CN103608107B - 制备用于将乙烯氧化为氧化乙烯的催化剂的方法 - Google Patents

制备用于将乙烯氧化为氧化乙烯的催化剂的方法 Download PDF

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Publication number
CN103608107B
CN103608107B CN201280028679.4A CN201280028679A CN103608107B CN 103608107 B CN103608107 B CN 103608107B CN 201280028679 A CN201280028679 A CN 201280028679A CN 103608107 B CN103608107 B CN 103608107B
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Chinese (zh)
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CN103608107A (zh
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T·罗森达尔
T·莫伊雷尔
C·K·杜布纳
T·盖格尔
A·格里茨奇
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/687—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)
CN201280028679.4A 2011-04-14 2012-04-13 制备用于将乙烯氧化为氧化乙烯的催化剂的方法 Expired - Fee Related CN103608107B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11162377.3 2011-04-14
EP11162377 2011-04-14
PCT/IB2012/051834 WO2012140614A1 (de) 2011-04-14 2012-04-13 Verfahren zur herstellung eines katalysators zur oxidation von ethen zu ethylenoxid

Publications (2)

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CN103608107A CN103608107A (zh) 2014-02-26
CN103608107B true CN103608107B (zh) 2015-11-25

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CN201280028679.4A Expired - Fee Related CN103608107B (zh) 2011-04-14 2012-04-13 制备用于将乙烯氧化为氧化乙烯的催化剂的方法

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EP (1) EP2696971A4 (enExample)
JP (1) JP6062417B2 (enExample)
CN (1) CN103608107B (enExample)
WO (1) WO2012140614A1 (enExample)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013066557A1 (en) * 2011-10-31 2013-05-10 Dow Technology Investments, Llc Methods for producing epoxidation catalysts and epoxidation methods utilizing these
US12629664B2 (en) 2018-02-07 2026-05-19 Basf Se Method for preparing a silver impregnation solution
TWI808125B (zh) 2018-02-07 2023-07-11 德商巴斯夫歐洲公司 有效地將乙烯氧化轉化為環氧乙烷之催化劑
EP3639924A1 (en) 2018-10-15 2020-04-22 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
EP3639923A1 (en) 2018-10-15 2020-04-22 Basf Se Process for producing ethylene oxide by gas-phase oxidation of ethylene
EP3659703A1 (en) 2018-11-28 2020-06-03 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
WO2021038027A1 (en) 2019-08-28 2021-03-04 Basf Se Process for preparing an epoxidation catalyst
EP3885038A1 (en) 2020-03-27 2021-09-29 Basf Se Process for producing an epoxidation catalyst
CN115867381B (zh) 2020-06-26 2025-01-10 巴斯夫欧洲公司 多孔催化剂载体成型体
WO2021260140A1 (en) 2020-06-26 2021-12-30 Basf Se Production of porous alpha-alumina supports from boehmitic derived aluminas
WO2021260138A1 (en) 2020-06-26 2021-12-30 Basf Se Shaped catalyst body for the production of ethylene oxide
US20240408585A1 (en) 2021-01-26 2024-12-12 Basf Se Epoxidation catalyst
WO2022268348A1 (en) 2021-06-25 2022-12-29 Basf Se High purity tableted alpha-alumina catalyst support
CN120051334A (zh) 2022-10-12 2025-05-27 巴斯夫欧洲公司 环氧化催化剂
WO2026027443A1 (en) 2024-07-29 2026-02-05 Basf Se Blended catalyst mix for epoxidation
WO2026125232A1 (en) 2024-12-09 2026-06-18 Basf Se Method for treating shaped catalyst bodies
CN121613037A (zh) * 2025-10-22 2026-03-06 上海润和盛建设备科技有限公司 一种表征催化剂表面活性氧物种的方法

Citations (3)

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US5102848A (en) * 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US5525740A (en) * 1993-03-01 1996-06-11 Scientific Design Company, Inc. Process for preparing silver catalyst and process of using same to produce ethylene oxide
CN101426573A (zh) * 2006-04-18 2009-05-06 陶氏环球技术公司 环氧烷催化剂及其应用

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IL84232A (en) * 1986-10-31 1992-06-21 Shell Int Research Catalyst and process for the catalytic production of ethylene oxide
US5070058A (en) * 1990-01-22 1991-12-03 Texaco, Inc. Method for making a catalyst composition used in the production of lower aliphatic alcohols
JPH0677685B2 (ja) * 1992-09-25 1994-10-05 三菱油化株式会社 エチレンからエチレンオキシドの製造方法
US5504052A (en) * 1994-12-02 1996-04-02 Scientific Design Company, Inc. Silver catalyst preparation
TW408034B (en) * 1997-12-16 2000-10-11 Nippon Catalytic Chem Ind Silver catalyst for production of ethylene oxide, method for production thereof, and method for production of ethylene oxide
JP4001429B2 (ja) * 1998-02-20 2007-10-31 株式会社日本触媒 エチレンオキシド製造用銀触媒、その製造方法およびエチレンオキシドの製造方法
DE69924453T2 (de) * 1998-11-17 2006-02-16 Nippon Shokubai Co., Ltd. Katalysatorträger zur Verwendung in der Herstellung von Ethylenoxid
JP2002320855A (ja) * 2001-04-25 2002-11-05 Scientific Design Co Inc 酸化エチレン用触媒
BR0307958B1 (pt) * 2002-02-25 2013-07-09 catalisador de prata suportado, processo para preparação do mesmo, processo para epoxidação de uma olefina e método para produção de um 1,2-diol, um 1,2-diol éter ou uma alcanolamina
TW200500351A (en) * 2003-05-07 2005-01-01 Shell Int Research Silver-containing catalysts, the manufacture of such silver- containing catalysts, and the use thereof
US7977274B2 (en) * 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5102848A (en) * 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US5525740A (en) * 1993-03-01 1996-06-11 Scientific Design Company, Inc. Process for preparing silver catalyst and process of using same to produce ethylene oxide
CN101426573A (zh) * 2006-04-18 2009-05-06 陶氏环球技术公司 环氧烷催化剂及其应用

Also Published As

Publication number Publication date
JP6062417B2 (ja) 2017-01-18
EP2696971A4 (de) 2014-11-26
CN103608107A (zh) 2014-02-26
JP2014516310A (ja) 2014-07-10
WO2012140614A1 (de) 2012-10-18
EP2696971A1 (de) 2014-02-19

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