CN103987878A - 通过蒸汽电解制备氢和氧的方法 - Google Patents

通过蒸汽电解制备氢和氧的方法 Download PDF

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Publication number
CN103987878A
CN103987878A CN201280057387.3A CN201280057387A CN103987878A CN 103987878 A CN103987878 A CN 103987878A CN 201280057387 A CN201280057387 A CN 201280057387A CN 103987878 A CN103987878 A CN 103987878A
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cathode
anode
proton
electrolyte
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Chinese (zh)
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B·萨拉
F·格拉塞
O·拉克鲁瓦
A·西拉
K·拉莫尼
M·凯达姆
竹之内久
D·格雨里奥
B·邦德热伊奥
P·科洛邦
A·范德利
J·G·桑什兹
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • B01D53/326—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00 in electrochemical cells
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/22—Non-catalytic cracking in the presence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/007—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C25B11/031—Porous electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/302—Sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/404—Nitrogen oxides other than dinitrogen oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/502—Carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
CN201280057387.3A 2011-10-12 2012-10-11 通过蒸汽电解制备氢和氧的方法 Pending CN103987878A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1159221A FR2981368B1 (fr) 2011-10-12 2011-10-12 Procede de generation d'hydrogene et d'oxygene par electrolyse de vapeur d'eau
FR1159221 2011-10-12
PCT/EP2012/070214 WO2013053858A1 (fr) 2011-10-12 2012-10-11 Procédé de génération d'hydrogène et d'oxygène par électrolyse de vapeur d'eau

Publications (1)

Publication Number Publication Date
CN103987878A true CN103987878A (zh) 2014-08-13

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US (1) US20140284220A1 (enExample)
EP (1) EP2766512A1 (enExample)
JP (1) JP2014532119A (enExample)
CN (1) CN103987878A (enExample)
BR (1) BR112014008732A2 (enExample)
FR (1) FR2981368B1 (enExample)
IN (1) IN2014DN03034A (enExample)
RU (1) RU2014118792A (enExample)
WO (1) WO2013053858A1 (enExample)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106185984A (zh) * 2016-07-23 2016-12-07 陈志强 基于水蒸汽电解法联合生产氨与硝酸的系统
CN108040487A (zh) * 2015-06-10 2018-05-15 西门子股份公司 用于合成氨的电化学电池
CN108350584A (zh) * 2015-11-16 2018-07-31 西门子股份公司 电化学电池和工艺
CN108698938A (zh) * 2016-02-25 2018-10-23 京瓷株式会社 光吸收构件、制氢用构件以及制氢装置
CN110804468A (zh) * 2019-11-27 2020-02-18 浙江天禄环境科技有限公司 一种合成气的干法脱硫工艺
CN111282410A (zh) * 2020-02-19 2020-06-16 华中师范大学 电化学法降解气态污染物的装置及其方法

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BR112016002269A2 (pt) 2013-07-31 2017-08-01 Aquahydrex Pty Ltd método e célula eletroquímica para gerenciar reações eletroquímicas
WO2016017251A1 (ja) * 2014-07-28 2016-02-04 株式会社日本触媒 水蒸気電解用セル
JP6747778B2 (ja) * 2014-07-28 2020-08-26 株式会社日本触媒 水蒸気電解用セル
EP3176287B1 (en) 2014-07-28 2020-11-18 Nippon Shokubai Co., Ltd. Steam electrolysis cell
JP6363425B2 (ja) * 2014-08-08 2018-07-25 株式会社東芝 水素製造システム及び水素製造方法
US9951430B2 (en) * 2015-04-16 2018-04-24 Saudi Arabian Oil Company Methods for co-processing carbon dioxide and hydrogen sulfide
JP6521830B2 (ja) * 2015-10-20 2019-05-29 東京瓦斯株式会社 高温水蒸気電解セル及び高温水蒸気電解システム
JP6886753B2 (ja) * 2015-10-29 2021-06-16 宏之 小原 水素生成装置及び水素生成方法
WO2017100847A1 (en) * 2015-12-14 2017-06-22 Aquahydrex Pty Ltd Electrochemical cell and components thereof capable of operating at high current density
WO2018170243A1 (en) * 2017-03-16 2018-09-20 Battelle Energy Alliance, Llc Methods and systems for carbon dioxide hydrogenation
DE102017218012A1 (de) 2017-10-10 2019-04-11 Technische Universität Bergakademie Freiberg Elektrolyse- und/oder Brennstoffzelle umfassend ein Elektrodenmaterial enthaltend einen metallokeramischen Verbundwerkstoff und Verfahren zur Herstellung dieser
EP3887578A1 (en) 2018-11-28 2021-10-06 Opus 12 Incorporated Electrolyzer and method of use
EP3899092A1 (en) 2018-12-18 2021-10-27 Opus 12 Incorporated Electrolyzer and method of use
JP2022519575A (ja) 2019-02-01 2022-03-24 アクアハイドレックス， インコーポレイテッド 閉じ込められた電解質を有する電気化学システム
GB2616256A (en) * 2022-02-24 2023-09-06 Ceres Ip Co Ltd Treatment plant electrolyser system
US12305304B2 (en) 2022-10-13 2025-05-20 Twelve Benefit Corporation Interface for carbon oxide electrolyzer bipolar membrane
FR3157815A1 (fr) * 2023-12-27 2025-07-04 Genvia Installation et procédé de traitement de gaz sulfurés et de récupération de soufre par couplage d’unité d’électrolyse haute température

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CN101107056A (zh) * 2005-01-21 2008-01-16 埃克森美孚研究工程公司 对来自氢源的含氢物流中氢的控制
EP1889650A1 (en) * 2006-08-10 2008-02-20 Ngk Insulators, Ltd. Electrochemical devices
FR2939450A1 (fr) * 2008-12-05 2010-06-11 Alex Hr Roustaei Systeme de production, conversion et restitution de h2 en cycle gaz-liquide-gaz avec absorption du co2 a chaque changement d'etat, utilisant une double electrolyse alcaline a base des nanoparticules
CN101842521A (zh) * 2007-08-02 2010-09-22 法国原子能委员会 具有异热功能和高生产能力的高温、高压电解槽
US20100314235A1 (en) * 2009-06-16 2010-12-16 Exxonmobil Research And Engineering Company High temperature hydropyrolysis of carbonaceous materials
CN102056866A (zh) * 2008-05-15 2011-05-11 阿海珐 通过还原二氧化碳(CO2)和/或一氧化碳(CO)制备CxHyO2型化合物的方法

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CA2595588C (en) * 2005-01-21 2013-12-24 Exxonmobil Research And Engineering Company Management of hydrogen in hydrogen-containing streams from hydrogen sources
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FR2916653B1 (fr) 2007-06-01 2011-05-06 Areva Np Procede d'optimisation de la conductivite ionique d'une membrane conductrice ionique.
KR20110094969A (ko) * 2010-02-18 2011-08-24 삼성전자주식회사 나노다이아몬드를 포함하는 전기화학적 수처리용 전극 및 상기 전극을 포함하는 전기화학적 수처리 장치

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4547273A (en) * 1984-06-07 1985-10-15 Energy Conversion Devices, Inc. Mobile atom insertion reaction, mobile atom transmissive membrane for carrying out the reaction, and reactor incorporating the mobile atom transmissive membrane
CN101107056A (zh) * 2005-01-21 2008-01-16 埃克森美孚研究工程公司 对来自氢源的含氢物流中氢的控制
EP1889650A1 (en) * 2006-08-10 2008-02-20 Ngk Insulators, Ltd. Electrochemical devices
CN101842521A (zh) * 2007-08-02 2010-09-22 法国原子能委员会 具有异热功能和高生产能力的高温、高压电解槽
CN102056866A (zh) * 2008-05-15 2011-05-11 阿海珐 通过还原二氧化碳(CO2)和/或一氧化碳(CO)制备CxHyO2型化合物的方法
FR2939450A1 (fr) * 2008-12-05 2010-06-11 Alex Hr Roustaei Systeme de production, conversion et restitution de h2 en cycle gaz-liquide-gaz avec absorption du co2 a chaque changement d'etat, utilisant une double electrolyse alcaline a base des nanoparticules
US20100314235A1 (en) * 2009-06-16 2010-12-16 Exxonmobil Research And Engineering Company High temperature hydropyrolysis of carbonaceous materials

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108040487A (zh) * 2015-06-10 2018-05-15 西门子股份公司 用于合成氨的电化学电池
CN108040487B (zh) * 2015-06-10 2019-09-06 西门子股份公司 用于合成氨的电化学电池
CN108350584A (zh) * 2015-11-16 2018-07-31 西门子股份公司 电化学电池和工艺
CN108350584B (zh) * 2015-11-16 2020-07-07 西门子股份公司 电化学电池和工艺
CN108698938A (zh) * 2016-02-25 2018-10-23 京瓷株式会社 光吸收构件、制氢用构件以及制氢装置
CN106185984A (zh) * 2016-07-23 2016-12-07 陈志强 基于水蒸汽电解法联合生产氨与硝酸的系统
CN106185984B (zh) * 2016-07-23 2021-06-29 陈志强 基于水蒸汽电解法联合生产氨与硝酸的系统
CN110804468A (zh) * 2019-11-27 2020-02-18 浙江天禄环境科技有限公司 一种合成气的干法脱硫工艺
CN111282410A (zh) * 2020-02-19 2020-06-16 华中师范大学 电化学法降解气态污染物的装置及其方法
CN111282410B (zh) * 2020-02-19 2021-07-06 华中师范大学 电化学法降解气态污染物的装置及其方法

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US20140284220A1 (en) 2014-09-25
FR2981368A1 (fr) 2013-04-19
RU2014118792A (ru) 2015-11-20
WO2013053858A1 (fr) 2013-04-18
IN2014DN03034A (enExample) 2015-05-08
EP2766512A1 (fr) 2014-08-20
JP2014532119A (ja) 2014-12-04
BR112014008732A2 (pt) 2017-04-25
FR2981368B1 (fr) 2013-11-15

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