CN103598188A - Azoxystrobin-containing pesticide composition - Google Patents
Azoxystrobin-containing pesticide composition Download PDFInfo
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- CN103598188A CN103598188A CN201310367688.2A CN201310367688A CN103598188A CN 103598188 A CN103598188 A CN 103598188A CN 201310367688 A CN201310367688 A CN 201310367688A CN 103598188 A CN103598188 A CN 103598188A
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- fluoxastrobin
- tebuconazole
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Abstract
The invention discloses an azoxystrobin-containing pesticide composition. The pesticide composition comprises azoxystrobin and a triazole fungicide. The weight ratio of the azoxystrobin to the triazole fungicide is 1:60-60:1, and particularly the weight ratio of the azoxystrobin to the triazole fungicide is 1:1-3:2. The triazole fungicide is one of epoxiconazole, flutriafol, propiconazole, tebuconazole, hexaconazole, fluazinam or penconazole. The composition of the triazole fungicide and the azoxystrobin has significant synergistic effects, and can be used for disease control of fruit trees, cotton, rice, vegetables, and other crops, especially for disease control of rice blast, powdery mildew, gray mold and anthracnose.
Description
Technical field
The present invention relates to composition pesticide, be specifically related to a kind of composition pesticide containing Fluoxastrobin.
Background technology
Current domestic pesticide control generally adopts conventional spray-on process, generally can only complete the spraying area of 3-5 mu every day, inefficiency, and labour intensity is large, is not suitable for the control of farm, implant mass area and explosive damage by disease and insect; Secondly general pesticidal preparations need to be watered in a large number, and to much regional away from water source and drought and water shortage, conventional spraying cannot be carried out or can not reach desirable control efficiency.
Along with China carries out land transformation contract system, the rise of labour and agriculture as the foundation of the economy material price, the increasing of agricultural cost, has higher requirement to the drug effect of agricultural chemicals and lasting effect.
Adopt at present the single and frequent use containing the pesticide species of Fluoxastrobin, can make biological target grow with each passing day to the resistance of medicament, frequent and dosage medication must cause the sharp increase of pesticide cost and the destruction of ecotope.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of composition pesticide containing Fluoxastrobin, after Fluoxastrobin and triazole bactericidal agent are composite, there is obvious synergistic effect, disease control, especially rice blast, powdery mildew, gray mold, anthracnose for crops such as fruit tree, cotton, paddy rice, vegetables.
For achieving the above object, technical scheme of the present invention is as follows:
A composition pesticide containing Fluoxastrobin, comprises Fluoxastrobin and triazole bactericidal agent, and described triazole bactericidal agent and Fluoxastrobin mass ratio are 1: 60～60: 1.
Preferably, the mass ratio of described triazole bactericidal agent and Fluoxastrobin is 1:1～3:2.
Preferably, described triazole bactericidal agent is a kind of in epoxiconazole, Flutriafol, propiconazole, Tebuconazole, own azoles alcohol, fluazinam or penconazole.
Preferably, described composition pesticide comprises following formulation: microemulsion, water dispersible granules and suspending agent.
Preferably, microemulsion comprises following composition according to percetage by weight meter: Fluoxastrobin 1～50%, Tebuconazole 1～50%, emulsifier 5～15%, antifreezing agent 0～8%, defoamer 0.1-0.5%, solvent 10～74%.
Preferably, described water dispersible granules comprises following composition according to percetage by weight meter: Fluoxastrobin 1～50%, Tebuconazole 1～50%, dispersant 3～12%, wetting agent 2～8%, disintegrant 0～8%, binding agent 0～5%, carrier 8-10%, filler 10～74%.
Preferably, described suspending agent comprises following composition according to percetage by weight meter: Fluoxastrobin 1～50%, Tebuconazole 1～50%, dispersant 3～12%, wetting agent 2～10%, defoamer 0.1～0.5%, thickener 0～2%, antifreezing agent 0～8%, surplus are deionized water.
By technique scheme, the invention has the beneficial effects as follows:
Bactericidal composition of the present invention; between two kinds of active components, remain in use good composite stability; compare with single dose control corps diseases; expanding prevention disease scope; delay drug-fast generation; obviously improve drug effect, reduced dosage and the spraying times of every mu of use, ensured better agriculture safety in production and protected ecotope.
Accompanying drawing explanation
Fig. 1 is the process schematic representation that the present invention prepares Fluoxastrobin tebuconazole microemulsion.
Fig. 2 is the process schematic representation that the present invention prepares Fluoxastrobin tebuconazole water dispersible granule.
Fig. 3 is the process schematic representation that the present invention prepares Fluoxastrobin tebuconazole suspension concentrates.
Embodiment
For technological means, creation characteristic that the present invention is realized, reach object and effect is easy to understand, below in conjunction with concrete diagram, further set forth the present invention.
A composition pesticide containing Fluoxastrobin, comprises Fluoxastrobin and triazole bactericidal agent, and described Fluoxastrobin and triazole bactericidal agent mass ratio are 60: 1～1: 60.
Preferably, the mass ratio of described triazole bactericidal agent and Fluoxastrobin is 1:1～3:2.
Preferably, described triazole bactericidal agent is a kind of in epoxiconazole, Flutriafol, Tebuconazole, propiconazole, own azoles alcohol, fluazinam and penconazole.
Preferably, described composition pesticide comprises following formulation: microemulsion, water dispersible granules and suspending agent.
1) microemulsion comprises following composition according to percetage by weight meter: Fluoxastrobin 1～50%, Tebuconazole 1～50%, emulsifier (calcium dodecyl benzene sulfonate) 5～15%, antifreezing agent (ethylene glycol) 0～8%, defoamer (organosilicon) 0.1-0.5%, solvent (water) 10～74%.
With reference to manufacture craft Fig. 1, by Fluoxastrobin and Tebuconazole mixing, emulsifier, antifreezing agent, defoamer, solvent, the about 30-60min of mix and blend in mixed cylinder, and through sample analysis, qualified products can be made into Fluoxastrobin tebuconazole microemulsion product.
2) water dispersible granules comprises following composition according to percetage by weight meter: Fluoxastrobin 1～50%, Tebuconazole 1～50%, dispersant (sodium methylene bis-naphthalene sulfonate) 3～12%, wetting agent (lauryl sodium sulfate) 2～8%, disintegrant (ammonium sulfate) 0～8%, binding agent (xanthans) 0～5%, carrier (White Carbon black) 8-10%, filler (kaolin) 10～74%.
Fluoxastrobin, Tebuconazole, dispersant, wetting agent, disintegrant, filler etc. are obtained to the particle diameter needing through air-flow crushing together, then add other auxiliary agents such as binding agent, obtain the materials of granulating.By item quantitatively send in fluidized bed granulation dryer through granulation and dry after, make Fluoxastrobin tebuconazole water dispersible granule product.
With reference to manufacture craft Fig. 2, Fluoxastrobin and the former medicine of triazole type (as Tebuconazole) and dispersant, wetting agent, carrier, disintegrant, filler etc. are mixed, and stir about 30min, obtains approximately 500 object particle diameters through air-flow crushing, add again binding agent to mix about 30min, obtain the materials of granulating.Item is quantitatively sent in fluidized bed granulation dryer and (kept 50 ℃ to continue to be dried, until moisture meets product standard, require) after granulating and being dried, then sieve, particle size range meets the requirements.Make Fluoxastrobin tebuconazole water dispersible granule product.Qualified packing completes whole production process by analysis.
3) suspending agent comprises following composition according to percetage by weight meter: Fluoxastrobin 1～50%, Tebuconazole 1～50%, dispersant (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 3～12%, wetting agent (lauryl sodium sulfate) 2～10%, defoamer (organosilicon) 0.1～0.5%, thickener (lignin) 0～2%, antifreezing agent (ethylene glycol) 0～8%, surplus are deionized water.
With reference to manufacture craft Fig. 3, Fluoxastrobin, Tebuconazole, dispersant, wetting agent, defoamer, thickener, antifreezing agent in above-mentioned formulation material are mixed to (about 30-60min) through high speed shear, add Fluoxastrobin, Tebuconazole ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make Fluoxastrobin tebuconazole suspension concentrates product.
Embodiment 1:50% Fluoxastrobin tebuconazole microemulsion
Fluoxastrobin 20%, Tebuconazole 30%, calcium dodecyl benzene sulfonate (emulsifier) 5%, ethylene glycol (antifreezing agent) 5%, organosilicon (defoamer) 0.2%, water (solvent) supply 100%, mixture carries out mix and blend, makes 50% Fluoxastrobin tebuconazole microemulsion.
Embodiment 2:30% Fluoxastrobin tebuconazole water dispersible granule
Fluoxastrobin 10%, Tebuconazole 20%, wetting agent (lauryl sodium sulfate) 6%, xanthans (binding agent) 3%, Nekal BX (dispersant) 6%, ammonium sulfate (disintegrant) 3%, white carbon (carrier) 20%, precipitated calcium carbonate or kaolin (filler) 32%, mix and make 30% Fluoxastrobin tebuconazole water dispersible granule.
Embodiment 3:50% Fluoxastrobin tebuconazole suspension concentrates
Fluoxastrobin 20%, Tebuconazole 30%, alkyl benzene sulfonate calcium salt (dispersant) 4%, sodium lignin sulfonate (wetting agent) 3%, lignin (thickener) 0.3%, ethylene glycol (antifreezing agent) 5%, organosilicon (defoamer) 0.3%, deionized water adds to 100%, mixes and makes 50% Fluoxastrobin tebuconazole suspension concentrates.
The auxiliary agent occurring in the present invention is as follows:
Dispersant: sodium methylene bis-naphthalene sulfonate;
Wetting agent: lauryl sodium sulfate or dodecyl sodium sulfate;
Disintegrant: ammonium sulfate;
Binding agent: xanthans;
Filler: kaolin;
Defoamer: polysiloxanes or organosilicon;
Thickener: wooden element
Antifreezing agent: ethylene glycol or glycerine;
Emulsifier: 602 or 1601 or alkyl benzene calcium sulfonate;
Retarder thinner: dimethylbenzene.
Virulence test of the present invention: Tebuconazole and azoxystrobin compound are to cucumber anthracnose Toxicity Determination
Test medicine provides by Shaanxi Kang He Li Feng biotechnology pharmaceutcal corporation, Ltd.
After the effective inhibition concentration scope of each medicament is determined in prerun, each medicament is established respectively 5 dosage by active constituent content and is processed, and establishes clear water contrast.With reference to < < farm-chemical indoor determination test rule bactericide > >, carry out, adopt pastille medium therapy to measure the virulence of medicament to cucumber anthracnose.After 4 days, measure colony diameter, calculate growth inhibition ratio.Result of the test is as shown in table 1:
Table 1 Tebuconazole, Fluoxastrobin and the composite toxicity test analysis of results table to cucumber anthracnose thereof
As shown in Table 1, Tebuconazole, the EC of Fluoxastrobin to cucumber anthracnose
50be respectively 0.76mg/L and 1.88mg/L.The virulence of Fluoxastrobin is higher than the virulence of Tebuconazole.The co-toxicity coefficient of Tebuconazole and Fluoxastrobin proportioning 3:1,3:2,1:1,1:2,1:3 is respectively 127.60,153.57,144.41,135.69,130.99, both proportionings show as certain synergistic effect while being 1:2,1:1,3:2, from the visible explanation of Toxicological testing result, when Tebuconazole and Fluoxastrobin, spend coefficient together all more than 140 during at 1:1 or 3:2, its synergistic effect is obvious.
More than show and described basic principle of the present invention and principal character and advantage of the present invention.The technical staff of the industry should understand; the present invention is not restricted to the described embodiments; that in above-described embodiment and specification, describes just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.
Claims (7)
1. containing a composition pesticide for Fluoxastrobin, it is characterized in that, comprise Fluoxastrobin and triazole bactericidal agent, described triazole bactericidal agent and Fluoxastrobin mass ratio are 1: 60～60: 1.
2. a kind of composition pesticide containing Fluoxastrobin according to claim 1, is characterized in that: the mass ratio of described triazole bactericidal agent and Fluoxastrobin is 1:1～3:2.
3. a kind of composition pesticide containing Fluoxastrobin according to claim 1, is characterized in that: described triazole bactericidal agent is a kind of in epoxiconazole, Flutriafol, propiconazole, Tebuconazole, own azoles alcohol, fluazinam or penconazole.
4. a kind of composition pesticide containing Fluoxastrobin according to claim 1, is characterized in that: described composition pesticide comprises following formulation: microemulsion, water dispersible granules and suspending agent.
5. a kind of composition pesticide containing Fluoxastrobin according to claim 4, is characterized in that: microemulsion comprises following composition according to percetage by weight meter: Fluoxastrobin 1～50%, Tebuconazole 1～50%, emulsifier 5～15%, antifreezing agent 0～8%, defoamer 0.1-0.5%, solvent 10～74%.
6. a kind of composition pesticide containing Fluoxastrobin according to claim 4, it is characterized in that: described water dispersible granules comprises following composition according to percetage by weight meter: Fluoxastrobin 1～50%, Tebuconazole 1～50%, dispersant 3～12%, wetting agent 2～8%, disintegrant 0～8%, binding agent 0～5%, carrier 8-10%, filler 10～74%.
7. a kind of composition pesticide containing Fluoxastrobin according to claim 4, is characterized in that: described suspending agent comprises following composition according to percetage by weight meter: Fluoxastrobin 1～50%, Tebuconazole 1～50%, dispersant 3～12%, wetting agent 2～10%, defoamer 0.1～0.5%, thickener 0～2%, antifreezing agent 0～8%, surplus are deionized water.
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104839172A (en) * | 2015-05-11 | 2015-08-19 | 吉林省农业科学院 | Method for efficiently preventing and treating northern corn leaf blight |
| CN104872140A (en) * | 2015-04-07 | 2015-09-02 | 河南中天恒信生物化学科技有限公司 | Wheat paddock composite bactericide containing flusilazole, propiconazole and azoxystrobin, and application thereof |
| WO2015139564A1 (en) * | 2014-03-18 | 2015-09-24 | Rotam Agrochem International Company Limited | A fungicidal composition comprising strobilurin fungicides and triazole fungicides |
| CN105010353A (en) * | 2015-07-20 | 2015-11-04 | 安徽农业大学 | Cytosporacarphosperma controlling combined formulation reagent and application thereof |
| CN105028528A (en) * | 2015-09-02 | 2015-11-11 | 刘淑静 | Pesticide for preventing and controlling cotton anthracnose |
| CN106472522A (en) * | 2016-08-31 | 2017-03-08 | 柳州市惠农化工有限公司 | A kind of composition pesticide disliking bacterium azoles and Fluoxastrobin containing dichloro |
| CN107372521A (en) * | 2017-07-17 | 2017-11-24 | 李爱莉 | A kind of azoxystrobin microemulsion and preparation method thereof |
| CN110278945A (en) * | 2019-07-02 | 2019-09-27 | 江阴苏利化学股份有限公司 | A kind of slow-release dry suspending agent and preparation method thereof containing Fluoxastrobin and Tebuconazole |
| CN111685120A (en) * | 2020-06-29 | 2020-09-22 | 广西南亚热带农业科学研究所 | Method for preventing and controlling seedling stage diseases of elaeagnus pungens |
| CN111838147A (en) * | 2020-06-05 | 2020-10-30 | 中国热带农业科学院南亚热带作物研究所 | Intelligent response type calcium carbonate-based micro-nano pesticide, preparation method thereof and application thereof in banana vascular wilt |
| CN114304163A (en) * | 2021-12-30 | 2022-04-12 | 江苏仁信作物保护技术有限公司 | Suspending agent containing azoxystrobin, tebuconazole and cyproconazole and preparation method thereof |
| CN114557360A (en) * | 2022-01-19 | 2022-05-31 | 海南浙江大学研究院 | Ternary compound bactericide for preventing and treating rice grain smut in hybrid rice seed production field and application |
| CN115316395A (en) * | 2022-08-26 | 2022-11-11 | 浙江禾本科技股份有限公司 | Preparation method of azoxystrobin and propiconazole bactericidal composition suspending agent |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015139564A1 (en) * | 2014-03-18 | 2015-09-24 | Rotam Agrochem International Company Limited | A fungicidal composition comprising strobilurin fungicides and triazole fungicides |
| CN104872140A (en) * | 2015-04-07 | 2015-09-02 | 河南中天恒信生物化学科技有限公司 | Wheat paddock composite bactericide containing flusilazole, propiconazole and azoxystrobin, and application thereof |
| CN104839172A (en) * | 2015-05-11 | 2015-08-19 | 吉林省农业科学院 | Method for efficiently preventing and treating northern corn leaf blight |
| CN105010353A (en) * | 2015-07-20 | 2015-11-04 | 安徽农业大学 | Cytosporacarphosperma controlling combined formulation reagent and application thereof |
| CN105028528A (en) * | 2015-09-02 | 2015-11-11 | 刘淑静 | Pesticide for preventing and controlling cotton anthracnose |
| CN105028528B (en) * | 2015-09-02 | 2017-10-13 | 刘淑静 | A kind of agricultural chemicals for preventing and treating cotton anthracnose |
| CN106472522A (en) * | 2016-08-31 | 2017-03-08 | 柳州市惠农化工有限公司 | A kind of composition pesticide disliking bacterium azoles and Fluoxastrobin containing dichloro |
| CN107372521A (en) * | 2017-07-17 | 2017-11-24 | 李爱莉 | A kind of azoxystrobin microemulsion and preparation method thereof |
| CN110278945A (en) * | 2019-07-02 | 2019-09-27 | 江阴苏利化学股份有限公司 | A kind of slow-release dry suspending agent and preparation method thereof containing Fluoxastrobin and Tebuconazole |
| CN111838147A (en) * | 2020-06-05 | 2020-10-30 | 中国热带农业科学院南亚热带作物研究所 | Intelligent response type calcium carbonate-based micro-nano pesticide, preparation method thereof and application thereof in banana vascular wilt |
| CN111685120A (en) * | 2020-06-29 | 2020-09-22 | 广西南亚热带农业科学研究所 | Method for preventing and controlling seedling stage diseases of elaeagnus pungens |
| CN111685120B (en) * | 2020-06-29 | 2021-10-26 | 广西南亚热带农业科学研究所 | Method for preventing and controlling seedling stage diseases of elaeagnus pungens |
| CN114304163A (en) * | 2021-12-30 | 2022-04-12 | 江苏仁信作物保护技术有限公司 | Suspending agent containing azoxystrobin, tebuconazole and cyproconazole and preparation method thereof |
| CN114557360A (en) * | 2022-01-19 | 2022-05-31 | 海南浙江大学研究院 | Ternary compound bactericide for preventing and treating rice grain smut in hybrid rice seed production field and application |
| CN114557360B (en) * | 2022-01-19 | 2023-11-03 | 海南浙江大学研究院 | Ternary compound bactericide for preventing and treating hybrid rice seed production field rice grain smut and application thereof |
| CN115316395A (en) * | 2022-08-26 | 2022-11-11 | 浙江禾本科技股份有限公司 | Preparation method of azoxystrobin and propiconazole bactericidal composition suspending agent |
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Application publication date: 20140226 |