CN103774276A - 采用物理共混制备木质素/聚丙烯腈共混熔纺纤维的方法 - Google Patents
采用物理共混制备木质素/聚丙烯腈共混熔纺纤维的方法 Download PDFInfo
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- CN103774276A CN103774276A CN201410014614.5A CN201410014614A CN103774276A CN 103774276 A CN103774276 A CN 103774276A CN 201410014614 A CN201410014614 A CN 201410014614A CN 103774276 A CN103774276 A CN 103774276A
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- lignin
- polyacrylonitrile
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- spun fibre
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- 239000000835 fiber Substances 0.000 title claims abstract description 71
- 229920005610 lignin Polymers 0.000 title claims abstract description 65
- 229920002239 polyacrylonitrile Polymers 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims abstract description 27
- 238000002464 physical blending Methods 0.000 title claims abstract description 14
- 238000009987 spinning Methods 0.000 claims abstract description 23
- 239000004014 plasticizer Substances 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 238000004804 winding Methods 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims description 20
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 150000002460 imidazoles Chemical class 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 238000002074 melt spinning Methods 0.000 abstract description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 230000015556 catabolic process Effects 0.000 abstract description 2
- 125000004093 cyano group Chemical group *C#N 0.000 abstract description 2
- 238000006731 degradation reaction Methods 0.000 abstract description 2
- 239000004480 active ingredient Substances 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 230000003993 interaction Effects 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 description 7
- 229920000049 Carbon (fiber) Polymers 0.000 description 5
- 239000004917 carbon fiber Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000002243 precursor Substances 0.000 description 5
- 238000004513 sizing Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 230000007096 poisonous effect Effects 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- 239000012675 alcoholic extract Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000002166 wet spinning Methods 0.000 description 2
- 241000826860 Trapezium Species 0.000 description 1
- 230000003026 anti-oxygenic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- -1 phenmethylol Chemical group 0.000 description 1
- 229920006350 polyacrylonitrile resin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
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CN201410014614.5A CN103774276B (zh) | 2014-01-13 | 2014-01-13 | 采用物理共混制备木质素/聚丙烯腈共混熔纺纤维的方法 |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103993378A (zh) * | 2014-05-30 | 2014-08-20 | 东华大学 | 一种木质素改性聚对苯二甲酸乙二醇酯纤维的制备方法 |
CN104593906A (zh) * | 2015-02-15 | 2015-05-06 | 东华大学 | 一种木质素基碳纤维的制备方法 |
CN105177758A (zh) * | 2015-10-26 | 2015-12-23 | 太仓市双宇化纤有限公司 | 一种抗静电聚丙烯腈/聚苯胺复合纤维材料及其制备方法 |
CN104593902B (zh) * | 2015-02-15 | 2017-01-04 | 东华大学 | 一种碳纤维前驱体聚丙烯腈/木质素纤维的制备方法 |
WO2017059507A1 (pt) * | 2015-10-05 | 2017-04-13 | Laboratórios Químicos E Metrológicos Quimlab Ltda | Composição de blenda de pol(acr!lon(triuvlignina e sua utilização na f5âção por fusão de precursor de fibra carbono |
CN108043249A (zh) * | 2017-12-18 | 2018-05-18 | 中国科学院山西煤炭化学研究所 | 一种木质素改性聚丙烯腈制备中空纤维膜的方法 |
CN108691024A (zh) * | 2018-06-29 | 2018-10-23 | 百事基材料(青岛)股份有限公司 | 含植物提取物的改性腈纶纤维及其制备方法 |
CN114369880A (zh) * | 2022-01-14 | 2022-04-19 | 中国纺织科学研究院有限公司 | 多孔聚乙烯纤维、其制备方法及其用途 |
CN114395823A (zh) * | 2021-12-09 | 2022-04-26 | 安徽元琛环保科技股份有限公司 | 一种耐氧化pps过滤材料的制作方法及制得的改性pps纤维 |
WO2023225010A1 (en) * | 2022-05-16 | 2023-11-23 | North Carolina State University | Melt spinning lignin/acrylic fibers |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS602711A (ja) * | 1983-06-14 | 1985-01-09 | Mitsubishi Rayon Co Ltd | 黒鉛繊維の製造法 |
CN101182653A (zh) * | 2007-11-20 | 2008-05-21 | 中国科学院长春应用化学研究所 | 一种含咪唑盐的聚丙烯腈纺丝液及其制备方法 |
CN101545148A (zh) * | 2009-03-31 | 2009-09-30 | 东华大学 | 一种咪唑型离子液体为增塑剂的聚丙烯腈pan熔融纺丝方法 |
CN102251320A (zh) * | 2011-06-30 | 2011-11-23 | 东华大学 | 一种快速氧化的聚丙烯腈纤维的制备方法 |
CN102485980A (zh) * | 2010-12-06 | 2012-06-06 | 财团法人工业技术研究院 | 聚丙烯腈类纤维原丝增塑剂、组合物以及其碳纤维的制法 |
CN102517689A (zh) * | 2011-12-02 | 2012-06-27 | 华南理工大学 | 一种木质素基皮芯结构纳/微米纤维及其制备方法 |
WO2013020919A1 (de) * | 2011-08-05 | 2013-02-14 | Sgl Carbon Se | Precursorfasern auf basis von nachwachsenden rohstoffen |
CN103080390A (zh) * | 2010-06-30 | 2013-05-01 | 韦尔豪泽Nr公司 | 含木质素/聚丙烯腈的纺丝液、纤维及其制备方法 |
KR20130078788A (ko) * | 2011-12-30 | 2013-07-10 | 코오롱인더스트리 주식회사 | 탄소섬유용 복합 전구체 멀티 필라멘트 및 탄소섬유의 제조방법 |
CN103451777A (zh) * | 2013-09-10 | 2013-12-18 | 北京梦狐宇通竹纤维研究开发中心 | 制备中间相木质素及其碳纤维的工艺方法 |
-
2014
- 2014-01-13 CN CN201410014614.5A patent/CN103774276B/zh active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS602711A (ja) * | 1983-06-14 | 1985-01-09 | Mitsubishi Rayon Co Ltd | 黒鉛繊維の製造法 |
CN101182653A (zh) * | 2007-11-20 | 2008-05-21 | 中国科学院长春应用化学研究所 | 一种含咪唑盐的聚丙烯腈纺丝液及其制备方法 |
CN101545148A (zh) * | 2009-03-31 | 2009-09-30 | 东华大学 | 一种咪唑型离子液体为增塑剂的聚丙烯腈pan熔融纺丝方法 |
CN103080390A (zh) * | 2010-06-30 | 2013-05-01 | 韦尔豪泽Nr公司 | 含木质素/聚丙烯腈的纺丝液、纤维及其制备方法 |
CN102485980A (zh) * | 2010-12-06 | 2012-06-06 | 财团法人工业技术研究院 | 聚丙烯腈类纤维原丝增塑剂、组合物以及其碳纤维的制法 |
CN102251320A (zh) * | 2011-06-30 | 2011-11-23 | 东华大学 | 一种快速氧化的聚丙烯腈纤维的制备方法 |
WO2013020919A1 (de) * | 2011-08-05 | 2013-02-14 | Sgl Carbon Se | Precursorfasern auf basis von nachwachsenden rohstoffen |
CN102517689A (zh) * | 2011-12-02 | 2012-06-27 | 华南理工大学 | 一种木质素基皮芯结构纳/微米纤维及其制备方法 |
KR20130078788A (ko) * | 2011-12-30 | 2013-07-10 | 코오롱인더스트리 주식회사 | 탄소섬유용 복합 전구체 멀티 필라멘트 및 탄소섬유의 제조방법 |
CN103451777A (zh) * | 2013-09-10 | 2013-12-18 | 北京梦狐宇通竹纤维研究开发中心 | 制备中间相木质素及其碳纤维的工艺方法 |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103993378A (zh) * | 2014-05-30 | 2014-08-20 | 东华大学 | 一种木质素改性聚对苯二甲酸乙二醇酯纤维的制备方法 |
CN103993378B (zh) * | 2014-05-30 | 2017-01-04 | 东华大学 | 一种木质素改性聚对苯二甲酸乙二醇酯纤维的制备方法 |
CN104593906A (zh) * | 2015-02-15 | 2015-05-06 | 东华大学 | 一种木质素基碳纤维的制备方法 |
CN104593902B (zh) * | 2015-02-15 | 2017-01-04 | 东华大学 | 一种碳纤维前驱体聚丙烯腈/木质素纤维的制备方法 |
WO2017059507A1 (pt) * | 2015-10-05 | 2017-04-13 | Laboratórios Químicos E Metrológicos Quimlab Ltda | Composição de blenda de pol(acr!lon(triuvlignina e sua utilização na f5âção por fusão de precursor de fibra carbono |
CN105177758A (zh) * | 2015-10-26 | 2015-12-23 | 太仓市双宇化纤有限公司 | 一种抗静电聚丙烯腈/聚苯胺复合纤维材料及其制备方法 |
CN108043249A (zh) * | 2017-12-18 | 2018-05-18 | 中国科学院山西煤炭化学研究所 | 一种木质素改性聚丙烯腈制备中空纤维膜的方法 |
CN108691024A (zh) * | 2018-06-29 | 2018-10-23 | 百事基材料(青岛)股份有限公司 | 含植物提取物的改性腈纶纤维及其制备方法 |
CN114395823A (zh) * | 2021-12-09 | 2022-04-26 | 安徽元琛环保科技股份有限公司 | 一种耐氧化pps过滤材料的制作方法及制得的改性pps纤维 |
CN114395823B (zh) * | 2021-12-09 | 2023-10-31 | 安徽元琛环保科技股份有限公司 | 一种耐氧化pps过滤材料的制作方法及制得的改性pps纤维 |
CN114369880A (zh) * | 2022-01-14 | 2022-04-19 | 中国纺织科学研究院有限公司 | 多孔聚乙烯纤维、其制备方法及其用途 |
WO2023225010A1 (en) * | 2022-05-16 | 2023-11-23 | North Carolina State University | Melt spinning lignin/acrylic fibers |
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Denomination of invention: Preparation of Lignin/Polyacrylonitrile Blended Melt Spinning Fiber by Physical Blending Effective date of registration: 20221006 Granted publication date: 20160504 Pledgee: Zhejiang Jiashan rural commercial bank Limited by Share Ltd. science and technology sub branch Pledgor: Youju new material (Zhejiang) Co.,Ltd. Registration number: Y2022330002458 |
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