CA2855572C - Organotemplate-free synthetic process for the production of a zeolitic material of the cha-type structure - Google Patents

Organotemplate-free synthetic process for the production of a zeolitic material of the cha-type structure Download PDF

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Publication number
CA2855572C
CA2855572C CA2855572A CA2855572A CA2855572C CA 2855572 C CA2855572 C CA 2855572C CA 2855572 A CA2855572 A CA 2855572A CA 2855572 A CA2855572 A CA 2855572A CA 2855572 C CA2855572 C CA 2855572C
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Prior art keywords
cha
zeolitic material
framework structure
seed crystals
present
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CA2855572A
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English (en)
French (fr)
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CA2855572A1 (en
Inventor
Stefan Maurer
Hanpeng Jin
Jeff Yang
Ulrich Muller
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7015—CHA-type, e.g. Chabazite, LZ-218
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/10—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least phosphorus atoms
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Compositions Of Oxide Ceramics (AREA)
CA2855572A 2011-11-11 2012-11-09 Organotemplate-free synthetic process for the production of a zeolitic material of the cha-type structure Active CA2855572C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11188857.4 2011-11-11
EP11188857 2011-11-11
PCT/IB2012/056292 WO2013068976A1 (en) 2011-11-11 2012-11-09 Organotemplate-free synthetic process for the production of a zeolitic material of the cha-type structure

Publications (2)

Publication Number Publication Date
CA2855572A1 CA2855572A1 (en) 2013-05-16
CA2855572C true CA2855572C (en) 2020-04-28

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA2855572A Active CA2855572C (en) 2011-11-11 2012-11-09 Organotemplate-free synthetic process for the production of a zeolitic material of the cha-type structure

Country Status (12)

Country Link
EP (1) EP2776369B1 (cg-RX-API-DMAC10.html)
JP (1) JP6324895B2 (cg-RX-API-DMAC10.html)
KR (1) KR102032584B1 (cg-RX-API-DMAC10.html)
CN (1) CN104039704B (cg-RX-API-DMAC10.html)
BR (1) BR112014011308B1 (cg-RX-API-DMAC10.html)
CA (1) CA2855572C (cg-RX-API-DMAC10.html)
IN (1) IN2014CN03353A (cg-RX-API-DMAC10.html)
MX (1) MX375064B (cg-RX-API-DMAC10.html)
PL (1) PL2776369T3 (cg-RX-API-DMAC10.html)
RU (1) RU2612697C2 (cg-RX-API-DMAC10.html)
WO (1) WO2013068976A1 (cg-RX-API-DMAC10.html)
ZA (1) ZA201404210B (cg-RX-API-DMAC10.html)

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JP6267225B2 (ja) 2012-12-10 2018-01-24 エクソンモービル リサーチ アンド エンジニアリング カンパニーExxon Research And Engineering Company アルミノシリケートモレキュラーシーブの種結晶形成による合成
CN107107046A (zh) * 2014-12-17 2017-08-29 沙特基础工业全球技术公司 用于氯甲烷转化的磷酸硅铝催化剂
ES2574500B1 (es) * 2014-12-17 2017-03-31 Consejo Superior De Investigaciones Científicas (Csic) Síntesis de la zeolita con la estructura cristalina CHA, procedimiento de síntesis y su uso en aplicaciones catalíticas
WO2017109705A1 (en) * 2015-12-22 2017-06-29 Basf Corporation Process for preparing iron(iii)-exchanged zeolite composition
CN121800199A (zh) 2016-06-08 2026-04-07 巴斯夫公司 来自无有机模板的合成的cha骨架结构的铜助催化沸石材料及其在nox的选择性催化还原中的用途
WO2017211237A1 (en) 2016-06-08 2017-12-14 Basf Corporation Copper-promoted gmelinite and use thereof in the selective catalytic reduction of nox
CN106145138B (zh) * 2016-06-27 2018-05-08 杨晓波 一种合成具有菱沸石结构的沸石分子筛的方法
CN106145137B (zh) * 2016-06-27 2018-06-05 杨晓波 一种直接水热合成中硅铝比菱沸石的方法
WO2018102555A1 (en) * 2016-12-02 2018-06-07 Ecolab USA, Inc. Polyaluminum salts and their uses in preparation of high-purity colloidal aluminum-silica composite particles and zeolites
BR112019021877A2 (pt) 2017-05-15 2020-05-26 Basf Corporation Processo para preparar um material zeolítico, material zeolítico e uso de um material zeolítico
CN110621622B (zh) 2017-05-15 2024-11-19 巴斯夫公司 制备包含金属m并具有aei骨架类型的沸石材料的方法
KR102578657B1 (ko) * 2017-07-11 2023-09-15 쉘 인터내셔날 리써취 마트샤피지 비.브이. 촉매 및 이의 사용 방법
KR102643225B1 (ko) 2017-09-07 2024-03-12 바스프 코포레이션 감소된 골격-외 알루미늄을 가진 제올라이트
CN108217681B (zh) * 2018-01-19 2021-07-06 山东齐鲁华信高科有限公司 一种高铁含量的Fe-ZSM-5分子筛的制备方法
CN108083292B (zh) * 2018-01-31 2020-12-29 吉林大学 一种磷掺杂cha分子筛、制备方法及其应用
US11219886B2 (en) 2018-05-25 2022-01-11 Basf Se Rare earth element containing aluminum-rich zeolitic material
JP7494174B2 (ja) 2018-07-27 2024-06-03 ビーエーエスエフ ソシエタス・ヨーロピア 骨格型ferを有するゼオライト材料の製造方法
CN113874321A (zh) 2019-05-15 2021-12-31 巴斯夫欧洲公司 制备cha-aft沸石共生coe-10的方法及其在非均相催化中的用途
CN111348660B (zh) * 2020-03-16 2022-08-09 江西师范大学 一种中硅cha型分子筛及其制备方法和应用
CN111762795B (zh) * 2020-07-13 2022-10-14 包头稀土研究院 含有稀土元素的分子筛及其生产方法
CN111762794B (zh) * 2020-07-13 2022-08-05 包头稀土研究院 分子筛及其制备方法
EP4015454A1 (en) * 2020-12-21 2022-06-22 Tosoh Corporation Cha-type zeolite and manufacturing method thereof
CN112919493B (zh) * 2021-02-05 2022-10-14 正大能源材料(大连)有限公司 一种低成本制备ssz-13分子筛的方法及应用

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US10583424B2 (en) * 2008-11-06 2020-03-10 Basf Corporation Chabazite zeolite catalysts having low silica to alumina ratios
CN104876237A (zh) * 2009-06-18 2015-09-02 巴斯夫欧洲公司 生产沸石材料的无有机模板合成方法
EP2504097B1 (en) * 2009-11-24 2018-05-30 Basf Se Process for the preparation of zeolites having cha structure
CN102134081A (zh) * 2010-01-25 2011-07-27 天津海赛纳米材料有限公司 无模板剂存在下一种sapo-34分子筛的合成方法
CN102285666B (zh) * 2010-06-18 2015-02-04 江西师范大学 一种菱沸石及菱沸石膜的制备方法
WO2012145323A1 (en) * 2011-04-18 2012-10-26 Pq Corporation Large crystal, organic-free chabazite, methods of making and using the same
CN102442679B (zh) * 2011-09-29 2013-08-14 南开大学 一种菱沸石的合成方法

Also Published As

Publication number Publication date
ZA201404210B (en) 2015-08-26
EP2776369B1 (en) 2022-02-23
CN104039704B (zh) 2017-10-24
IN2014CN03353A (cg-RX-API-DMAC10.html) 2015-07-03
CA2855572A1 (en) 2013-05-16
PL2776369T3 (pl) 2022-06-20
CN104039704A (zh) 2014-09-10
EP2776369A4 (en) 2015-08-05
RU2612697C2 (ru) 2017-03-13
JP2015511919A (ja) 2015-04-23
MX2014005537A (es) 2014-09-16
BR112014011308B1 (pt) 2021-04-13
EP2776369A1 (en) 2014-09-17
KR102032584B1 (ko) 2019-10-15
KR20140093982A (ko) 2014-07-29
RU2014123614A (ru) 2015-12-20
JP6324895B2 (ja) 2018-05-16
MX375064B (es) 2025-03-06
WO2013068976A1 (en) 2013-05-16
BR112014011308A2 (pt) 2017-05-09

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