CN103857626B - 用于锂离子电化学电池的高容量正极及其制备方法 - Google Patents

用于锂离子电化学电池的高容量正极及其制备方法 Download PDF

Info

Publication number
CN103857626B
CN103857626B CN201280042008.3A CN201280042008A CN103857626B CN 103857626 B CN103857626 B CN 103857626B CN 201280042008 A CN201280042008 A CN 201280042008A CN 103857626 B CN103857626 B CN 103857626B
Authority
CN
China
Prior art keywords
capacity
positive pole
lithium ion
ion electrochemical
electrochemical cells
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201280042008.3A
Other languages
English (en)
Chinese (zh)
Other versions
CN103857626A (zh
Inventor
莱夫·克里斯坦森
杰罗姆·E·斯坎兰
安东尼·P·林德特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN103857626A publication Critical patent/CN103857626A/zh
Application granted granted Critical
Publication of CN103857626B publication Critical patent/CN103857626B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Organic Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Secondary Cells (AREA)
CN201280042008.3A 2011-08-31 2012-08-21 用于锂离子电化学电池的高容量正极及其制备方法 Expired - Fee Related CN103857626B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161529307P 2011-08-31 2011-08-31
US61/529,307 2011-08-31
PCT/US2012/051644 WO2013070298A2 (en) 2011-08-31 2012-08-21 High capacity positive electrodes for use in lithium-ion electrochemical cells and methods of making same

Publications (2)

Publication Number Publication Date
CN103857626A CN103857626A (zh) 2014-06-11
CN103857626B true CN103857626B (zh) 2016-07-27

Family

ID=48290735

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280042008.3A Expired - Fee Related CN103857626B (zh) 2011-08-31 2012-08-21 用于锂离子电化学电池的高容量正极及其制备方法

Country Status (7)

Country Link
US (2) US9385368B2 (enExample)
EP (2) EP3159307A1 (enExample)
JP (2) JP6058671B2 (enExample)
KR (1) KR20140060544A (enExample)
CN (1) CN103857626B (enExample)
TW (1) TWI580101B (enExample)
WO (1) WO2013070298A2 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6369126B2 (ja) * 2014-05-21 2018-08-08 戸田工業株式会社 非水電解質二次電池用正極活物質粒子粉末及びその製造方法、並びに非水電解質二次電池
KR101762508B1 (ko) 2014-10-02 2017-07-27 주식회사 엘지화학 리튬 이차전지용 양극활물질, 이의 제조방법 및 이를 포함하는 리튬 이차전지
US11735721B2 (en) 2014-10-28 2023-08-22 Lg Energy Solution, Ltd. Positive electrode active material for lithium secondary battery, method for preparing the same and lithium secondary battery including the same
JP6487279B2 (ja) 2015-06-10 2019-03-20 住友化学株式会社 リチウム含有複合酸化物、正極活物質、リチウムイオン二次電池用正極およびリチウムイオン二次電池
CN106532158B (zh) * 2015-09-14 2018-12-28 丰田自动车株式会社 全固体电池系统及其制造方法
JP6699473B2 (ja) * 2015-09-14 2020-05-27 トヨタ自動車株式会社 全固体電池システム及びその製造方法
JP6109399B1 (ja) * 2016-03-31 2017-04-05 Ｂａｓｆ戸田バッテリーマテリアルズ合同会社 非水電解質二次電池用の正極活物質粒子及びその製造方法、並びに非水電解質二次電池
US10707531B1 (en) 2016-09-27 2020-07-07 New Dominion Enterprises Inc. All-inorganic solvents for electrolytes
EP3437149B1 (en) * 2017-02-22 2019-10-02 Lionano Inc. Core-shell electroactive materials
US11545662B2 (en) 2017-12-15 2023-01-03 Gs Yuasa International Ltd. Positive active material for nonaqueous electrolyte secondary battery, method of producing positive active material for nonaqueous electrolyte secondary battery, positive electrode for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery
CN112771695B (zh) 2018-06-21 2024-01-02 株式会社杰士汤浅国际 正极活性物质、正极、非水电解质二次电池及其使用方法
JP7147478B2 (ja) 2018-06-21 2022-10-05 株式会社Ｇｓユアサ 非水電解質二次電池、及び非水電解質二次電池の製造方法
JP6835888B2 (ja) * 2019-02-21 2021-02-24 住友化学株式会社 リチウム含有複合酸化物、正極活物質、リチウムイオン二次電池用正極およびリチウムイオン二次電池
US11804588B2 (en) * 2020-07-24 2023-10-31 Uchicago Argonne, Llc Low cobalt layered oxide materials for lithium ion battery electrodes
CN114361440A (zh) * 2022-01-07 2022-04-15 巴斯夫杉杉电池材料有限公司 一种具有核壳结构的高电压三元正极材料及其制备方法
PL247295B1 (pl) * 2022-07-25 2025-06-09 Politechnika Warszawska Sposób otrzymywania podwójnie domieszkowanego itrem i wapniem wysokoniklowego materiału katodowego oraz jego zastosowanie w bateriach litowo-jonowych

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2751135A1 (fr) 1996-07-12 1998-01-16 Accumulateurs Fixes Electrode de generateur electrochimique rechargeable au lithium
JPH1167274A (ja) 1997-08-22 1999-03-09 Daikin Ind Ltd リチウム二次電池及び高分子ゲル電解質並びにリチウム二次電池用結着剤
US6699336B2 (en) 2000-01-13 2004-03-02 3M Innovative Properties Company Amorphous electrode compositions
JP2001319652A (ja) 2000-05-11 2001-11-16 Sony Corp 正極活物質及び非水電解質電池、並びにそれらの製造方法
KR100337889B1 (ko) 2000-06-22 2002-05-24 김순택 리튬 2차전지
US6756154B2 (en) 2000-11-29 2004-06-29 Toda Kogyo Corporation Cathode active material for non-aqueous electrolyte secondary cell and process for producing the same
JP3588338B2 (ja) 2001-05-31 2004-11-10 三洋電機株式会社 非水電解質二次電池
US6680145B2 (en) 2001-08-07 2004-01-20 3M Innovative Properties Company Lithium-ion batteries
US7341804B2 (en) 2002-09-20 2008-03-11 3M Innovative Properties Company Anode compositions having an elastomeric binder and an adhesion promoter
US7498100B2 (en) 2003-08-08 2009-03-03 3M Innovative Properties Company Multi-phase, silicon-containing electrode for a lithium-ion battery
JP2005141983A (ja) 2003-11-05 2005-06-02 Mitsubishi Chemicals Corp リチウム二次電池正極材料用層状リチウムニッケル系複合酸化物粉体及びその製造方法、リチウム二次電池用正極並びにリチウム二次電池
EP1742281B1 (en) * 2004-04-27 2011-09-07 Mitsubishi Chemical Corporation Layered lithium nickel manganese cobalt composite oxide powder for material of positive electrode of lithium secondary battery, process for producing the same, positive electrode of lithium secondary battery therefrom, and lithium secondary battery
JP2005336004A (ja) 2004-05-26 2005-12-08 Mitsubishi Chemicals Corp ニッケルマンガンコバルト系複合酸化物、層状リチウムニッケルマンガンコバルト系複合酸化物及びリチウム二次電池正極材料とそれを用いたリチウム二次電池用正極、並びにリチウム二次電池
WO2005124898A1 (ja) * 2004-06-16 2005-12-29 Seimi Chemical Co., Ltd. リチウム二次電池用正極活物質粉末
US7871727B2 (en) 2005-07-25 2011-01-18 3M Innovative Properties Company Alloy composition for lithium ion batteries
US7767349B2 (en) 2005-07-25 2010-08-03 3M Innovative Properties Company Alloy compositions for lithium ion batteries
US7732095B2 (en) 2005-12-01 2010-06-08 3M Innovative Properties Company Electrode compositions based on an amorphous alloy having a high silicon content
US7906238B2 (en) 2005-12-23 2011-03-15 3M Innovative Properties Company Silicon-containing alloys useful as electrodes for lithium-ion batteries
US20080280205A1 (en) * 2007-05-07 2008-11-13 3M Innovative Properties Company Lithium mixed metal oxide cathode compositions and lithium-ion electrochemical cells incorporating same
KR20100137447A (ko) 2008-02-12 2010-12-30 쓰리엠 이노베이티브 프로퍼티즈 컴파니 고전압 캐소드용 산화환원 셔틀
JP5430920B2 (ja) 2008-03-17 2014-03-05 三洋電機株式会社 非水電解質二次電池
EP2277215A1 (en) 2008-03-24 2011-01-26 3M Innovative Properties Company High voltage cathode compositions
US8153301B2 (en) 2008-07-21 2012-04-10 3M Innovative Properties Company Cathode compositions for lithium-ion electrochemical cells
KR101115416B1 (ko) * 2009-06-08 2012-02-15 한양대학교 산학협력단 리튬 이차 전지용 양극 활물질, 이의 제조 방법 및 이를 포함하는 리튬 이차 전지
CN102639443B (zh) 2009-12-07 2015-04-15 住友化学株式会社 锂复合金属氧化物的制造方法、锂复合金属氧化物及非水电解质二次电池

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"Study of Li1+x(Mn4/9Co1/9Ni4/9)1-xO2 Cathode Materials for Vehicle Battery Applications";Sun-Ho Kang et al.;《Journal of The Electrochemical Society》;20110615;第158卷(第8期);第A936-A941页 *

Also Published As

Publication number Publication date
KR20140060544A (ko) 2014-05-20
EP2751030B1 (en) 2017-04-26
US20160276666A1 (en) 2016-09-22
JP2014529868A (ja) 2014-11-13
US9385368B2 (en) 2016-07-05
CN103857626A (zh) 2014-06-11
TW201312841A (zh) 2013-03-16
EP3159307A1 (en) 2017-04-26
WO2013070298A2 (en) 2013-05-16
JP6058671B2 (ja) 2017-01-11
WO2013070298A3 (en) 2014-03-20
TWI580101B (zh) 2017-04-21
EP2751030A2 (en) 2014-07-09
US20140234717A1 (en) 2014-08-21
JP2017084801A (ja) 2017-05-18

Similar Documents

Publication Publication Date Title
CN103857626B (zh) 用于锂离子电化学电池的高容量正极及其制备方法
JP6462250B2 (ja) リチウム二次電池用正極活物質、その製造方法、そしてこれを含むリチウム二次電池用正極およびリチウム二次電池
CN101107735B (zh) 锂离子二次电池
KR101762980B1 (ko) 정극 활성 물질 입자 분말 및 그의 제조 방법, 및 비수전해질 이차 전지
CN103348508B (zh) 复合粒子，其制备方法，以及包括所述复合粒子的物品
JP6583983B2 (ja) リチウム二次電池用正極活物質、その製造方法、及びこれを含むリチウム二次電池
TWI622212B (zh) 用於鋰離子電池的陰極組成物
US20110183209A1 (en) High capacity lithium-ion electrochemical cells
CN107768657A (zh) 一种锂离子电池正极材料、制备方法及锂离子电池
JP2023518984A (ja) リチウム電池のための低コバルト及びコバルトを含まない高エネルギー正極材料
WO2010113512A1 (ja) リチウムイオン二次電池用正極活物質及びその製造方法並びにリチウムイオン二次電池
CN102280637A (zh) 正极活性材料前驱物、正极活性材料和二次锂电池
US20160049644A1 (en) Positive active material for rechargeable lithium battery
JP6139573B2 (ja) リチウム二次電池用正極活物質の製造方法、及びそれを含むリチウム二次電池
CN105375026A (zh) 正极活性物质、制造其的方法和包括其的可再充电锂电池
CN111900361A (zh) 一种正极活性物质及其制备方法和在锂离子二次电池中的用途
WO2013043449A1 (en) High capacity lithium-ion electrochemical cells and methods of making same
US20140302393A1 (en) High capacity lithium-ion electrochemical cells and methods of making same
CN102280633A (zh) 正极活性材料、其制造方法和使用其的可充电锂电池
HK1161654A (en) Positive electrode materials for lithium ion batteries having a high specific discharge capacity and processes for the synthesis of these materials

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160727

Termination date: 20190821