CN103958568B - 通过均相催化醇胺化制备亲油性聚亚烷基多胺 - Google Patents

通过均相催化醇胺化制备亲油性聚亚烷基多胺 Download PDF

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Publication number
CN103958568B
CN103958568B CN201280057897.0A CN201280057897A CN103958568B CN 103958568 B CN103958568 B CN 103958568B CN 201280057897 A CN201280057897 A CN 201280057897A CN 103958568 B CN103958568 B CN 103958568B
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aliphatic
polyamines
reaction
catalyst
phase
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Chinese (zh)
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CN103958568A (zh
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J·斯特劳特曼
T·绍布
S·许弗
S·马斯
C·伍德
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0206—Polyalkylene(poly)amines
    • C08G73/0213—Preparatory process
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J179/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09J161/00 - C09J177/00
    • C09J179/02—Polyamines

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
CN201280057897.0A 2011-11-25 2012-11-19 通过均相催化醇胺化制备亲油性聚亚烷基多胺 Expired - Fee Related CN103958568B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11190791.1 2011-11-25
EP11190791 2011-11-25
PCT/EP2012/072944 WO2013076025A1 (de) 2011-11-25 2012-11-19 Lipophile polyalkylenpolyamine durch homogen-katalysierte alkohol-aminierung

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Publication Number Publication Date
CN103958568A CN103958568A (zh) 2014-07-30
CN103958568B true CN103958568B (zh) 2016-05-18

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CN201280057897.0A Expired - Fee Related CN103958568B (zh) 2011-11-25 2012-11-19 通过均相催化醇胺化制备亲油性聚亚烷基多胺

Country Status (9)

Country Link
US (1) US9550725B2 (enExample)
EP (1) EP2782948B1 (enExample)
JP (1) JP6124911B2 (enExample)
KR (1) KR20140098142A (enExample)
CN (1) CN103958568B (enExample)
BR (1) BR112014012587A2 (enExample)
ES (1) ES2590145T3 (enExample)
IN (1) IN2014CN03841A (enExample)
WO (1) WO2013076025A1 (enExample)

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ES2861300T3 (es) 2012-02-20 2021-10-06 Basf Se Potenciación de la actividad antimicrobiana de biocidas con polímeros
US8853400B2 (en) 2012-07-23 2014-10-07 Basf Se Process for the homogeneously catalyzed amination of alcohols with ammonia in the presence of a complex catalyst which comprises no anionic ligands
EP2842936A1 (en) 2013-08-26 2015-03-04 Basf Se Etheramines based on alkoxylated glycerine or trimethylolpropane.
KR20160048891A (ko) 2013-08-26 2016-05-04 바스프 에스이 저융점을 갖는 알콕실화 폴리에틸렌이민
WO2019066158A1 (ko) 2017-09-28 2019-04-04 주식회사 아주화장품 뷰리엘 민트차차 쿨아이스크림
US20230125610A1 (en) * 2020-06-17 2023-04-27 Basf Se Amphiphilic alkoxylated polyethylene/-propylene imine copolymers for multi-benefit detergent formulations
KR20230152102A (ko) * 2021-03-02 2023-11-02 도요보 가부시키가이샤 적층 필름 및 적층 필름의 제조 방법
CN116716031A (zh) * 2023-08-08 2023-09-08 广州市交通运输职业学校(广州市交通运输高级职业技术学校、广州市交通运输中等专业学校) 一种免喷漆速干车身修复材料及其制备方法

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US4032480A (en) * 1975-07-11 1977-06-28 David Solomonovich Zhuk Method of producing linear polyethylenimine
US5030740A (en) * 1988-10-14 1991-07-09 The Dow Chemical Company Process for preparing linearly-extended polyalkylenepolyamines
WO1997021760A1 (de) * 1995-12-08 1997-06-19 Basf Aktiengesellschaft Verfahren zur kontinuierlichen herstellung von homopolymerisaten des ethylenimins
WO1997023546A1 (en) * 1995-12-21 1997-07-03 The Procter & Gamble Company A process for ethoxylating polyamines
US5726284A (en) * 1992-08-20 1998-03-10 The Dupont Merck Pharmaceutical Company Crosslinked polymric ammonium salts
CN101959905A (zh) * 2008-02-01 2011-01-26 巴斯夫欧洲公司 特定的聚异丁烯胺以及它们在燃料中作为洗涤剂的用途
CN103025430A (zh) * 2010-05-31 2013-04-03 巴斯夫欧洲公司 通过均相催化醇胺化获得的聚亚烷基聚胺
CN103958566A (zh) * 2011-11-25 2014-07-30 巴斯夫欧洲公司 通过均相催化醇胺化提高聚亚烷基多胺的摩尔质量
CN103987757A (zh) * 2011-11-25 2014-08-13 巴斯夫欧洲公司 通过在氢气存在下均相催化醇胺化合成低比色指数的聚亚烷基多胺

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US3708539A (en) 1970-02-06 1973-01-02 Union Oil Co Condensation of ammonia or a primary or secondary amine with an alcohol
US4044053A (en) * 1975-06-02 1977-08-23 Texaco Development Corporation Preparation of polyalkylene polyamines
DE2744982A1 (de) * 1977-10-06 1979-04-19 Basf Ag Verfahren zur herstellung von polyalkylenpolyaminen
JPS5480400A (en) * 1977-12-09 1979-06-27 Nippon Oil Co Ltd Production of polyhexamethyleneimine
EP0034480A3 (en) 1980-02-14 1982-01-13 Grigg, Ronald Ernest Alkylation of amines
CA1228449A (en) * 1982-04-30 1987-10-20 William B. Herdle Preparation of polyalkylene polyamines
CA1224896A (en) * 1982-04-30 1987-07-28 Union Carbide Corporation Preparation of polyalkyline polyamines using phosphorus amide catalyst
US4745190A (en) 1984-07-25 1988-05-17 Air Products And Chemicals, Inc. Selective synthesis of substituted amines
US5011999A (en) * 1989-02-23 1991-04-30 The Dow Chemical Company Process of preparing non-cyclic polyalkylenepolyamines employing group VB metal catalysts
KR910016811A (ko) * 1990-03-30 1991-11-05 티모시 엔. 비숍 고급 폴리알킬렌 폴리아민 및 하이드록실-함유 폴리알킬렌 폴리아민의 선택적인 제조
JP2895973B2 (ja) * 1991-03-05 1999-05-31 花王株式会社 新規第３級アミノアルコール及びその製造方法
JP2971979B2 (ja) * 1991-05-24 1999-11-08 花王株式会社 線状ポリ第３級アミンの製造方法
SK31395A3 (en) * 1992-08-20 1995-08-09 Du Pont Crosslinked polymeric ammonium salts
US8697834B2 (en) 2010-05-31 2014-04-15 Basf Se Polyalkylenepolyamines by homogeneously catalyzed alcohol amination
US9193666B2 (en) 2011-03-08 2015-11-24 Basf Se Process for preparing alkanolamines by homogeneously catalyzed alcohol amination
US8637709B2 (en) 2011-03-08 2014-01-28 Basf Se Process for the preparation of primary amines by homogeneously catalyzed alcohol amination
US8912361B2 (en) 2011-03-08 2014-12-16 Basf Se Process for preparing di-, tri- and polyamines by homogeneously catalyzed alcohol amination
US8785693B2 (en) 2011-03-08 2014-07-22 Basf Se Process for the preparation of primary amines by homogeneously catalyzed alcohol amination
US8877977B2 (en) 2011-11-25 2014-11-04 Basf Se Synthesis of polyalkylenepolyamines having a low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4032480A (en) * 1975-07-11 1977-06-28 David Solomonovich Zhuk Method of producing linear polyethylenimine
US5030740A (en) * 1988-10-14 1991-07-09 The Dow Chemical Company Process for preparing linearly-extended polyalkylenepolyamines
US5726284A (en) * 1992-08-20 1998-03-10 The Dupont Merck Pharmaceutical Company Crosslinked polymric ammonium salts
WO1997021760A1 (de) * 1995-12-08 1997-06-19 Basf Aktiengesellschaft Verfahren zur kontinuierlichen herstellung von homopolymerisaten des ethylenimins
WO1997023546A1 (en) * 1995-12-21 1997-07-03 The Procter & Gamble Company A process for ethoxylating polyamines
CN101959905A (zh) * 2008-02-01 2011-01-26 巴斯夫欧洲公司 特定的聚异丁烯胺以及它们在燃料中作为洗涤剂的用途
CN103025430A (zh) * 2010-05-31 2013-04-03 巴斯夫欧洲公司 通过均相催化醇胺化获得的聚亚烷基聚胺
CN103958566A (zh) * 2011-11-25 2014-07-30 巴斯夫欧洲公司 通过均相催化醇胺化提高聚亚烷基多胺的摩尔质量
CN103987757A (zh) * 2011-11-25 2014-08-13 巴斯夫欧洲公司 通过在氢气存在下均相催化醇胺化合成低比色指数的聚亚烷基多胺

Also Published As

Publication number Publication date
CN103958568A (zh) 2014-07-30
KR20140098142A (ko) 2014-08-07
BR112014012587A2 (pt) 2017-06-13
EP2782948A1 (de) 2014-10-01
US9550725B2 (en) 2017-01-24
JP2014534247A (ja) 2014-12-18
EP2782948B1 (de) 2016-06-08
IN2014CN03841A (enExample) 2015-09-04
WO2013076025A1 (de) 2013-05-30
ES2590145T3 (es) 2016-11-18
US20140305339A1 (en) 2014-10-16
JP6124911B2 (ja) 2017-05-10

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