CN103771440B - 直接合成具有CHA结构的含Cu沸石的方法 - Google Patents
直接合成具有CHA结构的含Cu沸石的方法 Download PDFInfo
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- CN103771440B CN103771440B CN201410067224.4A CN201410067224A CN103771440B CN 103771440 B CN103771440 B CN 103771440B CN 201410067224 A CN201410067224 A CN 201410067224A CN 103771440 B CN103771440 B CN 103771440B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
- B01J29/763—CHA-type, e.g. Chabazite, LZ-218
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/072—Iron group metals or copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/7065—CHA-type, e.g. Chabazite, LZ-218
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/038—Precipitation; Co-precipitation to form slurries or suspensions, e.g. a washcoat
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/30—Ion-exchange
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2062—Ammonia
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- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/206—Rare earth metals
- B01D2255/2063—Lanthanum
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20761—Copper
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2255/50—Zeolites
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- B01D2255/9202—Linear dimensions
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- B01D2255/90—Physical characteristics of catalysts
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- B01D2255/9207—Specific surface
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2257/404—Nitrogen oxides other than dinitrogen oxide
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2257/40—Nitrogen compounds
- B01D2257/406—Ammonia
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/01—Engine exhaust gases
- B01D2258/012—Diesel engines and lean burn gasoline engines
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths
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- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- Dispersion Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08156625 | 2008-05-21 | ||
| EP08156625.9 | 2008-05-21 | ||
| CN200980128392.7A CN102099293B (zh) | 2008-05-21 | 2009-05-19 | 直接合成具有CHA结构的含Cu沸石的方法 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200980128392.7A Division CN102099293B (zh) | 2008-05-21 | 2009-05-19 | 直接合成具有CHA结构的含Cu沸石的方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103771440A CN103771440A (zh) | 2014-05-07 |
| CN103771440B true CN103771440B (zh) | 2015-12-30 |
Family
ID=40984899
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410067224.4A Active CN103771440B (zh) | 2008-05-21 | 2009-05-19 | 直接合成具有CHA结构的含Cu沸石的方法 |
| CN200980128392.7A Active CN102099293B (zh) | 2008-05-21 | 2009-05-19 | 直接合成具有CHA结构的含Cu沸石的方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200980128392.7A Active CN102099293B (zh) | 2008-05-21 | 2009-05-19 | 直接合成具有CHA结构的含Cu沸石的方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US8715618B2 (enExample) |
| EP (3) | EP3778484A1 (enExample) |
| JP (1) | JP5743885B2 (enExample) |
| CN (2) | CN103771440B (enExample) |
| ES (1) | ES2465004T3 (enExample) |
| WO (1) | WO2009141324A1 (enExample) |
Families Citing this family (93)
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|---|---|---|---|---|
| US10384162B2 (en) * | 2007-03-26 | 2019-08-20 | Pq Corporation | High silica chabazite for selective catalytic reduction, methods of making and using same |
| EP3778484A1 (en) * | 2008-05-21 | 2021-02-17 | Basf Se | Process for the direct synthesis of cu containing zeolites having cha structure |
| GB2464478A (en) * | 2008-10-15 | 2010-04-21 | Johnson Matthey Plc | Aluminosilicate zeolite catalyst and use thereof in exhaust gas after-treatment |
| US10583424B2 (en) * | 2008-11-06 | 2020-03-10 | Basf Corporation | Chabazite zeolite catalysts having low silica to alumina ratios |
| JP5482179B2 (ja) | 2008-12-22 | 2014-04-23 | 東ソー株式会社 | チャバザイト型ゼオライト及びその製造方法 |
| WO2010099649A1 (en) | 2009-03-03 | 2010-09-10 | Basf Se | Process for preparation of pillared silicates |
| EP2521615A1 (en) | 2009-10-14 | 2012-11-14 | Basf Se | Copper containing levyne molecular sieve for selective reduction of nox |
| JP5833560B2 (ja) * | 2009-11-24 | 2015-12-16 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | Cha構造を有するゼオライトの製造方法 |
| US8293199B2 (en) * | 2009-12-18 | 2012-10-23 | Basf Corporation | Process for preparation of copper containing molecular sieves with the CHA structure, catalysts, systems and methods |
| US8293198B2 (en) | 2009-12-18 | 2012-10-23 | Basf Corporation | Process of direct copper exchange into Na+-form of chabazite molecular sieve, and catalysts, systems and methods |
| US9289756B2 (en) | 2010-07-15 | 2016-03-22 | Basf Se | Copper containing ZSM-34, OFF and/or ERI zeolitic material for selective reduction of NOx |
| GB2502207A (en) * | 2010-12-02 | 2013-11-20 | Johnson Matthey Plc | Zeolite catalyst containing metal |
| CN102274720B (zh) * | 2010-12-24 | 2013-04-17 | 河南科技大学 | 一种改性活性氧化铝及其制备方法 |
| CN103402635A (zh) * | 2011-03-08 | 2013-11-20 | 三菱树脂株式会社 | 催化剂、氮氧化物净化用元件、和氮氧化物净化用系统 |
| KR101948254B1 (ko) * | 2011-04-18 | 2019-02-14 | 피큐 코포레이션 | 대결정 유기물-비함유 차바자이트, 이의 제조 및 사용 방법 |
| JP6320918B2 (ja) * | 2011-07-27 | 2018-05-09 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Public Limited Company | 低リンチャバサイト |
| US9174849B2 (en) * | 2011-08-25 | 2015-11-03 | Basf Corporation | Molecular sieve precursors and synthesis of molecular sieves |
| US9670415B2 (en) * | 2011-09-06 | 2017-06-06 | Basf Se | Synthesis of zeolitic materials using N,N-dimethyl organotemplates |
| US20120258032A1 (en) * | 2011-11-02 | 2012-10-11 | Johnson Matthey Public Limited Company | Catalyzed filter for treating exhaust gas |
| KR102229855B1 (ko) * | 2012-02-07 | 2021-03-19 | 바스프 에스이 | 제올라이트 재료의 제조 방법 |
| US10245582B2 (en) | 2012-04-11 | 2019-04-02 | Johnson Matthey Public Limited Company | Zeolite catalyst containing metals |
| BR112014030263B1 (pt) * | 2012-06-04 | 2021-11-03 | Basf Se | Processo para a preparação de um material zeolítico que tem uma estrutura framework do tipo cha que compreende yo2 e x2o3 , material zeolítico sintético e uso de um material zeolítico sintético |
| US9636667B2 (en) | 2012-06-04 | 2017-05-02 | Basf Se | CHA-type zeolite materials and methods for their preparation using cycloalkyammonium compounds |
| JP6239001B2 (ja) * | 2012-12-12 | 2017-11-29 | ハルドール・トプサー・アクチエゼルスカベット | Cu−SSZ−13を合成するためのワンポット方法、該方法によって得られる化合物並びにそれの使用 |
| SG11201505945UA (en) * | 2013-02-05 | 2015-08-28 | Basf Se | Process for preparing a boron containing zeolitic material having mww framework structure |
| CN103157505B (zh) * | 2013-03-25 | 2015-08-26 | 中国科学院生态环境研究中心 | 一种Cu-SSZ-13催化剂、制备方法及其用途 |
| DE202013012229U1 (de) | 2013-04-05 | 2015-10-08 | Umicore Ag & Co. Kg | CuCHA Material für die SCR-Katalyse |
| US20140357474A1 (en) * | 2013-05-30 | 2014-12-04 | Corning Incorporated | Formed ceramic substrate composition for catalyst integration |
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| US9296620B2 (en) * | 2013-08-09 | 2016-03-29 | Chevron U.S.A. Inc. | Preparation of high-silica cha-type molecular sieves using a mixed template |
| GB201421333D0 (en) * | 2013-12-02 | 2015-01-14 | Johnson Matthey Plc | Mixed template synthesis of high silica cu-cha |
| US11266981B2 (en) * | 2013-12-02 | 2022-03-08 | Johnson Matthey Public Limited Company | Mixed template synthesis of low silica CHA zeolite |
| KR102288100B1 (ko) * | 2013-12-02 | 2021-08-11 | 존슨 맛쎄이 퍼블릭 리미티드 컴파니 | Aei 제올라이트의 합성 |
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| WO2009141324A1 (en) | 2009-11-26 |
| JP5743885B2 (ja) | 2015-07-01 |
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| EP2551240B1 (en) | 2020-11-11 |
| EP2551240A3 (en) | 2016-04-20 |
| US9272272B2 (en) | 2016-03-01 |
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| EP2297036A1 (en) | 2011-03-23 |
| CN102099293A (zh) | 2011-06-15 |
| CN102099293B (zh) | 2014-03-26 |
| CN103771440A (zh) | 2014-05-07 |
| US20110076229A1 (en) | 2011-03-31 |
| US20140234206A1 (en) | 2014-08-21 |
| JP2011521871A (ja) | 2011-07-28 |
| EP2551240A2 (en) | 2013-01-30 |
| US8715618B2 (en) | 2014-05-06 |
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