FR2981368B1 - Procede de generation d'hydrogene et d'oxygene par electrolyse de vapeur d'eau - Google Patents
Procede de generation d'hydrogene et d'oxygene par electrolyse de vapeur d'eauInfo
- Publication number
- FR2981368B1 FR2981368B1 FR1159221A FR1159221A FR2981368B1 FR 2981368 B1 FR2981368 B1 FR 2981368B1 FR 1159221 A FR1159221 A FR 1159221A FR 1159221 A FR1159221 A FR 1159221A FR 2981368 B1 FR2981368 B1 FR 2981368B1
- Authority
- FR
- France
- Prior art keywords
- anode
- oxygen
- electrolysis
- cathode
- steam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title abstract 3
- 238000005868 electrolysis reaction Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 239000001301 oxygen Substances 0.000 title abstract 3
- 229910052760 oxygen Inorganic materials 0.000 title abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title abstract 2
- 239000001257 hydrogen Substances 0.000 title abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 2
- 239000000919 ceramic Substances 0.000 abstract 2
- 239000003792 electrolyte Substances 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- 239000002156 adsorbate Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000007784 solid electrolyte Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/32—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
- B01D53/326—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00 in electrochemical cells
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/44—Hydrogenation of the aromatic hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/22—Non-catalytic cracking in the presence of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/007—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
- C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
- C25B11/031—Porous electrodes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/25—Reduction
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
- C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/302—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/404—Nitrogen oxides other than dinitrogen oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/502—Carbon monoxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1159221A FR2981368B1 (fr) | 2011-10-12 | 2011-10-12 | Procede de generation d'hydrogene et d'oxygene par electrolyse de vapeur d'eau |
| RU2014118792/04A RU2014118792A (ru) | 2011-10-12 | 2012-10-11 | Способ получения водорода и кислорода электролизом водяного пара |
| IN3034DEN2014 IN2014DN03034A (enExample) | 2011-10-12 | 2012-10-11 | |
| EP12773302.0A EP2766512A1 (fr) | 2011-10-12 | 2012-10-11 | Procédé de génération d'hydrogène et d'oxygène par électrolyse de vapeur d'eau |
| CN201280057387.3A CN103987878A (zh) | 2011-10-12 | 2012-10-11 | 通过蒸汽电解制备氢和氧的方法 |
| BR112014008732A BR112014008732A2 (pt) | 2011-10-12 | 2012-10-11 | método para gerar hidrogênio e oxigênio por eletrólise a vapor |
| PCT/EP2012/070214 WO2013053858A1 (fr) | 2011-10-12 | 2012-10-11 | Procédé de génération d'hydrogène et d'oxygène par électrolyse de vapeur d'eau |
| US14/350,844 US20140284220A1 (en) | 2011-10-12 | 2012-10-11 | Method for generating hydrogen and oxygen by steam electrolysis |
| JP2014535087A JP2014532119A (ja) | 2011-10-12 | 2012-10-11 | 水蒸気の電気分解によって水素と酸素を発生させる方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1159221A FR2981368B1 (fr) | 2011-10-12 | 2011-10-12 | Procede de generation d'hydrogene et d'oxygene par electrolyse de vapeur d'eau |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2981368A1 FR2981368A1 (fr) | 2013-04-19 |
| FR2981368B1 true FR2981368B1 (fr) | 2013-11-15 |
Family
ID=47040711
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR1159221A Expired - Fee Related FR2981368B1 (fr) | 2011-10-12 | 2011-10-12 | Procede de generation d'hydrogene et d'oxygene par electrolyse de vapeur d'eau |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20140284220A1 (enExample) |
| EP (1) | EP2766512A1 (enExample) |
| JP (1) | JP2014532119A (enExample) |
| CN (1) | CN103987878A (enExample) |
| BR (1) | BR112014008732A2 (enExample) |
| FR (1) | FR2981368B1 (enExample) |
| IN (1) | IN2014DN03034A (enExample) |
| RU (1) | RU2014118792A (enExample) |
| WO (1) | WO2013053858A1 (enExample) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2014295915A1 (en) | 2013-07-31 | 2016-02-11 | Aquahydrex Pty Ltd | Modular electrochemical cells |
| US10480083B2 (en) | 2014-07-28 | 2019-11-19 | Nippon Shokubai Co., Ltd. | Steam electrolysis cell |
| WO2016017251A1 (ja) * | 2014-07-28 | 2016-02-04 | 株式会社日本触媒 | 水蒸気電解用セル |
| JP6747778B2 (ja) * | 2014-07-28 | 2020-08-26 | 株式会社日本触媒 | 水蒸気電解用セル |
| JP6363425B2 (ja) * | 2014-08-08 | 2018-07-25 | 株式会社東芝 | 水素製造システム及び水素製造方法 |
| US9951430B2 (en) * | 2015-04-16 | 2018-04-24 | Saudi Arabian Oil Company | Methods for co-processing carbon dioxide and hydrogen sulfide |
| GB2539233B (en) * | 2015-06-10 | 2019-12-18 | Siemens Plc | Electrochemical cell |
| JP6521830B2 (ja) * | 2015-10-20 | 2019-05-29 | 東京瓦斯株式会社 | 高温水蒸気電解セル及び高温水蒸気電解システム |
| JP6886753B2 (ja) * | 2015-10-29 | 2021-06-16 | 宏之 小原 | 水素生成装置及び水素生成方法 |
| GB2544485B (en) * | 2015-11-16 | 2018-09-19 | Siemens Ag | Electrochemical cell comprising a steam inlet and a solid oxide layer |
| EP3390694A4 (en) * | 2015-12-14 | 2019-10-23 | AquaHydrex Pty Ltd | METHOD AND SYSTEM FOR THE EFFICIENT OPERATION OF ELECTROCHEMICAL CELLS |
| EP3421443B1 (en) * | 2016-02-25 | 2020-11-04 | Kyocera Corporation | Light-absorbing member, hydrogen production member, and hydrogen production device |
| CN106185984B (zh) * | 2016-07-23 | 2021-06-29 | 陈志强 | 基于水蒸汽电解法联合生产氨与硝酸的系统 |
| US11421330B2 (en) * | 2017-03-16 | 2022-08-23 | Battelle Energy Alliance, Llc | Methods for carbon dioxide hydrogenation |
| DE102017218012A1 (de) | 2017-10-10 | 2019-04-11 | Technische Universität Bergakademie Freiberg | Elektrolyse- und/oder Brennstoffzelle umfassend ein Elektrodenmaterial enthaltend einen metallokeramischen Verbundwerkstoff und Verfahren zur Herstellung dieser |
| JP7468975B2 (ja) | 2018-11-28 | 2024-04-16 | トゥエルブ ベネフィット コーポレーション | 電解槽および使用方法 |
| CN113614287B (zh) * | 2018-12-18 | 2024-09-13 | 十二益公司 | 电解装置及使用方法 |
| CA3127358A1 (en) | 2019-02-01 | 2020-08-06 | Aquahydrex, Inc. | Electrochemical system with confined electrolyte |
| CN110804468B (zh) * | 2019-11-27 | 2023-03-31 | 浙江天禄环境科技有限公司 | 一种合成气的干法脱硫工艺 |
| CN111282410B (zh) * | 2020-02-19 | 2021-07-06 | 华中师范大学 | 电化学法降解气态污染物的装置及其方法 |
| GB2616256A (en) * | 2022-02-24 | 2023-09-06 | Ceres Ip Co Ltd | Treatment plant electrolyser system |
| US12305304B2 (en) | 2022-10-13 | 2025-05-20 | Twelve Benefit Corporation | Interface for carbon oxide electrolyzer bipolar membrane |
| FR3157815A1 (fr) * | 2023-12-27 | 2025-07-04 | Genvia | Installation et procédé de traitement de gaz sulfurés et de récupération de soufre par couplage d’unité d’électrolyse haute température |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4402804A (en) * | 1982-05-17 | 1983-09-06 | Ppg Industries, Inc. | Electrolytic synthesis of aryl alcohols, aryl aldehydes, and aryl acids |
| US4547273A (en) * | 1984-06-07 | 1985-10-15 | Energy Conversion Devices, Inc. | Mobile atom insertion reaction, mobile atom transmissive membrane for carrying out the reaction, and reactor incorporating the mobile atom transmissive membrane |
| JP5011127B2 (ja) * | 2005-01-21 | 2012-08-29 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | 水素源からの水素含有ストリーム中の水素の管理 |
| CN101163536B (zh) * | 2005-01-21 | 2011-12-07 | 埃克森美孚研究工程公司 | 采用精炼工艺单元如加氢处理、加氢裂化的快速循环压力摆动吸附的改进的集成 |
| DE102006035893A1 (de) * | 2006-07-31 | 2008-02-07 | Wolf, Bodo M., Dr. | Verfahren zur Wiederaufarbeitung von Verbrennungsprodukten fossiler Brennstoffe |
| US20080038621A1 (en) * | 2006-08-10 | 2008-02-14 | Ngk Insulators, Ltd. | Electrochemical devices |
| FR2916653B1 (fr) | 2007-06-01 | 2011-05-06 | Areva Np | Procede d'optimisation de la conductivite ionique d'une membrane conductrice ionique. |
| FR2919618B1 (fr) * | 2007-08-02 | 2009-11-13 | Commissariat Energie Atomique | Electrolyseur haute temperature et haute pression a fonctionnement allothermique et forte capacite de production |
| FR2931168B1 (fr) * | 2008-05-15 | 2010-07-30 | Areva | Procede de production de composes du type cxhyoz par reduction de dioxyde de carbone (co2) et/ou de monoxyde de carbone (co) |
| FR2939450B1 (fr) * | 2008-12-05 | 2013-11-01 | Alex Hr Roustaei | Systeme de production, conversion et restitution de h2 en cycle gaz-liquide-gaz avec absorption du co2 a chaque changement d'etat, utilisant une double electrolyse alcaline a base des nanoparticules |
| US20100314235A1 (en) * | 2009-06-16 | 2010-12-16 | Exxonmobil Research And Engineering Company | High temperature hydropyrolysis of carbonaceous materials |
| KR20110094969A (ko) * | 2010-02-18 | 2011-08-24 | 삼성전자주식회사 | 나노다이아몬드를 포함하는 전기화학적 수처리용 전극 및 상기 전극을 포함하는 전기화학적 수처리 장치 |
-
2011
- 2011-10-12 FR FR1159221A patent/FR2981368B1/fr not_active Expired - Fee Related
-
2012
- 2012-10-11 CN CN201280057387.3A patent/CN103987878A/zh active Pending
- 2012-10-11 JP JP2014535087A patent/JP2014532119A/ja active Pending
- 2012-10-11 IN IN3034DEN2014 patent/IN2014DN03034A/en unknown
- 2012-10-11 WO PCT/EP2012/070214 patent/WO2013053858A1/fr not_active Ceased
- 2012-10-11 EP EP12773302.0A patent/EP2766512A1/fr not_active Withdrawn
- 2012-10-11 BR BR112014008732A patent/BR112014008732A2/pt not_active Application Discontinuation
- 2012-10-11 RU RU2014118792/04A patent/RU2014118792A/ru not_active Application Discontinuation
- 2012-10-11 US US14/350,844 patent/US20140284220A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| US20140284220A1 (en) | 2014-09-25 |
| JP2014532119A (ja) | 2014-12-04 |
| BR112014008732A2 (pt) | 2017-04-25 |
| IN2014DN03034A (enExample) | 2015-05-08 |
| CN103987878A (zh) | 2014-08-13 |
| RU2014118792A (ru) | 2015-11-20 |
| EP2766512A1 (fr) | 2014-08-20 |
| WO2013053858A1 (fr) | 2013-04-18 |
| FR2981368A1 (fr) | 2013-04-19 |
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