IN2014CN03353A (cg-RX-API-DMAC10.html) |
| MX (1) | MX375064B (cg-RX-API-DMAC10.html) |
| PL (1) | PL2776369T3 (cg-RX-API-DMAC10.html) |
| RU (1) | RU2612697C2 (cg-RX-API-DMAC10.html) |
| WO (1) | WO2013068976A1 (cg-RX-API-DMAC10.html) |
| ZA (1) | ZA201404210B (cg-RX-API-DMAC10.html) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019140750A1 (zh) * | 2018-01-19 | 2019-07-25 | 山东齐鲁华信高科有限公司 | 一种高铁含量的Fe-ZSM-5分子筛的制备方法 |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6267225B2 (ja) | 2012-12-10 | 2018-01-24 | エクソンモービル リサーチ アンド エンジニアリング カンパニーExxon Research And Engineering Company | アルミノシリケートモレキュラーシーブの種結晶形成による合成 |
| CN107107046A (zh) * | 2014-12-17 | 2017-08-29 | 沙特基础工业全球技术公司 | 用于氯甲烷转化的磷酸硅铝催化剂 |
| ES2574500B1 (es) * | 2014-12-17 | 2017-03-31 | Consejo Superior De Investigaciones Científicas (Csic) | Síntesis de la zeolita con la estructura cristalina CHA, procedimiento de síntesis y su uso en aplicaciones catalíticas |
| WO2017109705A1 (en) * | 2015-12-22 | 2017-06-29 | Basf Corporation | Process for preparing iron(iii)-exchanged zeolite composition |
| CN121800199A (zh) | 2016-06-08 | 2026-04-07 | 巴斯夫公司 | 来自无有机模板的合成的cha骨架结构的铜助催化沸石材料及其在nox的选择性催化还原中的用途 |
| WO2017211237A1 (en) | 2016-06-08 | 2017-12-14 | Basf Corporation | Copper-promoted gmelinite and use thereof in the selective catalytic reduction of nox |
| CN106145138B (zh) * | 2016-06-27 | 2018-05-08 | 杨晓波 | 一种合成具有菱沸石结构的沸石分子筛的方法 |
| CN106145137B (zh) * | 2016-06-27 | 2018-06-05 | 杨晓波 | 一种直接水热合成中硅铝比菱沸石的方法 |
| WO2018102555A1 (en) * | 2016-12-02 | 2018-06-07 | Ecolab USA, Inc. | Polyaluminum salts and their uses in preparation of high-purity colloidal aluminum-silica composite particles and zeolites |
| BR112019021877A2 (pt) | 2017-05-15 | 2020-05-26 | Basf Corporation | Processo para preparar um material zeolítico, material zeolítico e uso de um material zeolítico |
| CN110621622B (zh) | 2017-05-15 | 2024-11-19 | 巴斯夫公司 | 制备包含金属m并具有aei骨架类型的沸石材料的方法 |
| KR102578657B1 (ko) * | 2017-07-11 | 2023-09-15 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | 촉매 및 이의 사용 방법 |
| KR102643225B1 (ko) | 2017-09-07 | 2024-03-12 | 바스프 코포레이션 | 감소된 골격-외 알루미늄을 가진 제올라이트 |
| CN108083292B (zh) * | 2018-01-31 | 2020-12-29 | 吉林大学 | 一种磷掺杂cha分子筛、制备方法及其应用 |
| US11219886B2 (en) | 2018-05-25 | 2022-01-11 | Basf Se | Rare earth element containing aluminum-rich zeolitic material |
| JP7494174B2 (ja) | 2018-07-27 | 2024-06-03 | ビーエーエスエフ ソシエタス・ヨーロピア | 骨格型ferを有するゼオライト材料の製造方法 |
| CN113874321A (zh) | 2019-05-15 | 2021-12-31 | 巴斯夫欧洲公司 | 制备cha-aft沸石共生coe-10的方法及其在非均相催化中的用途 |
| CN111348660B (zh) * | 2020-03-16 | 2022-08-09 | 江西师范大学 | 一种中硅cha型分子筛及其制备方法和应用 |
| CN111762795B (zh) * | 2020-07-13 | 2022-10-14 | 包头稀土研究院 | 含有稀土元素的分子筛及其生产方法 |
| CN111762794B (zh) * | 2020-07-13 | 2022-08-05 | 包头稀土研究院 | 分子筛及其制备方法 |
| EP4015454A1 (en) * | 2020-12-21 | 2022-06-22 | Tosoh Corporation | Cha-type zeolite and manufacturing method thereof |
| CN112919493B (zh) * | 2021-02-05 | 2022-10-14 | 正大能源材料(大连)有限公司 | 一种低成本制备ssz-13分子筛的方法及应用 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102134081A (zh) * | 2010-01-25 | 2011-07-27 | 天津海赛纳米材料有限公司 | 无模板剂存在下一种sapo-34分子筛的合成方法 |
| CN103561865A (zh) * | 2011-04-18 | 2014-02-05 | Pq公司 | 大晶体、不含有机物的菱沸石以及制造和使用其的方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU833498A1 (ru) * | 1979-06-25 | 1981-05-30 | Институт Общей И Неорганической Химииан Армянской Ccp | Способ получени шабазита |
| SU1640112A1 (ru) * | 1987-12-28 | 1991-04-07 | Предприятие П/Я Р-6518 | Синтетический натриево-цезиевый цеолит типа шабазит |
| WO2000006494A1 (en) | 1998-07-29 | 2000-02-10 | Exxon Chemical Patents, Inc. | Crystalline molecular sieves |
| WO2003078324A1 (en) * | 2002-03-15 | 2003-09-25 | Exxonmobil Chemical Patents Inc. | High silica chabazite, its synthesis and its use in the conversion of oxygenates to olefins |
| WO2005063622A2 (en) | 2003-12-23 | 2005-07-14 | Exxonmobil Chemical Patents Inc. | Chabazite-type molecular sieve, its synthesis and its use in the conversion of oxygenates to olefins |
| US20090196812A1 (en) * | 2008-01-31 | 2009-08-06 | Basf Catalysts Llc | Catalysts, Systems and Methods Utilizing Non-Zeolitic Metal-Containing Molecular Sieves Having the CHA Crystal Structure |
| US10583424B2 (en) * | 2008-11-06 | 2020-03-10 | Basf Corporation | Chabazite zeolite catalysts having low silica to alumina ratios |
| CN104876237A (zh) * | 2009-06-18 | 2015-09-02 | 巴斯夫欧洲公司 | 生产沸石材料的无有机模板合成方法 |
| EP2504097B1 (en) * | 2009-11-24 | 2018-05-30 | Basf Se | Process for the preparation of zeolites having cha structure |
| CN102285666B (zh) * | 2010-06-18 | 2015-02-04 | 江西师范大学 | 一种菱沸石及菱沸石膜的制备方法 |
| CN102442679B (zh) * | 2011-09-29 | 2013-08-14 | 南开大学 | 一种菱沸石的合成方法 |
-
2012
- 2012-11-09 CN CN201280066497.6A patent/CN104039704B/zh active Active
- 2012-11-09 IN IN3353CHN2014 patent/IN2014CN03353A/en unknown
- 2012-11-09 RU RU2014123614A patent/RU2612697C2/ru active
- 2012-11-09 CA CA2855572A patent/CA2855572C/en active Active
- 2012-11-09 WO PCT/IB2012/056292 patent/WO2013068976A1/en not_active Ceased
- 2012-11-09 PL PL12847478T patent/PL2776369T3/pl unknown
- 2012-11-09 MX MX2014005537A patent/MX375064B/es active IP Right Grant
- 2012-11-09 JP JP2014540621A patent/JP6324895B2/ja active Active
- 2012-11-09 EP EP12847478.0A patent/EP2776369B1/en active Active
- 2012-11-09 BR BR112014011308-4A patent/BR112014011308B1/pt active IP Right Grant
- 2012-11-09 KR KR1020147015629A patent/KR102032584B1/ko active Active
-
2014
- 2014-06-09 ZA ZA2014/04210A patent/ZA201404210B/en unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102134081A (zh) * | 2010-01-25 | 2011-07-27 | 天津海赛纳米材料有限公司 | 无模板剂存在下一种sapo-34分子筛的合成方法 |
| CN103561865A (zh) * | 2011-04-18 | 2014-02-05 | Pq公司 | 大晶体、不含有机物的菱沸石以及制造和使用其的方法 |
Non-Patent Citations (1)
| Title |
|---|
| "Aluminum distribution in chabazite: an experimental and computational study";Duncan E.Akporiaye等;《JOURNAL OF PHYSICAL CHEMISTRY》;19961231;第100卷(第10期);第4148-4153页 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019140750A1 (zh) * | 2018-01-19 | 2019-07-25 | 山东齐鲁华信高科有限公司 | 一种高铁含量的Fe-ZSM-5分子筛的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| ZA201404210B (en) | 2015-08-26 |
| EP2776369B1 (en) | 2022-02-23 |
| IN2014CN03353A (cg-RX-API-DMAC10.html) | 2015-07-03 |
| CA2855572A1 (en) | 2013-05-16 |
| PL2776369T3 (pl) | 2022-06-20 |
| CN104039704A (zh) | 2014-09-10 |
| EP2776369A4 (en) | 2015-08-05 |
| RU2612697C2 (ru) | 2017-03-13 |
| JP2015511919A (ja) | 2015-04-23 |
| MX2014005537A (es) | 2014-09-16 |
| BR112014011308B1 (pt) | 2021-04-13 |
| EP2776369A1 (en) | 2014-09-17 |
| KR102032584B1 (ko) | 2019-10-15 |
| KR20140093982A (ko) | 2014-07-29 |
| RU2014123614A (ru) | 2015-12-20 |
| JP6324895B2 (ja) | 2018-05-16 |
| MX375064B (es) | 2025-03-06 |
| CA2855572C (en) | 2020-04-28 |
| WO2013068976A1 (en) | 2013-05-16 |
| BR112014011308A2 (pt) | 2017-05-09 |
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